ES2173046A1 - Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes. - Google Patents

Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes.

Info

Publication number
ES2173046A1
ES2173046A1 ES200100650A ES200100650A ES2173046A1 ES 2173046 A1 ES2173046 A1 ES 2173046A1 ES 200100650 A ES200100650 A ES 200100650A ES 200100650 A ES200100650 A ES 200100650A ES 2173046 A1 ES2173046 A1 ES 2173046A1
Authority
ES
Spain
Prior art keywords
diethyl
alkoxy
dimethyl
derivatives
piperidine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES200100650A
Other languages
English (en)
Other versions
ES2173046B1 (es
Inventor
Peter Nesvadba
Marie-Odile Zink
Andreas Kramer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Ciba SC Holding AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2173046A1 publication Critical patent/ES2173046A1/es
Application granted granted Critical
Publication of ES2173046B1 publication Critical patent/ES2173046B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Abstract

Compuestos de 2, 2, 6, 6-Dimetildietil-1-Alcoxi-Piperidina y sus 1-Oxidos correspondientes. Estos compuestos corresponden a las fórmulas Ia o IIa, en donde los radicales X e Y y los significados de los diferentes radicales R se corresponden con lo descrito en las reivindicaciones. La invención se refiere también a composiciones polimerizables que comprenden a) por los menos un monómero etilénicamente insaturado, y b) dichos derivados de piperidina. También se refiere a un procedimiento para la polimerización de monómeros etilénicamente insaturados. Los compuestos de la invención que están sustituidos en la posición 4 por un átomo de oxígeno o nitrógeno se usan para la polimerización de monómeros etilénicamente insaturados.
ES200100650A 2000-03-22 2001-03-21 Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes. Expired - Fee Related ES2173046B1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22
EP00810246 2000-03-22

Publications (2)

Publication Number Publication Date
ES2173046A1 true ES2173046A1 (es) 2002-10-01
ES2173046B1 ES2173046B1 (es) 2004-06-16

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
ES200100650A Expired - Fee Related ES2173046B1 (es) 2000-03-22 2001-03-21 Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes.

Country Status (16)

Country Link
US (3) US6624306B2 (es)
JP (1) JP2001316365A (es)
KR (1) KR100743975B1 (es)
CN (1) CN1319590A (es)
AU (1) AU784894B2 (es)
BE (1) BE1014058A5 (es)
BR (1) BR0101108A (es)
CA (1) CA2341791C (es)
DE (1) DE10113209A1 (es)
ES (1) ES2173046B1 (es)
FR (1) FR2806720B1 (es)
GB (1) GB2361235B (es)
IT (1) ITMI20010546A1 (es)
NL (1) NL1017635C2 (es)
NO (1) NO20011436L (es)
TW (1) TW541303B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
ATE491687T1 (de) * 2001-06-13 2011-01-15 Basf Se 4-imin-n-alkoxy- oder oxy-polyalkyl-piperidin- verbindungen zur verwendung als polymerisationsregulatoren
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
WO2003054073A1 (en) 2001-12-21 2003-07-03 Ciba Specialty Chemicals Holding Inc. Novel flame retarding compounds
CN100455614C (zh) * 2002-01-22 2009-01-28 阿托菲纳公司 抗冲击性增强且含有在氮氧化物存在下由受控的自由基聚合获得的嵌段共聚物材料的生产和使用方法
MXPA04008321A (es) * 2002-03-05 2004-11-26 Ciba Sc Holding Ag Alcoxiaminas de cadera abierta y sus nitroxidos correspondientes para la polimerizacion por radicales a baja temperatura, controlada.
WO2005032479A2 (en) * 2003-10-01 2005-04-14 Unviversity Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
US20070078197A1 (en) * 2003-10-07 2007-04-05 Coloplast A/S Adhesive composition and use of such composition
ATE387464T1 (de) * 2004-05-27 2008-03-15 Ciba Sc Holding Ag Alkoxyamine mit radikalisch polymerisierbarer gruppe
US20090221739A1 (en) 2005-01-11 2009-09-03 Ralf Knischka Process for the Post-Modification of Homo and Copolymers Prepared by Controlled Free Radical Polymerization Processes
CN105998028A (zh) * 2007-02-22 2016-10-12 科尔比制药公司 羟胺化合物及其用法
MX2009010535A (es) * 2007-04-05 2009-10-22 Basf Se Protector solar y composiciones para el cuidado personal que comprenden un copolimero seleccionado.
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
US8664324B2 (en) 2008-06-23 2014-03-04 Basf Se Pigment dispersants with modified copolymers
JP5377647B2 (ja) * 2008-08-28 2013-12-25 ビーエーエスエフ ソシエタス・ヨーロピア 無生物有機材料のための安定剤
WO2011120947A1 (en) 2010-03-30 2011-10-06 Basf Se End-functionalized polymers
JP4821916B1 (ja) * 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
RU2013103600A (ru) 2010-06-29 2014-08-10 Басф Се Способ улучшения свойств текучести расплавов полимеров
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
JP6242822B2 (ja) 2012-02-23 2017-12-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 低い動的表面張力を有するフッ素化されたアクリレートブロックコポリマー
KR20150135489A (ko) 2013-03-27 2015-12-02 바스프 에스이 세탁 과정에서 오염물 방출제로서 블록 공중합체
EP3700988B1 (en) 2017-10-23 2021-08-18 Basf Se Aqueous silicone polymer emulsion
EP4314155A1 (en) 2021-03-26 2024-02-07 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2333795A1 (fr) * 1975-05-28 1977-07-01 Ciba Geigy Ag Derives de la 4-aminopiperidine utilisables pour stabiliser des matieres polymeres
FR2777892A1 (fr) * 1998-03-09 1999-10-29 Ciba Sc Holding Ag Derive de 1-alcoxy-polyalkyl-piperidine, composition polymerisable le contenant et son utilisation
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd （メタ）アクリル酸ピペリジン−１−オキシルエステル誘導体からなる（メタ）アクリル酸エステル用重合防止剤およびその製造方法
WO2000014134A1 (en) * 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
WO2001002345A2 (en) * 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
US4141883A (en) * 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
US4581429A (en) 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby
DE69708896T2 (de) 1996-09-25 2002-06-20 Akzo Nobel Nv Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation
US6271340B1 (en) 1997-01-10 2001-08-07 E. I. Du Pont De Nemours And Company Method of controlling polymer molecular weight and structure
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
DE69812633T2 (de) 1997-07-15 2003-10-23 Ciba Sc Holding Ag Von nitrone- oder nitroso-verbindungen abgeleitete alkoxyaminverbindungen-enthaltende polymerisierbare zusammensetzungen
TWI246519B (en) * 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2333795A1 (fr) * 1975-05-28 1977-07-01 Ciba Geigy Ag Derives de la 4-aminopiperidine utilisables pour stabiliser des matieres polymeres
FR2777892A1 (fr) * 1998-03-09 1999-10-29 Ciba Sc Holding Ag Derive de 1-alcoxy-polyalkyl-piperidine, composition polymerisable le contenant et son utilisation
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd （メタ）アクリル酸ピペリジン−１−オキシルエステル誘導体からなる（メタ）アクリル酸エステル用重合防止剤およびその製造方法
WO2000014134A1 (en) * 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
WO2001002345A2 (en) * 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers

Also Published As

Publication number Publication date
ES2173046B1 (es) 2004-06-16
US7160966B2 (en) 2007-01-09
US20030166939A1 (en) 2003-09-04
CA2341791A1 (en) 2001-09-22
GB2361235A (en) 2001-10-17
FR2806720A1 (fr) 2001-09-28
KR100743975B1 (ko) 2007-07-30
FR2806720B1 (fr) 2006-12-08
GB0105678D0 (en) 2001-04-25
GB2361235B (en) 2002-06-12
BE1014058A5 (fr) 2003-03-04
CN1319590A (zh) 2001-10-31
BR0101108A (pt) 2001-11-06
US20050143539A1 (en) 2005-06-30
ITMI20010546A1 (it) 2002-09-15
AU2804901A (en) 2001-09-27
JP2001316365A (ja) 2001-11-13
NO20011436L (no) 2001-09-24
NL1017635C2 (nl) 2001-09-25
AU784894B2 (en) 2006-07-20
TW541303B (en) 2003-07-11
US6624306B2 (en) 2003-09-23
US20030065184A1 (en) 2003-04-03
US6891008B2 (en) 2005-05-10
CA2341791C (en) 2010-02-23
DE10113209A1 (de) 2001-09-27
NO20011436D0 (no) 2001-03-21
KR20010092697A (ko) 2001-10-26

Similar Documents

Publication Publication Date Title
ES2173046A1 (es) Compuestos de 2,2,6,6, dietil-dimetil-1-alcoxi-piperidina y sus 1-oxidos correspondientes.
ES2155014A1 (es) Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion.
FR2789991B1 (fr) Alcoxyamines issues de nitroxyde beta-phosphores, leur utilisation en polymerisation radicalaire
MXPA03010132A (es) Compuestos de 4-imino-n-alcoxi u oxi-polialquil-piperidina y su uso como reguladores de la polimerizacion.
SE9903593D0 (sv) Polymeriserbar komposition
WO2002010223A3 (fr) Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
AU2484002A (en) N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
DE69617962T2 (de) Methoden zur verhinderung der polymerisation von aromatischen vinylmonomeren
CA2256083A1 (fr) Procede de polymerisation radicalaire controlee faisant intervenir une faible quantite de radical libre stable
WO2002013767A3 (en) Polyaminoester and their application in dental compositions
ES8103118A1 (es) Un procedimiento de preparacion de un copolimero de bajo pe-so molecular controlado
PT1507807E (pt) Processo de polimerização radicalar e polímeros halogenados
MY104869A (en) Styrene-based polymer and method for the preparation thereof
AU1864500A (en) Polymeric stabilizers having low polydispersity
AU2003212272A1 (en) Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
AU2003208787A1 (en) Uv- crosslinkable copolymers
CA2534535A1 (en) Composition and process for the controlled synthesis of block copolymers
AU1979600A (en) Composition and process for controlled radical polymerization using multifunctional initiator/regulator compounds
NO975097L (no) Polymert bindemiddel for grohindrende malingssystem, og slikt malingssystem
DE50307980D1 (de) Kaschierklebstoff
ATE288451T1 (de) Verfahren zur lebenden freien radikalischen polymerisation
WO2007060374A3 (fr) Procede de polymerisation ou copolymerisation radicalaire controlee de monomeres methacryliques et/ou methacrylates pour realiser des polymeres methacryliques ou methacrylates ou des copolymeres exclusivement methacryliques et/ou methacrylates
GB2368343B (en) Resin material for deture base
DE59901005D1 (de) Verfahren zum Verdichten ethylenisch ungesättigter Monomerer
CA2347298A1 (en) Organic initiators and their use in the polymerization of unsaturated monomers

Legal Events

Date Code Title Description
EC2A Search report published

Date of ref document: 20021001

Kind code of ref document: A1

Effective date: 20021001

FG2A Definitive protection

Ref document number: 2173046B1

Country of ref document: ES

FD2A Announcement of lapse in spain

Effective date: 20180807