SE7406934L - - Google Patents

Info

Publication number
SE7406934L
SE7406934L SE7406934A SE7406934A SE7406934L SE 7406934 L SE7406934 L SE 7406934L SE 7406934 A SE7406934 A SE 7406934A SE 7406934 A SE7406934 A SE 7406934A SE 7406934 L SE7406934 L SE 7406934L
Authority
SE
Sweden
Prior art keywords
isobutylene
ammonia
propylene
mixtures
ammoxidation
Prior art date
Application number
SE7406934A
Other versions
SE420496B (en
Inventor
R K Graselli
A F Miller
D D Suresh
H F Harman
Original Assignee
Standard Oil Co Ohio
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/430,964 external-priority patent/US4139552A/en
Application filed by Standard Oil Co Ohio filed Critical Standard Oil Co Ohio
Publication of SE7406934L publication Critical patent/SE7406934L/xx
Publication of SE420496B publication Critical patent/SE420496B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8875—Germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

1478621 (Meth)acrylonitrile STANDARD OIL CO 4 June 1974 [4 June 1973 19 July 1973 4 Jan 1974] 24600/74 Heading C2C [Also in Division B1] Acrylonitrile or methacrylonitrile are produced by the reaction of propylene or isobutylene with molecular oxygen and ammonia at 200-600‹ C. in the presence of a catalyst of the empirical formula wherein: X is Ge, Sn, Cu, Ag, Cr, Ru, W, Be, B, Ga, In, Mn, Sb, Th, Zr, Y or mixtures thereof; A is alkali metal, alkaline earth metal, Sc, Y, rare earth metal, Nb, Ta, P, As or mixtures thereof and is different from " X " or " C "; C is Ni, Co, Mg, Zn, Cd, Ca or mixtures thereof; a is 0.01 to 4; 6 is 0 to 4; c and d are 0À01 to 12; e is 0.01 to 6; and x is a number to satisfy valency requirements. The examples describe the ammoxidation of propylene using a feed of propylene / ammonia / oxygen / nitrogen / steam molar ratio 1.8/2.2/3.6/2.4/6, a contact time of 3 seconds, a WWH of 0-10 and a temperature of 420‹ C., and the ammoxidation of isobutylene with a feed of isobutylene/ammonia/air/steam of 1/1.2 or 1.5/11/4 at a temperature of 400‹ C.
SE7406934A 1973-06-04 1974-05-24 PROCEDURE FOR THE PREPARATION OF ACRYLNITRIL OR METACRYLNITRIL BY THE TRANSACTION OF PROPEN OR ISOBUTEN, MOLECULATED ACID AND AMMONIA AT A TEMPERATURE OF YOUNGER 200? 59C TO YOUNGER 600? 59C IN THE PRESENT OF A ... SE420496B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US36704273A 1973-06-04 1973-06-04
US38052773A 1973-07-19 1973-07-19
US05/430,964 US4139552A (en) 1974-01-04 1974-01-04 Production of unsaturated nitriles

Publications (2)

Publication Number Publication Date
SE7406934L true SE7406934L (en) 1974-12-05
SE420496B SE420496B (en) 1981-10-12

Family

ID=27408795

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7406934A SE420496B (en) 1973-06-04 1974-05-24 PROCEDURE FOR THE PREPARATION OF ACRYLNITRIL OR METACRYLNITRIL BY THE TRANSACTION OF PROPEN OR ISOBUTEN, MOLECULATED ACID AND AMMONIA AT A TEMPERATURE OF YOUNGER 200? 59C TO YOUNGER 600? 59C IN THE PRESENT OF A ...

Country Status (23)

Country Link
JP (1) JPS5950667B2 (en)
AR (1) AR201590A1 (en)
BE (1) BE815893A (en)
BG (1) BG24943A3 (en)
BR (1) BR7404534D0 (en)
CH (1) CH593242A5 (en)
CS (1) CS188923B2 (en)
DD (1) DD115115A5 (en)
DE (1) DE2424934A1 (en)
DK (1) DK295474A (en)
EG (1) EG11454A (en)
ES (1) ES426907A1 (en)
FI (1) FI168274A (en)
FR (1) FR2231669B1 (en)
GB (1) GB1478621A (en)
HU (1) HU168551B (en)
IE (1) IE39402B1 (en)
IL (1) IL44916A (en)
IT (1) IT1017645B (en)
MY (1) MY7800272A (en)
NL (1) NL7407314A (en)
NO (1) NO143740C (en)
SE (1) SE420496B (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5245692B2 (en) * 1973-10-16 1977-11-17
JPS5432766B2 (en) * 1974-06-04 1979-10-16
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
JPS5163112A (en) * 1974-11-27 1976-06-01 Nippon Kayaku Kk Metakuroreinno seizoho
JPS5231026A (en) * 1975-09-05 1977-03-09 Ube Ind Ltd Process for preparation of acrylonitrile
IL55073A (en) * 1977-07-28 1982-01-31 Standard Oil Co Catalysts for the oxidation and ammoxidation of olefins
JPS584691B2 (en) * 1977-11-07 1983-01-27 宇部興産株式会社 Method for producing methacrolein
CA1127137A (en) * 1977-12-20 1982-07-06 Dev D. Suresh Ammoxidation of olefins with novel antimonate catalysts
JPS5538330A (en) * 1978-09-13 1980-03-17 Ube Ind Ltd Preparation of acrylonitrile
JPS5556839A (en) 1978-10-20 1980-04-26 Ube Ind Ltd Acrylonitrile preparing catalyst using fludized bed reactor
JPS5916817B2 (en) * 1979-04-18 1984-04-18 宇部興産株式会社 Catalyst for acrylonitrile production
DE3270713D1 (en) * 1982-02-15 1986-05-28 Standard Oil Co Ohio Production of catalysts by impregnation and use thereof in oxidation type reactions
DE3521766A1 (en) * 1985-06-19 1987-01-02 Basf Ag HONEYCOMB CATALYST, ITS PRODUCTION AND USE
JPH0437710Y2 (en) * 1987-03-20 1992-09-04
JP2520279B2 (en) * 1988-03-03 1996-07-31 日東化学工業株式会社 Method for producing acrylonitrile
JP2520282B2 (en) * 1988-04-15 1996-07-31 日東化学工業株式会社 Method for producing acrylonitrile
CN1100034C (en) * 1996-03-12 2003-01-29 旭化成株式会社 Process for preparing unsaturated nitrile

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS494452B1 (en) * 1970-09-18 1974-02-01
NL175175C (en) * 1970-10-30 1984-10-01 Standard Oil Co Ohio PROCESS FOR CONVERTING PROPENE AND / OR ISOBUTENE WITH A MOLECULAR OXYGEN-CONTAINING GAS AND AMMONIA IN THE PRESENCE OF A CATALYST.
CA975382A (en) * 1971-02-04 1975-09-30 Arthur F. Miller Process for the manufacture of acrylonitrile and methacrylonitrile
CA1004232A (en) * 1971-12-30 1977-01-25 The Standard Oil Company Coproduction of methacrylonitrile and butadiene

Also Published As

Publication number Publication date
NL7407314A (en) 1974-12-06
IE39402L (en) 1974-12-04
BE815893A (en) 1974-12-04
FR2231669B1 (en) 1980-04-11
SE420496B (en) 1981-10-12
DK295474A (en) 1975-02-03
NO143740C (en) 1981-04-08
JPS5950667B2 (en) 1984-12-10
GB1478621A (en) 1977-07-06
MY7800272A (en) 1978-12-31
FI168274A (en) 1974-12-05
ES426907A1 (en) 1976-09-01
NO143740B (en) 1980-12-29
BR7404534D0 (en) 1975-09-30
HU168551B (en) 1976-05-28
DD115115A5 (en) 1975-09-12
AR201590A1 (en) 1975-03-31
IT1017645B (en) 1977-08-10
NO741957L (en) 1974-12-05
IE39402B1 (en) 1978-09-27
JPS5025528A (en) 1975-03-18
AU6976874A (en) 1975-12-04
IL44916A0 (en) 1974-07-31
BG24943A3 (en) 1978-06-15
EG11454A (en) 1977-09-30
IL44916A (en) 1978-01-31
FR2231669A1 (en) 1974-12-27
CH593242A5 (en) 1977-11-30
CS188923B2 (en) 1979-03-30
DE2424934A1 (en) 1975-01-02

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