MX2015002752A - Metodo de preparación de una d,l-metionina limpia. - Google Patents

Metodo de preparación de una d,l-metionina limpia.

Info

Publication number
MX2015002752A
MX2015002752A MX2015002752A MX2015002752A MX2015002752A MX 2015002752 A MX2015002752 A MX 2015002752A MX 2015002752 A MX2015002752 A MX 2015002752A MX 2015002752 A MX2015002752 A MX 2015002752A MX 2015002752 A MX2015002752 A MX 2015002752A
Authority
MX
Mexico
Prior art keywords
methionine
solution
preparing
temperature
glycolyurea
Prior art date
Application number
MX2015002752A
Other languages
English (en)
Other versions
MX362811B (es
Inventor
Zhirong Chen
Cunchao Wang
Chuqiu Zhao
Sujuan Wang
Chengfeng Zhang
Tao Long
Xinhong Liu
Original Assignee
Zhejiang Nhu Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Nhu Co Ltd filed Critical Zhejiang Nhu Co Ltd
Publication of MX2015002752A publication Critical patent/MX2015002752A/es
Publication of MX362811B publication Critical patent/MX362811B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/57—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C323/58—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups with amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36—Oxygen or sulfur atoms
    • C07D207/38—2-Pyrrolones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención describe un método para la preparación de una D,L-metionina limpia, que comprende las siguientes etapas: prepara una solución de cianuro de potasio absorbiendo el ácido cianhídrico con un licor madre de cristalización que contiene carbonato de potasio como el líquido absorbente, a continuación, la solución de cianuro de potasio reacciona con 3-metiltio propionaldehido y solución de bicarbonato de amonio a 50-150°C durante 3-15 minutos logrando la solución de 5-(ß-metiltioetilo)gl icoliurea, y luego se calienta esta solución de 5-(ß-metiltioetilo)glicoliurea a una temperatura de 140-220°C para la reacción de saponificación durante 2-5 minutos, al finalizar la saponificación, se baja la temperatura a 140-220°C, y se lleva a cabo la extracción con un disolvente orgánico, la fase acuosa se neutralizada y cristaliza con el CO2, y al filtrar, lavar y sacar, se logra el producto calificado de D,L -metionina; después de que el licor madre filtrado de cristalización de D,L-metionina se caliente a 110-160°C y remueva CO2, el ciclo completo se aplica como liquido absorbente de ácido cianhídrico; la ruta de proceso de la presente invención es una ruta adecuada para la producción continua y limpia, sin producir sustancialmente aguas y gases residuales.
MX2015002752A 2012-09-03 2013-01-06 Método limpio de preparación de una d,l-metionina. MX362811B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210320297.0A CN102796033B (zh) 2012-09-03 2012-09-03 一种清洁的d，l-蛋氨酸制备方法
PCT/CN2013/070129 WO2014032401A1 (zh) 2012-09-03 2013-01-06 一种清洁的d,l-蛋氨酸制备方法

Publications (2)

Publication Number Publication Date
MX2015002752A true MX2015002752A (es) 2015-09-25
MX362811B MX362811B (es) 2019-02-13

Family

ID=47195373

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015002752A MX362811B (es) 2012-09-03 2013-01-06 Método limpio de preparación de una d,l-metionina.

Country Status (14)

Country Link
US (1) US9206120B2 (es)
EP (1) EP2894147B1 (es)
JP (1) JP6026663B2 (es)
KR (1) KR101689366B1 (es)
CN (1) CN102796033B (es)
AU (1) AU2013307993B2 (es)
BR (1) BR112015004487B1 (es)
ES (1) ES2687247T3 (es)
MX (1) MX362811B (es)
MY (1) MY191517A (es)
RU (1) RU2604064C2 (es)
SG (1) SG11201501553PA (es)
WO (1) WO2014032401A1 (es)
ZA (1) ZA201502259B (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102796033B (zh) * 2012-09-03 2014-02-26 浙江新和成股份有限公司 一种清洁的d，l-蛋氨酸制备方法
JP2014108956A (ja) * 2012-12-04 2014-06-12 Sumitomo Chemical Co Ltd メチオニンの製造方法
CN105061193B (zh) * 2015-08-10 2017-03-22 蓝星（北京）技术中心有限公司 蛋氨酸生产废水处理中回收有机物的方法
CN105296557A (zh) * 2015-10-31 2016-02-03 高大元 一种D,L-α-蛋氨酸钙的合成方法
CN106119311A (zh) * 2016-07-11 2016-11-16 雷春生 一种腐乳废水制备高纯蛋氨酸的方法
CN106432018A (zh) * 2016-09-14 2017-02-22 宁夏紫光天化蛋氨酸有限责任公司 一种d,l‑蛋氨酸的环保清洁生产方法
CN106432020B (zh) * 2016-09-14 2018-11-20 宁夏紫光天化蛋氨酸有限责任公司 一种d,l-蛋氨酸的分离纯化方法
CN106565608A (zh) * 2016-09-30 2017-04-19 宁夏紫光天化蛋氨酸有限责任公司 一种高纯度5‑(2‑甲硫基乙基)‑乙内酰脲的制备方法
EP3725770B1 (en) * 2017-12-13 2022-08-10 Sumitomo Chemical Company, Limited Method for producing methionine
EP3730479B1 (en) * 2017-12-19 2022-10-19 Sumitomo Chemical Company, Limited Method for manufacturing methionine
JP6983256B2 (ja) * 2017-12-27 2021-12-17 住友化学株式会社 精製メチオニンの製造方法
EP3733645B1 (en) * 2017-12-28 2022-07-20 Sumitomo Chemical Company, Limited Method for producing methionine
CN109232335B (zh) * 2018-10-15 2021-02-26 天宝动物营养科技股份有限公司 一种蛋氨酸制备方法
KR20200138606A (ko) 2019-06-01 2020-12-10 장환석 치약 칫솔
CN112445254B (zh) * 2019-09-05 2022-11-08 中石油吉林化工工程有限公司 脱氢氰酸塔塔顶冷凝器液位与塔顶温度的控制系统及方法
CN111362453B (zh) * 2020-03-18 2020-11-03 北京百灵天地环保科技股份有限公司 一种高矿化度煤矿矿井水达标处理及资源化利用装置及其使用方法
CN112661682B (zh) * 2020-12-21 2023-08-01 宁夏紫光天化蛋氨酸有限责任公司 一种生产dl-蛋氨酸的方法
CN112679399A (zh) * 2020-12-22 2021-04-20 宁夏紫光天化蛋氨酸有限责任公司 一种蛋氨酸结晶母液后处理方法及分离设备
CN112694428B (zh) * 2020-12-24 2023-09-26 宁夏紫光天化蛋氨酸有限责任公司 一种蛋氨酸生产中油相杂质的处理方法
CN116535338B (zh) * 2023-04-25 2023-11-03 重庆渝化新材料有限责任公司 一种d,l-蛋氨酸生产过程中钾盐回收循环工艺
CN116675631B (zh) * 2023-06-07 2023-12-12 重庆渝化新材料有限责任公司 一种d,l-蛋氨酸的循环生产方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069251A (en) * 1969-02-08 1978-01-17 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Continuous process for the manufacture of methionine
JPS49818B1 (es) * 1970-08-12 1974-01-10
CN85108505A (zh) 1985-11-14 1987-05-20 西北大学 5-(β-甲硫基乙基)海因的催化一步合成法
CN85108531A (zh) 1985-11-14 1987-05-20 西北大学 5-(β-甲硫基乙基)海因水解制备蛋氨酸的方法
DE4235295A1 (de) 1992-10-20 1994-04-21 Degussa Kontinuierlich durchführbares Verfahren zur Herstellung von Methionin oder Methioninderivaten
DE19547236A1 (de) * 1995-12-18 1997-07-03 Degussa Verfahren zur Herstellung von D,L-Methionin oder dessen Salz
JP3292119B2 (ja) * 1997-11-26 2002-06-17 住友化学工業株式会社 メチオニンの製造方法
CN1589259A (zh) 2001-11-29 2005-03-02 日本曹达株式会社 蛋氨酸的制备方法
DE10238212A1 (de) 2002-08-21 2004-03-04 Degussa Ag Verfahren zur Herstellung von α-Aminosäuren durch Hydrolyse von Hydantoinen bei erhöhtem Druck und erhöhter Temperatur
ES2365849T3 (es) * 2004-02-14 2011-10-11 Evonik Degussa Gmbh Procedimiento para producir metionina.
JP4997729B2 (ja) 2005-08-29 2012-08-08 住友化学株式会社 メチオニンの製造方法
DE102005060316A1 (de) * 2005-12-16 2007-06-21 Kiefer, Hans, Dr. Verfahren zur Herstellung von Methionin
JP2008266298A (ja) * 2007-03-27 2008-11-06 Sumitomo Chemical Co Ltd メチオニンの製造方法
JP2009292796A (ja) * 2008-06-09 2009-12-17 Sumitomo Chemical Co Ltd メチオニンの製造方法
JP5307512B2 (ja) * 2008-11-07 2013-10-02 住友化学株式会社 メチオニンの製造方法
JP2010111642A (ja) * 2008-11-07 2010-05-20 Sumitomo Chemical Co Ltd メチオニンの製造方法
JP2010111640A (ja) * 2008-11-07 2010-05-20 Sumitomo Chemical Co Ltd メチオニンの製造方法
FR2938535B1 (fr) * 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
JP2011126794A (ja) * 2009-12-15 2011-06-30 Sumitomo Chemical Co Ltd メチオニンの製造方法
JP5524736B2 (ja) * 2010-06-29 2014-06-18 住友化学株式会社 メチオニンの製造方法
CN102399177B (zh) * 2010-09-15 2016-02-24 李宽义 连续化合成蛋氨酸的环保清洁工艺方法
CN102796033B (zh) * 2012-09-03 2014-02-26 浙江新和成股份有限公司 一种清洁的d，l-蛋氨酸制备方法

Also Published As

Publication number Publication date
MX362811B (es) 2019-02-13
US20150284323A1 (en) 2015-10-08
CN102796033A (zh) 2012-11-28
RU2015111118A (ru) 2016-10-27
JP2015526485A (ja) 2015-09-10
EP2894147A4 (en) 2016-05-25
SG11201501553PA (en) 2015-05-28
JP6026663B2 (ja) 2016-11-16
CN102796033B (zh) 2014-02-26
BR112015004487B1 (pt) 2020-04-14
EP2894147A1 (en) 2015-07-15
AU2013307993B2 (en) 2017-02-02
AU2013307993A1 (en) 2015-04-30
ZA201502259B (en) 2016-06-29
US9206120B2 (en) 2015-12-08
EP2894147B1 (en) 2018-07-18
MY191517A (en) 2022-06-28
KR101689366B1 (ko) 2016-12-26
ES2687247T3 (es) 2018-10-24
RU2604064C2 (ru) 2016-12-10
WO2014032401A1 (zh) 2014-03-06
BR112015004487A2 (pt) 2017-08-08
KR20150084774A (ko) 2015-07-22

Similar Documents

Publication Publication Date Title
MX2015002752A (es) Metodo de preparación de una d,l-metionina limpia.
MY169253A (en) Low-energy-consumption process for the production of high-purity melamine, through the pyrolysis of urea, and relative equipment
ATE528277T1 (de) Herstellungsverfahren für xylylendiamin
MY198293A (en) Method of reprocessing alkanesulfonic acid
PH12015500173A1 (en) Method for removing an ester from a vapor mixture
PH12019500435A1 (en) Method for producing scandium compound, and scandium compound
WO2012019674A3 (en) High temperature lactam neutralisation
RU2016142459A (ru) Способ производства молочной кислоты
AR081267A1 (es) Procedimiento de obtencion de la forma cristalina a del febuxostat
RU2014108016A (ru) Способ выделения и очистки 1, 4-диаминобутана из ферметационного раствора
JP2013173717A (ja) 精製メチオニンの製造方法
WO2016105107A3 (ko) 무수당 알코올의 효과적인 생산 및 정제 방법
SG193010A1 (en) Cellulose phosphate powder product and process for manufacture thereof, and application to removal of contaminants from aqueous solutions
WO2016105106A3 (ko) 무수당 알코올의 연속적인 생산방법
CN102304093A (zh) 一种磺胺二甲嘧啶生产工艺
PH12019550110A1 (en) Method for producing acetic acid
MY167894A (en) Method for producing 2-furaldehyde
CN104163790B (zh) 一种2-氨基-4-甲基-5溴吡啶的制备工艺
CN104387351A (zh) 一种4,4’-二氟二苯并呋喃的合成方法
AR080279A1 (es) Procedimiento de preparacion del acido 4-nitro-oxi-metil-benzoico
UA105563U (uk) Спосіб дезактивації високосольових радіоактивних розчинів з відмиванням кристалів у режимі витіснення
RU2013129405A (ru) Способ регенерации калиевой селитры
UA105888U (uk) Спосіб дезактивації високосолевих радіоактивних розчинів з відмиванням кристалів у режимі змішування
RU2009139698A (ru) Способ регенерации калиевой селитры
RU2011108852A (ru) Способ переработки сивушного масла

Legal Events

Date Code Title Description
FG Grant or registration