FR2806720B1 - Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants - Google Patents

Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants

Info

Publication number
FR2806720B1
FR2806720B1 FR0103797A FR0103797A FR2806720B1 FR 2806720 B1 FR2806720 B1 FR 2806720B1 FR 0103797 A FR0103797 A FR 0103797A FR 0103797 A FR0103797 A FR 0103797A FR 2806720 B1 FR2806720 B1 FR 2806720B1
Authority
FR
France
Prior art keywords
alcoxypiperidine
diethyl
oxides
dimethyl
derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0103797A
Other languages
English (en)
French (fr)
Other versions
FR2806720A1 (fr
Inventor
Peter Nesvadba
Marie Odile Zink
Andreas Kramer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of FR2806720A1 publication Critical patent/FR2806720A1/fr
Application granted granted Critical
Publication of FR2806720B1 publication Critical patent/FR2806720B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94Oxygen atom, e.g. piperidine N-oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/02Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Pyridine Compounds (AREA)
FR0103797A 2000-03-22 2001-03-21 Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants Expired - Fee Related FR2806720B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22

Publications (2)

Publication Number Publication Date
FR2806720A1 FR2806720A1 (fr) 2001-09-28
FR2806720B1 true FR2806720B1 (fr) 2006-12-08

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0103797A Expired - Fee Related FR2806720B1 (fr) 2000-03-22 2001-03-21 Derives de 2,2,6,6-diethyl-dimethyl-1-alcoxypiperidines et 1-oxydes correspondants

Country Status (16)

Country Link
US (3) US6624306B2 (enExample)
JP (1) JP2001316365A (enExample)
KR (1) KR100743975B1 (enExample)
CN (1) CN1319590A (enExample)
AU (1) AU784894B2 (enExample)
BE (1) BE1014058A5 (enExample)
BR (1) BR0101108A (enExample)
CA (1) CA2341791C (enExample)
DE (1) DE10113209A1 (enExample)
ES (1) ES2173046B1 (enExample)
FR (1) FR2806720B1 (enExample)
GB (1) GB2361235B (enExample)
IT (1) ITMI20010546A1 (enExample)
NL (1) NL1017635C2 (enExample)
NO (1) NO20011436L (enExample)
TW (1) TW541303B (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
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SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
CN1249035C (zh) * 2001-06-13 2006-04-05 西巴特殊化学品控股有限公司 4-亚氨基-n-烷氧基或氧基-多烷基-哌啶化合物以及它们作为聚合调节剂的用途
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
ATE439401T1 (de) * 2001-12-21 2009-08-15 Basf Se Neue flammhemmer
JP4189815B2 (ja) 2002-01-22 2008-12-03 アルケマ フランス ニトロオキシド存在下の制御されたラジカル重合で得られるブロック共重合体を含む耐衝撃性に優れた材料の製造方法および使用
JP4602671B2 (ja) * 2002-03-05 2010-12-22 チバ ホールディング インコーポレーテッド 制御された低温ラジカル重合のための開鎖アルコキシアミン及びそれらの相当するニトロキシド。
WO2005032479A2 (en) * 2003-10-01 2005-04-14 Unviversity Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
US20070078197A1 (en) * 2003-10-07 2007-04-05 Coloplast A/S Adhesive composition and use of such composition
KR101246639B1 (ko) * 2004-05-27 2013-03-25 시바 홀딩 인크 방사상 중합성 그룹을 함유하는 알콕시아민
EP1861429B1 (en) 2005-01-11 2013-03-13 Basf Se Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes
US20080280890A1 (en) * 2007-02-22 2008-11-13 Ghanshyam Patil Hydroxylamine compounds and methods of their use
CN101677937A (zh) * 2007-04-05 2010-03-24 巴斯夫欧洲公司 包含所选共聚物的防晒剂和个人护理组合物
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
US8664324B2 (en) 2008-06-23 2014-03-04 Basf Se Pigment dispersants with modified copolymers
EP2450400A3 (de) * 2008-08-28 2012-08-08 Basf Se Stabilisatoren für unbelebte organische materialien
CN102822211B (zh) 2010-03-30 2015-04-22 巴斯夫欧洲公司 端基官能化聚合物
JP4821916B1 (ja) 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
CN102958993B (zh) 2010-06-29 2015-07-22 巴斯夫欧洲公司 改善聚合物熔体的流动性能的方法
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
WO2013124421A1 (en) 2012-02-23 2013-08-29 Basf Se Fluorinated acrylate block copolymers with low dynamic surface tension
EP2978786A1 (en) 2013-03-27 2016-02-03 Basf Se Block copolymers as soil release agents in laundry processes
WO2019081277A1 (en) 2017-10-23 2019-05-02 Basf Se AQUEOUS SILICONE POLYMER EMULSION
CN117062872A (zh) 2021-03-26 2023-11-14 巴斯夫欧洲公司 作为分散剂的包含聚丙烯酸系嵌段共聚物和芳族基聚氧化烯的聚合物组合物
CN120271495B (zh) * 2025-06-12 2025-09-19 成都道合尔医药技术有限公司 一种(3r,4r)-n-pg-4-氨基-3-甲基哌啶的合成方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5848580B2 (ja) * 1975-05-28 1983-10-29 三共株式会社 ゴウセイコウブンシザイリヨウヨウアンテイザイ
US4141883A (en) * 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
GB1492494A (en) * 1975-05-28 1977-11-23 Sankyo Co Derivatives of 4-aminopiperidine
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
KR930000892B1 (ko) 1983-07-11 1993-02-11 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス サイエンテイフイツク アンド インダストリアル リサ−チ オ−ガニゼ−シヨン 遊離基重合開始用化合物
AU4773997A (en) 1996-09-25 1998-04-17 Akzo Nobel N.V. No-compounds for pseudo-living radical polymerization
EP0951485B1 (en) 1997-01-10 2003-04-02 E.I. Du Pont De Nemours And Company Method of controlling polymer molecular weight and structure
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
AU8440798A (en) 1997-07-15 1999-02-10 Ciba Specialty Chemicals Holding Inc. Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI246519B (en) * 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd (メタ)アクリル酸ピペリジン−1−オキシルエステル誘導体からなる(メタ)アクリル酸エステル用重合防止剤およびその製造方法
CA2341372A1 (en) 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
JP4829447B2 (ja) 1999-07-02 2011-12-07 チバ ホールディング インコーポレーテッド 官能化されたマクロマーの製造のための1および多官能価アルコキシアミン

Also Published As

Publication number Publication date
CN1319590A (zh) 2001-10-31
BE1014058A5 (fr) 2003-03-04
CA2341791A1 (en) 2001-09-22
US20050143539A1 (en) 2005-06-30
ES2173046B1 (es) 2004-06-16
NL1017635C2 (nl) 2001-09-25
TW541303B (en) 2003-07-11
US20030065184A1 (en) 2003-04-03
JP2001316365A (ja) 2001-11-13
GB2361235A (en) 2001-10-17
FR2806720A1 (fr) 2001-09-28
AU2804901A (en) 2001-09-27
US6624306B2 (en) 2003-09-23
BR0101108A (pt) 2001-11-06
US7160966B2 (en) 2007-01-09
US6891008B2 (en) 2005-05-10
DE10113209A1 (de) 2001-09-27
ES2173046A1 (es) 2002-10-01
GB0105678D0 (en) 2001-04-25
AU784894B2 (en) 2006-07-20
US20030166939A1 (en) 2003-09-04
CA2341791C (en) 2010-02-23
ITMI20010546A1 (it) 2002-09-15
NO20011436L (no) 2001-09-24
NO20011436D0 (no) 2001-03-21
KR100743975B1 (ko) 2007-07-30
KR20010092697A (ko) 2001-10-26
GB2361235B (en) 2002-06-12

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Effective date: 20111130