MXPA04004764A - Proceso y sistemas de epoxidacion de olefinas. - Google Patents
Proceso y sistemas de epoxidacion de olefinas.Info
- Publication number
- MXPA04004764A MXPA04004764A MXPA04004764A MXPA04004764A MXPA04004764A MX PA04004764 A MXPA04004764 A MX PA04004764A MX PA04004764 A MXPA04004764 A MX PA04004764A MX PA04004764 A MXPA04004764 A MX PA04004764A MX PA04004764 A MXPA04004764 A MX PA04004764A
- Authority
- MX
- Mexico
- Prior art keywords
- olefin
- epoxidation
- value
- reaction
- feed
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un proceso de epoxidacion de olefinas, que incluye la reaccion de una fuente con olefinas con oxigeno y un modificador de reaccion en presencia de un catalizador de plata altamente selectivo a una temperatura de reaccion T, en degree C, y con un modificador de reaccion presente en cantidades relativas Q que es la relacion entre la cantidad molar efectiva de especies activas del modificador de reaccion presente en la fuente con una cantidad molar efectiva de hidrocarburos presente en la fuente. Las etapas del proceso son las siguientes:- funcionamiento en una primera fase operativa en la que el valor de T es T1 y el valor de Q es Q1 y- subsecuentemente funcionando en una segunda fase operativa a una temperatura de reaccion distinta a la de la primera fase, de tal modo que el valor de T es T2 y el valor de Q es Q2, en donde Q2 se determina por medio de calculos y Q2 se obtiene la siguiente formula: Q2 = Q1 + B (T2 - T1), En la que B es un factor constante, en (??C)-1, que es mayor que 0; un sistema de reaccion adecuado para preparar el proceso de la epoxidacion de una olefina; un producto de un programa informatico que incluye un codigo de programa de lectura informatico, registrado en el medio de lectura informatico, adecuado para instruir al sistema reprocesamiento de datos para la realizacion de los calculos relacionados con el proceso de la epoxidacion de una olefina; y un sistema de informatica que incluye un producto de informatica y un sistema de procesamientos de datos.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US33182801P | 2001-11-20 | 2001-11-20 | |
US33187401P | 2001-11-20 | 2001-11-20 | |
PCT/US2002/037026 WO2003044003A1 (en) | 2001-11-20 | 2002-11-19 | A process and systems for the epoxidation of an olefin |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA04004764A true MXPA04004764A (es) | 2004-07-30 |
Family
ID=26987943
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA04004764A MXPA04004764A (es) | 2001-11-20 | 2002-11-19 | Proceso y sistemas de epoxidacion de olefinas. |
MXPA04004639A MXPA04004639A (es) | 2001-11-20 | 2002-11-19 | Proceso y sistema para la epoxidacion de una olefina. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA04004639A MXPA04004639A (es) | 2001-11-20 | 2002-11-19 | Proceso y sistema para la epoxidacion de una olefina. |
Country Status (14)
Country | Link |
---|---|
EP (2) | EP1458698B1 (es) |
JP (2) | JP4516313B2 (es) |
KR (2) | KR100977098B1 (es) |
CN (2) | CN100358879C (es) |
AT (2) | ATE309232T1 (es) |
AU (2) | AU2002356973B2 (es) |
BR (2) | BR0214282A (es) |
CA (2) | CA2467574C (es) |
DE (2) | DE60207299T2 (es) |
ES (2) | ES2252552T3 (es) |
MX (2) | MXPA04004764A (es) |
RU (2) | RU2294327C2 (es) |
TW (1) | TWI332950B (es) |
WO (2) | WO2003044003A1 (es) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7193094B2 (en) | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
RU2328491C2 (ru) | 2003-04-01 | 2008-07-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ эпоксидирования олефинов и катализатор для применения в способе |
CA2540563C (en) | 2003-09-29 | 2013-01-08 | Union Carbide Chemicals & Plastics Technology Corporation | A process for the production of alkylene oxide using a gas-phase promoter system |
CA2541992C (en) | 2003-10-16 | 2013-07-09 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production |
EP1786797B1 (en) * | 2004-08-12 | 2014-11-26 | Velocys, Inc. | Process for converting ethylene to ethylene oxide using microchannel process technology |
KR20080090385A (ko) * | 2005-10-10 | 2008-10-08 | 페어스톡 테크놀로지스 코포레이션 | 액화된 금속 합금을 이용한 유기 화합물의 전환 방법 및관련 장치 |
CN101448804A (zh) * | 2006-04-21 | 2009-06-03 | 巴斯夫欧洲公司 | 在微通道反应器中制备环氧乙烷的方法 |
US7977274B2 (en) | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
WO2008120639A1 (ja) * | 2007-03-30 | 2008-10-09 | Nippon Shokubai Co., Ltd. | エチレンオキシドの製造方法 |
WO2008141030A1 (en) | 2007-05-09 | 2008-11-20 | Shell Oil Company | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
US7803957B2 (en) * | 2007-09-11 | 2010-09-28 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
JP5194727B2 (ja) * | 2007-11-12 | 2013-05-08 | 三菱化学株式会社 | オレフィンオキシドの連続製造方法 |
DE102008011767B4 (de) | 2008-02-28 | 2012-07-26 | Basf Se | Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen |
DE102008014910A1 (de) | 2008-03-19 | 2009-09-24 | Basf Se | Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung |
CA2730550A1 (en) * | 2008-07-14 | 2010-01-21 | Velocys Inc. | Process for making ethylene oxide using microchannel process technology |
US8933254B2 (en) | 2008-07-14 | 2015-01-13 | Basf Se | Process for making ethylene oxide |
WO2010123844A1 (en) | 2009-04-21 | 2010-10-28 | Dow Technology Investments Llc | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
CN102414187B (zh) * | 2009-04-21 | 2016-06-01 | 陶氏技术投资有限公司 | 采用催化剂随其老化而制备环氧烷的方法 |
WO2010123856A1 (en) * | 2009-04-21 | 2010-10-28 | Dow Technology Investments Llc | Epoxidation reactions and operating conditions thereof |
US8524927B2 (en) | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
JP2012522061A (ja) | 2009-12-28 | 2012-09-20 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | アルキレンオキサイドの製造における銀触媒上への塩化銀の生成の制御方法 |
RU2581365C2 (ru) | 2010-09-29 | 2016-04-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения этиленоксида с улучшенным регулированием |
US8742147B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
US8742146B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
CA2818525C (en) | 2010-12-10 | 2019-02-26 | Dow Technology Investments Llc | Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
CN103261178B (zh) | 2010-12-15 | 2016-11-09 | 陶氏技术投资有限责任公司 | 使用高效催化剂生产环氧烷的工艺的启动方法 |
KR102027597B1 (ko) * | 2011-04-29 | 2019-10-01 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | Eo 촉매의 선택성 개선 방법 |
BR112014009339A2 (pt) * | 2011-10-18 | 2017-04-18 | S Padia Ashok | processo de epoxidação com adição de moderador |
US9181207B2 (en) | 2011-12-09 | 2015-11-10 | Dow Technology Investments Llc | Method of reducing or maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
EP2920159B1 (en) | 2012-12-31 | 2020-02-12 | Scientific Design Company Inc. | Start-up process for high selectivity ethylene oxide catalysts |
CN105143161B (zh) | 2013-03-15 | 2018-08-10 | 陶氏技术投资有限责任公司 | 用于制造环氧乙烷的方法 |
WO2015100209A1 (en) * | 2013-12-23 | 2015-07-02 | Scientific Design Company, Inc. | Epoxidation process |
CN105233824B (zh) * | 2015-11-05 | 2018-02-06 | 中国海洋石油总公司 | 一种高选择性乙烯氧化制环氧乙烷银催化剂及其使用方法 |
CN114057669B (zh) * | 2020-07-29 | 2023-12-08 | 中国石油化工股份有限公司 | 一种乙烯环氧化恒温开车方法 |
TW202239752A (zh) | 2020-12-29 | 2022-10-16 | 荷蘭商蜆殼國際研究所 | 用於生產環氧乙烷之製程 |
CA3214971A1 (en) | 2021-04-08 | 2022-10-13 | Shell Internationale Research Maatschappij B.V. | Moderator and catalyst performance optimization for epoxidation of ethylene |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1339317C (en) * | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
AU656537B2 (en) * | 1990-10-12 | 1995-02-09 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or stability |
US5262551A (en) | 1992-04-20 | 1993-11-16 | Texaco Chemical Company | Process for ethylene expoxidation |
US5908942A (en) * | 1995-09-15 | 1999-06-01 | Eastman Chemical Company | Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions |
US5625084A (en) * | 1996-01-31 | 1997-04-29 | Arco Chemical Technology, L.P. | Vapor phase oxidation of propylene to propylene oxide |
US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
CN1286689A (zh) * | 1997-12-24 | 2001-03-07 | 出光兴产株式会社 | 三酮衍生物 |
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2002
- 2002-11-19 MX MXPA04004764A patent/MXPA04004764A/es active IP Right Grant
- 2002-11-19 WO PCT/US2002/037026 patent/WO2003044003A1/en active IP Right Grant
- 2002-11-19 BR BR0214282-1A patent/BR0214282A/pt not_active Application Discontinuation
- 2002-11-19 EP EP02803665A patent/EP1458698B1/en not_active Revoked
- 2002-11-19 BR BR0214251-1A patent/BR0214251A/pt not_active Application Discontinuation
- 2002-11-19 AT AT02803666T patent/ATE309232T1/de not_active IP Right Cessation
- 2002-11-19 DE DE60207299T patent/DE60207299T2/de not_active Expired - Lifetime
- 2002-11-19 MX MXPA04004639A patent/MXPA04004639A/es active IP Right Grant
- 2002-11-19 CN CNB028230590A patent/CN100358879C/zh not_active Expired - Fee Related
- 2002-11-19 JP JP2003545640A patent/JP4516313B2/ja not_active Expired - Fee Related
- 2002-11-19 CN CNB028243943A patent/CN100358880C/zh not_active Expired - Fee Related
- 2002-11-19 WO PCT/US2002/037022 patent/WO2003044002A1/en active IP Right Grant
- 2002-11-19 CA CA2467574A patent/CA2467574C/en not_active Expired - Fee Related
- 2002-11-19 EP EP02803666A patent/EP1458699B1/en not_active Revoked
- 2002-11-19 DE DE60203822T patent/DE60203822T2/de not_active Expired - Lifetime
- 2002-11-19 AT AT02803665T patent/ATE293612T1/de not_active IP Right Cessation
- 2002-11-19 CA CA2472017A patent/CA2472017C/en not_active Expired - Fee Related
- 2002-11-19 ES ES02803666T patent/ES2252552T3/es not_active Expired - Lifetime
- 2002-11-19 AU AU2002356973A patent/AU2002356973B2/en not_active Ceased
- 2002-11-19 ES ES02803665T patent/ES2240852T3/es not_active Expired - Lifetime
- 2002-11-19 JP JP2003545639A patent/JP4516751B2/ja not_active Expired - Fee Related
- 2002-11-19 KR KR1020047007572A patent/KR100977098B1/ko not_active IP Right Cessation
- 2002-11-19 AU AU2002356974A patent/AU2002356974B2/en not_active Ceased
- 2002-11-19 RU RU2004118491/04A patent/RU2294327C2/ru not_active IP Right Cessation
- 2002-11-19 KR KR1020047007573A patent/KR100977097B1/ko not_active IP Right Cessation
- 2002-11-19 RU RU2004118669/04A patent/RU2296126C2/ru not_active IP Right Cessation
- 2002-11-20 TW TW091133824A patent/TWI332950B/zh not_active IP Right Cessation
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