ES2155014B1 - Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion. - Google Patents
Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion.Info
- Publication number
- ES2155014B1 ES2155014B1 ES009900470A ES9900470A ES2155014B1 ES 2155014 B1 ES2155014 B1 ES 2155014B1 ES 009900470 A ES009900470 A ES 009900470A ES 9900470 A ES9900470 A ES 9900470A ES 2155014 B1 ES2155014 B1 ES 2155014B1
- Authority
- ES
- Spain
- Prior art keywords
- sub
- derivatives
- polialquil
- piperidina
- alcoxi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000001404 mediated effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/40—Oxygen atoms
- C07D211/44—Oxygen atoms attached in position 4
- C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D211/74—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Hydrogenated Pyridines (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Plural Heterocyclic Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerización. Forman parte de composiciones polimerizables que comprenden a) por lo menos un monómero etilénicamente insaturado, y b) un derivado 1-alcoxi-polialquil- piperidina de fórmula estructural (I), en donde G{sub,1}, G{sub,2}, G{sub,3}, G{sub,4}, G{sub,5}, G{sub,6} y X representan lo especificado en la descripción y en las reivindicaciones, excluyéndose los compuestos (A{sub,1}) y (A{sub,a}). Los compuestos de la invención se utilizan para procedimientos de polimerización mediados por radical libre para obtener productos de resina polimérica que tienen baja polidispersabilidad.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98810194 | 1998-03-09 | ||
| EP98810531 | 1998-06-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2155014A1 ES2155014A1 (es) | 2001-04-16 |
| ES2155014B1 true ES2155014B1 (es) | 2001-12-01 |
Family
ID=26151881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES009900470A Expired - Fee Related ES2155014B1 (es) | 1998-03-09 | 1999-03-08 | Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion. |
Country Status (18)
| Country | Link |
|---|---|
| US (4) | US6353107B1 (es) |
| JP (1) | JP4651137B2 (es) |
| KR (1) | KR100581654B1 (es) |
| CN (1) | CN1171871C (es) |
| AT (1) | AT408655B (es) |
| AU (1) | AU754927B2 (es) |
| BE (1) | BE1012399A3 (es) |
| BR (1) | BR9900977B1 (es) |
| CA (1) | CA2264460A1 (es) |
| CH (1) | CH693416A5 (es) |
| CZ (1) | CZ78999A3 (es) |
| DE (1) | DE19909767B4 (es) |
| ES (1) | ES2155014B1 (es) |
| FR (1) | FR2777892B1 (es) |
| GB (1) | GB2335190B (es) |
| IT (1) | IT1309590B1 (es) |
| NL (1) | NL1011493C2 (es) |
| SG (1) | SG82601A1 (es) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH693416A5 (de) * | 1998-03-09 | 2003-07-31 | Ciba Sc Holding Ag | 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler. |
| AU759817B2 (en) * | 1998-07-31 | 2003-05-01 | Ciba Specialty Chemicals Holding Inc. | Open chain alkoxyamine compounds and their use as polymerization regulators |
| JP5000038B2 (ja) | 1998-10-06 | 2012-08-15 | トタル ペトロケミカルス フランス | 開始/制御剤の存在下でエチレンを高圧フリーラジカル重合または共重合する方法 |
| TWI225483B (en) | 1998-10-16 | 2004-12-21 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization process |
| AU6429300A (en) * | 1999-07-02 | 2001-01-22 | Ciba Specialty Chemicals Holding Inc. | Mono and multifunctional alkoxyamines for the preparation of functionalized macromers |
| TW546311B (en) * | 1999-11-25 | 2003-08-11 | Ciba Sc Holding Ag | Composition and method for color improvement of nitroxyl containing polymers |
| TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
| PT1282630E (pt) | 2000-05-19 | 2006-09-29 | Ciba Sc Holding Ag | Processo para reducao do peso molecular de polipropileno usando esteres de hidroxilamina. |
| TW572896B (en) * | 2000-05-26 | 2004-01-21 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| TWI225492B (en) † | 2000-09-25 | 2004-12-21 | Ciba Sc Holding Ag | Composition and process for enhancing controlled free radical polymerization |
| TW574236B (en) * | 2000-09-25 | 2004-02-01 | Ciba Sc Holding Ag | Process for controlled radical polymerization in aqueous dispersion |
| TWI236482B (en) * | 2000-11-13 | 2005-07-21 | Ciba Sc Holding Ag | Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical |
| TW557305B (en) * | 2000-12-14 | 2003-10-11 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith |
| TWI274053B (en) * | 2000-12-14 | 2007-02-21 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization |
| US6849679B2 (en) | 2001-05-21 | 2005-02-01 | Ciba Specialty Chemicals Corporation | Pigment compositions with modified block copolymer dispersants |
| EP1397349B1 (en) * | 2001-06-13 | 2010-12-15 | Basf Se | 4-imino-n-alkoxy or oxy-polyalkyl-piperidine compounds and their use as polymerization regulators |
| US7868171B2 (en) * | 2001-11-12 | 2011-01-11 | Ciba Specialty Chemicals Corp. | N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators |
| TW200407307A (en) * | 2001-11-26 | 2004-05-16 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| US7297819B2 (en) * | 2002-03-05 | 2007-11-20 | Ciba Specialty Chemicals Corp. | Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization |
| DE10212831A1 (de) * | 2002-03-22 | 2003-10-02 | Tesa Ag | Verfahren zur Herstellung copolymerer Polyacrylat-Haftklebemassen, damit erhaltene Nitroxid-modifizierte Polyacrylate und Kamm-Blockpolymere |
| CN1310972C (zh) * | 2002-05-01 | 2007-04-18 | 西巴特殊化学品控股有限公司 | Pvc聚合的链终止方法 |
| EP1375457A1 (en) | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | One-pot process for the preparation of functionalized alkoxyamines |
| EP1375476A1 (en) * | 2002-06-25 | 2004-01-02 | Bayer Aktiengesellschaft | A new process for the synthesis of alkoxyamines active in controlled radical polymerization |
| CA2514167A1 (en) * | 2003-02-10 | 2004-08-19 | Ciba Specialty Chemicals Holding Inc. | Comb copolymers with defined side chains and process for their manufacture |
| JP4107996B2 (ja) * | 2003-04-25 | 2008-06-25 | 大塚化学株式会社 | リビングラジカルポリマーの製造方法及びポリマー |
| JP4046678B2 (ja) * | 2003-10-15 | 2008-02-13 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ |
| KR20100009562A (ko) * | 2004-06-09 | 2010-01-27 | 히다치 가세고교 가부시끼가이샤 | 회로접속재료, 필름상 회로접속재, 및 회로부재의 접속 구조 |
| CN100577692C (zh) * | 2005-01-11 | 2010-01-06 | 西巴特殊化学品控股有限公司 | 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法 |
| JP4046734B2 (ja) | 2005-01-18 | 2008-02-13 | 横浜ゴム株式会社 | ポリマーの変性方法 |
| WO2006106048A1 (en) * | 2005-04-04 | 2006-10-12 | Ciba Specialty Chemicals Holding Inc. | Process for the preparation of star and block-copolymers via epoxy-functionalized alkoxyamines |
| RU2425057C2 (ru) * | 2005-08-30 | 2011-07-27 | Циба Спешиалти Кемикэлз Холдинг Инк. | Полимеры, полученные путем полимеризации под действием нитроксильных радикалов |
| CN101490620B (zh) * | 2006-07-11 | 2013-02-20 | 西巴控股有限公司 | 滤色器组合物 |
| US20080087380A1 (en) * | 2006-10-13 | 2008-04-17 | Dow Global Technologies Inc. | Reactively-coupled articles and related methods |
| EP2129363A2 (en) * | 2007-04-05 | 2009-12-09 | Basf Se | Sunscreen and personal care compositions comprising a select copolymer |
| WO2008145595A1 (en) * | 2007-06-01 | 2008-12-04 | Basf Se | Modified printable surfaces |
| EP2235146B1 (en) * | 2007-12-18 | 2016-04-20 | Basf Se | Biodiesel cold flow improver |
| CN102015911B (zh) | 2008-01-17 | 2015-11-25 | 巴斯夫欧洲公司 | 聚合毛发染料 |
| US9062209B2 (en) * | 2009-12-01 | 2015-06-23 | Silberline Manufacturing Company, Inc. | Polymer encapsulated aluminum particulates |
| KR101524342B1 (ko) | 2010-03-30 | 2015-07-06 | 바스프 에스이 | 말단-관능화 중합체 |
| WO2012000992A1 (en) | 2010-06-29 | 2012-01-05 | Basf Se | Process for improving the flow properties of polymer melts |
| US8815982B2 (en) | 2010-07-20 | 2014-08-26 | Silberline Manufacturing Company, Inc. | Colored system |
| US8912252B2 (en) | 2010-07-20 | 2014-12-16 | Silberline Manufacturing Company, Inc. | Film-forming pigments and coating system including the same |
| US9051478B2 (en) | 2010-07-22 | 2015-06-09 | Basf Se | Additive combination for sealants applications |
| US20140298591A1 (en) | 2011-10-25 | 2014-10-09 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| EP2817370B1 (en) | 2012-02-23 | 2020-08-19 | Basf Se | Fluorinated acrylate block copolymers with low dynamic surface tension |
| CN103073695B (zh) * | 2012-12-27 | 2015-03-11 | 中山大学 | 一种本征型室温自修复结晶性聚合物 |
| EP2978786A1 (en) | 2013-03-27 | 2016-02-03 | Basf Se | Block copolymers as soil release agents in laundry processes |
| WO2015004580A1 (en) | 2013-07-08 | 2015-01-15 | Basf Se | Novel light stabilizers |
| KR101595087B1 (ko) * | 2015-09-23 | 2016-02-18 | 주식회사 엘림산업 | 피혁용 버핑머신 구동롤러 |
| KR101595084B1 (ko) * | 2015-09-23 | 2016-02-29 | 주식회사 엘림산업 | 피혁용 버핑머신 |
| KR101635582B1 (ko) * | 2015-10-02 | 2016-07-20 | (주)이미인 | 원단 유연화 장치 |
| US11292906B2 (en) | 2017-10-23 | 2022-04-05 | Basf Se | Aqueous silicone polymer emulsion |
| CN116490535A (zh) | 2020-11-30 | 2023-07-25 | 巴斯夫欧洲公司 | 制备聚合物分散体的方法 |
| CN117062872A (zh) | 2021-03-26 | 2023-11-14 | 巴斯夫欧洲公司 | 作为分散剂的包含聚丙烯酸系嵌段共聚物和芳族基聚氧化烯的聚合物组合物 |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3503982A (en) * | 1966-08-24 | 1970-03-31 | Sankyo Co | 2,2-dimethyl-6,6 disubstituted-4-substituted aminopiperidine-1-oxides |
| JPS4940557B1 (es) * | 1969-03-06 | 1974-11-02 | ||
| US3975357A (en) | 1973-04-19 | 1976-08-17 | Sankyo Company Limited | Stabilized synthetic polymer compositions |
| GB1493996A (en) * | 1975-05-28 | 1977-12-07 | Sankyo Co | 4-siloxy derivatives of polyalkylated piperidines |
| GB1496844A (en) * | 1975-05-28 | 1978-01-05 | Ciba Geigy Ag | Stabilization of polymers |
| GB1492494A (en) * | 1975-05-28 | 1977-11-23 | Sankyo Co | Derivatives of 4-aminopiperidine |
| GB1478261A (en) * | 1975-05-28 | 1977-06-29 | Ciba Geigy Ag | Derivatives of 4-oxopiperidines |
| US4141883A (en) | 1975-05-28 | 1979-02-27 | Sankyo Company, Limited | Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives |
| JPS5848580B2 (ja) * | 1975-05-28 | 1983-10-29 | 三共株式会社 | ゴウセイコウブンシザイリヨウヨウアンテイザイ |
| US4581429A (en) * | 1983-07-11 | 1986-04-08 | Commonwealth Scientific And Industrial Research Organization | Polymerization process and polymers produced thereby |
| JPS6089452A (ja) * | 1983-07-11 | 1985-05-20 | コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン | 遊離基重合開始用化合物 |
| AU571240B2 (en) * | 1983-07-11 | 1988-04-14 | Commonwealth Scientific And Industrial Research Organisation | Alkoxy-amines, useful as initiators |
| EP0155912A3 (de) | 1984-03-20 | 1986-06-04 | Ciba-Geigy Ag | Strahlenstabilisierte polymere Zusammensetzungen |
| US5185448A (en) | 1991-05-07 | 1993-02-09 | Ciba-Geigy Corporation | Substituted 1-oxy-4-acyloxypiperidine and 1-oxy-4-acylaminopiperidine stabilizers |
| TW270131B (es) | 1993-07-13 | 1996-02-11 | Ciba Geigy | |
| EP0638617A1 (de) | 1993-08-13 | 1995-02-15 | Ciba-Geigy Ag | Pigmentsalze |
| US5608023A (en) | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
| TW358820B (en) | 1995-04-11 | 1999-05-21 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
| EP0792911A3 (en) | 1996-02-27 | 1998-01-14 | Fmc Corporation | Flame resistant polyolefin compositions |
| AU712769B2 (en) | 1996-03-29 | 1999-11-18 | Dow Chemical Company, The | In situ block copolymer formation during polymerization of a vinyl aromatic monomer |
| TW467931B (en) | 1996-08-22 | 2001-12-11 | Ciba Sc Holding Ag | Stabilizer mixtures |
| AU4773997A (en) * | 1996-09-25 | 1998-04-17 | Akzo Nobel N.V. | No-compounds for pseudo-living radical polymerization |
| EP0951485B1 (en) | 1997-01-10 | 2003-04-02 | E.I. Du Pont De Nemours And Company | Method of controlling polymer molecular weight and structure |
| US6281311B1 (en) | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| WO1999003894A1 (en) * | 1997-07-15 | 1999-01-28 | Ciba Specialty Chemicals Holding Inc. | Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds |
| SG74700A1 (en) | 1998-02-25 | 2000-08-22 | Ciba Sc Holding Ag | Preparation of sterically hindered amine ethers |
| TW495515B (en) * | 1998-03-09 | 2002-07-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives, a polymerizable composition containing the same and a process for polymerization |
| CH693416A5 (de) * | 1998-03-09 | 2003-07-31 | Ciba Sc Holding Ag | 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler. |
| DE69941028D1 (de) * | 1998-09-03 | 2009-08-06 | Ciba Holding Inc | Propfung von äthylenisch ungesättigten monomeren auf polymeren |
| TW541303B (en) * | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
-
1999
- 1999-03-02 CH CH00379/99A patent/CH693416A5/de not_active IP Right Cessation
- 1999-03-02 SG SG9901047A patent/SG82601A1/en unknown
- 1999-03-04 BE BE9900152A patent/BE1012399A3/fr not_active IP Right Cessation
- 1999-03-04 US US09/262,804 patent/US6353107B1/en not_active Expired - Lifetime
- 1999-03-05 DE DE1999109767 patent/DE19909767B4/de not_active Expired - Lifetime
- 1999-03-05 CZ CZ99789A patent/CZ78999A3/cs unknown
- 1999-03-05 IT IT1999MI000453A patent/IT1309590B1/it active
- 1999-03-05 CA CA002264460A patent/CA2264460A1/en not_active Abandoned
- 1999-03-08 AU AU18636/99A patent/AU754927B2/en not_active Ceased
- 1999-03-08 GB GB9905152A patent/GB2335190B/en not_active Expired - Lifetime
- 1999-03-08 AT AT0038799A patent/AT408655B/de not_active IP Right Cessation
- 1999-03-08 CN CNB991020987A patent/CN1171871C/zh not_active Expired - Lifetime
- 1999-03-08 FR FR9902814A patent/FR2777892B1/fr not_active Expired - Lifetime
- 1999-03-08 JP JP06019899A patent/JP4651137B2/ja not_active Expired - Lifetime
- 1999-03-08 ES ES009900470A patent/ES2155014B1/es not_active Expired - Fee Related
- 1999-03-09 NL NL1011493A patent/NL1011493C2/nl not_active IP Right Cessation
- 1999-03-09 KR KR1019990007738A patent/KR100581654B1/ko not_active Expired - Lifetime
- 1999-03-09 BR BRPI9900977-3B1A patent/BR9900977B1/pt active IP Right Grant
-
2001
- 2001-12-11 US US10/013,884 patent/US6683142B2/en not_active Expired - Lifetime
-
2003
- 2003-04-24 US US10/422,497 patent/US6927295B2/en not_active Expired - Lifetime
-
2005
- 2005-01-14 US US11/035,915 patent/US7402639B2/en not_active Expired - Fee Related
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2155014B1 (es) | Derivados de 1-alcoxi-polialquil-piperidina y su empleo como reguladores de polimerizacion. | |
| ES2170605B1 (es) | Nuevos fotoiniciadores de o-aciloximas. | |
| ES2185781T3 (es) | Cianofeniluracilos substituidos. | |
| ES2110667T3 (es) | N-cianoaril-heterociclos nitrogenados. | |
| ES2127859T3 (es) | Derivados de la 3-aril-4-hidroxi-3-dihidrofuranona. | |
| ES520272A0 (es) | Procedimiento para la obtencion de una composicion fotopolimerizable conteniendo al menos un monomero polimerizable etilinicamente insaturado. | |
| ES2189510T3 (es) | Producto de revestimiento consistente como minimo en tres componentes, procedimiento para su produccion y utilizacion del mismo. | |
| ES2172092T3 (es) | Asociacion de un retinoide con un polimero poliaminado. | |
| BR0110854A (pt) | ésteres de hidroxilamina como iniciadores de polimerização | |
| ES2183372T3 (es) | Procedimiento para la produccion de un laqueado multicapa y una laca acuosa. | |
| ES2173138T3 (es) | Composicion adhesiva antimicrobiana para uso dental. | |
| ES2094380T3 (es) | Nuevos pirazolilpirazoles sustituidos, procedimientos para su preparacion, asi como compuestos intermedios, y su uso como herbicidas. | |
| BR9000850A (pt) | Formulacao aclaradora estavel a armazenagem,processo para sua preparacao e aplicacao | |
| ES2154318T3 (es) | Agentes antitromboticos. | |
| BR0113153B1 (pt) | processo para a produção de uma dispersão de polìmero, dispersão de polìmero, e, uso da mesma. | |
| AR246664A1 (es) | Mezcla microbiocida efectiva en el control de hongos. | |
| BR9901393A (pt) | Dispositivos oculares produzidos com absorvedores de ultravioleta latente polimerizável por radicais livres | |
| ES2134777T3 (es) | Nuevos compuestos de sulfonilo. | |
| ES2072170T3 (es) | Cianoacrilatos resistentes termicamente que emplean un aditivo de naftosultona sustituido. | |
| CY1106081T1 (el) | Διepγασια για την παρασκευη παστας εξελασμενων συνθεσεων σουλφοναμιδης | |
| AR021150A1 (es) | Enaminonas ciclicas fenil-substituidas | |
| ES2054944T3 (es) | Bis-(tri-t-alquilfenoxi) difosfaespiroundecanos. | |
| ES2123811T3 (es) | Empleo de copolimeros reticulados de acidos carboxilicos monoetilenicamente insaturados como estabilizantes en emulsiones de aceite-en-agua. | |
| ES2114533T3 (es) | Herbicidas sinergicos. | |
| DE69918629D1 (de) | Radikalische Polymerisation in Gegenwart von mehreren stabilen, freien Radikalen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EC2A | Search report published |
Date of ref document: 20010416 Kind code of ref document: A1 Effective date: 20010416 |
|
| FD1A | Patent lapsed |
Effective date: 20100312 |