ES2155014A1 - Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion. - Google Patents

Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion.

Info

Publication number
ES2155014A1
ES2155014A1 ES009900470A ES9900470A ES2155014A1 ES 2155014 A1 ES2155014 A1 ES 2155014A1 ES 009900470 A ES009900470 A ES 009900470A ES 9900470 A ES9900470 A ES 9900470A ES 2155014 A1 ES2155014 A1 ES 2155014A1
Authority
ES
Spain
Prior art keywords
polyalkyl
alkoxy
ethylenically unsaturated
group
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009900470A
Other languages
English (en)
Other versions
ES2155014B1 (es
Inventor
Andreas Kramer
Peter Nesvadba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Ciba SC Holding AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2155014A1 publication Critical patent/ES2155014A1/es
Application granted granted Critical
Publication of ES2155014B1 publication Critical patent/ES2155014B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40—Oxygen atoms
    • C07D211/44—Oxygen atoms attached in position 4
    • C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D211/74—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerización. Forman parte de composiciones polimerizables que comprenden a) por lo menos un monómero etilénicamente insaturado, y b) un derivado 1-alcoxi-polialquil- piperidina de fórmula estructural (I), en donde G{sub,1}, G{sub,2}, G{sub,3}, G{sub,4}, G{sub,5}, G{sub,6} y X representan lo especificado en la descripción y en las reivindicaciones, excluyéndose los compuestos (A{sub,1}) y (A{sub,a}). Los compuestos de la invención se utilizan para procedimientos de polimerización mediados por radical libre para obtener productos de resina polimérica que tienen baja polidispersabilidad.
ES009900470A 1998-03-09 1999-03-08 Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion. Expired - Fee Related ES2155014B1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98810194 1998-03-09
EP98810531 1998-06-11

Publications (2)

Publication Number Publication Date
ES2155014A1 true ES2155014A1 (es) 2001-04-16
ES2155014B1 ES2155014B1 (es) 2001-12-01

Family

ID=26151881

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009900470A Expired - Fee Related ES2155014B1 (es) 1998-03-09 1999-03-08 Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion.

Country Status (18)

Country Link
US (4) US6353107B1 (es)
JP (1) JP4651137B2 (es)
KR (1) KR100581654B1 (es)
CN (1) CN1171871C (es)
AT (1) AT408655B (es)
AU (1) AU754927B2 (es)
BE (1) BE1012399A3 (es)
BR (1) BR9900977B1 (es)
CA (1) CA2264460A1 (es)
CH (1) CH693416A5 (es)
CZ (1) CZ78999A3 (es)
DE (1) DE19909767B4 (es)
ES (1) ES2155014B1 (es)
FR (1) FR2777892B1 (es)
GB (1) GB2335190B (es)
IT (1) IT1309590B1 (es)
NL (1) NL1011493C2 (es)
SG (1) SG82601A1 (es)

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DE69918151T2 (de) 1998-10-06 2005-06-30 Atofina Verfahren zur kontrollierten radikalischen Hochdruck-(Co)Polymerisation von Ethylen in Gegenwart von einem Kontrollfunktionsinitiator
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
WO2001002345A2 (en) * 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers
TW546311B (en) * 1999-11-25 2003-08-11 Ciba Sc Holding Ag Composition and method for color improvement of nitroxyl containing polymers
TW541303B (en) * 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
RU2298563C2 (ru) 2000-05-19 2007-05-10 Циба Спешиалти Кемикэлз Холдинг Инк. Способ уменьшения молекулярной массы полипропилена
TWI225492B (en) * 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
TW574236B (en) * 2000-09-25 2004-02-01 Ciba Sc Holding Ag Process for controlled radical polymerization in aqueous dispersion
TWI236482B (en) * 2000-11-13 2005-07-21 Ciba Sc Holding Ag Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
TW557305B (en) 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
US6849679B2 (en) 2001-05-21 2005-02-01 Ciba Specialty Chemicals Corporation Pigment compositions with modified block copolymer dispersants
CA2443718A1 (en) * 2001-06-13 2002-12-19 Ciba Specialty Chemicals Holding Inc. 4-imino-n-alkoxy or oxy-polyalkyl-piperidine compounds and their use as polymerization regulators
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
TW200407307A (en) * 2001-11-26 2004-05-16 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
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RU2300536C2 (ru) * 2002-05-01 2007-06-10 Циба Спешиалти Кемикэлз Холдинг Инк. Способ обрыва цепи в процессе полимеризации пвх
EP1375476A1 (en) * 2002-06-25 2004-01-02 Bayer Aktiengesellschaft A new process for the synthesis of alkoxyamines active in controlled radical polymerization
EP1375457A1 (en) 2002-06-25 2004-01-02 Bayer Aktiengesellschaft One-pot process for the preparation of functionalized alkoxyamines
JP2006517248A (ja) * 2003-02-10 2006-07-20 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 特定の側鎖を有する櫛形共重合体及びその製造方法
JP4107996B2 (ja) * 2003-04-25 2008-06-25 大塚化学株式会社 リビングラジカルポリマーの製造方法及びポリマー
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
JP4466650B2 (ja) 2004-06-09 2010-05-26 日立化成工業株式会社 フィルム状接着剤、フィルム状回路接続材、回路部材の接続方法及び半導体装置
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DE602006017187D1 (de) * 2005-04-04 2010-11-11 Basf Se Verfahren zur herstellung von stern- und blockcopolymeren über epoxidfunktionelle alkoxyamine
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PL2771445T3 (pl) 2011-10-25 2019-05-31 Henkel Ag & Co Kgaa Zastosowanie kopolimerów grzebieniowych lub blokowych jako środków zapobiegających ponownemu osadzaniu zabrudzeń i środków uwalniających zabrudzenia w procesach prania
EP3778768A1 (en) 2012-02-23 2021-02-17 Basf Se Fluorinated acrylate block copolymers with low dynamic surface tension
CN103073695B (zh) * 2012-12-27 2015-03-11 中山大学 一种本征型室温自修复结晶性聚合物
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
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KR101595087B1 (ko) * 2015-09-23 2016-02-18 주식회사 엘림산업 피혁용 버핑머신 구동롤러
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Also Published As

Publication number Publication date
DE19909767B4 (de) 2015-04-30
BE1012399A3 (fr) 2000-10-03
GB2335190B (en) 2000-05-31
NL1011493C2 (nl) 1999-10-28
US6683142B2 (en) 2004-01-27
ATA38799A (de) 2001-06-15
CN1228424A (zh) 1999-09-15
CA2264460A1 (en) 1999-09-09
ES2155014B1 (es) 2001-12-01
US7402639B2 (en) 2008-07-22
US20050131177A1 (en) 2005-06-16
ITMI990453A1 (it) 2000-09-05
SG82601A1 (en) 2001-08-21
AU754927B2 (en) 2002-11-28
NL1011493A1 (nl) 1999-09-10
AU1863699A (en) 1999-09-23
AT408655B (de) 2002-02-25
CH693416A5 (de) 2003-07-31
US6927295B2 (en) 2005-08-09
US6353107B1 (en) 2002-03-05
BR9900977B1 (pt) 2013-10-29
KR100581654B1 (ko) 2006-05-22
US20030220423A1 (en) 2003-11-27
US20020107397A1 (en) 2002-08-08
JP4651137B2 (ja) 2011-03-16
JPH11322714A (ja) 1999-11-24
KR19990077710A (ko) 1999-10-25
GB2335190A (en) 1999-09-15
FR2777892A1 (fr) 1999-10-29
CN1171871C (zh) 2004-10-20
GB9905152D0 (en) 1999-04-28
FR2777892B1 (fr) 2000-12-29
DE19909767A1 (de) 1999-09-16
IT1309590B1 (it) 2002-01-24
CZ78999A3 (cs) 1999-09-15
BR9900977A (pt) 2000-03-21

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