MX2012004362A - Polibutadienos catalizados con neodimio. - Google Patents

Polibutadienos catalizados con neodimio.

Info

Publication number
MX2012004362A
MX2012004362A MX2012004362A MX2012004362A MX2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A MX 2012004362 A MX2012004362 A MX 2012004362A
Authority
MX
Mexico
Prior art keywords
neodymium
polybutadiene
sub
catalyzed
molar mass
Prior art date
Application number
MX2012004362A
Other languages
English (en)
Inventor
Norbert Steinhauser
Heike Kloppenburg
Original Assignee
Lanxess Deutschland Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Deutschland Gmbh filed Critical Lanxess Deutschland Gmbh
Publication of MX2012004362A publication Critical patent/MX2012004362A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06Butadiene
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B37/00Solid balls; Rigid hollow balls; Marbles
    • A63B37/0003Golf balls
    • A63B37/005Cores
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18Homopolymers or copolymers of nitriles
    • C08L33/20Homopolymers or copolymers of acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L47/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/907Specified means of reacting components of transition metal catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physical Education & Sports Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)

Abstract

La invención se refiere a un polibutadieno de alto peso molecular, lineal y catalizado con neodimio que tiene una alta proporción de unidades de cis-1,4 > 95 % y una proporción reducida de contenido de 1,2-vinilo < 1 % y con un índice de distribución de masas molares (IDMM) reducido, presentando el butadieno una viscosidad Mooney (ML1+4 100 °C) de 70 - 90 y un índice de distribución de masas molares inferior a 10.
MX2012004362A 2009-10-16 2010-10-14 Polibutadienos catalizados con neodimio. MX2012004362A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09173297A EP2311889A1 (de) 2009-10-16 2009-10-16 Neodym-katalysierte Polybutadiene
PCT/EP2010/065461 WO2011045393A1 (de) 2009-10-16 2010-10-14 Neodym-katalysierte polybutadiene

Publications (1)

Publication Number Publication Date
MX2012004362A true MX2012004362A (es) 2012-05-29

Family

ID=41651376

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012004362A MX2012004362A (es) 2009-10-16 2010-10-14 Polibutadienos catalizados con neodimio.

Country Status (14)

Country Link
US (3) US20120208964A1 (es)
EP (2) EP2311889A1 (es)
JP (1) JP5577406B2 (es)
KR (1) KR101393830B1 (es)
CN (1) CN102574955B (es)
BR (1) BR112012008782B1 (es)
ES (1) ES2661064T3 (es)
HU (1) HUE036937T2 (es)
MX (1) MX2012004362A (es)
PL (1) PL2488561T3 (es)
RU (1) RU2554351C9 (es)
TW (1) TWI488867B (es)
WO (1) WO2011045393A1 (es)
ZA (1) ZA201202719B (es)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2311889A1 (de) * 2009-10-16 2011-04-20 LANXESS Deutschland GmbH Neodym-katalysierte Polybutadiene
US20130280460A1 (en) * 2010-12-24 2013-10-24 Toyo Styrene Co., Ltd. Flame-retardant styrene resin composition and toner cartridge container produced by using it
US9758646B2 (en) * 2011-11-03 2017-09-12 Arlanxeo Deutschland Gmbh NdBR wet masterbatch
JP6073379B2 (ja) * 2012-02-29 2017-02-01 トリンゼオ ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング ジエンポリマーの製造工程
ITUD20130076A1 (it) * 2012-05-28 2013-11-29 Beijing Res Inst Of Chemical Industry Poliisoprene, suo metodo di preparazione, composti in gomma poliisoprenica e suo vulcanizzato
CN103626926B (zh) * 2012-08-21 2016-03-30 中国石油化工股份有限公司 一种聚丁二烯接枝异戊橡胶及其制备方法和硫化胶及混炼胶
FR3005438B1 (fr) * 2013-05-13 2015-04-24 Michelin & Cie Pneumatique adapte pour un roulage a plat comprenant une nappe de carcasse en polyester
FR3005471B1 (fr) 2013-05-13 2015-04-24 Michelin & Cie Composition de caoutchouc a haute processabilite pour pneumatique adapte pour un roulage a plat
JP5933497B2 (ja) 2013-09-17 2016-06-08 住友ゴム工業株式会社 空気入りタイヤ
CN105764928A (zh) * 2013-10-16 2016-07-13 阿朗新科德国有限责任公司 具有摩尔质量断裂的NdBR
JP2015098561A (ja) * 2013-11-20 2015-05-28 住友ゴム工業株式会社 空気入りタイヤ
WO2015151625A1 (ja) * 2014-03-31 2015-10-08 宇部興産株式会社 ポリブタジエン
EP3250617B1 (en) 2015-01-28 2019-01-02 Bridgestone Corporation Cis-1,4-polydienes with improved cold flow resistance
EP3250616B1 (en) 2015-01-28 2019-01-23 Bridgestone Corporation Aged lanthanide-based catalyst systems and their use in the preparation of cis-1,4-polydienes
JP6869333B2 (ja) 2016-09-02 2021-05-12 株式会社ブリヂストン ポリマーセメントのその場ヒドロシリル化により調製される複数のシラン官能基を有するシス−1,4−ポリジエンの製造
WO2018081798A2 (en) 2016-10-31 2018-05-03 Bridgestone Corporation Methods to prepare catalysts for in-line bulk polymerization
RU2720010C1 (ru) 2016-11-09 2020-04-23 Бриджстоун Корпорейшн Блок-сополимеры полибутадиена и полиизопрена с высоким содержанием цис-1,4-связей
KR102632287B1 (ko) 2018-08-27 2024-02-01 프라운호퍼-게젤샤프트 츄어 푀르더룽 데어 안게반텐 포르슝에.파우. 생체모방형 합성 고무
EP4495146A3 (en) 2019-05-07 2025-04-09 Bridgestone Americas Tire Operations, LLC Modified high-cis polybutadiene polymer, related methods and rubber compositions
CN113825777B (zh) 2019-05-14 2025-01-28 株式会社普利司通 改性的高顺式聚丁二烯聚合物、相关方法和轮胎部件
EP3838932B1 (en) * 2019-12-20 2022-08-10 The Goodyear Tire & Rubber Company Synthesis of isoprene-butadiene copolymer rubbers
KR102923646B1 (ko) 2020-08-21 2026-02-05 주식회사 엘지화학 공액디엔계 중합체, 이의 제조방법 및 상기 중합체를 포함하는 고무 조성물
US12404359B2 (en) * 2020-10-22 2025-09-02 Korea Kumho Petrochemical Co., Ltd. Rubber polymer, method for preparing thereof, and rubber composition comprising the same
CN112552441B (zh) * 2020-12-09 2021-09-07 浙江传化合成材料有限公司 一种钕系稀土橡胶的制备方法
CN118696068A (zh) * 2022-04-08 2024-09-24 阿朗新科德国有限责任公司 支化的改性二烯橡胶

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2141159C3 (de) 1971-08-17 1983-11-24 Degussa Ag, 6000 Frankfurt Schwefel enthaltende Organosiliciumverbindungen
US4076550A (en) 1971-08-17 1978-02-28 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Reinforcing additive
DE2830080A1 (de) 1978-07-08 1980-01-17 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
DE2848964A1 (de) * 1978-11-11 1980-05-22 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
IT1140452B (it) 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
JPS5945337A (ja) * 1982-09-07 1984-03-14 Japan Synthetic Rubber Co Ltd 生強度の改良されたポリブタジエンゴム組成物
IT1164238B (it) 1983-05-25 1987-04-08 Anic Spa Procedimento per la polimerizzazione del butadiene
JPS6040109A (ja) * 1983-08-15 1985-03-02 Asahi Chem Ind Co Ltd ポリブタジエンおよびその製造方法
SU1539199A1 (ru) * 1987-07-27 1990-01-30 Институт нефтехимических процессов им.Ю.Г.Мамедалиева Каталитическа композици дл полимеризации бутадиена
GB8830007D0 (en) 1988-12-22 1989-02-15 Enichem Elastomers Polymerization of butadiene
EP0447066B2 (en) 1990-03-02 2000-08-16 Bridgestone Corporation Pneumatic tyres
GB9119234D0 (en) 1991-09-09 1991-10-23 Enichem Elastomers Ltd Conjugated diene polymerisation
RU2028309C1 (ru) * 1993-07-05 1995-02-09 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-полибутадиена
DE4406947A1 (de) 1994-03-03 1995-09-07 Bayer Ag Schwefel-/Silizium-haltige Verstärkungsadditive enthaltende Kautschukmischungen
DE4435311A1 (de) 1994-10-01 1996-04-04 Huels Silicone Gmbh Verstärkungsadditive
DE19544469A1 (de) 1995-09-23 1997-03-27 Degussa Organosilanverbindungen und Kieselsäure enthaltende vulkanisierbare Kautschukmischungen und Verfahren zur Herstellung
MX9603304A (es) 1995-09-23 1997-03-29 Degussa Proceso para la produccion de mezclas de caucho vulcanizables.
DE69714663T2 (de) * 1996-06-28 2003-04-10 Ube Industries, Ltd. Verfahren zur Herstellung von Polybutadien
BR9902609B1 (pt) 1999-05-27 2010-08-10 processo para a preparação de neodecanoato de neodìmio, processo para a preparação de um sistema catalìtico homogêneo de coordenação, processo para polimerização em solução para a preparação de polibutadieno de alto teor de ligações 1,4-cis.
KR100352764B1 (ko) * 2000-03-16 2002-09-16 금호석유화학 주식회사 신규한 단분자 니오디뮴 카르복실레이트 화합물 및 이를포함하는 디엔 중합용 촉매
DE10037076A1 (de) * 2000-07-27 2002-02-07 Bayer Ag Polybutadiene mit verringertem Verhältnis Lösungsviskosität/ Mooney-Viskosität
DE60213380T2 (de) 2001-02-28 2007-08-23 Bridgestone Corp. Kontinuierliches verfahren zur herstellung von engeren molekulargewichtverteilungen konjugierten dien-polymeren und dadurch hergestellten produkten
CN1176121C (zh) * 2001-10-12 2004-11-17 中国科学院长春应用化学研究所 稀土催化体系及丁二烯聚合工艺
CN1342719A (zh) * 2001-10-12 2002-04-03 中国科学院长春应用化学研究所 稀土催化体系及其催化丁二烯顺式聚合工艺
US6780948B2 (en) * 2002-03-28 2004-08-24 The Goodyear Tire & Rubber Company Synthesis of polyisoprene with neodymium catalyst
JP4075533B2 (ja) * 2002-08-30 2008-04-16 日本ゼオン株式会社 共役ジエン重合触媒、その製造方法および共役ジエン重合体の製造方法
RU2348653C2 (ru) * 2003-02-21 2009-03-10 Дау Глобал Текнолоджиз Инк. Способ гомо- или сополимеризации сопряженных олефинов
JP4333181B2 (ja) * 2003-03-27 2009-09-16 宇部興産株式会社 ゴム組成物
CN1528794A (zh) * 2003-09-25 2004-09-15 中国科学院长春应用化学研究所 稀土顺丁橡胶分子质量分布的调节方法
US7094849B2 (en) * 2003-12-15 2006-08-22 Bridgestone Corporation Bulk polymerization process for producing polydienes
EP2311889A1 (de) * 2009-10-16 2011-04-20 LANXESS Deutschland GmbH Neodym-katalysierte Polybutadiene

Also Published As

Publication number Publication date
ES2661064T3 (es) 2018-03-27
PL2488561T3 (pl) 2018-06-29
US20120208964A1 (en) 2012-08-16
RU2554351C9 (ru) 2016-06-20
BR112012008782A2 (pt) 2018-04-17
JP2013507510A (ja) 2013-03-04
US20140364573A1 (en) 2014-12-11
BR112012008782A8 (pt) 2018-06-12
KR101393830B1 (ko) 2014-05-12
EP2488561A1 (de) 2012-08-22
CN102574955B (zh) 2014-04-30
BR112012008782B1 (pt) 2020-02-11
EP2488561B1 (de) 2017-12-20
ZA201202719B (en) 2013-09-25
HUE036937T2 (hu) 2018-08-28
KR20120091216A (ko) 2012-08-17
CN102574955A (zh) 2012-07-11
JP5577406B2 (ja) 2014-08-20
TWI488867B (zh) 2015-06-21
US20130237669A1 (en) 2013-09-12
WO2011045393A1 (de) 2011-04-21
US8846837B2 (en) 2014-09-30
RU2554351C2 (ru) 2015-06-27
US9279025B2 (en) 2016-03-08
EP2311889A1 (de) 2011-04-20
RU2012119827A (ru) 2013-11-27
TW201129577A (en) 2011-09-01

Similar Documents

Publication Publication Date Title
MX2012004362A (es) Polibutadienos catalizados con neodimio.
MY159678A (en) Bimodal neodymium-catalyzed polybutadiene
EP4550349A3 (en) User interfaces for group workouts
WO2011084553A3 (en) Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
MY176435A (en) Ndbr with molar mass breakdown
MY150517A (en) Modified diene rubber, production method thereof, and rubber composition and tire using the rubber
MX2009006033A (es) Composiciones y articulos que contienen una matriz de polimero reticulado y un liquido activo inmovilizado, asi como metodos para fabricarlos.
GB2475666A (en) Polymers derived from benzobis (silolothiophene) and their use as organic semiconductors
GEP20135754B (en) Spirocycles as inhibitors of 11-beta hydroxyl steroid dehydrogenase type 1
EP3670551A3 (en) Copolymer, rubber composition, rubber composition for tire side use, crosslinked rubber composition and tire
GB2475667A (en) Polymers derived from bis (thienocyclopenta) benzothiadiazole and their use as organic semiconductors
MY157704A (en) Silico-sodo-calcic glass sheet
SG143136A1 (en) Allophanate-modified stabilizers and the polymer polyols prepared from these stabilizers
MX341648B (es) Hule de estireno butadieno con una incorporacion novedosa de estireno.
WO2010144344A3 (en) Melanocortin receptor-specific peptides
IN2012DN05019A (es)
MX2016003817A (es) Copolimeros elastomericos modificados por enlaces de bajo vinilo.
MX341179B (es) Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo.
PH12013501407A1 (en) Fiber and probiotics for reducing intestinal symptoms related to stress
MX338029B (es) Composiciones farmaceuticas topicas.
MY156963A (en) Ethanol compositions
MX2014005224A (es) Lote madre húmedo de ndbr.
EP4356750A3 (en) Compositions and methods
PH12013501406A1 (en) Fiber and probiotics for reducing intestinal symptoms related to chronic stress
WO2009134368A3 (en) Methods of producing bacterial alginates

Legal Events

Date Code Title Description
FG Grant or registration