BR0316851A - Composições de catalisador e processo de conversão de uma olefina - Google Patents

Composições de catalisador e processo de conversão de uma olefina

Info

Publication number
BR0316851A
BR0316851A BR0316851-4A BR0316851A BR0316851A BR 0316851 A BR0316851 A BR 0316851A BR 0316851 A BR0316851 A BR 0316851A BR 0316851 A BR0316851 A BR 0316851A
Authority
BR
Brazil
Prior art keywords
catalyst
mixtures
nickel
magnesium
optionally
Prior art date
Application number
BR0316851-4A
Other languages
English (en)
Other versions
BR0316851B1 (pt
Inventor
Christos Paparizos
Stephen C Jevne
Michael J Seely
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of BR0316851A publication Critical patent/BR0316851A/pt
Publication of BR0316851B1 publication Critical patent/BR0316851B1/pt

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/24Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19Molybdenum
    • B01J27/192Molybdenum with bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0081Preparation by melting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876Arsenic, antimony or bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/185Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"COMPOSIçãO DE CATALISADOR E PROCESSO DE CONVERSãO DE UMA OLEFINA". Um catalisador que compreende um complexo de óxidos catalíticos compreendendo rubídio, cério, cromo, magnésio, ferro, bismuto, molibdênio e pelo menos um dentre níquel ou níquel e cobalto, opcionalmente magnésio e opcionalmente um dentre fósforo, antimónio, telúrio, sódio, lítio, potássio, césio, tálio, boro, tungstênio, cálcio, em que as proporções relativas destes elementos são representadas pela seguinte fórmula geral: Rb~ a~ Ce~ b~ Cr~ c~ Mg~ d~ A~ e~ Fe~ f~ Bi~ g~ Y~ h~ M0~ 12~ 0~ x~ em que A é Ni ou a combinação de Ni e Co, Y é pelo menos um dentre P, Sb, Te, Li, Na, K, Cs, T1, B, Ge, W, CA, Zn, um elemento de terras raras ou misturas dos mesmos, a é desde mais ou menos 0,01 a cerca de 1, b é desde mais ou menos 0,01 a cerca de 3, c é desde mais ou menos 0,01 a cerca de 2, d é desde mais ou menos 0,01 a cerca de 7, e é desde mais ou menos 0,01 a cerca de 10, f é desde mais ou menos 0,01 a cerca de 4, g é desde mais ou menos 0,05 a cerca de 4, h é desde O a cerca de 3, x é um número determinado pelos requisitos de valência dos outros elementos presentes, em que 'b'+'c' é maior do que 'g' e em que o catalisador é substancialmente isento de manganês, um metal nobre ou vanádio. O catalisador é útil em processos para a amoxidação de uma olefina selecionada a partir do grupo que consiste em propileno, isobutileno ou suas misturas, a acrilonitrila, metacrilonitrila e suas misturas, respectivamente.
BRPI0316851-4A 2002-12-02 2003-11-19 Composições de catalisador e processo de conversão de uma olefina BR0316851B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US43016302P 2002-12-02 2002-12-02
US60/430.163 2002-12-02
US10/717.130 2003-11-18
US10/717,130 US7071140B2 (en) 2002-12-02 2003-11-18 Catalyst for the manufacture of acrylonitrile
PCT/US2003/036940 WO2004050238A1 (en) 2002-12-02 2003-11-19 Mixed oxide catalyst of rb, ce, cr, ni, fe, bi and mo for the manufacture of acrylonitrile

Publications (2)

Publication Number Publication Date
BR0316851A true BR0316851A (pt) 2005-10-18
BR0316851B1 BR0316851B1 (pt) 2014-07-29

Family

ID=32397239

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0316851-4A BR0316851B1 (pt) 2002-12-02 2003-11-19 Composições de catalisador e processo de conversão de uma olefina

Country Status (10)

Country Link
US (1) US7071140B2 (pt)
EP (1) EP1590083B1 (pt)
JP (1) JP4709549B2 (pt)
KR (1) KR101010891B1 (pt)
AU (1) AU2003291572A1 (pt)
BR (1) BR0316851B1 (pt)
CA (1) CA2507181A1 (pt)
MX (1) MXPA05005757A (pt)
RU (1) RU2347612C2 (pt)
WO (1) WO2004050238A1 (pt)

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KR102519507B1 (ko) * 2019-09-30 2023-04-07 주식회사 엘지화학 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법
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Also Published As

Publication number Publication date
KR20050085258A (ko) 2005-08-29
KR101010891B1 (ko) 2011-01-25
EP1590083A1 (en) 2005-11-02
RU2347612C2 (ru) 2009-02-27
JP2006507937A (ja) 2006-03-09
AU2003291572A1 (en) 2004-06-23
US7071140B2 (en) 2006-07-04
WO2004050238A1 (en) 2004-06-17
EP1590083B1 (en) 2018-04-04
US20040106817A1 (en) 2004-06-03
RU2005120764A (ru) 2006-01-20
BR0316851B1 (pt) 2014-07-29
JP4709549B2 (ja) 2011-06-22
MXPA05005757A (es) 2005-09-08
CA2507181A1 (en) 2004-06-17

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