NO301076B1 - Fremgangsmåte for fremstilling av faste bærepartikler med ensartet störrelse for en polymerisasjonskatalysator under anvendelse av en roterende atomeriseringsanordning, fremstilling av katalysatoren og anvendelse av en slik ved polymerisering av - Google Patents
Fremgangsmåte for fremstilling av faste bærepartikler med ensartet störrelse for en polymerisasjonskatalysator under anvendelse av en roterende atomeriseringsanordning, fremstilling av katalysatoren og anvendelse av en slik ved polymerisering av Download PDFInfo
- Publication number
- NO301076B1 NO301076B1 NO934313A NO934313A NO301076B1 NO 301076 B1 NO301076 B1 NO 301076B1 NO 934313 A NO934313 A NO 934313A NO 934313 A NO934313 A NO 934313A NO 301076 B1 NO301076 B1 NO 301076B1
- Authority
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- Norway
- Prior art keywords
- nozzle
- melt
- catalyst
- spray area
- rotating
- Prior art date
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- 239000002245 particle Substances 0.000 title claims description 66
- 238000000034 method Methods 0.000 title claims description 44
- 239000007787 solid Substances 0.000 title claims description 21
- 239000003054 catalyst Substances 0.000 title claims description 19
- 239000002685 polymerization catalyst Substances 0.000 title claims description 13
- 238000006116 polymerization reaction Methods 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title claims description 4
- 239000007921 spray Substances 0.000 claims description 43
- 239000000155 melt Substances 0.000 claims description 34
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- 238000002425 crystallisation Methods 0.000 claims description 28
- 239000011261 inert gas Substances 0.000 claims description 27
- 230000008025 crystallization Effects 0.000 claims description 26
- 150000001875 compounds Chemical class 0.000 claims description 25
- 238000009826 distribution Methods 0.000 claims description 20
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 238000003723 Smelting Methods 0.000 claims description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 6
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- 230000004913 activation Effects 0.000 claims description 5
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 239000003426 co-catalyst Substances 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 150000003623 transition metal compounds Chemical class 0.000 claims description 4
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 claims description 3
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 15
- 235000011147 magnesium chloride Nutrition 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 11
- -1 titanium halide Chemical class 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 238000013019 agitation Methods 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000013078 crystal Substances 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
- 101000648997 Homo sapiens Tripartite motif-containing protein 44 Proteins 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 102100028017 Tripartite motif-containing protein 44 Human genes 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 150000008365 aromatic ketones Chemical class 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 239000012803 melt mixture Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI912639A FI90247C (sv) | 1991-05-31 | 1991-05-31 | Förfarande för framställning av aktiva och jämnstora bärarpartiklar för polymerisationskatalysatorer |
PCT/FI1992/000170 WO1992021705A1 (en) | 1991-05-31 | 1992-05-29 | Method for preparing solid carrier particles of equal size for polymerization catalyst using rotating atomizing means |
Publications (3)
Publication Number | Publication Date |
---|---|
NO934313L NO934313L (no) | 1993-11-29 |
NO934313D0 NO934313D0 (no) | 1993-11-29 |
NO301076B1 true NO301076B1 (no) | 1997-09-08 |
Family
ID=8532623
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO934313A NO301076B1 (no) | 1991-05-31 | 1993-11-29 | Fremgangsmåte for fremstilling av faste bærepartikler med ensartet störrelse for en polymerisasjonskatalysator under anvendelse av en roterende atomeriseringsanordning, fremstilling av katalysatoren og anvendelse av en slik ved polymerisering av |
Country Status (8)
Country | Link |
---|---|
US (1) | US5905050A (sv) |
EP (1) | EP0655073B1 (sv) |
JP (1) | JP3300349B2 (sv) |
CA (1) | CA2109834C (sv) |
DE (1) | DE69228075T2 (sv) |
FI (1) | FI90247C (sv) |
NO (1) | NO301076B1 (sv) |
WO (1) | WO1992021705A1 (sv) |
Families Citing this family (116)
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Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4293673A (en) * | 1978-12-28 | 1981-10-06 | Union Carbide Corporation | Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization |
DK143154C (da) * | 1979-01-19 | 1981-11-16 | Niro Atomizer As | Forstoeverhjul til forstoevning af vaesker |
IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
IT1154555B (it) * | 1982-11-11 | 1987-01-21 | Anic Spa | Procedimento per la preparazione di polimeri dell'etilene e catalizzatore relativo |
FI80055C (sv) * | 1986-06-09 | 1990-04-10 | Neste Oy | Förfarande för framställning av katalytkomponenter för polymerisation av olefiner |
-
1991
- 1991-05-31 FI FI912639A patent/FI90247C/sv active
-
1992
- 1992-05-29 WO PCT/FI1992/000170 patent/WO1992021705A1/en active IP Right Grant
- 1992-05-29 CA CA002109834A patent/CA2109834C/en not_active Expired - Lifetime
- 1992-05-29 EP EP92917458A patent/EP0655073B1/en not_active Expired - Lifetime
- 1992-05-29 JP JP51014492A patent/JP3300349B2/ja not_active Expired - Lifetime
- 1992-05-29 US US08/157,014 patent/US5905050A/en not_active Expired - Lifetime
- 1992-05-29 DE DE69228075T patent/DE69228075T2/de not_active Expired - Lifetime
-
1993
- 1993-11-29 NO NO934313A patent/NO301076B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
FI90247C (sv) | 1994-01-10 |
FI912639A (sv) | 1992-12-01 |
EP0655073B1 (en) | 1998-12-30 |
NO934313L (no) | 1993-11-29 |
WO1992021705A1 (en) | 1992-12-10 |
DE69228075D1 (de) | 1999-02-11 |
US5905050A (en) | 1999-05-18 |
FI90247B (sv) | 1993-09-30 |
JPH06507656A (ja) | 1994-09-01 |
DE69228075T2 (de) | 1999-08-19 |
JP3300349B2 (ja) | 2002-07-08 |
NO934313D0 (no) | 1993-11-29 |
CA2109834C (en) | 2003-03-25 |
FI912639A0 (sv) | 1991-05-31 |
EP0655073A1 (en) | 1995-05-31 |
CA2109834A1 (en) | 1992-12-10 |
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