CN1104282C - 丙烯、异丁烯氨氧化流化床催化剂 - Google Patents
丙烯、异丁烯氨氧化流化床催化剂 Download PDFInfo
- Publication number
- CN1104282C CN1104282C CN99119906A CN99119906A CN1104282C CN 1104282 C CN1104282 C CN 1104282C CN 99119906 A CN99119906 A CN 99119906A CN 99119906 A CN99119906 A CN 99119906A CN 1104282 C CN1104282 C CN 1104282C
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- CN
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- Prior art keywords
- mixture
- catalyst
- propylene
- ammoxidation
- isobutylene
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- Expired - Lifetime
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8898—Manganese, technetium or rhenium containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8877—Vanadium, tantalum, niobium or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
(NH4)6Mo7O24*4H2O | Bi(NO3)3·5H2O | Fe(NO3)3·9H2O | Ni(NO3)2·6H2O | Mg(NO3)2·6H2O | Ce(NO3)3·6H2O | La(NO3)3·nH2O | Sm(NO3)3·nH2O | Sb2O3 | CrO3 | Mn(NO3)2 | Pb(NO3)2 | KNO3 | RbNO3 | CsNO3 | NaNO3 | H7P(W2O7)·nH2O | NH4VO3 | |
实施例1 | 423.2 | 101.4 | 149.4 | 405.6 | 104.5 | —— | 44.4 | —— | —— | —— | —— | —— | 1.9 | 2.4 | —— | —— | —— | 4.7 |
实施例2 | 419.4 | 50.7 | 124.5 | 292.2 | 125.4 | 26.6 | —— | —— | 41.4 | —— | —— | —— | 1.7 | —— | 0.4 | 0.9 | 14.7 | —— |
实施例3 | 408.7 | 20.3 | 199.2 | 268.4 | 94.1 | 53.2 | —— | —— | 69.0 | —— | —— | —— | 0.4 | 2.1 | 2.4 | —— | 4.9 | 11.8 |
实施例4 | 405.3 | 20.3 | 132.8 | 280.3 | 104.5 | —— | 17.8 | —— | 117.3 | 10.2 | —— | —— | 1.1 | 0.6 | 1.6 | —— | —— | 16.5 |
实施例5 | 394.5 | 101.4 | 157.7 | 149.1 | 62.7 | 71.0 | —— | —— | 138.0 | —— | —— | —— | 0.4 | 2.4 | 2.0 | —— | 39.2 | 4.7 |
实施例6 | 398.1 | 405.6 | 207.5 | 238.6 | 104.5 | —— | 44.4 | —— | 117.3 | —— | 14.5 | —— | 0.8 | —— | 2.0 | 0.4 | 19.6 | 11.8 |
实施例7 | 416.1 | 456.3 | 149.4 | 369.8 | 104.5 | 26.6 | 35.5 | —— | 72.5 | 4.1 | —— | —— | 1.7 | 1.5 | —— | 0.8 | —— | 9.4 |
实施例8 | 405.3 | 50.7 | 265.6 | 345.9 | 167.2 | —— | 44.4 | —— | 96.6 | 4.1 | 3.6 | —— | —— | 2.4 | 2.0 | —— | 14.7 | 9.4 |
实施例9 | 412.5 | 243.4 | 207.5 | 310.1 | 104.5 | 117.3 | —— | 7.3 | 121.0 | —— | 2.7 | 2.4 | —— | —— | 11.8 | |||
实施例10 | 401.7 | 111.5 | 149.4 | 405.6 | 73.2 | —— | —— | —— | 96.6 | 10.2 | —— | 235.2 | 0.8 | 2.7 | —— | —— | 39.2 | —— |
实施例11 | 412.5 | 182.5 | 199.2 | 268.4 | 94.1 | —— | —— | —— | —— | —— | —— | 302.4 | 1.5 | 1.5 | —— | 0.4 | 14.7 | 4.7 |
实施例12 | 394.5 | 142.0 | 149.4 | 238.6 | 146.3 | —— | —— | —— | 55.2 | 20.3 | 36.3 | 134.4 | —— | 4.5 | —— | 1.2 | 9.8 | 18.8 |
实施例13 | 365.8 | 354.9 | 166.0 | 381.7 | 94.1 | 17.7 | 71.0 | —— | 138.0 | —— | 7.3 | 241.9 | —— | 0.6 | 3.2 | —— | 49.0 | 18.8 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN99119906A CN1104282C (zh) | 1999-10-28 | 1999-10-28 | 丙烯、异丁烯氨氧化流化床催化剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN99119906A CN1104282C (zh) | 1999-10-28 | 1999-10-28 | 丙烯、异丁烯氨氧化流化床催化剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1302690A CN1302690A (zh) | 2001-07-11 |
CN1104282C true CN1104282C (zh) | 2003-04-02 |
Family
ID=5281197
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99119906A Expired - Lifetime CN1104282C (zh) | 1999-10-28 | 1999-10-28 | 丙烯、异丁烯氨氧化流化床催化剂 |
Country Status (1)
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CN (1) | CN1104282C (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7071140B2 (en) | 2002-12-02 | 2006-07-04 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
BR0316852B1 (pt) | 2002-12-02 | 2013-03-19 | composiÇÕes de catalisador e processo de conversço de uma olefina. | |
CN100398204C (zh) * | 2005-08-15 | 2008-07-02 | 中国石油化工股份有限公司 | 丙烯氨氧化生产丙烯腈催化剂 |
US8420566B2 (en) | 2010-03-23 | 2013-04-16 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
US8258073B2 (en) | 2010-03-23 | 2012-09-04 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
US8455388B2 (en) | 2010-03-23 | 2013-06-04 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
US8153546B2 (en) | 2010-03-23 | 2012-04-10 | Ineos Usa Llc | Mixed metal oxide ammoxidation catalysts |
MX2016015443A (es) * | 2014-05-29 | 2017-03-23 | Ineos Europe Ag | Catalizadores para amoxidacion selectiva mejorados. |
CN112121811B (zh) * | 2019-11-15 | 2021-12-14 | 北京水木滨华科技有限公司 | 一种制备甲基丙烯腈用催化剂及制备甲基丙烯腈的方法 |
-
1999
- 1999-10-28 CN CN99119906A patent/CN1104282C/zh not_active Expired - Lifetime
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Publication number | Publication date |
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CN1302690A (zh) | 2001-07-11 |
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Owner name: CHINA PETROLEUM & CHEMICAL CORPORATION Free format text: FORMER OWNER: SHANGHAI PETROCHEMIAL CO LTD, CHINA PETROCHEMICAL CORP Effective date: 20051014 |
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Effective date of registration: 20051014 Address after: 100029, No. 6, Xin Xin Street East, Beijing, Chaoyang District Patentee after: Sinopec Corp. Address before: 200540 Jinshan District Petrochemical Company, Shanghai Patentee before: Shanghai Petrochemical Co., Ltd., SINOPEC |
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Granted publication date: 20030402 |