NL8302942A - Gestabiliseerde enzym-houdende detergenspreparaten. - Google Patents
Gestabiliseerde enzym-houdende detergenspreparaten. Download PDFInfo
- Publication number
- NL8302942A NL8302942A NL8302942A NL8302942A NL8302942A NL 8302942 A NL8302942 A NL 8302942A NL 8302942 A NL8302942 A NL 8302942A NL 8302942 A NL8302942 A NL 8302942A NL 8302942 A NL8302942 A NL 8302942A
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- NL
- Netherlands
- Prior art keywords
- acid
- water
- weight
- carbon atoms
- soap
- Prior art date
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- 239000003599 detergent Substances 0.000 title claims description 48
- 238000002360 preparation method Methods 0.000 title claims description 43
- 239000000203 mixture Substances 0.000 claims description 41
- 125000004432 carbon atom Chemical group C* 0.000 claims description 34
- 102000004190 Enzymes Human genes 0.000 claims description 27
- 108090000790 Enzymes Proteins 0.000 claims description 27
- 229940088598 enzyme Drugs 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- -1 nonionic Chemical group 0.000 claims description 22
- 239000000344 soap Substances 0.000 claims description 21
- 150000003839 salts Chemical class 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 239000003381 stabilizer Substances 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 11
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 10
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 10
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 8
- 108091005804 Peptidases Proteins 0.000 claims description 8
- 229910001424 calcium ion Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 102000035195 Peptidases Human genes 0.000 claims description 7
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 7
- 235000011037 adipic acid Nutrition 0.000 claims description 6
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 6
- 239000003352 sequestering agent Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 5
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 5
- 102000013142 Amylases Human genes 0.000 claims description 5
- 108010065511 Amylases Proteins 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 5
- 239000005642 Oleic acid Substances 0.000 claims description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000001361 adipic acid Substances 0.000 claims description 5
- 235000019418 amylase Nutrition 0.000 claims description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- 239000005639 Lauric acid Substances 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 claims description 3
- 159000000007 calcium salts Chemical class 0.000 claims description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 2
- 229940025131 amylases Drugs 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000011591 potassium Chemical class 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 150000002191 fatty alcohols Chemical class 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000004382 Amylase Substances 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000001450 anions Chemical group 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 3
- 235000003441 saturated fatty acids Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 108010056079 Subtilisins Proteins 0.000 description 2
- 102000005158 Subtilisins Human genes 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
- 229940079919 digestives enzyme preparation Drugs 0.000 description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical class OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
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- LMTSQIZQTFBYRL-UHFFFAOYSA-N n'-octadecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCCCCCNCCN LMTSQIZQTFBYRL-UHFFFAOYSA-N 0.000 description 2
- QIBKKTQVKFEWCH-UHFFFAOYSA-N n'-tetradecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCNCCN QIBKKTQVKFEWCH-UHFFFAOYSA-N 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
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- 125000001424 substituent group Chemical group 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
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- XINQFOMFQFGGCQ-UHFFFAOYSA-L (2-dodecoxy-2-oxoethyl)-[6-[(2-dodecoxy-2-oxoethyl)-dimethylazaniumyl]hexyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCOC(=O)C[N+](C)(C)CCCCCC[N+](C)(C)CC(=O)OCCCCCCCCCCCC XINQFOMFQFGGCQ-UHFFFAOYSA-L 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical group C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- QUBNFZFTFXTLKH-UHFFFAOYSA-N 2-aminododecanoic acid Chemical compound CCCCCCCCCCC(N)C(O)=O QUBNFZFTFXTLKH-UHFFFAOYSA-N 0.000 description 1
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- RXHDXDIEHWVFOC-UHFFFAOYSA-M ethyl-dimethyl-octadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC RXHDXDIEHWVFOC-UHFFFAOYSA-M 0.000 description 1
- 229940093476 ethylene glycol Drugs 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002311 glutaric acids Chemical class 0.000 description 1
- 235000013882 gravy Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- RNYJXPUAFDFIQJ-UHFFFAOYSA-N hydron;octadecan-1-amine;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH3+] RNYJXPUAFDFIQJ-UHFFFAOYSA-N 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- YECIFGHRMFEPJK-UHFFFAOYSA-N lidocaine hydrochloride monohydrate Chemical compound O.[Cl-].CC[NH+](CC)CC(=O)NC1=C(C)C=CC=C1C YECIFGHRMFEPJK-UHFFFAOYSA-N 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 125000005528 methosulfate group Chemical group 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000570 polyether Chemical group 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical class [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 150000003444 succinic acids Chemical class 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41269082 | 1982-08-30 | ||
| US06/412,690 US4529525A (en) | 1982-08-30 | 1982-08-30 | Stabilized enzyme-containing detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8302942A true NL8302942A (nl) | 1984-03-16 |
Family
ID=23634046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8302942A NL8302942A (nl) | 1982-08-30 | 1983-08-22 | Gestabiliseerde enzym-houdende detergenspreparaten. |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US4529525A (fr) |
| AT (1) | AT394205B (fr) |
| AU (1) | AU552398B2 (fr) |
| BE (1) | BE897610A (fr) |
| BR (1) | BR8304644A (fr) |
| CA (1) | CA1207256A (fr) |
| CH (1) | CH657372A5 (fr) |
| DE (1) | DE3330323A1 (fr) |
| DK (1) | DK159554C (fr) |
| ES (1) | ES525214A0 (fr) |
| FR (1) | FR2532324B1 (fr) |
| GB (3) | GB2126242B (fr) |
| GR (1) | GR78984B (fr) |
| IT (1) | IT1168886B (fr) |
| MX (1) | MX158409A (fr) |
| NL (1) | NL8302942A (fr) |
| NO (1) | NO157460C (fr) |
| NZ (1) | NZ205257A (fr) |
| PH (1) | PH19070A (fr) |
| PT (1) | PT77260B (fr) |
| SE (1) | SE456426B (fr) |
| ZA (1) | ZA836073B (fr) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3471687D1 (en) * | 1983-02-14 | 1988-07-07 | Procter & Gamble | Stabilized aqueous enzyme composition |
| GB8311314D0 (en) * | 1983-04-26 | 1983-06-02 | Unilever Plc | Aqueous enzyme-containing compositions |
| FR2556364B1 (fr) * | 1983-12-10 | 1989-10-27 | Sandoz Sa | Compositions detergentes liquides exemptes de phosphate |
| US4537706A (en) * | 1984-05-14 | 1985-08-27 | The Procter & Gamble Company | Liquid detergents containing boric acid to stabilize enzymes |
| DE3574729D1 (de) * | 1984-05-14 | 1990-01-18 | Procter & Gamble | Borsaeure enthaltende fluessige reinigungsmittel zur stabilisierung von enzymen. |
| US4537707A (en) * | 1984-05-14 | 1985-08-27 | The Procter & Gamble Company | Liquid detergents containing boric acid and formate to stabilize enzymes |
| CA1263944A (fr) * | 1984-09-12 | 1989-12-19 | Barbara H. Munk | Compositions aux enzymes pour emploi avant la lessive |
| GB8424812D0 (en) * | 1984-10-02 | 1984-11-07 | Unilever Plc | Enzymatic detergent composition |
| EP0199405B1 (fr) * | 1985-04-15 | 1992-06-24 | The Procter & Gamble Company | Détergents liquides contenant un composé tensioactif, une enzyme protéolytique et de l'acide borique |
| SE468518B (sv) * | 1985-07-26 | 1993-02-01 | Colgate Palmolive Co | Stabiliserad textilmjukgoerande enzyminnehaallande foerstaerkt flytande detergentkomposition och dess anvaendning vid tvaett av textilier |
| SE467827B (sv) * | 1985-07-26 | 1992-09-21 | Colgate Palmolive Co | Stabiliserad enzyminnehaallande foerstaerkt flytande detergentkomposition och dess anvaendning vid tvaettning av textilier |
| US4842769A (en) * | 1985-07-26 | 1989-06-27 | Colgate-Palmolive Co. | Stabilized fabric softening built detergent composition containing enzymes |
| US4900475A (en) * | 1985-07-26 | 1990-02-13 | Colgate-Palmolive Co. | Stabilized built liquid detergent composition containing enzyme |
| US4771003A (en) * | 1985-10-22 | 1988-09-13 | Genex Corporation | Heat stable alkaline proteases produced by a bacillus |
| US4764470A (en) * | 1986-02-05 | 1988-08-16 | Genex Corporation | Alkaline protease produced by a bacillus |
| US4842758A (en) * | 1986-10-31 | 1989-06-27 | Colgate-Palmolive Company | Stabilized enzyme system for use in aqueous liquid built detergent compositions |
| DE3704465C2 (de) * | 1987-02-13 | 1995-11-02 | Roehm Gmbh | Flüssig-Formulierungen von Enzymen |
| AU3667189A (en) * | 1988-06-23 | 1990-01-04 | Unilever Plc | Enzyme-containing liquid detergents |
| GB8900496D0 (en) * | 1989-01-10 | 1989-03-08 | Procter & Gamble | Liquid detergent composition containing enzyme and enzyme stabilization system |
| DE3918761C1 (fr) * | 1989-06-08 | 1990-06-28 | Henkel Kgaa, 4000 Duesseldorf, De | |
| US5030378A (en) * | 1990-01-02 | 1991-07-09 | The Procter & Gamble Company | Liquid detergents containing anionic surfactant, builder and proteolytic enzyme |
| US5221495A (en) * | 1990-04-13 | 1993-06-22 | Colgate-Palmolive Company | Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions |
| US5364553A (en) * | 1990-04-13 | 1994-11-15 | Colgate-Palmolive Company | Stabilized built aqueous liquid softergent compositions |
| US5275945A (en) * | 1991-10-08 | 1994-01-04 | Vista Chemical Company | Alkaline proteases stable in heavy-duty detergent liquids |
| US5527487A (en) * | 1991-11-27 | 1996-06-18 | Novo Nordisk A/S | Enzymatic detergent composition and method for enzyme stabilization |
| US5580849A (en) * | 1992-09-01 | 1996-12-03 | The Procter & Gamble Company | Liquid or gel detergent compositions containing calcium and stabilizing agent thereof |
| WO1994005758A1 (fr) * | 1992-09-01 | 1994-03-17 | The Procter & Gamble Company | Compositions detergentes liquides ou en gel contenant du calcium et stabilisant de celles-ci |
| NZ268301A (en) * | 1993-06-21 | 1997-10-24 | Boehringer Mannheim Corp | The stabilisation of diagnostic compositions comprising glucose oxidase and/or ferricyanide using succinic acid or a salt thereof |
| SK68996A3 (en) * | 1993-12-03 | 1997-06-04 | Buckman Labor Inc | Enzyme stabilization by block-copolymers |
| BR9712114A (pt) | 1996-09-24 | 1999-08-31 | Procter & Gamble | Composições detergente líquidas para lavanderia contendo enzima proteolítica e inibidores de protease. |
| US6165966A (en) * | 1996-09-24 | 2000-12-26 | The Procter & Gamble Company | Liquid detergents containing proteolytic enzyme and protease inhibitors |
| US6162783A (en) * | 1996-09-24 | 2000-12-19 | The Procter & Gamble Company | Liquid detergents containing proteolytic enzyme and protease inhibitors |
| US8933131B2 (en) | 2010-01-12 | 2015-01-13 | The Procter & Gamble Company | Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same |
| DE102010038501A1 (de) * | 2010-07-27 | 2012-02-02 | Henkel Ag & Co. Kgaa | Stabilisierte flüssige enzymhaltige Tensidzubereitung |
| DE102010038498A1 (de) * | 2010-07-27 | 2012-02-02 | Henkel Ag & Co. Kgaa | Stabilisierte flüssige enzymhaltige Tensidzubereitung |
| RU2013136500A (ru) | 2011-02-17 | 2015-03-27 | Дзе Проктер Энд Гэмбл Компани | Композиции, содержащие смеси с10-с13-алкилфенилсульфонатов |
| CN103380107B (zh) | 2011-02-17 | 2015-06-10 | 宝洁公司 | 生物基直链烷基苯基磺酸盐 |
| US9133424B2 (en) * | 2011-12-16 | 2015-09-15 | Ecolab Usa Inc. | Stabilization and activation of protease for use at high temperature |
| CN104508103A (zh) * | 2012-07-26 | 2015-04-08 | 宝洁公司 | 含酶的低ph液体清洁组合物 |
| US9267095B2 (en) | 2013-05-24 | 2016-02-23 | The Procter & Gamble Company | Low pH detergent composition comprising nonionic surfactants |
| WO2014190129A1 (fr) | 2013-05-24 | 2014-11-27 | The Procter & Gamble Company | Composition de détergent à faible ph |
| CN105283530A (zh) | 2013-05-24 | 2016-01-27 | 宝洁公司 | 浓缩型表面活性剂组合物 |
| CN105369638A (zh) * | 2014-08-25 | 2016-03-02 | 江苏欣隆羽绒有限公司 | 一种羽绒脱脂剂 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1204123A (en) * | 1966-11-29 | 1970-09-03 | Unilever Ltd | Detergent composition |
| DK130417A (fr) * | 1968-08-08 | |||
| DK132038A (fr) * | 1969-03-21 | |||
| US3634266A (en) * | 1969-07-23 | 1972-01-11 | Procter & Gamble | Liquid detergent compositions containing amylolytic enzymes |
| US3682842A (en) * | 1970-05-04 | 1972-08-08 | Irving Innerfield | Stabilized enzymic compositions containing protease and alpha amylase of bacterial origin and method of stabilizing such compositions |
| GB1368599A (en) * | 1970-09-29 | 1974-10-02 | Unilever Ltd | Softening compositions |
| GB1349650A (en) * | 1970-11-27 | 1974-04-10 | Pegg S & Son Ltd | Textile processing |
| US4092273A (en) * | 1974-10-03 | 1978-05-30 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
| GB1572605A (en) * | 1976-03-08 | 1980-07-30 | Procter & Gamble | Liqid enzyme containing detergent composition |
| IT1106254B (it) * | 1976-03-08 | 1985-11-11 | Procter & Gamble Europ | Composizione detergente liquida contenente enzimi |
| GB1590445A (en) * | 1976-11-01 | 1981-06-03 | Unilever Ltd | Enzymatic liquid composition |
| DE2857294A1 (de) * | 1977-09-26 | 1980-02-28 | Procter & Gamble | Detergensgemisch mit niedrigem phosphatgehalt zum waschen von textilien |
| DE2833991A1 (de) * | 1978-08-03 | 1980-02-21 | Basf Ag | Verfahren zum mechanischen spuelen von geschirr unter einsatz mehrwertiger alkohole, carbonsaeuren und/oder estern daraus als klarspuelmittel |
| US4243546A (en) * | 1979-03-23 | 1981-01-06 | The Drackett Company | Stable aqueous compositions containing enzymes |
| EP0019315B1 (fr) * | 1979-05-16 | 1983-05-25 | Procter & Gamble European Technical Center | Compositions détergentes liquides contenant un acide gras très concentré |
| IT1129814B (it) * | 1980-07-02 | 1986-06-11 | Unilever Nv | Composizione detergente enzimatica liquida |
| US4305837A (en) * | 1980-10-30 | 1981-12-15 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| EP0028866B1 (fr) * | 1979-11-09 | 1984-07-11 | THE PROCTER & GAMBLE COMPANY | Composition enzymatique aqueuse stabilisée contenant un des ions formiate et calcium |
| US4318818A (en) * | 1979-11-09 | 1982-03-09 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| US4287082A (en) * | 1980-02-22 | 1981-09-01 | The Procter & Gamble Company | Homogeneous enzyme-containing liquid detergent compositions containing saturated acids |
| GB2094826B (en) * | 1981-03-05 | 1985-06-12 | Kao Corp | Cellulase enzyme detergent composition |
| US4462922A (en) * | 1981-11-19 | 1984-07-31 | Lever Brothers Company | Enzymatic liquid detergent composition |
| GB8311314D0 (en) * | 1983-04-26 | 1983-06-02 | Unilever Plc | Aqueous enzyme-containing compositions |
-
1982
- 1982-08-30 US US06/412,690 patent/US4529525A/en not_active Expired - Fee Related
-
1983
- 1983-08-12 NZ NZ205257A patent/NZ205257A/en unknown
- 1983-08-17 ZA ZA836073A patent/ZA836073B/xx unknown
- 1983-08-17 MX MX198420A patent/MX158409A/es unknown
- 1983-08-18 DK DK378283A patent/DK159554C/da not_active IP Right Cessation
- 1983-08-22 NL NL8302942A patent/NL8302942A/nl not_active Application Discontinuation
- 1983-08-23 DE DE19833330323 patent/DE3330323A1/de not_active Ceased
- 1983-08-24 AT AT0301783A patent/AT394205B/de not_active IP Right Cessation
- 1983-08-25 AU AU18410/83A patent/AU552398B2/en not_active Ceased
- 1983-08-25 PH PH29444A patent/PH19070A/en unknown
- 1983-08-26 BR BR8304644A patent/BR8304644A/pt not_active IP Right Cessation
- 1983-08-26 CH CH4685/83A patent/CH657372A5/de not_active IP Right Cessation
- 1983-08-26 FR FR8313806A patent/FR2532324B1/fr not_active Expired
- 1983-08-29 PT PT77260A patent/PT77260B/pt not_active IP Right Cessation
- 1983-08-29 CA CA000435530A patent/CA1207256A/fr not_active Expired
- 1983-08-29 NO NO833102A patent/NO157460C/no unknown
- 1983-08-29 ES ES525214A patent/ES525214A0/es active Granted
- 1983-08-29 BE BE211413A patent/BE897610A/fr unknown
- 1983-08-29 SE SE8304663A patent/SE456426B/sv not_active IP Right Cessation
- 1983-08-30 GR GR72337A patent/GR78984B/el unknown
- 1983-08-30 IT IT48896/83A patent/IT1168886B/it active
- 1983-08-30 GB GB08323182A patent/GB2126242B/en not_active Expired
-
1985
- 1985-12-02 GB GB08529667A patent/GB2168375B/en not_active Expired
- 1985-12-02 GB GB08529668A patent/GB2168376B/en not_active Expired
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A85 | Still pending on 85-01-01 | ||
| BA | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| BC | A request for examination has been filed | ||
| BV | The patent application has lapsed |