CA2437256A1 - Improved method for the manufacture of acrylic acid - Google Patents

Improved method for the manufacture of acrylic acid Download PDF

Info

Publication number
CA2437256A1
CA2437256A1 CA002437256A CA2437256A CA2437256A1 CA 2437256 A1 CA2437256 A1 CA 2437256A1 CA 002437256 A CA002437256 A CA 002437256A CA 2437256 A CA2437256 A CA 2437256A CA 2437256 A1 CA2437256 A1 CA 2437256A1
Authority
CA
Canada
Prior art keywords
acrylic acid
manufacture
improved method
acrolein
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002437256A
Other languages
French (fr)
Other versions
CA2437256C (en
Inventor
Dev D. Suresh
Christos Paparizos
Patrick E. Mosier
Ying Wu
Maria Strada Friedrich
Michael J. Seely
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos USA LLC
Original Assignee
The Standard Oil Company
Dev D. Suresh
Christos Paparizos
Patrick E. Mosier
Ying Wu
Maria Strada Friedrich
Michael J. Seely
O&D Usa Llc
Innovene Usa Llc
Ineos Usa Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Standard Oil Company, Dev D. Suresh, Christos Paparizos, Patrick E. Mosier, Ying Wu, Maria Strada Friedrich, Michael J. Seely, O&D Usa Llc, Innovene Usa Llc, Ineos Usa Llc filed Critical The Standard Oil Company
Publication of CA2437256A1 publication Critical patent/CA2437256A1/en
Application granted granted Critical
Publication of CA2437256C publication Critical patent/CA2437256C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/31—Chromium, molybdenum or tungsten combined with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8871—Rare earth metals or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J35/19—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

A process for the manufacture of acrylic acid comprising reacting propylene and oxygen (preferably in the form of air) in a reaction zone having a catalyst characterized by the following formula: AaBbCcCadFeeBifMo12=Ox, where A = one or more of Li, Na, K, Rb and Cs; B = one or more of Mg, Sr, Mn, Ni, Co and Zn; C = one or more of Ce, Cr, Al, Sb, P, Ge, Sn, Cu, V and W and; a =
0.01 to 1.0; b and e = 1.0 - 10; c = 0 to 5.0, preferably 0.05 to 5.0, especially preferred being 0.05 to 4.0, and x is a number determined by the valence requirements of the other elements present; at an elevated temperature to produce acrylic acid and acrolein.
CA002437256A 2001-02-05 2001-02-05 Improved method for the manufacture of acrylic acid Expired - Fee Related CA2437256C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2001/003606 WO2002062741A1 (en) 2001-02-05 2001-02-05 Improved method for the manufacture of acrylic acid

Publications (2)

Publication Number Publication Date
CA2437256A1 true CA2437256A1 (en) 2002-08-15
CA2437256C CA2437256C (en) 2009-04-14

Family

ID=21742305

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002437256A Expired - Fee Related CA2437256C (en) 2001-02-05 2001-02-05 Improved method for the manufacture of acrylic acid

Country Status (8)

Country Link
EP (1) EP1358147A1 (en)
JP (1) JP2004522757A (en)
KR (1) KR100711044B1 (en)
CN (1) CN1216846C (en)
BR (1) BR0116860A (en)
CA (1) CA2437256C (en)
MX (1) MXPA03006957A (en)
WO (1) WO2002062741A1 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS584691B2 (en) * 1977-11-07 1983-01-27 宇部興産株式会社 Method for producing methacrolein
US5218146A (en) * 1987-05-27 1993-06-08 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for production of acrylic acid
US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide

Also Published As

Publication number Publication date
CN1489568A (en) 2004-04-14
EP1358147A1 (en) 2003-11-05
MXPA03006957A (en) 2004-05-24
CN1216846C (en) 2005-08-31
WO2002062741A1 (en) 2002-08-15
JP2004522757A (en) 2004-07-29
CA2437256C (en) 2009-04-14
KR20030076655A (en) 2003-09-26
KR100711044B1 (en) 2007-04-24
BR0116860A (en) 2004-01-13

Similar Documents

Publication Publication Date Title
AU2001287622A1 (en) Method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane
MY121722A (en) Improved catalyst for the manufacture of acrylonitrile and hydrogen cyanide
MY124766A (en) Complex oxide catalysts and process for producing (meth)acrolein and (meth)acrylic acid
ATE363944T1 (en) METHOD FOR PRODUCING ACRYLIC ACID
EP1459803A4 (en) Oxide catalyst composition
RU2003107043A (en) CATALYTIC COMPOSITION (OPTIONS) AND METHOD FOR OLEFIN CONVERSION WITH ITS APPLICATION
EP0861819A1 (en) Process for the preparation of acrolein from propyle by reaction
WO2001098247A3 (en) Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hycrocarbons
SE7406934L (en)
CA2437256A1 (en) Improved method for the manufacture of acrylic acid
BR0316852A (en) Catalyst Compositions and Process of Converting an Olefin
US3907859A (en) Coproduction of acrylonitrile and acrylic acid
MY142421A (en) Process for producing oxygen-containing unsaturated compound
JPS5767555A (en) Production of s-(aminoalkyl)thiosulfate salt
TW331556B (en) Paraffin ammoxidation using vanadium antimony oxide based catalysts with halide promoters
JPS55153743A (en) Preparation of unsaturated carboxylic acid ester
US6268529B1 (en) Method for the manufacture of acrylic acid
ES2191813T3 (en) PROCEDURE TO PREPARE IMPROVED OXIDATION AND AMOXIDATION CATALYSTS BASED ON VANADIO-ANTIMONY OXIDE.
RU2003127408A (en) METHOD FOR PRODUCING ACRYLIC ACID
EP0968981A3 (en) Micronutrient foliar fertilizer based on magnesium sulphate and process for obtaining thereof
JPS5738764A (en) Preparation of 4,4'-dinitrostilbene-2,2'-disulfonic acid
JPS5522614A (en) Preparation of formylated phenol compound
TH36431A (en) Catalyst for acrylonitrite and hydrogen cyanide production
TH10427B (en) Catalyst for acrylonitrite and hydrogen cyanide production
ZA200305892B (en) Improved method for the manufacture of acrylic acid.

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed