MX2011013037A - Proceso para preparar glicidil esteres de acidos monocarboxilicos ramificados. - Google Patents
Proceso para preparar glicidil esteres de acidos monocarboxilicos ramificados.Info
- Publication number
- MX2011013037A MX2011013037A MX2011013037A MX2011013037A MX2011013037A MX 2011013037 A MX2011013037 A MX 2011013037A MX 2011013037 A MX2011013037 A MX 2011013037A MX 2011013037 A MX2011013037 A MX 2011013037A MX 2011013037 A MX2011013037 A MX 2011013037A
- Authority
- MX
- Mexico
- Prior art keywords
- sup
- acid
- epoxyalkyl halide
- epoxyalkyl
- halide
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Por lo tanto, la invención se relaciona con un proceso para la preparación de un glicidil éster de un ácido monocarboxílico ramificado mediante la reacción de un ácido monocarboxílico alifático de la fórmula R1R2R3COOH, en donde R1, R2, y R3 cada uno representan independientemente un radical alquilo de la estructura normal o ramificada que contiene desde 1 hasta 20 átomos de carbono y un haluro de epoxialquilo que contiene desde 3 hasta 13 átomos de carbono en la presencia de un catalizador, en donde mayor que una cantidad estequiométrica de haluro de epoxialquilo es reaccionada con el ácido (por ejemplo, preferiblemente en la proporción molar de haluro de epoxialquilo con respecto al ácido que está en el intervalo desde 1.02:1 hasta 1.50:1) para formar un producto de reacción intermediario que comprende una halohidrina, el haluro de epoxialquilo se agrega al ácido con enfriamiento apropiado de los reactivos y/o la mezcla de reacción para mantener la temperatura de la mezcla de reacción debajo de 80°C, con lo cual el haluro de epoxialquilo y el ácido son reaccionados a una temperatura debajo de 80°C (preferiblemente en el intervalo desde 55 hasta 75°C) por un tiempo suficiente para reducir la cantidad de ácido a no más de 2 % en peso pero no menos de 0.1 % en peso calculados en la cantidad inicial de ácido, extraer opcionalmente cualquier exceso de haluro de epoxialquilo del producto de reacción antes de la reacción de cierre del anillo, someter el producto de reacción a una reacción de cierre del anillo (DHC) y opcionalmente a uno o más tratamientos posteriores (ADHC) para la extracción de cualquier funcionalidad halo restante.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09075264A EP2261220A1 (en) | 2009-06-11 | 2009-06-11 | Process for preparing glycidyl esters of branched monocarboxylic acids |
| PCT/EP2010/003334 WO2010142396A1 (en) | 2009-06-11 | 2010-06-02 | Process for preparing glycidyl esters of branched monocarboxylic acids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2011013037A true MX2011013037A (es) | 2012-02-21 |
Family
ID=41100757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2011013037A MX2011013037A (es) | 2009-06-11 | 2010-06-02 | Proceso para preparar glicidil esteres de acidos monocarboxilicos ramificados. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8802872B2 (es) |
| EP (2) | EP2261220A1 (es) |
| JP (1) | JP5726180B2 (es) |
| KR (1) | KR101384835B1 (es) |
| CN (1) | CN102803242B (es) |
| BR (1) | BRPI1013046A2 (es) |
| MX (1) | MX2011013037A (es) |
| RU (2) | RU2515897C2 (es) |
| TW (1) | TWI405758B (es) |
| WO (1) | WO2010142396A1 (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2474537A1 (en) * | 2010-12-22 | 2012-07-11 | Momentive Specialty Chemicals Research Belgium S.A. | glycidyl esters of alpha, alpha branched acids compositions |
| EP2476672A1 (en) | 2010-12-22 | 2012-07-18 | Momentive Specialty Chemicals Research Belgium S.A. | Glycidyl esters of alpha , alpha branched acids compositions |
| US9803051B2 (en) | 2011-10-19 | 2017-10-31 | Hexion Inc. | Acrylic polyol resins compositions |
| US9663597B2 (en) | 2011-10-19 | 2017-05-30 | Hexicon Inc. | Acrylic polyol resins compositions |
| DK2768903T3 (da) | 2011-10-19 | 2020-08-24 | Hexion Res Belgium Sa | Sammensætninger af polyetherpolyolresiner |
| EP2780315B1 (de) * | 2011-11-17 | 2018-01-24 | BASF Coatings GmbH | Verwendung von glyceroldiestern als reaktivverdünner und diese enthaltende beschichtungsmittel |
| WO2013075805A2 (en) * | 2011-11-25 | 2013-05-30 | Momentive Specialty Chemicals Research Beigium S.A. | Epoxy compositions |
| CN102924407A (zh) * | 2012-11-30 | 2013-02-13 | 西南化工研究设计院有限公司 | 一种一元羧酸缩水甘油酯的精制方法 |
| KR101650528B1 (ko) * | 2015-04-24 | 2016-08-23 | 대달산업주식회사 | 알파-분지형 지방족 모노카르복시산의 글리시딜 에스테르의 제조 방법 |
| EP3115409A1 (en) * | 2015-07-10 | 2017-01-11 | Hexion Research Belgium SA | Odorless polyester stabilizer compositions |
| KR20170112515A (ko) | 2016-03-31 | 2017-10-12 | 코오롱인더스트리 주식회사 | 글리시딜에스테르 화합물의 제조방법 |
| US20190225734A1 (en) | 2016-07-08 | 2019-07-25 | Resinate Materials Group, Inc. | Sustainable polyol blends for high-performance coatings |
| US20190119510A1 (en) * | 2017-10-23 | 2019-04-25 | Hexion Inc. | Glycidyl esters of alpha, alpha branched acids compositions |
| EP3808823A1 (en) * | 2019-10-14 | 2021-04-21 | Hexion Research Belgium SA | Glycidyl esters of alpha, alpha branched acids from renewable sources and formulation thereof |
| CN110683996A (zh) * | 2019-11-01 | 2020-01-14 | 于翔 | 一种叔碳酸缩水甘油酯的制备方法 |
| KR20220152321A (ko) * | 2020-03-20 | 2022-11-15 | 인제비티 사우스 캐롤라이나, 엘엘씨 | 톨유 유래 글리시딜 에스테르 및 그 제조 방법 |
| CN111978502B (zh) * | 2020-08-18 | 2022-04-22 | 北京化工大学常州先进材料研究院 | 一种氨酯油丙烯酸酯光固化树脂及其制备方法 |
| CN117777060A (zh) * | 2023-12-26 | 2024-03-29 | 同宇新材料(广东)股份有限公司 | 一种亚麻油酸缩水甘油酯的制备方法 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3075999A (en) | 1963-01-29 | Glycidyl esteks | ||
| GB763559A (en) | 1953-11-23 | 1956-12-12 | Bataafsche Petroleum | A process for preparing epoxy esters |
| US2992239A (en) | 1957-08-01 | 1961-07-11 | American Cyanamid Co | Preparing glycidyl esters of higher fatty acids |
| DE1219481B (de) | 1958-12-29 | 1966-06-23 | Shell Int Research | Verfahren zur Herstellung von Carbonsaeureglycidylestern |
| US3178454A (en) | 1959-05-19 | 1965-04-13 | Shell Oil Co | Epoxy esters of alpha, alpha-dialkyl monocarboxylic acids |
| NL239308A (es) | 1959-05-19 | |||
| DE1211177B (de) | 1964-08-27 | 1966-02-24 | Bayer Ag | Verfahren zur Herstellung von Epoxyalkylestern von hydroaromatischen Mono- und Polycarbonsaeuren |
| US3859314A (en) | 1967-06-29 | 1975-01-07 | Celanese Coatings Co | Process for preparing glycidyl esters of polycarboxylic acids |
| JPS49815B1 (es) | 1970-10-27 | 1974-01-10 | ||
| DE2127699C3 (de) | 1971-06-04 | 1979-08-23 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von hydrolyseresistenten Glycidylestern |
| SU431162A1 (ru) * | 1972-06-23 | 1974-06-05 | Способ получения глицидиловых эфиров карбоновых кислот | |
| JPS5133528B2 (es) | 1972-09-19 | 1976-09-20 | ||
| JPS53147018A (en) | 1977-05-26 | 1978-12-21 | Nippon Oil & Fats Co Ltd | Preparation of carboxylic acid glycidyl ester |
| JPS57130980A (en) | 1981-02-07 | 1982-08-13 | Toto Kasei Kk | Preparation of epoxyalkyl ester |
| JPS57203077A (en) | 1981-06-06 | 1982-12-13 | New Japan Chem Co Ltd | Production of alpha-branched saturated fatty acid glycidyl ester |
| EP0475238A3 (en) | 1990-09-13 | 1994-05-25 | Dow Chemical Co | Mesogenic glycidyl esters |
| JPH0578340A (ja) | 1991-09-19 | 1993-03-30 | Nippon Oil & Fats Co Ltd | グリシジルエステルの製造方法及びこの方法により得られた多価グリシジルエステル |
| AU714033B2 (en) | 1996-07-19 | 1999-12-16 | Nissan Chemical Industries Ltd. | Method for producing purified epoxy compound |
| TW455584B (en) | 1998-09-23 | 2001-09-21 | Shell Int Research | Process for the preparation of glycidylesters of branched carboxylic acids |
| US6570028B1 (en) | 2000-02-25 | 2003-05-27 | Resolution Performance Products Llc | Process for the preparation of glycidylesters of branched carboxylic acids |
| JP2003171371A (ja) | 2001-12-10 | 2003-06-20 | Yokkaichi Chem Co Ltd | α−モノ分岐飽和脂肪族カルボン酸グリシジルエステルの製造方法 |
| CN1425729A (zh) | 2002-12-30 | 2003-06-25 | 中国科学院广州化学研究所 | 丙烯海松酸二缩水甘油酯及其环氧树脂和它们的制法 |
| CN101245053B (zh) | 2007-02-15 | 2011-04-13 | 天津市四友精细化学品有限公司 | 叔碳酸缩水甘油酯的制备方法 |
| CN101245033A (zh) | 2007-02-16 | 2008-08-20 | 上海天伟生物制药有限公司 | 异丝氨酸酯衍生物及其制备方法 |
| US8372994B2 (en) | 2007-06-28 | 2013-02-12 | Basf Se | C10 alkanoic acid glycidyl esters and use thereof |
| CN100545154C (zh) | 2007-07-09 | 2009-09-30 | 南京林业大学 | (甲基)丙烯酸缩水甘油酯的合成方法 |
| CN101220134A (zh) * | 2007-12-14 | 2008-07-16 | 中国科学院广州化学研究所 | 聚合松香二缩水甘油酯环氧树脂及其制备方法 |
-
2009
- 2009-06-11 EP EP09075264A patent/EP2261220A1/en not_active Withdrawn
-
2010
- 2010-06-02 EP EP10739480.1A patent/EP2440539B1/en active Active
- 2010-06-02 CN CN201080025488.3A patent/CN102803242B/zh active Active
- 2010-06-02 RU RU2012100273/04A patent/RU2515897C2/ru active
- 2010-06-02 JP JP2012514373A patent/JP5726180B2/ja active Active
- 2010-06-02 US US13/377,470 patent/US8802872B2/en active Active
- 2010-06-02 WO PCT/EP2010/003334 patent/WO2010142396A1/en active Application Filing
- 2010-06-02 KR KR1020127000517A patent/KR101384835B1/ko active IP Right Grant
- 2010-06-02 BR BRPI1013046A patent/BRPI1013046A2/pt not_active Application Discontinuation
- 2010-06-02 MX MX2011013037A patent/MX2011013037A/es active IP Right Grant
- 2010-06-02 RU RU2014102706/04A patent/RU2560877C2/ru active
- 2010-06-11 TW TW099119175A patent/TWI405758B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CN102803242A (zh) | 2012-11-28 |
| JP2012529447A (ja) | 2012-11-22 |
| WO2010142396A1 (en) | 2010-12-16 |
| CN102803242B (zh) | 2015-09-23 |
| EP2261220A1 (en) | 2010-12-15 |
| JP5726180B2 (ja) | 2015-05-27 |
| KR101384835B1 (ko) | 2014-04-15 |
| RU2014102706A (ru) | 2015-06-27 |
| US8802872B2 (en) | 2014-08-12 |
| KR20120016313A (ko) | 2012-02-23 |
| TW201114751A (en) | 2011-05-01 |
| EP2440539B1 (en) | 2017-10-04 |
| RU2012100273A (ru) | 2013-07-20 |
| EP2440539A1 (en) | 2012-04-18 |
| US20120095244A1 (en) | 2012-04-19 |
| RU2515897C2 (ru) | 2014-05-20 |
| TWI405758B (zh) | 2013-08-21 |
| BRPI1013046A2 (pt) | 2015-09-15 |
| RU2560877C2 (ru) | 2015-08-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |