MX2012004362A - Polibutadienos catalizados con neodimio. - Google Patents
Polibutadienos catalizados con neodimio.Info
- Publication number
- MX2012004362A MX2012004362A MX2012004362A MX2012004362A MX2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A
- Authority
- MX
- Mexico
- Prior art keywords
- neodymium
- polybutadiene
- sub
- catalyzed
- molar mass
- Prior art date
Links
- 229920002857 polybutadiene Polymers 0.000 title abstract 4
- 239000005062 Polybutadiene Substances 0.000 abstract 3
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/005—Cores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
- C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L47/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/907—Specified means of reacting components of transition metal catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
Abstract
La invención se refiere a un polibutadieno de alto peso molecular, lineal y catalizado con neodimio que tiene una alta proporción de unidades de cis-1,4 > 95 % y una proporción reducida de contenido de 1,2-vinilo < 1 % y con un índice de distribución de masas molares (IDMM) reducido, presentando el butadieno una viscosidad Mooney (ML1+4 100 °C) de 70 - 90 y un índice de distribución de masas molares inferior a 10.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09173297A EP2311889A1 (de) | 2009-10-16 | 2009-10-16 | Neodym-katalysierte Polybutadiene |
| PCT/EP2010/065461 WO2011045393A1 (de) | 2009-10-16 | 2010-10-14 | Neodym-katalysierte polybutadiene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2012004362A true MX2012004362A (es) | 2012-05-29 |
Family
ID=41651376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2012004362A MX2012004362A (es) | 2009-10-16 | 2010-10-14 | Polibutadienos catalizados con neodimio. |
Country Status (14)
| Country | Link |
|---|---|
| US (3) | US20120208964A1 (es) |
| EP (2) | EP2311889A1 (es) |
| JP (1) | JP5577406B2 (es) |
| KR (1) | KR101393830B1 (es) |
| CN (1) | CN102574955B (es) |
| BR (1) | BR112012008782B1 (es) |
| ES (1) | ES2661064T3 (es) |
| HU (1) | HUE036937T2 (es) |
| MX (1) | MX2012004362A (es) |
| PL (1) | PL2488561T3 (es) |
| RU (1) | RU2554351C9 (es) |
| TW (1) | TWI488867B (es) |
| WO (1) | WO2011045393A1 (es) |
| ZA (1) | ZA201202719B (es) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2311889A1 (de) * | 2009-10-16 | 2011-04-20 | LANXESS Deutschland GmbH | Neodym-katalysierte Polybutadiene |
| US20130280460A1 (en) * | 2010-12-24 | 2013-10-24 | Toyo Styrene Co., Ltd. | Flame-retardant styrene resin composition and toner cartridge container produced by using it |
| US9758646B2 (en) * | 2011-11-03 | 2017-09-12 | Arlanxeo Deutschland Gmbh | NdBR wet masterbatch |
| EP2819853B1 (en) * | 2012-02-29 | 2015-11-18 | Trinseo Europe GmbH | Process for producing diene polymers |
| KR101511187B1 (ko) * | 2012-05-28 | 2015-04-10 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 폴리이소프렌, 그것의 제조방법, 그로부터 제조되는 폴리이소프렌 고무 화합물 및 가황물 |
| CN103626926B (zh) * | 2012-08-21 | 2016-03-30 | 中国石油化工股份有限公司 | 一种聚丁二烯接枝异戊橡胶及其制备方法和硫化胶及混炼胶 |
| FR3005471B1 (fr) | 2013-05-13 | 2015-04-24 | Michelin & Cie | Composition de caoutchouc a haute processabilite pour pneumatique adapte pour un roulage a plat |
| FR3005438B1 (fr) * | 2013-05-13 | 2015-04-24 | Michelin & Cie | Pneumatique adapte pour un roulage a plat comprenant une nappe de carcasse en polyester |
| JP5933497B2 (ja) | 2013-09-17 | 2016-06-08 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| BR112016008352B1 (pt) * | 2013-10-16 | 2021-09-08 | Arlanxeo Deutschland Gmbh | Processo para a produção de polibutadienos catalisados com neodímio (ndbr), composição de borracha que contêm um polibutadieno catalisado com neodímio (ndbr) e uso de composição de borracha |
| JP2015098561A (ja) * | 2013-11-20 | 2015-05-28 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| MY174801A (en) * | 2014-03-31 | 2020-05-15 | Ube Elastomer Co Ltd | Polybutadiene |
| CN113105573A (zh) | 2015-01-28 | 2021-07-13 | 株式会社普利司通 | 具有改善的耐冷流性的顺式-1,4-聚二烯 |
| JP6717840B2 (ja) * | 2015-01-28 | 2020-07-08 | 株式会社ブリヂストン | 熟成ランタニド系触媒系及びシス−1,4−ポリジエンの調製における同触媒系の使用 |
| EP3507104B1 (en) | 2016-09-02 | 2024-03-27 | Bridgestone Corporation | Production of cis-1,4-polydienes with multiple silane functional groups prepared byin-situ |
| US10954327B2 (en) | 2016-10-31 | 2021-03-23 | Bridgestone Corporation | Methods to prepare catalysts for in-line bulk polymerization |
| JP6928102B2 (ja) | 2016-11-09 | 2021-09-01 | 株式会社ブリヂストン | ポリブタジエンとポリイソプレンとの高シス−1,4ブロックコポリマー |
| CA3110627C (en) | 2018-08-27 | 2023-10-03 | Fraunhofer-Gesellschaft Zur Forderung Der Angewandten Forschung E.V. | Biomimetic synthetic rubber |
| PL3966259T3 (pl) * | 2019-05-07 | 2025-03-03 | Bridgestone Americas Tire Operations, Llc | Modyfikowany polimer polibutadienowy o wysokiej zawartości wiązania cis, powiązane sposoby i kompozycje gumy |
| WO2020232212A1 (en) | 2019-05-14 | 2020-11-19 | Bridgestone Corporation | Modified high-cis polybutadiene polymer, related methods and tire components |
| EP3838932B1 (en) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthesis of isoprene-butadiene copolymer rubbers |
| US12404359B2 (en) * | 2020-10-22 | 2025-09-02 | Korea Kumho Petrochemical Co., Ltd. | Rubber polymer, method for preparing thereof, and rubber composition comprising the same |
| CN112552441B (zh) * | 2020-12-09 | 2021-09-07 | 浙江传化合成材料有限公司 | 一种钕系稀土橡胶的制备方法 |
| US20250206856A1 (en) * | 2022-04-08 | 2025-06-26 | Arlanxeo Deutschland Gmbh | Branched modified diene rubbers |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2141159C3 (de) | 1971-08-17 | 1983-11-24 | Degussa Ag, 6000 Frankfurt | Schwefel enthaltende Organosiliciumverbindungen |
| US4076550A (en) | 1971-08-17 | 1978-02-28 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Reinforcing additive |
| DE2830080A1 (de) | 1978-07-08 | 1980-01-17 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| DE2848964A1 (de) | 1978-11-11 | 1980-05-22 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| IT1140452B (it) | 1981-09-25 | 1986-09-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
| JPS5945337A (ja) * | 1982-09-07 | 1984-03-14 | Japan Synthetic Rubber Co Ltd | 生強度の改良されたポリブタジエンゴム組成物 |
| IT1164238B (it) | 1983-05-25 | 1987-04-08 | Anic Spa | Procedimento per la polimerizzazione del butadiene |
| JPS6040109A (ja) * | 1983-08-15 | 1985-03-02 | Asahi Chem Ind Co Ltd | ポリブタジエンおよびその製造方法 |
| SU1539199A1 (ru) * | 1987-07-27 | 1990-01-30 | Институт нефтехимических процессов им.Ю.Г.Мамедалиева | Каталитическа композици дл полимеризации бутадиена |
| GB8830007D0 (en) | 1988-12-22 | 1989-02-15 | Enichem Elastomers | Polymerization of butadiene |
| DE69119125T3 (de) | 1990-03-02 | 2001-01-11 | Bridgestone Corp., Tokio/Tokyo | Luftreifen |
| GB9119234D0 (en) | 1991-09-09 | 1991-10-23 | Enichem Elastomers Ltd | Conjugated diene polymerisation |
| RU2028309C1 (ru) * | 1993-07-05 | 1995-02-09 | Акционерное общество открытого типа "Ефремовский завод синтетического каучука" | Способ получения цис-полибутадиена |
| DE4406947A1 (de) | 1994-03-03 | 1995-09-07 | Bayer Ag | Schwefel-/Silizium-haltige Verstärkungsadditive enthaltende Kautschukmischungen |
| DE4435311A1 (de) | 1994-10-01 | 1996-04-04 | Huels Silicone Gmbh | Verstärkungsadditive |
| DE19544469A1 (de) | 1995-09-23 | 1997-03-27 | Degussa | Organosilanverbindungen und Kieselsäure enthaltende vulkanisierbare Kautschukmischungen und Verfahren zur Herstellung |
| MX9603304A (es) | 1995-09-23 | 1997-03-29 | Degussa | Proceso para la produccion de mezclas de caucho vulcanizables. |
| DE69714663T2 (de) * | 1996-06-28 | 2003-04-10 | Ube Industries, Ltd. | Verfahren zur Herstellung von Polybutadien |
| BR9902609B1 (pt) | 1999-05-27 | 2010-08-10 | processo para a preparação de neodecanoato de neodìmio, processo para a preparação de um sistema catalìtico homogêneo de coordenação, processo para polimerização em solução para a preparação de polibutadieno de alto teor de ligações 1,4-cis. | |
| KR100352764B1 (ko) * | 2000-03-16 | 2002-09-16 | 금호석유화학 주식회사 | 신규한 단분자 니오디뮴 카르복실레이트 화합물 및 이를포함하는 디엔 중합용 촉매 |
| DE10037076A1 (de) * | 2000-07-27 | 2002-02-07 | Bayer Ag | Polybutadiene mit verringertem Verhältnis Lösungsviskosität/ Mooney-Viskosität |
| WO2002068484A1 (en) | 2001-02-28 | 2002-09-06 | Bridgestone Corporation | Continuous process for the production of conjugated diene polymers having narrow molecular weight distribution and products therefrom |
| CN1176121C (zh) * | 2001-10-12 | 2004-11-17 | 中国科学院长春应用化学研究所 | 稀土催化体系及丁二烯聚合工艺 |
| CN1342719A (zh) * | 2001-10-12 | 2002-04-03 | 中国科学院长春应用化学研究所 | 稀土催化体系及其催化丁二烯顺式聚合工艺 |
| US6780948B2 (en) * | 2002-03-28 | 2004-08-24 | The Goodyear Tire & Rubber Company | Synthesis of polyisoprene with neodymium catalyst |
| JP4075533B2 (ja) * | 2002-08-30 | 2008-04-16 | 日本ゼオン株式会社 | 共役ジエン重合触媒、その製造方法および共役ジエン重合体の製造方法 |
| WO2004076504A2 (en) * | 2003-02-21 | 2004-09-10 | Dow Global Technologies, Inc. | Process for homo- or copolymerization of conjugated olefines |
| JP4333181B2 (ja) * | 2003-03-27 | 2009-09-16 | 宇部興産株式会社 | ゴム組成物 |
| CN1528794A (zh) * | 2003-09-25 | 2004-09-15 | 中国科学院长春应用化学研究所 | 稀土顺丁橡胶分子质量分布的调节方法 |
| US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
| EP2311889A1 (de) * | 2009-10-16 | 2011-04-20 | LANXESS Deutschland GmbH | Neodym-katalysierte Polybutadiene |
-
2009
- 2009-10-16 EP EP09173297A patent/EP2311889A1/de not_active Withdrawn
-
2010
- 2010-10-14 HU HUE10763728A patent/HUE036937T2/hu unknown
- 2010-10-14 PL PL10763728T patent/PL2488561T3/pl unknown
- 2010-10-14 US US13/500,440 patent/US20120208964A1/en not_active Abandoned
- 2010-10-14 CN CN201080046732.4A patent/CN102574955B/zh active Active
- 2010-10-14 ES ES10763728.2T patent/ES2661064T3/es active Active
- 2010-10-14 BR BR112012008782-7A patent/BR112012008782B1/pt not_active IP Right Cessation
- 2010-10-14 JP JP2012533639A patent/JP5577406B2/ja active Active
- 2010-10-14 RU RU2012119827/04A patent/RU2554351C9/ru active
- 2010-10-14 WO PCT/EP2010/065461 patent/WO2011045393A1/de not_active Ceased
- 2010-10-14 EP EP10763728.2A patent/EP2488561B1/de active Active
- 2010-10-14 MX MX2012004362A patent/MX2012004362A/es active IP Right Grant
- 2010-10-14 KR KR1020127012473A patent/KR101393830B1/ko active Active
- 2010-10-15 TW TW099135151A patent/TWI488867B/zh not_active IP Right Cessation
-
2012
- 2012-04-13 ZA ZA2012/02719A patent/ZA201202719B/en unknown
-
2013
- 2013-04-11 US US13/860,892 patent/US8846837B2/en active Active
-
2014
- 2014-08-27 US US14/470,287 patent/US9279025B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2554351C9 (ru) | 2016-06-20 |
| WO2011045393A1 (de) | 2011-04-21 |
| ES2661064T3 (es) | 2018-03-27 |
| KR20120091216A (ko) | 2012-08-17 |
| EP2311889A1 (de) | 2011-04-20 |
| KR101393830B1 (ko) | 2014-05-12 |
| ZA201202719B (en) | 2013-09-25 |
| RU2012119827A (ru) | 2013-11-27 |
| US20120208964A1 (en) | 2012-08-16 |
| BR112012008782A2 (pt) | 2018-04-17 |
| US9279025B2 (en) | 2016-03-08 |
| EP2488561A1 (de) | 2012-08-22 |
| US8846837B2 (en) | 2014-09-30 |
| PL2488561T3 (pl) | 2018-06-29 |
| EP2488561B1 (de) | 2017-12-20 |
| JP2013507510A (ja) | 2013-03-04 |
| US20130237669A1 (en) | 2013-09-12 |
| JP5577406B2 (ja) | 2014-08-20 |
| TW201129577A (en) | 2011-09-01 |
| BR112012008782A8 (pt) | 2018-06-12 |
| CN102574955B (zh) | 2014-04-30 |
| TWI488867B (zh) | 2015-06-21 |
| HUE036937T2 (hu) | 2018-08-28 |
| BR112012008782B1 (pt) | 2020-02-11 |
| CN102574955A (zh) | 2012-07-11 |
| RU2554351C2 (ru) | 2015-06-27 |
| US20140364573A1 (en) | 2014-12-11 |
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