BR0101108A - Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes - Google Patents

Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes

Info

Publication number
BR0101108A
BR0101108A BR0101108-1A BR0101108A BR0101108A BR 0101108 A BR0101108 A BR 0101108A BR 0101108 A BR0101108 A BR 0101108A BR 0101108 A BR0101108 A BR 0101108A
Authority
BR
Brazil
Prior art keywords
diethyl
alkoxy
piperidine
dimethyl
derivatives
Prior art date
Application number
BR0101108-1A
Other languages
English (en)
Inventor
Peter Nesvadba
Marie-Odile Zink
Andreas Kramer
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of BR0101108A publication Critical patent/BR0101108A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

Patente de Invenção: "COMPOSTOS DE 2,2,6,6-DIETIL-DIMETIL-1-ALCóXI-PIPERIDINA E SEUS 1-óXIDOS CORRESPONDENTES". A presente invenção refere-se a derivados selecionados de 1-alcóxi-2,2-dietil-6,6-dimetil piperidina e de 1-alcóxi-2,6-dietil-2,3,6-trimetil piperidina que estão substituídos na posição 4 por um átomo de oxigênio ou de nitrogênio; a uma composição polimerizável que compreende a)pelo menos um monómero etilenicamente insaturado e b) os ditos derivados de piperidina. Outros aspectos da presente invenção são um processo para a polimerização de monómeros etilenicamente insaturados e para o uso de derivados de 1-alcóxi-2,2-dietil-6,6-dimetil piperidina e de 1-alcóxi-2,6-dietil-2,3,6-trimetil piperidina que estão substituídos na posição 4 por um átomo de oxigênio ou de nitrogênio para polimerização controlada. Os derivados de N-oxila intermediários, uma composição dos derivados de N-oxila com monómeros etilenicamente insaturados e um iniciador de radical livre, assim como um processo para a polimerização também são assuntos da presente invenção.
BR0101108-1A 2000-03-22 2001-03-21 Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes BR0101108A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22

Publications (1)

Publication Number Publication Date
BR0101108A true BR0101108A (pt) 2001-11-06

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0101108-1A BR0101108A (pt) 2000-03-22 2001-03-21 Compostos de 2,2,6,6-dietil-dimetil-1-alcóxi-piperidina e seus 1-óxidos correspondentes

Country Status (16)

Country Link
US (3) US6624306B2 (pt)
JP (1) JP2001316365A (pt)
KR (1) KR100743975B1 (pt)
CN (1) CN1319590A (pt)
AU (1) AU784894B2 (pt)
BE (1) BE1014058A5 (pt)
BR (1) BR0101108A (pt)
CA (1) CA2341791C (pt)
DE (1) DE10113209A1 (pt)
ES (1) ES2173046B1 (pt)
FR (1) FR2806720B1 (pt)
GB (1) GB2361235B (pt)
IT (1) ITMI20010546A1 (pt)
NL (1) NL1017635C2 (pt)
NO (1) NO20011436L (pt)
TW (1) TW541303B (pt)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH693416A5 (de) * 1998-03-09 2003-07-31 Ciba Sc Holding Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler.
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
DE60238606D1 (de) * 2001-06-13 2011-01-27 Basf Se 4-imin-n-alkoxy- oder oxy-polyalkyl-piperidin-verboren
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
ATE439401T1 (de) 2001-12-21 2009-08-15 Basf Se Neue flammhemmer
CA2473791C (en) * 2002-01-22 2009-08-04 Atofina Method of producing and using materials which are reinforced against impact and which contain block copolymers that are obtained by means of controlled radical polymerization in the presence of nitroxides
CA2477728A1 (en) * 2002-03-05 2003-09-12 Ciba Specialty Chemicals Holding Inc. Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
US7531555B2 (en) * 2003-10-01 2009-05-12 University Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
EP1675629A1 (en) * 2003-10-07 2006-07-05 Coloplast A/S An adhesive composition and use of such composition
EP1749032B1 (en) * 2004-05-27 2008-02-27 Ciba Specialty Chemicals Holding Inc. Alkoxyamines containing a radically polymerizable group
US20090221739A1 (en) 2005-01-11 2009-09-03 Ralf Knischka Process for the Post-Modification of Homo and Copolymers Prepared by Controlled Free Radical Polymerization Processes
CN101687786B (zh) * 2007-02-22 2013-05-22 奥特拉控股公司 羟胺化合物及其用法
BRPI0809925A2 (pt) * 2007-04-05 2014-09-23 Basf Se Composição de protetor solar, e, métodos para aumentar o fator de proteção solar de uma composição de protetor solar, e de proteção contra uv melhorada de cabelo e/ou pele de mamífero dos efeitos danificadores de radiação uv.
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
EP2291422B1 (en) 2008-06-23 2015-10-21 Basf Se Pigment dispersants with modified copolymers
WO2010023115A1 (de) * 2008-08-28 2010-03-04 Basf Se Stabilisatoren für unbelebte organische materialien
WO2011120947A1 (en) 2010-03-30 2011-10-06 Basf Se End-functionalized polymers
JP4821916B1 (ja) 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
CN102958993B (zh) 2010-06-29 2015-07-22 巴斯夫欧洲公司 改善聚合物熔体的流动性能的方法
CN104105786A (zh) 2011-10-25 2014-10-15 巴斯夫欧洲公司 梳形或嵌段共聚物作为抗污垢再沉积剂和去污剂在洗衣过程中的用途
US9587105B2 (en) 2012-02-23 2017-03-07 Basf Se Fluorinated acrylate block copolymers with low dynamic surface tension
KR20150135489A (ko) 2013-03-27 2015-12-02 바스프 에스이 세탁 과정에서 오염물 방출제로서 블록 공중합체
WO2019081277A1 (en) 2017-10-23 2019-05-02 Basf Se AQUEOUS SILICONE POLYMER EMULSION
US20240182746A1 (en) 2021-03-26 2024-06-06 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant

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Publication number Priority date Publication date Assignee Title
US4141883A (en) 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
GB1492494A (en) * 1975-05-28 1977-11-23 Sankyo Co Derivatives of 4-aminopiperidine
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
KR930000892B1 (ko) 1983-07-11 1993-02-11 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법
ATE210156T1 (de) 1996-09-25 2001-12-15 Akzo Nobel Nv Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation
KR100504055B1 (ko) 1997-01-10 2005-07-27 이 아이 듀폰 디 네모아 앤드 캄파니 중합체 분자량 및 구조의 조절 방법
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EP1189875B1 (en) 1999-07-02 2004-08-04 Ciba SC Holding AG Mono and multifunctional alkoxyamines for the preparation of functionalized macromers

Also Published As

Publication number Publication date
US6624306B2 (en) 2003-09-23
FR2806720B1 (fr) 2006-12-08
US6891008B2 (en) 2005-05-10
KR100743975B1 (ko) 2007-07-30
US20030166939A1 (en) 2003-09-04
AU2804901A (en) 2001-09-27
US20050143539A1 (en) 2005-06-30
CA2341791A1 (en) 2001-09-22
CN1319590A (zh) 2001-10-31
US20030065184A1 (en) 2003-04-03
FR2806720A1 (fr) 2001-09-28
JP2001316365A (ja) 2001-11-13
BE1014058A5 (fr) 2003-03-04
DE10113209A1 (de) 2001-09-27
NO20011436D0 (no) 2001-03-21
ES2173046A1 (es) 2002-10-01
TW541303B (en) 2003-07-11
NL1017635C2 (nl) 2001-09-25
GB2361235A (en) 2001-10-17
US7160966B2 (en) 2007-01-09
KR20010092697A (ko) 2001-10-26
AU784894B2 (en) 2006-07-20
NO20011436L (no) 2001-09-24
CA2341791C (en) 2010-02-23
GB0105678D0 (en) 2001-04-25
ITMI20010546A1 (it) 2002-09-15
GB2361235B (en) 2002-06-12
ES2173046B1 (es) 2004-06-16

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A, 6A E 7A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1962 DE 12/08/2008.