DE60305715D1 - Katalysatorsysteme für die ethylen-oligomerisierung zu linearen alpha-olefinen - Google Patents

Katalysatorsysteme für die ethylen-oligomerisierung zu linearen alpha-olefinen

Info

Publication number
DE60305715D1
DE60305715D1 DE60305715T DE60305715T DE60305715D1 DE 60305715 D1 DE60305715 D1 DE 60305715D1 DE 60305715 T DE60305715 T DE 60305715T DE 60305715 T DE60305715 T DE 60305715T DE 60305715 D1 DE60305715 D1 DE 60305715D1
Authority
DE
Germany
Prior art keywords
sub
catalyst systems
linear alpha
ethylene oligomerisation
alpha olefines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60305715T
Other languages
English (en)
Other versions
DE60305715T2 (de
Inventor
Boer Johannes De
Boer-Wildschut Marijke De
Der Heijden Harry Van
Zon Arie Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of DE60305715D1 publication Critical patent/DE60305715D1/de
Publication of DE60305715T2 publication Critical patent/DE60305715T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B01J2531/0294—"Non-innocent" or "non-spectator" ligands, i.e. ligands described as, or evidently, taking part in the catalytic reaction beyond merely stabilizing the central metal as spectator or ancilliary ligands, e.g. by electron transfer to or from the central metal or by intra-/intermolecular chemical reactions, e.g. disulfide coupling, H-abstraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B01J2531/0297—Non-coordinating anions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE60305715T 2002-09-25 2003-09-23 Katalysatorsysteme für die ethylen-oligomerisierung zu linearen alpha-olefinen Expired - Fee Related DE60305715T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP02256666 2002-09-25
EP02256666 2002-09-25
PCT/EP2003/010708 WO2004037415A2 (en) 2002-09-25 2003-09-23 Catalyst systems for ethylene oligomerisation to linear alpha olefins

Publications (2)

Publication Number Publication Date
DE60305715D1 true DE60305715D1 (de) 2006-07-06
DE60305715T2 DE60305715T2 (de) 2007-05-31

Family

ID=32116321

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60305715T Expired - Fee Related DE60305715T2 (de) 2002-09-25 2003-09-23 Katalysatorsysteme für die ethylen-oligomerisierung zu linearen alpha-olefinen

Country Status (12)

Country Link
US (1) US7053020B2 (de)
EP (1) EP1542797B1 (de)
JP (1) JP2006501067A (de)
CN (1) CN100371075C (de)
AT (1) ATE327826T1 (de)
AU (1) AU2003293320A1 (de)
CA (1) CA2499844A1 (de)
DE (1) DE60305715T2 (de)
ES (1) ES2260678T3 (de)
RU (1) RU2315658C2 (de)
WO (1) WO2004037415A2 (de)
ZA (1) ZA200502081B (de)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6559091B1 (en) * 1999-02-22 2003-05-06 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
DE50001649D1 (de) * 1999-08-20 2003-05-08 Basf Ag Bisimidinoverbindungen und ihre übergangsmetallkomplexe sowie deren verwendung als katalysatoren
US6710006B2 (en) * 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
US7037988B2 (en) * 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
ATE344268T1 (de) * 2001-08-01 2006-11-15 Shell Int Research Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen
CA2499887C (en) * 2002-09-25 2011-08-16 Shell Internationale Research Maatschappij B.V. Process for making a linear alpha-olefin oligomer using a heat exchanger
ES2260678T3 (es) 2002-09-25 2006-11-01 Shell Internationale Research Maatschappij B.V. Sistema cataliticos para la oligomerizacion de etileno a alfa-olefinas lineales.
CN1684930A (zh) * 2002-09-25 2005-10-19 国际壳牌研究有限公司 使用换热器制备直链α－烯烃低聚物的方法
US20050014983A1 (en) * 2003-07-07 2005-01-20 De Boer Eric Johannes Maria Process for producing linear alpha olefins
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
ATE388158T1 (de) * 2004-03-24 2008-03-15 Shell Int Research Übergangsmetallkomplexe
AR049714A1 (es) * 2004-07-13 2006-08-30 Shell Int Research Proceso de preparacion de alfa olefinas lineales
US7727926B2 (en) * 2005-07-21 2010-06-01 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
US7268096B2 (en) * 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7271121B2 (en) * 2005-07-21 2007-09-18 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
DE102006001959A1 (de) * 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
US7378537B2 (en) * 2006-07-25 2008-05-27 Chevron Phillips Chemical Company Lp Olefin oligomerization catalysts and methods of using same
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
US8415443B2 (en) 2009-07-10 2013-04-09 Momentive Performance Materials Inc. Hydrosilylation catalysts
US8236915B2 (en) 2009-07-10 2012-08-07 Momentive Performance Materials Inc. Hydrosilylation catalysts
US20130012659A1 (en) 2010-03-29 2013-01-10 E I Dupont De Nemours And Company Lubricant component
US8765987B2 (en) 2010-11-24 2014-07-01 Cornell University In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US9586872B2 (en) * 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US8927674B2 (en) 2012-08-16 2015-01-06 Princeton University Dehydrogenative silylation and crosslinking using cobalt catalysts
ITMI20122206A1 (it) * 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-immino-piridinico di cobalto
WO2014182670A2 (en) 2013-05-06 2014-11-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
EP2996804B1 (de) 2013-05-15 2020-12-30 Momentive Performance Materials Inc. Aktivierung von metallsalzen mit silylhydriden und deren verwendung in hydrosilylierungsreaktionen
WO2015023328A1 (en) 2013-08-14 2015-02-19 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine dimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US10112961B2 (en) 2013-11-19 2018-10-30 The Trustees Of Princeton University Hydroboration and borylation with cobalt catalysts
CN106414469A (zh) 2013-11-19 2017-02-15 莫门蒂夫性能材料股份有限公司 使用钴催化剂的脱氢硅烷化、氢化硅烷化和交联
EP3071585B1 (de) 2013-11-19 2018-11-07 Momentive Performance Materials Inc. Kobaltkatalysatoren und deren verwendung zur hydrosilylierung und dehydrogenativen silylierung
US9387468B2 (en) 2013-11-19 2016-07-12 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
CN108026126B (zh) * 2015-07-24 2021-04-20 莫门蒂夫性能材料股份有限公司 使用吡啶二亚胺羧酸钴催化剂的脱氢硅烷化、氢化硅烷化和交联
US9944661B2 (en) 2016-08-09 2018-04-17 Chevron Phillips Chemical Company Lp Olefin hydroboration
CN106632764B (zh) * 2016-10-17 2018-10-26 曲阜师范大学 一种铁系催化剂及其制备方法及在异戊二烯聚合中的应用
US10604457B2 (en) 2016-12-29 2020-03-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
US10407360B2 (en) 2017-12-22 2019-09-10 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
US20180186708A1 (en) 2016-12-29 2018-07-05 Chevron Phillips Chemical Company Lp Ethylene Oligomerization Processes
EP3562584B1 (de) 2016-12-30 2021-04-07 SABIC Global Technologies B.V. Verfahren zur herstellung einer katalysatorlösung zur selektiven 1-hexen-herstellung
JP7402003B2 (ja) * 2018-09-28 2023-12-20 日本ポリケム株式会社 オレフィン重合用触媒
CN111408410B (zh) * 2019-01-04 2023-03-24 中国石油化工股份有限公司 一种催化剂组合物、其制备方法及其在乙烯选择性二聚化合成1-丁烯的反应中的应用
RU2704263C1 (ru) * 2019-07-25 2019-10-25 Федеральное государственное бюджетное учреждение науки Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) Компонент катализатора для полимеризации этилена в высоколинейный полиэтилен, катализатор и способ его приготовления
AR124325A1 (es) * 2020-12-15 2023-03-15 Shell Int Research UN PROCESO PARA PRODUCIR a-OLEFINAS

Family Cites Families (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU418462A1 (ru) 1971-08-16 1974-03-05 СПОСОБ ПОЛУЧЕНИЯ СМЕСИ ОЛЕФИНОВ С^—С^1Изобретение относитс к способу получени смеси олефинов С4—Се с преобладанием альфа-изомеров, которые наход т широкое применение в качестве мономеров и промежуточных продуктов при синтезе пластмасс и кау- чуков.Известен способ получени смеси олефииов С4—Сб содимеризацией этилена с пропиленом при температуре 100—160°С и давлении 40 атм в присутствии триалкилалюмини , например триэтилалюмини или диэтилалюми- нийхлорида, и соединени переходного металла, например хлорида никел или его окиси.К недостаткам известного способа относ тс низкий выход альфа-олефинов и недостаточно высока степень конверсии пропилена.С целью повышени выхода альфа-олефинов предлагаетс в качестве соединени переходного .металла использовать пальмитат никел .Пример. 250 мл (180 г) катализатора, состо щего из 3%-ного раствора триэтилалю-5 мини в н-декапе и пальмитата никел (А1 : N1 = 500 : 1), помещают в предварительно освобожденный от влаги и кислорода автоклав емкостью 2 л, снабженный магнитной мешалкой (1400 об/мин). Затем подают 235 г10 пропилена (чистота 99,5%) и 157 г этилена (чистота 99,8%). Мольное соотношение 1:1. Нагревают до нужной температуры и перемешивают 20 час. Вместе с альфа-олефинами С4—Сб образуетс небольшое количество аль-15 фа-олефинов Cs—Сэ
US4728583A (en) 1984-08-31 1988-03-01 Fuji Photo Film Co., Ltd. Radiation image storage panel and process for the preparation of the same
DE3762689D1 (de) 1986-01-21 1990-06-13 Fuji Photo Film Co Ltd Strahlungsbildspeicherplatte.
EP0308728B1 (de) 1987-09-21 1991-06-05 Siemens Aktiengesellschaft Verfahren zum Betreiben eines Durchlaufdampferzeugers
US4912333A (en) 1988-09-12 1990-03-27 Eastman Kodak Company X-ray intensifying screen permitting an improved relationship of imaging speed to sharpness
US5348935A (en) * 1988-10-28 1994-09-20 The Regents Of The University Of California Highly oxidized superconductors
JPH042999A (ja) 1990-04-20 1992-01-07 Fuji Photo Film Co Ltd 放射線像変換パネル
WO1992012162A1 (en) 1990-12-27 1992-07-23 Exxon Chemical Patents Inc. An amido transition metal compound and a catalyst system for the production of isotactic polypropylene
JP3115345B2 (ja) 1991-04-26 2000-12-04 三菱化学株式会社 オレフィン重合体の製造法
CA2112797C (en) * 1991-07-09 2002-10-15 Raymond W. Singleton Treated polymeric non-woven fabric
KR19980702645A (ko) 1995-03-08 1998-08-05 알베르투스 빌헬무스 요아네스 쩨스트라텐 촉매 조성물내 브리지된 비스-아미도 4족 금속 화합물
JP3479574B2 (ja) 1995-07-04 2003-12-15 富士写真フイルム株式会社 フロント側用放射線増感スクリーン及び放射線増感スクリーン組体
US5830629A (en) 1995-11-01 1998-11-03 Eastman Kodak Company Autoradiography assemblage using transparent screen
DE69730838T2 (de) 1996-07-23 2006-02-16 E.I. Du Pont De Nemours And Co., Wilmington Polymerisationsverfahren für olefinen
EP0927201B1 (de) 1996-09-06 2004-04-14 Hyundai Petrochemical Co., Ltd. Katalysatorsystem für die (co)polymerisierung von olefinen und verfahren zur herstellung von olefin-(co)polymeren unter verwendung des katalysatorsystems
US6214761B1 (en) 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6432862B1 (en) 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
IL129929A0 (en) * 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
US6417305B2 (en) 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
US6423848B2 (en) 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
JP2001508107A (ja) 1997-01-13 2001-06-19 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー プロピレンの重合
US5905014A (en) 1997-03-19 1999-05-18 Agfa-Gevaert, N.V. Radiation image storage panel comprising a colorant
US6103946A (en) 1997-07-15 2000-08-15 E. I. Du Pont De Nemours And Company Manufacture of α-olefins
US6740715B2 (en) 1997-07-15 2004-05-25 E. I. Du Pont De Nemours And Company Manufacture of alpha-olefins
ID24448A (id) 1997-09-05 2000-07-20 Bp Chemical Ltd Katalis-katalis polimerisasi
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
US6462155B1 (en) 1998-02-12 2002-10-08 Idemitsu Petrochemical Co., Ltd. Catalyst for olefin polymerization and process for producing olefin polymer with the catalyst
EP1062255B1 (de) 1998-03-12 2003-07-02 BP Chemicals Limited Äthylen-homopolymer
ID27209A (id) 1998-03-12 2001-03-08 Bp Chem Int Ltd Katalis-katalis polimerisasi
WO1999046303A1 (en) 1998-03-12 1999-09-16 Bp Chemicals Limited Polymerisation catalysts
US6232259B1 (en) 1998-03-31 2001-05-15 E. I. Du Pont De Nemours And Company Preparation of transition metal imine complexes
US6063881A (en) 1998-04-02 2000-05-16 E. I. Du Pont De Nemours And Company Oligomerization of propylene
EP0952165A1 (de) 1998-04-24 1999-10-27 Fina Research S.A. Herstellung von Polyethylene mit verbesserten mechanischen Eigenschaften
JP2002517526A (ja) 1998-05-29 2002-06-18 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー オレフィンの共重合
GB9817004D0 (en) 1998-08-06 1998-09-30 Bp Chem Int Ltd Preparation of polymerisation catalysts
GB9819847D0 (en) 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
DE69904739T2 (de) 1998-10-02 2003-09-18 Bp Chem Int Ltd Polymerisationskatalysatoren
EP1131361B8 (de) 1998-10-26 2005-07-27 O & D Trading Limited Polymerisationskatalysatoren
AU1169200A (en) 1998-11-30 2000-06-19 Bp Chemicals Limited Polymerisation process
JP2002532585A (ja) 1998-12-15 2002-10-02 バセル テクノロジー カンパニー ビー．ブイ． オレフィン重合用触媒系
DE60018870T2 (de) 1999-01-22 2006-04-13 Mitsui Chemicals, Inc. Verfahren zur herstellung eines olefinpolymers und olefinpolymer
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
US6559091B1 (en) 1999-02-22 2003-05-06 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
GB9906296D0 (en) 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
DE19931873A1 (de) 1999-04-14 2000-10-19 Bayer Ag Katalysatorsystem zur Olefinpolymerisation
US6365690B1 (en) 1999-05-06 2002-04-02 E. I. Du Pont De Nemours And Company Polymerization of ethylene
US6825297B1 (en) * 1999-05-14 2004-11-30 The Dow Chemical Company Transition metal complexes and olefin polymerization process
US6479601B1 (en) 1999-08-06 2002-11-12 The Goodyear Tire & Rubber Company Transition metal catalysts for diene polymerizations
US6458905B1 (en) 1999-08-16 2002-10-01 Phillips Petroleum Company Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts
US6441117B1 (en) 1999-09-01 2002-08-27 E. I. Du Pont De Nemours And Company High density polyethylene packaging
CA2347385A1 (en) * 1999-09-02 2001-03-15 Haruhito Sato Transition metal compounds, catalysts for the production of .alpha.-olefins and process therefor
US6407188B1 (en) 1999-09-29 2002-06-18 E. I. Du Pont De Nemours And Company Polymerization of olefins
AU1306401A (en) 1999-11-11 2001-05-30 Idemitsu Petrochemical Co., Ltd. Transition metal compound, olefin polymerization catalyst, and method of polymerizing olefin
EP2267045B1 (de) 2000-01-26 2015-07-15 Mitsui Chemicals, Inc. Olefinpolymer mit sehr niedriger Polydispersität und Verfahren zu seiner Herstellung
US6710006B2 (en) 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
TW572969B (en) 2000-02-10 2004-01-21 Hayashibara Biochem Lab Trimethine cyanine dye, light absorbent, light-resistant improver and optical recording medium containing same, and process for producing same
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
DE10009253A1 (de) 2000-02-28 2001-08-30 Aquis Sanitaer Ag Rebstein Spülvorrichtung für Toiletten
GC0000291A (en) * 2000-06-30 2006-11-01 Shell Int Research Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
US6555723B2 (en) 2000-07-18 2003-04-29 E. I. Du Pont De Nemours And Company Continuous manufacturing process for alpha-olefins
US6534691B2 (en) 2000-07-18 2003-03-18 E. I. Du Pont De Nemours And Company Manufacturing process for α-olefins
EP1305271B1 (de) 2000-08-03 2009-03-04 E.I. Du Pont De Nemours And Company Kontinuierliches verfahren zur herstellung von alpha-olefinen
US7037988B2 (en) 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
US6521329B2 (en) 2001-06-18 2003-02-18 Eastman Kodak Company Radiographic phosphor panel having reflective polymeric supports
ES2278933T3 (es) 2001-06-20 2007-08-16 Shell Internationale Research Maatschappij B.V. Procedimiento para la preparacion de oligomeros.
ATE344268T1 (de) 2001-08-01 2006-11-15 Shell Int Research Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen
ES2260678T3 (es) 2002-09-25 2006-11-01 Shell Internationale Research Maatschappij B.V. Sistema cataliticos para la oligomerizacion de etileno a alfa-olefinas lineales.
US20050014983A1 (en) 2003-07-07 2005-01-20 De Boer Eric Johannes Maria Process for producing linear alpha olefins

Also Published As

Publication number Publication date
EP1542797B1 (de) 2006-05-31
US7053020B2 (en) 2006-05-30
DE60305715T2 (de) 2007-05-31
WO2004037415A2 (en) 2004-05-06
ATE327826T1 (de) 2006-06-15
AU2003293320A8 (en) 2004-05-13
CN1684768A (zh) 2005-10-19
US20040116758A1 (en) 2004-06-17
EP1542797A2 (de) 2005-06-22
WO2004037415A3 (en) 2004-08-26
CN100371075C (zh) 2008-02-27
CA2499844A1 (en) 2004-05-06
RU2005112251A (ru) 2006-01-20
RU2315658C2 (ru) 2008-01-27
JP2006501067A (ja) 2006-01-12
AU2003293320A1 (en) 2004-05-13
ZA200502081B (en) 2005-11-24
ES2260678T3 (es) 2006-11-01

Similar Documents

Publication Publication Date Title
DE60305715D1 (de) Katalysatorsysteme für die ethylen-oligomerisierung zu linearen alpha-olefinen
ATE344268T1 (de) Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen
IN2012DN06460A (de)
DE60109773D1 (de) Liganden und katalysatorsysteme für die oligomerisierung von ethylen zu linearen alpha olefinen
ZA986801B (en) Chemical compound.
MY133678A (en) Catalyst system and process for the polymerization of olefins
CA2295215A1 (en) Catalyst for the production of olefin polymers
WO2005058916A3 (en) Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins
RU2003112616A (ru) Способ соолигомеризации этилена и альфа-олефинов
MY133958A (en) Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
ATE120768T1 (de) Herstellung von metallocenkatalysatoren für olefinpolymerisation.
WO2004005360A3 (en) Catalyst system for the polymerization of olefins
PT955304E (pt) Complexo de metaloceno com pontes para a (co) polimerizacao de olefinas
DE602004016391D1 (de) Katalysatorsystem zur polymerisation von olefinen
DE60334073D1 (de) Übergangsmetallkomplexe, liganden, katalysatoren für die polymerisation von olefinen und verfahren zur herstellung von olefinpolymeren
DZ2573A1 (fr) Catalyseurs de polyéthylène à activité élevée.
ATE360039T1 (de) Feste cokatalysatorkomponente für die olefinpolymerisation und katalysatorsystem davon
WO2002024714A1 (fr) Composes de metaux de transition, catalyseurs de polymerisation d'olefines, polymeres d'olefines et procede de production associe
JP2004537405A5 (de)
WO2002028870A1 (fr) Composes de metaux de transition, catalyseurs de polymerisation pour olefines, polymeres d"olefines et procede de production correspondant
EP1396503A4 (de) Feste katalysatorkomponente für die olefinpolymerisation
DE50209734D1 (de) Katalysatorsysteme für die ziegler-natta-propen-polymerisation
TH49679A (de)
TH27829B (th) ตัวเร่งปฏิกิริยาและกรรมวิธีสำหรับการเตรียมแอลดิไฮด์ โดยมีตัวเร่งปฏิกิริยานี้อยู่ด้วย
TH51153A (th) สารเชิงซ้อนของโลหะแทรนซิชัน และกรรมวิธีโพลิเมอไรเซชันโอลีฟิน

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee