ES2182777T3 - Alcoxiaminas procedentes de nitroxido beta-fosforados. - Google Patents

Alcoxiaminas procedentes de nitroxido beta-fosforados.

Info

Publication number
ES2182777T3
ES2182777T3 ES00903787T ES00903787T ES2182777T3 ES 2182777 T3 ES2182777 T3 ES 2182777T3 ES 00903787 T ES00903787 T ES 00903787T ES 00903787 T ES00903787 T ES 00903787T ES 2182777 T3 ES2182777 T3 ES 2182777T3
Authority
ES
Spain
Prior art keywords
beta
alcoxiamins
phosphorated
nitroxide
phosphorated nitroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES00903787T
Other languages
English (en)
Inventor
Jean-Luc Couturier
Christiane Henriet-Bernard
Mercier Christophe Le
Paul Tordo
Jean-Francois Lutz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atofina SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina SA filed Critical Atofina SA
Application granted granted Critical
Publication of ES2182777T3 publication Critical patent/ES2182777T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Luminescent Compositions (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Compuestos de fórmula **(Fórmula)** en la que R1 y R2, idénticos o diferentes, representan un átomo de hidrógeno, un radical alquilo lineal o ramificado, que tiene un número de átomos de carbono que va desde 1 hasta 10, un radical arilo, un radical aralquilo, que tiene un número de átomos de carbono como máximo igual a 10, o bien R1 y R2 están enlazados entre sí con el fin de formar un ciclo que incluya al átomo de carbono que porta a los citados R1 y R2, teniendo dicho ciclo un número de átomos de carbono, incluyendo el carbono portador de los radicales R1 y R2, que va de 3 a 8; R3 representa un radical hidrocarbonado, lineal o ramificado, saturado o insaturado, que puede comprender al menos un ciclo, teniendo dicho radical un número de átomos de carbono, que va de 1 a 30; R4 y R5, idénticos o diferentes, representan un radical alquilo, lineal o ramificado, un radical cicloalquilo, arilo, alcoxilo, ariloxilo, aralquiloxilo, perflúoralquilo, aralquilo, tioalquilo que tiene un número de átomos de carbono que va de 1 a 20, o bien R4 y R5 están enlazadas entre sí, con el fin de formar un ciclo que incluya al átomo de fósforo, teniendo dicho heterociclo un número de átomos de carbono que va de 2 a 6 y que puede contener además uno o varios átomos de oxígeno o de azufre; Z es un radical CF3 (CF2)5-, (CH3)2 C(CN)- o un resto de fórmula: **(Fórmula)** en la que R6, R7 y R8, idénticos o diferentes representan un átomo de hidrógeno, o un radical ciano, un radical cicloalquilo que tiene un número de átomos de carbono que va de 3 a 12; un radical -(CH2)n C(O)OR9 en el que R9 representa un radical alquilo, lineal o ramificado, que tiene un número de átomos de carbono que va de 1 hasta 6, n = 0 a 6.
ES00903787T 1999-02-18 2000-02-10 Alcoxiaminas procedentes de nitroxido beta-fosforados. Expired - Lifetime ES2182777T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9901998A FR2789991B1 (fr) 1999-02-18 1999-02-18 Alcoxyamines issues de nitroxyde beta-phosphores, leur utilisation en polymerisation radicalaire

Publications (1)

Publication Number Publication Date
ES2182777T3 true ES2182777T3 (es) 2003-03-16

Family

ID=9542200

Family Applications (1)

Application Number Title Priority Date Filing Date
ES00903787T Expired - Lifetime ES2182777T3 (es) 1999-02-18 2000-02-10 Alcoxiaminas procedentes de nitroxido beta-fosforados.

Country Status (10)

Country Link
US (1) US6569967B1 (es)
EP (1) EP1153030B1 (es)
JP (1) JP4975904B2 (es)
AT (1) ATE223922T1 (es)
AU (1) AU2555200A (es)
DE (1) DE60000442T2 (es)
DK (1) DK1153030T3 (es)
ES (1) ES2182777T3 (es)
FR (1) FR2789991B1 (es)
WO (1) WO2000049027A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2807439B1 (fr) 2000-04-07 2003-06-13 Atofina Polymeres multimodaux par polymerisation radicalaire controlee en presence d'alcoxyamines
US6762263B2 (en) * 2002-02-01 2004-07-13 Atofina Chemicals, Inc. High-solids coatings resins via controlled radical polymerization
EP1375476A1 (en) * 2002-06-25 2004-01-02 Bayer Aktiengesellschaft A new process for the synthesis of alkoxyamines active in controlled radical polymerization
EP1375457A1 (en) 2002-06-25 2004-01-02 Bayer Aktiengesellschaft One-pot process for the preparation of functionalized alkoxyamines
FR2843394B1 (fr) * 2002-08-07 2005-12-30 Atofina Alcoxyamines issues de nitroxydes b-phosphore, leur utilisation en polymerisation radicalaire
FR2843393B1 (fr) * 2002-08-07 2005-12-30 Atofina Alcoxyamines issues de nitroxydes b-phosphore, leur utilisation en polymerisation radicalaire
US20060113509A1 (en) * 2002-12-23 2006-06-01 Basf Aktiengesellschaft Hydrophobic-hydrophilic compounds for treating metallic surfaces
FR2853317B1 (fr) * 2003-04-01 2006-07-07 Atofina Alcoxyamines issues de nitroxydes b-phosphores, leur utilisation pour la preparation de mono-ou polyalcoxyamines, polymerisees ou non
FR2861394B1 (fr) * 2003-10-24 2006-01-20 Arkema Procede de preparation de polyalcoaxymines utilisables comme amorceurs pour la polymerisation radicalaire de (co)polymeres vivants polyfonctionnels
FR2866026B1 (fr) * 2004-02-06 2008-05-23 Arkema Procede de polymerisation radicalaire en emulsion mettant en oeuvre des alcoxyamines hydrosolubles
FR2870240B1 (fr) * 2004-05-13 2006-07-07 Arkema Sa Procede de preparation d'une alcoxyamine ou de ses sels comprenant une etape de photolyse
US8541541B2 (en) * 2005-03-07 2013-09-24 Arkema Inc. Conductive block copolymers
CA2617547C (en) 2005-08-02 2013-10-08 Arkema Inc. Methods of producing vinyl aromatic polymers using (meth)acrylic macroinitiators
WO2007059350A2 (en) * 2005-11-17 2007-05-24 Carnegie Mellon University Preparation of alkoxyamines
WO2007068453A2 (en) * 2005-12-14 2007-06-21 Novartis Ag Method for preparing silicone hydrogels
CA2633263A1 (en) * 2005-12-16 2007-07-12 Arkema Inc. Low surface energy block co-polymer preparation methods and applications
US7498398B2 (en) * 2006-03-21 2009-03-03 Sabic Innovative Plastics Ip B.V. Thermoplastic composition, method of making, and articles formed therefrom
FR2905951A1 (fr) * 2006-09-20 2008-03-21 Arkema France Procede de preparation d'un copolymere tribloc comprenant un bloc semi-cristallin et/ou hydrolysable, un bloc elastomere et un bloc amorphe
WO2008079677A2 (en) * 2006-12-20 2008-07-03 Arkema Inc. Polymer encapsulation and/or binding
US7985826B2 (en) 2006-12-22 2011-07-26 Reichhold, Inc. Molding resins using renewable resource component
DE102011005493A1 (de) 2011-03-14 2012-09-20 Evonik Rohmax Additives Gmbh Estergruppen-umfassende Copolymere und deren Verwendung in Schmiermitteln
FR3030529B1 (fr) 2014-12-23 2017-01-27 Arkema France Copolymere a blocs hydrosoluble et son utilisation comme materiau support pour impression 3d
FR3030530B1 (fr) 2014-12-23 2017-01-27 Arkema France Copolymere dibloc hydrosoluble

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3767708A (en) * 1971-10-18 1973-10-23 Upjohn Co Aminomethyl phospholenes
FR2579210B1 (fr) * 1985-03-21 1987-09-11 Rhone Poulenc Agrochimie Preparation d'herbicides a groupe phosphonates et d'intermediaires a partir de benzoxazines
JPH01100182A (ja) * 1987-10-13 1989-04-18 Sumitomo Chem Co Ltd ホスホネート類またはホスフィネート類およびその製造法
US5077329A (en) * 1990-04-06 1991-12-31 Ciba-Geigy Corporation Hydroxyaminomethylphosphonates and stabilized compositions
FR2769316B1 (fr) * 1997-10-03 1999-12-03 Atochem Elf Sa Copolymere greffe par polymerisation radicalaire en presence de radicaux stables, sa preparation et ses applications
FR2781487B1 (fr) * 1998-07-10 2000-12-08 Atochem Elf Sa Polymerisation en emulsion en presence d'un radical libre stable
FR2788270B1 (fr) * 1999-01-08 2001-03-16 Atochem Elf Sa Procede de preparation de radicaux nitroxyde beta-phosphores

Also Published As

Publication number Publication date
WO2000049027A1 (fr) 2000-08-24
JP2002537304A (ja) 2002-11-05
DE60000442T2 (de) 2003-07-31
US6569967B1 (en) 2003-05-27
FR2789991A1 (fr) 2000-08-25
DK1153030T3 (da) 2003-01-13
JP4975904B2 (ja) 2012-07-11
ATE223922T1 (de) 2002-09-15
FR2789991B1 (fr) 2002-02-22
AU2555200A (en) 2000-09-04
EP1153030A1 (fr) 2001-11-14
DE60000442D1 (de) 2002-10-17
EP1153030B1 (fr) 2002-09-11

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