CA2341791C - 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides - Google Patents

2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides Download PDF

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Publication number
CA2341791C
CA2341791C CA2341791A CA2341791A CA2341791C CA 2341791 C CA2341791 C CA 2341791C CA 2341791 A CA2341791 A CA 2341791A CA 2341791 A CA2341791 A CA 2341791A CA 2341791 C CA2341791 C CA 2341791C
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CA
Canada
Prior art keywords
phenyl
diethyl
ethoxy
piperidin
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2341791A
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English (en)
French (fr)
Other versions
CA2341791A1 (en
Inventor
Peter Nesvadba
Marie-Odile Zink
Andreas Kramer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
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Filing date
Publication date
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Publication of CA2341791A1 publication Critical patent/CA2341791A1/en
Application granted granted Critical
Publication of CA2341791C publication Critical patent/CA2341791C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Pyridine Compounds (AREA)
CA2341791A 2000-03-22 2001-03-20 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides Expired - Fee Related CA2341791C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE00810246.9 2000-03-22
EP00810246 2000-03-22

Publications (2)

Publication Number Publication Date
CA2341791A1 CA2341791A1 (en) 2001-09-22
CA2341791C true CA2341791C (en) 2010-02-23

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2341791A Expired - Fee Related CA2341791C (en) 2000-03-22 2001-03-20 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides

Country Status (16)

Country Link
US (3) US6624306B2 (enExample)
JP (1) JP2001316365A (enExample)
KR (1) KR100743975B1 (enExample)
CN (1) CN1319590A (enExample)
AU (1) AU784894B2 (enExample)
BE (1) BE1014058A5 (enExample)
BR (1) BR0101108A (enExample)
CA (1) CA2341791C (enExample)
DE (1) DE10113209A1 (enExample)
ES (1) ES2173046B1 (enExample)
FR (1) FR2806720B1 (enExample)
GB (1) GB2361235B (enExample)
IT (1) ITMI20010546A1 (enExample)
NL (1) NL1017635C2 (enExample)
NO (1) NO20011436L (enExample)
TW (1) TW541303B (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
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CH693416A5 (de) * 1998-03-09 2003-07-31 Ciba Sc Holding Ag 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler.
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
CN1249035C (zh) * 2001-06-13 2006-04-05 西巴特殊化学品控股有限公司 4－亚氨基－n－烷氧基或氧基－多烷基－哌啶化合物以及它们作为聚合调节剂的用途
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
KR101029863B1 (ko) * 2001-12-21 2011-04-18 시바 홀딩 인코포레이티드 신규한 난연제 화합물
CN100455614C (zh) * 2002-01-22 2009-01-28 阿托菲纳公司 抗冲击性增强且含有在氮氧化物存在下由受控的自由基聚合获得的嵌段共聚物材料的生产和使用方法
EP1481012B1 (en) * 2002-03-05 2006-05-17 Ciba SC Holding AG Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
US7531555B2 (en) * 2003-10-01 2009-05-12 University Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
EP1675629A1 (en) * 2003-10-07 2006-07-05 Coloplast A/S An adhesive composition and use of such composition
EP1749032B1 (en) * 2004-05-27 2008-02-27 Ciba Specialty Chemicals Holding Inc. Alkoxyamines containing a radically polymerizable group
CN100577692C (zh) 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
CN103497148B (zh) * 2007-02-22 2016-06-01 科尔比制药公司 羟胺化合物及其用法
WO2008122516A2 (en) * 2007-04-05 2008-10-16 Basf Se Sunscreen and personal care compositions comprising a select copolymer
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
EP2291422B1 (en) 2008-06-23 2015-10-21 Basf Se Pigment dispersants with modified copolymers
JP5377647B2 (ja) * 2008-08-28 2013-12-25 ビーエーエスエフ ソシエタス・ヨーロピア 無生物有機材料のための安定剤
WO2011120947A1 (en) 2010-03-30 2011-10-06 Basf Se End-functionalized polymers
JP4821916B1 (ja) * 2010-05-07 2011-11-24 横浜ゴム株式会社 変性ポリマーの製造法
CN102958993B (zh) 2010-06-29 2015-07-22 巴斯夫欧洲公司 改善聚合物熔体的流动性能的方法
RU2014120925A (ru) 2011-10-25 2015-12-10 Басф Се Применение гребенчатых или блок-сополимеров в качестве средств против повторного осаждения загрязнения и грязеотталкивающих средств в процессах стирки
US9587105B2 (en) 2012-02-23 2017-03-07 Basf Se Fluorinated acrylate block copolymers with low dynamic surface tension
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
CN111278934B (zh) 2017-10-23 2022-04-12 巴斯夫欧洲公司 硅氧烷聚合物水乳液
WO2022200398A1 (en) 2021-03-26 2022-09-29 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant
CN120271495B (zh) * 2025-06-12 2025-09-19 成都道合尔医药技术有限公司 一种(3r,4r)-n-pg-4-氨基-3-甲基哌啶的合成方法

Family Cites Families (15)

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US4141883A (en) 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
GB1492494A (en) 1975-05-28 1977-11-23 Sankyo Co Derivatives of 4-aminopiperidine
JPS5848580B2 (ja) * 1975-05-28 1983-10-29 三共株式会社 ゴウセイコウブンシザイリヨウヨウアンテイザイ
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス　サイエンテイフイツク　アンド　インダストリアル　リサ−チ　オ−ガニゼ−シヨン 遊離基重合開始用化合物
KR930000892B1 (ko) 1983-07-11 1993-02-11 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법
DE69708896T2 (de) 1996-09-25 2002-06-20 Akzo Nobel N.V., Arnheim/Arnhem Nitroso verbindungen zur pseudo-lebenden radikalpolymerisation
JP2001508485A (ja) 1997-01-10 2001-06-26 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ポリマーの分子量および構造の制御方法
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TWI246519B (en) * 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
JP2000072718A (ja) * 1998-09-01 2000-03-07 Mitsubishi Rayon Co Ltd （メタ）アクリル酸ピペリジン−１−オキシルエステル誘導体からなる（メタ）アクリル酸エステル用重合防止剤およびその製造方法
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Also Published As

Publication number Publication date
KR100743975B1 (ko) 2007-07-30
US20030065184A1 (en) 2003-04-03
BR0101108A (pt) 2001-11-06
GB0105678D0 (en) 2001-04-25
ITMI20010546A1 (it) 2002-09-15
FR2806720B1 (fr) 2006-12-08
DE10113209A1 (de) 2001-09-27
NO20011436D0 (no) 2001-03-21
FR2806720A1 (fr) 2001-09-28
AU2804901A (en) 2001-09-27
US20030166939A1 (en) 2003-09-04
JP2001316365A (ja) 2001-11-13
US6891008B2 (en) 2005-05-10
ES2173046B1 (es) 2004-06-16
GB2361235A (en) 2001-10-17
US7160966B2 (en) 2007-01-09
BE1014058A5 (fr) 2003-03-04
KR20010092697A (ko) 2001-10-26
GB2361235B (en) 2002-06-12
US6624306B2 (en) 2003-09-23
NO20011436L (no) 2001-09-24
CA2341791A1 (en) 2001-09-22
CN1319590A (zh) 2001-10-31
ES2173046A1 (es) 2002-10-01
AU784894B2 (en) 2006-07-20
NL1017635C2 (nl) 2001-09-25
TW541303B (en) 2003-07-11
US20050143539A1 (en) 2005-06-30

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