MXPA03001409A - Catalizador mejorado para la fabricacion de acrilonitrilo. - Google Patents
Catalizador mejorado para la fabricacion de acrilonitrilo.Info
- Publication number
- MXPA03001409A MXPA03001409A MXPA03001409A MXPA03001409A MXPA03001409A MX PA03001409 A MXPA03001409 A MX PA03001409A MX PA03001409 A MXPA03001409 A MX PA03001409A MX PA03001409 A MXPA03001409 A MX PA03001409A MX PA03001409 A MXPA03001409 A MX PA03001409A
- Authority
- MX
- Mexico
- Prior art keywords
- mixtures
- acrylonitrile
- manufacture
- improved catalyst
- catalyst
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 229910052701 rubidium Inorganic materials 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- 229910052716 thallium Inorganic materials 0.000 abstract 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- 229910052738 indium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 abstract 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
Una composicion de catalizador que comprende un complejo de oxidos cataliticos de hierro, bismuto, molibdeno, cobalto, cerio, antimonio, al menos uno de niquel y magnesio y al menos uno de litio, sodio, potasio, rubidio o talio y caracterizado por la siguiente formula empirica: AaBbCcFedBieCofCegSbhMomOx; en donde A es al menos uno de Cr, P, Sn, Te, B, Ge, Z n , In, Mn, Ca, W, o mezclas de los mismos, B es al menos uno de Li, Na, K, Rb, Cs, T1, o mezclas de los mismos, C es al menos uno de Ni, Mg o mezclas de los mismos, a es de 0 hasta 4.0, b es de 0.01 hasta 1.5, c es de 1.0 hasta 10.0, d es de 0.1 hasta 5.0, e es de 0.1 hasta 2.0, f es de 0.1 hasta 10.0, g es de 0.1 hasta 2.0, h es de 0.1 hasta 2.0, m es de 12.0 hasta 18.0, y x es un numero determinado por los requerimientos de Valencia de los otros elementos presentes. El catalizador es util en procesos para la amoxidacion de una olefina seleccionada del grupo que consiste de propileno, e isobutileno o mezclas de los mismos hacia acrilonitrilo, metacrilonitrilo y mezclas de los mismos respectivamente.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/641,380 US6458742B1 (en) | 2000-08-17 | 2000-08-17 | Catalyst for the manufacture of acrylonitrile |
PCT/US2001/024253 WO2002013963A2 (en) | 2000-08-17 | 2001-08-02 | Improved catalyst for the manufacture of acrylonitrile |
Publications (1)
Publication Number | Publication Date |
---|---|
MXPA03001409A true MXPA03001409A (es) | 2004-05-04 |
Family
ID=24572105
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MXPA03001409A MXPA03001409A (es) | 2000-08-17 | 2001-08-02 | Catalizador mejorado para la fabricacion de acrilonitrilo. |
Country Status (17)
Country | Link |
---|---|
US (2) | US6458742B1 (es) |
EP (1) | EP1309402B1 (es) |
JP (1) | JP4937487B2 (es) |
KR (1) | KR100786051B1 (es) |
CN (1) | CN1255215C (es) |
AT (1) | ATE363944T1 (es) |
AU (1) | AU2001278136A1 (es) |
BG (2) | BG66322B1 (es) |
BR (1) | BR0113310B1 (es) |
CA (1) | CA2417987C (es) |
DE (1) | DE60128811T2 (es) |
ES (1) | ES2287146T3 (es) |
MX (1) | MXPA03001409A (es) |
RU (1) | RU2266784C2 (es) |
TW (1) | TWI284058B (es) |
WO (1) | WO2002013963A2 (es) |
ZA (1) | ZA200301006B (es) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003039744A1 (fr) * | 2001-11-08 | 2003-05-15 | Mitsubishi Chemical Corporation | Catalyseur a base d'oxyde composite et son procede de preparation |
CA2507182A1 (en) * | 2002-12-02 | 2004-06-17 | The Standard Oil Company | Mixed oxide catalyst of k, cs, ce, cr, co, ni, fe, bi and mo for the manufacture of acrylonitrile |
US7071140B2 (en) * | 2002-12-02 | 2006-07-04 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
CN100408173C (zh) * | 2005-08-15 | 2008-08-06 | 中国石油化工股份有限公司 | 制备丙烯腈的流化床催化剂 |
US7456313B2 (en) * | 2006-01-10 | 2008-11-25 | Rohm And Haas Company | Liquid-phase (AMM)oxidation process |
US7576232B2 (en) * | 2006-05-02 | 2009-08-18 | Ineos Usa Llc | In situ modification of molybdenum-based catalysts |
KR101431293B1 (ko) * | 2006-10-26 | 2014-08-20 | 다이야니트릭스 가부시키가이샤 | 아크릴로니트릴 제조용 유동상 촉매 및 아크릴로니트릴의 제조 방법 |
JP5491037B2 (ja) * | 2009-01-30 | 2014-05-14 | 旭化成ケミカルズ株式会社 | アクリロニトリルの製造用触媒及びアクリロニトリルの製造方法 |
US8153546B2 (en) * | 2010-03-23 | 2012-04-10 | Ineos Usa Llc | Mixed metal oxide ammoxidation catalysts |
US8420566B2 (en) * | 2010-03-23 | 2013-04-16 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
US8455388B2 (en) * | 2010-03-23 | 2013-06-04 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
US8258073B2 (en) * | 2010-03-23 | 2012-09-04 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
US9433929B2 (en) * | 2011-09-21 | 2016-09-06 | Ineos Europe Ag | Mixed metal oxide catalysts |
US8835666B2 (en) * | 2012-11-26 | 2014-09-16 | Ineos Usa Llc | Pre calcination additives for mixed metal oxide ammoxidation catalysts |
CN103894203B (zh) * | 2012-12-27 | 2017-02-08 | 中国石油化工股份有限公司 | 烯烃氨氧化反应高负荷催化剂 |
FR3004713B1 (fr) * | 2013-04-17 | 2015-05-15 | Centre Nat Rech Scient | Procede de production de nitriles mettant en oeuvre un catalyseur a base d'antimoine et de fer. |
EP3148692B1 (en) * | 2014-05-29 | 2019-07-10 | Ineos Europe AG | Improved selective ammoxidation catalysts |
US20150343427A1 (en) * | 2014-05-29 | 2015-12-03 | Ineos Usa, Llc | Selective ammoxidation catalysts |
US20190009252A1 (en) * | 2016-01-09 | 2019-01-10 | Ascend Performance Materials Operations Llc | Catalyst compositions and process for direct production of hydrogen cyanide in an acrylonitrile reactor feed stream |
CN107282094B (zh) * | 2016-04-13 | 2020-04-17 | 中国石油化工股份有限公司 | 氨氧化法丙烯腈催化剂 |
CN106000461A (zh) * | 2016-05-27 | 2016-10-12 | 张玲 | 一种甲基丙烯腈催化剂的制备方法 |
US10626082B2 (en) | 2016-10-11 | 2020-04-21 | Ineos Europe Ag | Ammoxidation catalyst with selective co-product HCN production |
KR102519507B1 (ko) * | 2019-09-30 | 2023-04-07 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법 |
CN114669306B (zh) * | 2022-03-27 | 2023-11-28 | 上海师范大学 | (甲基)丙烯醛氨氧化法制(甲基)丙烯腈的催化剂及其制备方法和应用 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57130548A (en) * | 1981-02-05 | 1982-08-13 | Mitsubishi Chem Ind Ltd | Catalyst composition |
US4746753A (en) | 1981-04-29 | 1988-05-24 | The Standard Oil Company | Preparation of acrylonitrile from propylene, oxygen and ammonia in the presence of an alkali metal promoted bismuth, cerium, molybdenum, tungsten catalyst |
US4939286A (en) | 1985-09-10 | 1990-07-03 | The Standard Oil Company | Promoted bismuth cerium molybdate catalysts |
JPS63122642A (ja) | 1986-11-11 | 1988-05-26 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
JPH0267556A (ja) * | 1988-09-02 | 1990-03-07 | Fuji Photo Film Co Ltd | ハロゲン化銀感光材料の処理方法 |
US5175334A (en) | 1990-01-09 | 1992-12-29 | The Standard Oil Company | Process for the manufacture of acrylonitrile and methacrylonitrile |
US5093299A (en) * | 1990-01-09 | 1992-03-03 | The Standard Oil Company | Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile |
US5212137A (en) * | 1990-01-09 | 1993-05-18 | Standard Oil Company | Catalyst for the manufacture of acrylonitrile and methacrylonitrile |
US5235088A (en) | 1990-03-19 | 1993-08-10 | The Standard Oil Company | Process and catalyst for propylene ammoxidation to acrylonitrile |
US5134105A (en) | 1990-03-19 | 1992-07-28 | The Standard Oil Company | Catalyst for propylene ammoxidation to acrylonitrile |
DE4220859A1 (de) * | 1992-06-25 | 1994-01-05 | Basf Ag | Multimetalloxidmassen |
US5583086A (en) * | 1993-03-09 | 1996-12-10 | Basf Aktiengesellschaft | Cesium containing multimetal oxide catalyst compositions for the preparation of methacrolein by gas-phase-catalytic oxidation |
JP3534431B2 (ja) | 1993-08-06 | 2004-06-07 | 旭化成ケミカルズ株式会社 | 不飽和ニトリルの製法 |
US5658842A (en) | 1993-08-10 | 1997-08-19 | Asahi Kasei Kogyo Kabushiki Kaisha | Ammoxidation catalyst composition, and process for producing acrylonitrile or methacrylonitrile using the same |
US5780664A (en) * | 1993-08-17 | 1998-07-14 | Asahi Kasei Kogyo Kabushi Kaisha | Ammoxidation catalyst composition |
DE4332542A1 (de) * | 1993-09-24 | 1995-03-30 | Basf Ag | Katalysator auf der Basis von Fe-, Co-, Bi- und Mo-Oxiden |
DE4405059A1 (de) * | 1994-02-17 | 1995-08-24 | Basf Ag | Multimetalloxidmassen |
JP3214975B2 (ja) * | 1994-04-25 | 2001-10-02 | 旭化成株式会社 | アンモ酸化触媒組成物および製造方法 |
JP3838705B2 (ja) | 1996-07-31 | 2006-10-25 | 旭化成ケミカルズ株式会社 | アンモ酸化用触媒組成物 |
US5840648A (en) * | 1997-09-02 | 1998-11-24 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile and hydrogen cyanide |
JP3875023B2 (ja) | 1998-02-13 | 2007-01-31 | コリア リサーチ インスティチュート オブ ケミカル テクノロジイ | コアー殻触媒相の固形触媒とその製造方法 |
ES2226375T3 (es) | 1998-04-23 | 2005-03-16 | Mitsubishi Rayon Co., Ltd. | Catalizador para producir nitrilo insaturado. |
WO1999054037A1 (fr) * | 1998-04-23 | 1999-10-28 | Mitsubishi Rayon Co., Ltd. | Catalyseur de production de nitrile insature |
JP3680115B2 (ja) * | 1998-04-23 | 2005-08-10 | ダイヤニトリックス株式会社 | 不飽和ニトリル製造用触媒組成物 |
US6143690A (en) * | 1998-05-07 | 2000-11-07 | Asahi Kasei Kogyo Kabushiki Kaisha | Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane |
AU5387100A (en) | 1999-08-19 | 2001-03-19 | China Petro-Chemical Corporation | Fluid bed catalyst for ammoxidation of propylene to acrylonitrile |
DE60030747T2 (de) * | 1999-10-18 | 2007-09-20 | Mitsubishi Rayon Co., Ltd. | Ein verfahren zur herstellung von acrylnitril, ein katalysator für diese verwendung und ein verfahren zu dessen herstellung |
-
2000
- 2000-08-17 US US09/641,380 patent/US6458742B1/en not_active Expired - Lifetime
-
2001
- 2001-08-02 ES ES01956103T patent/ES2287146T3/es not_active Expired - Lifetime
- 2001-08-02 KR KR1020037002308A patent/KR100786051B1/ko active IP Right Grant
- 2001-08-02 CN CNB018141366A patent/CN1255215C/zh not_active Expired - Lifetime
- 2001-08-02 BR BRPI0113310-1A patent/BR0113310B1/pt not_active IP Right Cessation
- 2001-08-02 CA CA002417987A patent/CA2417987C/en not_active Expired - Fee Related
- 2001-08-02 JP JP2002519095A patent/JP4937487B2/ja not_active Expired - Lifetime
- 2001-08-02 EP EP01956103A patent/EP1309402B1/en not_active Expired - Lifetime
- 2001-08-02 WO PCT/US2001/024253 patent/WO2002013963A2/en active IP Right Grant
- 2001-08-02 MX MXPA03001409A patent/MXPA03001409A/es active IP Right Grant
- 2001-08-02 AU AU2001278136A patent/AU2001278136A1/en not_active Abandoned
- 2001-08-02 DE DE60128811T patent/DE60128811T2/de not_active Expired - Lifetime
- 2001-08-02 AT AT01956103T patent/ATE363944T1/de not_active IP Right Cessation
- 2001-08-02 RU RU2003107043/04A patent/RU2266784C2/ru active
- 2001-08-16 TW TW090120073A patent/TWI284058B/zh not_active IP Right Cessation
-
2002
- 2002-08-06 US US10/213,755 patent/US6965046B2/en not_active Expired - Lifetime
-
2003
- 2003-02-05 ZA ZA200301006A patent/ZA200301006B/xx unknown
- 2003-02-05 BG BG107525A patent/BG66322B1/bg unknown
- 2003-02-05 BG BG107525D patent/BG107525A/bg unknown
Also Published As
Publication number | Publication date |
---|---|
CN1255215C (zh) | 2006-05-10 |
KR100786051B1 (ko) | 2007-12-17 |
RU2266784C2 (ru) | 2005-12-27 |
CN1450934A (zh) | 2003-10-22 |
US6458742B1 (en) | 2002-10-01 |
EP1309402A2 (en) | 2003-05-14 |
ATE363944T1 (de) | 2007-06-15 |
JP4937487B2 (ja) | 2012-05-23 |
KR20030027036A (ko) | 2003-04-03 |
DE60128811D1 (de) | 2007-07-19 |
ES2287146T3 (es) | 2007-12-16 |
ZA200301006B (en) | 2004-02-13 |
CA2417987A1 (en) | 2002-02-21 |
BG107525A (bg) | 2003-12-31 |
WO2002013963A3 (en) | 2002-05-02 |
BG66322A (en) | 2013-05-31 |
AU2001278136A1 (en) | 2002-02-25 |
CA2417987C (en) | 2007-10-23 |
BR0113310B1 (pt) | 2012-01-24 |
EP1309402B1 (en) | 2007-06-06 |
WO2002013963A2 (en) | 2002-02-21 |
TWI284058B (en) | 2007-07-21 |
JP2004505766A (ja) | 2004-02-26 |
DE60128811T2 (de) | 2008-02-21 |
US20020198398A1 (en) | 2002-12-26 |
BR0113310A (pt) | 2003-06-24 |
US6965046B2 (en) | 2005-11-15 |
BG66322B1 (bg) | 2013-05-31 |
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