NL1017635C2 - 2,2,6,6-diethyldimethyl-1-alkoxypiperidine-verbindingen en de overeenkomstige 1-oxiden daarvan. - Google Patents

2,2,6,6-diethyldimethyl-1-alkoxypiperidine-verbindingen en de overeenkomstige 1-oxiden daarvan. Download PDF

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Publication number
NL1017635C2
NL1017635C2 NL1017635A NL1017635A NL1017635C2 NL 1017635 C2 NL1017635 C2 NL 1017635C2 NL 1017635 A NL1017635 A NL 1017635A NL 1017635 A NL1017635 A NL 1017635A NL 1017635 C2 NL1017635 C2 NL 1017635C2
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NL
Netherlands
Prior art keywords
diethyl
phenylethoxy
piperidin
ester
acid
Prior art date
Application number
NL1017635A
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English (en)
Dutch (nl)
Inventor
Andreas Kramer
Peter Nesvadba
Marie-Odile Zink
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Application granted granted Critical
Publication of NL1017635C2 publication Critical patent/NL1017635C2/nl

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)
NL1017635A 2000-03-22 2001-03-19 2,2,6,6-diethyldimethyl-1-alkoxypiperidine-verbindingen en de overeenkomstige 1-oxiden daarvan. NL1017635C2 (nl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22
EP00810246 2000-03-22

Publications (1)

Publication Number Publication Date
NL1017635C2 true NL1017635C2 (nl) 2001-09-25

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
NL1017635A NL1017635C2 (nl) 2000-03-22 2001-03-19 2,2,6,6-diethyldimethyl-1-alkoxypiperidine-verbindingen en de overeenkomstige 1-oxiden daarvan.

Country Status (16)

Country Link
US (3) US6624306B2 (enExample)
JP (1) JP2001316365A (enExample)
KR (1) KR100743975B1 (enExample)
CN (1) CN1319590A (enExample)
AU (1) AU784894B2 (enExample)
BE (1) BE1014058A5 (enExample)
BR (1) BR0101108A (enExample)
CA (1) CA2341791C (enExample)
DE (1) DE10113209A1 (enExample)
ES (1) ES2173046B1 (enExample)
FR (1) FR2806720B1 (enExample)
GB (1) GB2361235B (enExample)
IT (1) ITMI20010546A1 (enExample)
NL (1) NL1017635C2 (enExample)
NO (1) NO20011436L (enExample)
TW (1) TW541303B (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
DE60238606D1 (de) * 2001-06-13 2011-01-27 Basf Se 4-imin-n-alkoxy- oder oxy-polyalkyl-piperidin-verboren
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
CA2467119C (en) 2001-12-21 2012-02-07 Ciba Specialty Chemicals Holding Inc. Novel flame retarding compounds
CN100455614C (zh) * 2002-01-22 2009-01-28 阿托菲纳公司 抗冲击性增强且含有在氮氧化物存在下由受控的自由基聚合获得的嵌段共聚物材料的生产和使用方法
US7297819B2 (en) * 2002-03-05 2007-11-20 Ciba Specialty Chemicals Corp. Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
US7531555B2 (en) * 2003-10-01 2009-05-12 University Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
WO2005032610A1 (en) * 2003-10-07 2005-04-14 Coloplast A/S An adhesive composition and use of such composition
CN101712646B (zh) * 2004-05-27 2012-07-11 西巴特殊化学品控股有限公司 含有一个自由基聚合基团的烷氧基胺
WO2006074969A1 (en) 2005-01-11 2006-07-20 Ciba Specialty Chemicals Holding Inc. Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes
WO2008103613A2 (en) * 2007-02-22 2008-08-28 Othera Holding, Inc. Hydroxylamine compounds and methods of their use
KR20090127193A (ko) * 2007-04-05 2009-12-09 바스프 에스이 선택 공중합체를 포함하는 선스크린 및 개인 위생 조성물
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
WO2009156277A1 (en) 2008-06-23 2009-12-30 Basf Se Pigment dispersants with modified copolymers
JP5377647B2 (ja) * 2008-08-28 2013-12-25 ビーエーエスエフ ソシエタス・ヨーロピア 無生物有機材料のための安定剤
KR101524342B1 (ko) 2010-03-30 2015-07-06 바스프 에스이 말단-관능화 중합체
JP4821916B1 (ja) * 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
US9309391B2 (en) 2010-06-29 2016-04-12 Basf Se Process for improving the flow of properties of polymer melts
IN2014CN03743A (enExample) 2011-10-25 2015-09-25 Basf Se
JP6242822B2 (ja) 2012-02-23 2017-12-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 低い動的表面張力を有するフッ素化されたアクリレートブロックコポリマー
AU2014243274B2 (en) 2013-03-27 2017-10-12 Henkel Ag & Co. Kgaa Block copolymers as soil release agents in laundry processes
CN111278934B (zh) 2017-10-23 2022-04-12 巴斯夫欧洲公司 硅氧烷聚合物水乳液
WO2022200398A1 (en) 2021-03-26 2022-09-29 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant
CN121202763A (zh) * 2025-06-12 2025-12-26 成都道合尔医药技术有限公司 (3r,4r)-n-pg-4-氨基-3-甲基哌啶及其中间体的合成方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2621870A1 (de) * 1975-05-28 1976-12-16 Ciba Geigy Ag Neue derivate von 4-aminopiperidin
DE19909767A1 (de) * 1998-03-09 1999-09-16 Ciba Geigy Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
JPS5848580B2 (ja) * 1975-05-28 1983-10-29 三共株式会社 ゴウセイコウブンシザイリヨウヨウアンテイザイ
US4141883A (en) 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス　サイエンテイフイツク　アンド　インダストリアル　リサ−チ　オ−ガニゼ−シヨン 遊離基重合開始用化合物
KR930000892B1 (ko) 1983-07-11 1993-02-11 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법
AU4773997A (en) 1996-09-25 1998-04-17 Akzo Nobel N.V. No-compounds for pseudo-living radical polymerization
EP0951485B1 (en) 1997-01-10 2003-04-02 E.I. Du Pont De Nemours And Company Method of controlling polymer molecular weight and structure
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
EP0996643B1 (en) 1997-07-15 2003-03-26 Ciba SC Holding AG Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds
TWI246519B (en) * 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd （メタ）アクリル酸ピペリジン−１−オキシルエステル誘導体からなる（メタ）アクリル酸エステル用重合防止剤およびその製造方法
WO2000014134A1 (en) 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
WO2001002345A2 (en) 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2621870A1 (de) * 1975-05-28 1976-12-16 Ciba Geigy Ag Neue derivate von 4-aminopiperidin
DE19909767A1 (de) * 1998-03-09 1999-09-16 Ciba Geigy Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler

Also Published As

Publication number Publication date
CN1319590A (zh) 2001-10-31
US6624306B2 (en) 2003-09-23
ITMI20010546A1 (it) 2002-09-15
BE1014058A5 (fr) 2003-03-04
US20050143539A1 (en) 2005-06-30
AU2804901A (en) 2001-09-27
GB2361235A (en) 2001-10-17
US6891008B2 (en) 2005-05-10
TW541303B (en) 2003-07-11
JP2001316365A (ja) 2001-11-13
FR2806720A1 (fr) 2001-09-28
KR100743975B1 (ko) 2007-07-30
NO20011436D0 (no) 2001-03-21
ES2173046B1 (es) 2004-06-16
GB2361235B (en) 2002-06-12
FR2806720B1 (fr) 2006-12-08
DE10113209A1 (de) 2001-09-27
NO20011436L (no) 2001-09-24
BR0101108A (pt) 2001-11-06
US20030065184A1 (en) 2003-04-03
AU784894B2 (en) 2006-07-20
GB0105678D0 (en) 2001-04-25
US7160966B2 (en) 2007-01-09
CA2341791A1 (en) 2001-09-22
US20030166939A1 (en) 2003-09-04
ES2173046A1 (es) 2002-10-01
CA2341791C (en) 2010-02-23
KR20010092697A (ko) 2001-10-26

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Effective date: 20111001