FI90248B - Förfarande för framställning av en partikelformig bärare för olefinpolymerisationskatalysatorer - Google Patents
Förfarande för framställning av en partikelformig bärare för olefinpolymerisationskatalysatorer Download PDFInfo
- Publication number
- FI90248B FI90248B FI915632A FI915632A FI90248B FI 90248 B FI90248 B FI 90248B FI 915632 A FI915632 A FI 915632A FI 915632 A FI915632 A FI 915632A FI 90248 B FI90248 B FI 90248B
- Authority
- FI
- Finland
- Prior art keywords
- temperature
- complex
- mgcl2
- c2h5oh
- chamber
- Prior art date
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- 150000001336 alkenes Chemical class 0.000 title claims description 9
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000002685 polymerization catalyst Substances 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 49
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 35
- 235000019441 ethanol Nutrition 0.000 claims description 34
- 230000008569 process Effects 0.000 claims description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 16
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 10
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 8
- 150000003623 transition metal compounds Chemical class 0.000 claims description 7
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 description 30
- 235000011147 magnesium chloride Nutrition 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 16
- 239000007921 spray Substances 0.000 description 13
- 238000009826 distribution Methods 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 10
- 238000005507 spraying Methods 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 238000001694 spray drying Methods 0.000 description 9
- -1 titanium halide Chemical class 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- 238000002425 crystallisation Methods 0.000 description 6
- 230000008025 crystallization Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 239000013078 crystal Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000282326 Felis catus Species 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000010076 replication Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- PSXUKPCAIKETHF-UHFFFAOYSA-N 2-[4-[3-[4-(4,5-dihydro-1h-imidazol-2-yl)phenoxy]propoxy]phenyl]-4,5-dihydro-1h-imidazole Chemical compound C=1C=C(C=2NCCN=2)C=CC=1OCCCOC(C=C1)=CC=C1C1=NCCN1 PSXUKPCAIKETHF-UHFFFAOYSA-N 0.000 description 1
- IXGQUXURSKQJJI-UHFFFAOYSA-N CO[SiH2]CC1CCCCC1 Chemical compound CO[SiH2]CC1CCCCC1 IXGQUXURSKQJJI-UHFFFAOYSA-N 0.000 description 1
- 102100029579 Diphosphoinositol polyphosphate phosphohydrolase 1 Human genes 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 101710153356 mRNA-decapping protein g5R Proteins 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 150000003682 vanadium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Claims (10)
1. Förfarande för framställning av en partikelformig bära-10 re för en olefinpolymerisationsprokatalysator innefattande en pä en bärare omsatt övergängsmetallförening, i vilket förfarande a) ett smält MgCl2-C2HjOH -komplex ästadkommes, innehällande i genomsnitt mellan 3,3 och 5,5 C2H3OH-molekyler per MgCl2-mole- 15 kyl, b) det smälta MgCl2-C2H5OH -komplexet sprutas genom ett ato-miserande munstycke i en kammare, där det bildar en partikelformig bärare och c) den partikelformiga bäraren avlägsnas ur kammaren, 20 kännetecknat av att sä mycket C2HsOH avlägsnas i steg b) ur MgCl2-C2H5OH -komplexet medelst värme, att den erhällna partikelformiga bäraren innehäller i genomsnitt mellan 2,0 och 3,2 C2HjOH-molekyler per MgCl2-molekyl. 25 2. Förfarande enligt patentkravet 1, kännetecknat av att en smälta ästadkommes i steg a), som innehäller i medeltal mellan 3,5 och 4,0, företrädesvis cirka 3,7, C2H5OH-molekyler per MgCl2-molekyl. 30 3. Förfarande enligt patentkravet 1 eller 2, kännetecknat av att sä mycket C2Hs0H avlägsnas i steg b) ur MgCl2-C2HjOH -komplexet, att den erhällna partikelformiga bäraren innehäller i medeltal mellan 2,5 och 3,0, företrädesvis cirka 2,7 tili 2,9, C2H5OH-molekyler per MgCl2-molekyl. 1 35 Förfarande enligt patentkravet 1, 2 eller 3, kännetecknat av att det smälta MgCl2-C2HsOH -komplexet sprutas i kam-marens övre del, där det hälles vid en temperatur, som av- ie 90248 lägsnar C2H5OH, och leds därefter i kammarens nedre del, där det avkyles för att bringa kömpiexsmältan innehällande mind-re C2H5OH att stelna tili den partikelformiga bäraren. 5 5. Förfarande enligt patentkravet 4, kännetecknat av att det smälta MgCl2-C2H5OH -komplexet hälles vid en temperatur där C2H5OH avlägsnas genom att spruta det i kammarens övre del upphettat väsentligen over dess smältpunkt och/eller genom att upprätthälla en temperatur i kammarens övre del, 10 som är högre än temperaturen i kammarens nedre del.
6. Förfarande enligt patentkravet 5, kännetecknat av att det smälta MgCl2-C2H5OH -komplexet sprutas i kammarens övre del upphettat tili en temperatur av cirka +120...+250°C. 15
7. Förfarande enligt patentkravet 5 eller 6, kännetecknat av att temperaturen +20...+150°C, företrädesvis +30...+80°C upprätthälles i kammarens övre del och temperaturen -30... +40°C, företrädesvis -20...+40°C, upprätthälles i kammarens 20 nedre del, under förutsättningen, att temperaturen i den nedre delen är lägre än temperaturen i den övre delen.
8. Förfarande enligt nägot av patentkraven 1-7, kännetecknat av att MgCl2-C2H5OH -komplexet sprutas i kammarens övre 25 del upphettat tili en temperatur, som överstiger komplexets smälttemperatur och är högre än en temperatur, som är cirka (+130°C - temperaturen i kammarens övre del).
9. Förfarande enligt nägot av de föregäende patentkraven, 3. kännetecknat av att MgCl2-C2H5OH -komplexet sprutas i kairana - ren medelst en het kväveström.
10. Förfarande enligt nägot av de föregäende patentkraven, kännetecknat av att temperaturerna i den övre och nedre de-
35 Ien av kammaren upprätthälles medelst en eller flera kväv-gasströmmar. i9 90248
11. Förfarande enligt nägot av de föregäende patentkraven, kannetecknat av att munstycket, som atomiserar det smälta MgCl2-C2H50H -komplexet är ett gas-vätska-fluidiseringsmun-stycke, ett roterande munstycke eller ett ultraljudsmun- 5 stycke.
12. Förfarande enligt nägot av de föregäende patentkraven, kännetecknat av att den erhällna partikelformiga bäraren omsättes med TiCl4 och eventuellt en elektrondonor för 10 ästadkommande av en olefinpolymerisationsprokatalysator.
13. Förfarande enligt ndgot av patentkraven 1-11, känne-tecknat av att den erhällna partikelformiga bäraren omsättes med TiCl4 och en elektrondonor för ästadkommande av en ole- 15 finpolymerisationprokatalysator.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI915632A FI90248C (sv) | 1991-11-29 | 1991-11-29 | Förfarande för framställning av en partikelformig bärare för olefinpolymerisationskatalysatorer |
| PCT/FI1992/000324 WO1993011166A1 (en) | 1991-11-29 | 1992-11-27 | Method for the preparation of a particulate carrier for a polymerization catalyst |
| US08/240,732 US5468698A (en) | 1991-11-29 | 1992-11-27 | Method for the preparation of a particulate carrier for a polymerization catalyst |
| DE69208265T DE69208265T2 (de) | 1991-11-29 | 1992-11-27 | Verfahren zur herstellung eines teilchenförmigen trägers für einen polymerisationskatalysator |
| CA002124572A CA2124572A1 (en) | 1991-11-29 | 1992-11-27 | Method for the preparation of an olefin polymerization catalyst consisting of particles of equal size |
| EP92924735A EP0614467B1 (en) | 1991-11-29 | 1992-11-27 | Method for the preparation of a particulate carrier for a polymerization catalyst |
| NO941874A NO941874D0 (no) | 1991-11-29 | 1994-05-19 | Fremgangsmåte for fremstilling av en partikkelformig bærer for en polymerisasjonskatalysator |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI915632A FI90248C (sv) | 1991-11-29 | 1991-11-29 | Förfarande för framställning av en partikelformig bärare för olefinpolymerisationskatalysatorer |
| FI915632 | 1991-11-29 | ||
| CA2124572 | 1992-11-27 | ||
| CA002124572A CA2124572A1 (en) | 1991-11-29 | 1992-11-27 | Method for the preparation of an olefin polymerization catalyst consisting of particles of equal size |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI915632A0 FI915632A0 (sv) | 1991-11-29 |
| FI915632A FI915632A (sv) | 1993-05-30 |
| FI90248B true FI90248B (sv) | 1993-09-30 |
| FI90248C FI90248C (sv) | 1994-01-10 |
Family
ID=25677285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI915632A FI90248C (sv) | 1991-11-29 | 1991-11-29 | Förfarande för framställning av en partikelformig bärare för olefinpolymerisationskatalysatorer |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5468698A (sv) |
| EP (1) | EP0614467B1 (sv) |
| CA (1) | CA2124572A1 (sv) |
| FI (1) | FI90248C (sv) |
| WO (1) | WO1993011166A1 (sv) |
Families Citing this family (115)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2143623T3 (es) * | 1994-03-17 | 2000-05-16 | Exxon Chemical Patents Inc | Polimero secado por pulverizacion para soporte de catalizador. |
| TW400342B (en) * | 1994-09-06 | 2000-08-01 | Chisso Corp | A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer |
| US6407028B1 (en) | 1997-03-29 | 2002-06-18 | Basell Technology Company Bv | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
| AU773932B2 (en) * | 1997-03-29 | 2004-06-10 | Montell Technology Company B.V. | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
| US6323152B1 (en) | 1998-03-30 | 2001-11-27 | Basell Technology Company Bv | Magnesium dichloride-alcohol adducts process for their preparation and catalyst components obtained therefrom |
| ES2213898T3 (es) * | 1997-03-29 | 2004-09-01 | Basell Poliolefine Italia S.P.A. | Aductos de dicloruro de magnesio/alcohol, procedimiento para su preparacion y componentes catalizadores obtenidos a partir de estos. |
| ES2338758T3 (es) * | 2000-12-22 | 2010-05-12 | Basell Poliolefine Italia S.R.L. | Procedimiento para la preparacion de un soporte esferico que comprende un dihaluro de mg. |
| KR20050046652A (ko) * | 2002-09-17 | 2005-05-18 | 바셀 폴리올레핀 이탈리아 에스.피.에이. | 마그네슘 디클로라이드-에탄올 첨가 생성물 및 이로부터수득되는 촉매 성분 |
| CN1267508C (zh) | 2003-08-08 | 2006-08-02 | 中国石油化工股份有限公司 | 一种卤化镁/醇加合物及其制备方法和应用 |
| ES2478299T3 (es) | 2003-11-20 | 2014-07-21 | Union Carbide Chemicals & Plastics Technology Llc | Composiciones de catalizador Ziegler de metal mixto, secadas por pulverización |
| CN1289542C (zh) * | 2004-07-05 | 2006-12-13 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的球形催化剂组分及其催化剂 |
| KR101173267B1 (ko) | 2006-04-06 | 2012-08-10 | 베이징 리서치 인스티튜트 오브 케미컬 인더스트리, 차이나 페트로리움 앤드 케미컬 코포레이션 | 할로겐화마그네슘 부가물, 이로부터 제조되는 올레핀 중합용 촉매 성분 및 촉매 |
| KR20130062377A (ko) * | 2008-06-11 | 2013-06-12 | 루머스 노보렌 테크놀로지 게엠베하 | 고활성 지글러-나타 촉매, 촉매의 제조방법 및 이의 용도 |
| US8450421B2 (en) | 2008-12-29 | 2013-05-28 | Borealis Ag | Cable layer of modified soft polypropylene with improved stress whitening resistance |
| EP2216347A1 (en) | 2009-01-30 | 2010-08-11 | Borealis AG | A method of catalyst transitions in olefin polymerizations |
| ES2370689T3 (es) | 2009-02-25 | 2011-12-21 | Borealis Ag | Polímero multimodal de polipropileno, composición que comprende el mismo y un procedimiento para producir el mismo. |
| RU2497847C2 (ru) | 2009-04-09 | 2013-11-10 | Бореалис Аг | Композиция термопластичного полиолефина |
| ES2478017T3 (es) | 2009-07-15 | 2014-07-18 | China Petroleum&Chemical Corporation | Aducto de haluro de magnesio esférico, componente de catalizador y catalizador para la polimerización de olefinas preparado a partir del mismo |
| SA3686B1 (ar) | 2009-10-16 | 2014-10-22 | China Petroleum& Chemical Corp | مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه |
| EP2452956A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for polymerising propylene |
| EP2452957A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Improved process for producing heterophasic propylene copolymers |
| EP2452920A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | A method for recovering transition metal tetrahalide and hydrocarbons from a waste stream |
| EP2452959B1 (en) | 2010-11-12 | 2015-01-21 | Borealis AG | Process for producing propylene random copolymers and their use |
| EP2452976A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Heterophasic propylene copolymers with improved stiffness/impact/flowability balance |
| EP2452975A1 (en) | 2010-11-12 | 2012-05-16 | Borealis AG | Soft heterophasic propylene copolymers |
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| HUE051319T2 (hu) | 2011-03-02 | 2021-03-01 | Borealis Ag | Nagy átmenõteljesítményû reaktoregység olefinek polimerizálására |
| ES2817776T3 (es) | 2011-03-02 | 2021-04-08 | Borealis Ag | Un procedimiento para la producción de polímeros |
| ITMI20120877A1 (it) | 2011-05-27 | 2012-11-28 | Beijing Res Inst Of Chemi Cal Industry | Addotto di alogenuro di magnesio, componente catalitico/catalizzatore comprendente addotto di alogenuro di magnesio e sua preparazione. |
| ES2605429T3 (es) | 2011-06-15 | 2017-03-14 | Borealis Ag | Mezcla del reactor in situ de un polipropileno nucleado catalizado por Ziegler-Natta y un polipropileno catalizado por metaloceno |
| EP2617741B1 (en) | 2012-01-18 | 2016-01-13 | Borealis AG | Process for polymerizing olefin polymers in the presence of a catalyst system and a method of controlling the process |
| WO2014032794A1 (en) | 2012-08-29 | 2014-03-06 | Borealis Ag | Reactor assembly and method for polymerization of olefins |
| EP2719725B1 (en) | 2012-10-11 | 2018-12-05 | Abu Dhabi Polymers Company Limited (Borouge) | Nucleated polypropylene composition for containers |
| US9522968B2 (en) | 2012-11-26 | 2016-12-20 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof |
| EP2745927A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Fluidized bed reactor with internal moving bed reaction unit |
| EP2745926A1 (en) | 2012-12-21 | 2014-06-25 | Borealis AG | Gas phase polymerization and reactor assembly comprising a fluidized bed reactor and an external moving bed reactor |
| EP2749580B1 (en) | 2012-12-28 | 2016-09-14 | Borealis AG | Process for producing copolymers of propylene |
| EP2787034A1 (en) | 2013-04-05 | 2014-10-08 | Borealis AG | High stiffness polypropylene compositions |
| EP2796498B1 (en) | 2013-04-22 | 2018-09-12 | Abu Dhabi Polymers Company Limited (Borouge) | Multimodal polypropylene composition for pipe applications |
| ES2632593T3 (es) | 2013-04-22 | 2017-09-14 | Borealis Ag | Procedimiento de dos fases de producción de composiciones de polipropileno |
| EP3235832B1 (en) | 2013-04-22 | 2018-06-20 | Borealis AG | Polypropylene compositions |
| EP2796502A1 (en) | 2013-04-22 | 2014-10-29 | Abu Dhabi Polymers Company Limited (Borouge) | Propylene random copolymer composition for pipe applications |
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| EP4144435A1 (en) | 2021-09-01 | 2023-03-08 | Borealis AG | Gas phase polymerization process with improved gas recycling |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4071674A (en) * | 1972-09-14 | 1978-01-31 | Mitsui Petrochemical Industries Ltd. | Process for polymerization or copolymerization of olefin and catalyst compositions used therefor |
| IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| JPS59215301A (ja) * | 1983-05-24 | 1984-12-05 | Mitsui Petrochem Ind Ltd | エチレンの重合もしくは共重合方法 |
| FI80055C (sv) * | 1986-06-09 | 1990-04-10 | Neste Oy | Förfarande för framställning av katalytkomponenter för polymerisation av olefiner |
| IT1203330B (it) * | 1987-02-06 | 1989-02-15 | Enichem Base Spa | Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine |
| US5204303A (en) * | 1988-12-30 | 1993-04-20 | Neste Oy | Preparation and use of a new ziegler-natta catayst component |
| JP2879347B2 (ja) * | 1989-10-02 | 1999-04-05 | チッソ株式会社 | オレフィン重合用触媒の製法 |
| FI84357C (sv) * | 1989-10-20 | 1991-11-25 | Neste Oy | Förfarande och apparatur för framställning av bärare för polymerisatio nskatalysatorer |
-
1991
- 1991-11-29 FI FI915632A patent/FI90248C/sv not_active IP Right Cessation
-
1992
- 1992-11-27 CA CA002124572A patent/CA2124572A1/en not_active Abandoned
- 1992-11-27 WO PCT/FI1992/000324 patent/WO1993011166A1/en active IP Right Grant
- 1992-11-27 US US08/240,732 patent/US5468698A/en not_active Expired - Lifetime
- 1992-11-27 EP EP92924735A patent/EP0614467B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2124572A1 (en) | 1993-06-10 |
| FI90248C (sv) | 1994-01-10 |
| EP0614467B1 (en) | 1996-02-07 |
| WO1993011166A1 (en) | 1993-06-10 |
| EP0614467A1 (en) | 1994-09-14 |
| US5468698A (en) | 1995-11-21 |
| FI915632A (sv) | 1993-05-30 |
| FI915632A0 (sv) | 1991-11-29 |
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