MX166114B - Peliculas de alcohol polivinilico modificadas con comonomeros anionicos no hidrolizables - Google Patents
Peliculas de alcohol polivinilico modificadas con comonomeros anionicos no hidrolizablesInfo
- Publication number
- MX166114B MX166114B MX011345A MX1134588A MX166114B MX 166114 B MX166114 B MX 166114B MX 011345 A MX011345 A MX 011345A MX 1134588 A MX1134588 A MX 1134588A MX 166114 B MX166114 B MX 166114B
- Authority
- MX
- Mexico
- Prior art keywords
- film
- cleaning composition
- resin
- unsaturated
- butanoic
- Prior art date
Links
- 239000004372 Polyvinyl alcohol Substances 0.000 title 1
- 229920002451 polyvinyl alcohol Polymers 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 4
- 238000004140 cleaning Methods 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 150000001266 acyl halides Chemical class 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- YIYBQIKDCADOSF-UHFFFAOYSA-N pentenoic acid group Chemical group C(C=CCC)(=O)O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 150000003460 sulfonic acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Detergent Compositions (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La presente invención se refiere a una combinación de película polimérica soluble en agua y composición limpiadora, caracterizada porque comprende: a) una película soluble en agua, con un espesor de aproximadamente 25.4-127 micras, formada a partir de una resina copolimérica de alcohol vinílico que tiene aproximadamente 0-10 por ciento molar de grupos acetato residuales y aproximadamente 1-6 por ciento molar de un comonómero aniónico no hidrolizable, convertido del grupo de comonómeros que consisten de: (i) ácidos insaturados, tales como ácido acrílico, metacrílico, cis-2-butanoico, 3-butanoico, cinámico, fenilcinámico, pentenoico, metilenmalónico, sus sales de metal alcalino y de amonio y sus derivados halogenuro de acilo; (ii) ésteres insaturados, amidas y halogenuros de acilo de la siguiente estructura I: (v) ácidos sulfónicos insaturados y sus derivados; (vi) mezclas de los mismos: polimerizándose la resina a un grado que dé por resultado una viscosidad de resina, cuando se disuelve en agua a 25 grados C, a un nivel aproximado de 4 por ciento de entre aproximadamente 4-35 cPs, incluyendo la película una cantidad efectiva plastificadora de un plastificante; y (b) una composición limpiadora alcalina o que contiene borato, por lo menos parcialmente encerrada por la película, en donde la película se disolverá cuando se coloca en un medio acuoso, liberando la composición limpiadora.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/050,260 US4747976A (en) | 1987-05-14 | 1987-05-14 | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
| US07/175,778 US4885105A (en) | 1987-05-14 | 1988-03-31 | Films from PVA modified with nonhydrolyzable anionic comonomers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX166114B true MX166114B (es) | 1992-12-21 |
Family
ID=26728073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX011345A MX166114B (es) | 1987-05-14 | 1988-05-02 | Peliculas de alcohol polivinilico modificadas con comonomeros anionicos no hidrolizables |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US4885105A (es) |
| EP (1) | EP0291198B1 (es) |
| JP (1) | JPS6414244A (es) |
| AR (1) | AR245748A1 (es) |
| AU (1) | AU604890B2 (es) |
| BR (1) | BR8802311A (es) |
| CA (1) | CA1309924C (es) |
| DE (1) | DE3885507T2 (es) |
| ES (1) | ES2059512T3 (es) |
| MX (1) | MX166114B (es) |
Families Citing this family (103)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| JP2847308B2 (ja) * | 1989-12-22 | 1999-01-20 | 日東化学工業株式会社 | ラジカル硬化性ポリビニルアルコール誘導体 |
| US5080226A (en) * | 1990-07-18 | 1992-01-14 | Rhone-Poulenc Ag Company | Containerization system for agrochemicals and the like |
| US5280835A (en) * | 1990-05-02 | 1994-01-25 | Rhone-Poulenc Inc. | Laminated bags for containerization of toxic and hazardous materials |
| US5328025A (en) * | 1990-07-18 | 1994-07-12 | Rhone-Poulenc Inc. | Containerization system for agrochemicals and the like |
| US5224601A (en) * | 1990-07-18 | 1993-07-06 | Rhone-Poulenc Ag Company | Water soluble package |
| US5139152A (en) * | 1990-07-18 | 1992-08-18 | Rhone-Poulenc Ag Company | Water dispersible gel formulations |
| US5222595A (en) * | 1990-07-18 | 1993-06-29 | Rhone-Poulenc Ag Company | Bag in a bag for containerization of toxic or hazardous material |
| US5248038A (en) * | 1990-07-18 | 1993-09-28 | Rhone-Poulenc Inc. | Containerization system for agrochemicals and the like |
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| US5316688A (en) * | 1991-05-14 | 1994-05-31 | Ecolab Inc. | Water soluble or dispersible film covered alkaline composition |
| AU655282B2 (en) * | 1991-06-14 | 1994-12-15 | Rhone-Poulenc Agro | New aqueous formulations |
| WO1993000476A1 (en) * | 1991-06-20 | 1993-01-07 | Jujo Paper Co., Ltd. | Packaging material and methods of manufacturing and disposing of said material |
| US5439683A (en) * | 1992-10-09 | 1995-08-08 | Rhone-Poulenc Inc. | Paddy rice treatment |
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| TW399096B (en) | 1996-07-03 | 2000-07-21 | Kao Corp | The sheet-like article for laundry |
| JP3126675B2 (ja) * | 1997-01-23 | 2001-01-22 | 花王株式会社 | シート状洗剤 |
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| GB9906176D0 (en) * | 1999-03-17 | 1999-05-12 | Unilever Plc | Process for producing a water soluble package |
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| AU5405300A (en) * | 1999-06-25 | 2001-01-31 | Henkel Kommanditgesellschaft Auf Aktien | Packaging for a portion of an active substance |
| DE19934254A1 (de) * | 1999-07-21 | 2001-01-25 | Henkel Kgaa | Wasch- oder Reinigungsmittel-Portion mit neuer Verpackung und Verpackung für Wasch- oder Reinigungsmittel |
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| BR0110724A (pt) | 2000-05-15 | 2003-03-11 | Unilever Nv | Composição detergente lìquida não aquosa concentrada, e, processo para a preparação de uma composição detergente lìquida concentrada |
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| US8940676B2 (en) | 2000-11-27 | 2015-01-27 | The Procter & Gamble Company | Detergent products, methods and manufacture |
| EP1672058B2 (en) * | 2000-11-27 | 2022-03-30 | The Procter & Gamble Company | Dishwashing method |
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| US1897856A (en) * | 1929-02-06 | 1933-02-14 | Eastman Kodak Co | Manufacture of polymerized vinyl alcohol |
| US2328922A (en) * | 1939-06-13 | 1943-09-07 | Rohm & Haas | Process of preparing vinyl alcoholmethacrylic ester copolymers |
| US2403004A (en) * | 1942-07-10 | 1946-07-02 | Eastman Kodak Co | Deesterification of copolymers of acrylic esters and vinyl esters |
| US2467774A (en) * | 1945-02-16 | 1949-04-19 | Du Pont | Process of hydrolyzing vinyl ester polymers |
| US2715590A (en) * | 1952-11-24 | 1955-08-16 | Pont Company Of Canada Ltd Du | Process for sizing nylon yarn |
| US3005809A (en) * | 1957-09-05 | 1961-10-24 | Air Reduction | Vinyl alcohol-crotonic acid copolymers |
| NL266245A (es) * | 1960-06-22 | |||
| US3161621A (en) * | 1961-04-19 | 1964-12-15 | Air Reduction | Water soluble films of vinyl alcoholvinylalkyl ether-vinyl acetate copolymers |
| US3284364A (en) * | 1963-01-25 | 1966-11-08 | American Cyanamid Co | Soil anti-redeposition agents |
| US3365408A (en) * | 1963-08-12 | 1968-01-23 | Kurashiki Rayon Co | Adhesives comprising polyvinyl alcohol bearing or mixed with substances bearing carboxyl groups, and a stabilizer |
| US3299012A (en) * | 1963-12-17 | 1967-01-17 | Monsanto Co | Process for the preparation of polylactones |
| US3409598A (en) * | 1964-06-18 | 1968-11-05 | Denki Kagaku Kogyo Kk | Process for the manufacture of water soluble polyvinyl alcohol film |
| US3300546A (en) * | 1965-10-05 | 1967-01-24 | American Cyanamid Co | Water soluble envelope prepared from a graft polymer of alkyl acrylate on a polyvinyl alcohol/polyvinyl acetate co-polymer |
| US3505303A (en) * | 1966-12-30 | 1970-04-07 | Air Reduction | Water soluble modified polyvinyl alcohol films |
| US3513142A (en) * | 1969-03-07 | 1970-05-19 | Du Pont | Production of polyvinyl alcohol of improved color by oxygen purge |
| US3689469A (en) * | 1969-07-15 | 1972-09-05 | Du Pont | Copolymers of vinyl alcohol and methyl methacrylate and uses therefor |
| BE757441A (fr) * | 1969-10-14 | 1971-04-13 | Armstrong Richard M | Agencement pour monter des lames de raclage |
| US3892905A (en) * | 1970-08-12 | 1975-07-01 | Du Pont | Cold water soluble plastic films |
| US3904806A (en) * | 1973-02-28 | 1975-09-09 | Du Pont | Composite films of glassine-polyolefin copolymer resins exhibiting high oxygen barrier characteristics |
| US4155971A (en) * | 1976-08-18 | 1979-05-22 | E. I. Du Pont De Nemours And Company | Method of making water-soluble films from polyvinyl alcohol compositions |
| US4156047A (en) * | 1976-08-18 | 1979-05-22 | E. I. Du Pont De Nemours And Company | Water-soluble films from polyvinyl alcohol compositions |
| US4119604A (en) * | 1976-08-18 | 1978-10-10 | E. I. Du Pont De Nemours And Company | Polyvinyl alcohol compositions for use in the preparation of water-soluble films |
| GB1543136A (en) * | 1976-10-18 | 1979-03-28 | Sumitomo Chemical Co | Method for the preparation of water-insoluble hydrophilic gels |
| JPS53111189A (en) * | 1977-03-07 | 1978-09-28 | Kuraray Co | Fiber size agent |
| US4115292A (en) * | 1977-04-20 | 1978-09-19 | The Procter & Gamble Company | Enzyme-containing detergent articles |
| FR2421928A1 (fr) * | 1978-02-13 | 1979-11-02 | Rhone Poulenc Ind | Composition polymere de revetement et son emploi pour la fabrication d'emballages stratifies |
| US4388442A (en) * | 1979-10-13 | 1983-06-14 | Denki Kagaku Kogyo Kabushiki Kaisha | Stabilizer or dispersing agent for use in a suspension polymerization of a vinyl compound comprising a modified and partially hydrolyzed anionic polyvinyl alcohol |
| US4359440A (en) * | 1980-11-24 | 1982-11-16 | Gulf Oil Corporation | Coextrusion process for preparing a composite polymer film construction |
| NZ199130A (en) * | 1980-12-15 | 1985-07-31 | Colgate Palmolive Co | Water-soluble film;mixture of polyvinyl alcohol and polyacrylic acid |
| CA1230795A (en) * | 1981-11-10 | 1987-12-29 | Edward J. Kaufmann | Borate solution soluble polyvinyl alcohol films |
| US4626372A (en) * | 1981-11-10 | 1986-12-02 | The Clorox Company | Borate solution soluble polyvinyl alcohol films |
| US4550141A (en) * | 1983-08-22 | 1985-10-29 | E. I. Du Pont De Nemours And Company | Blends of ionomer with propylene copolymer |
| US4539263A (en) * | 1983-08-22 | 1985-09-03 | E. I. Du Pont De Nemours And Company | Blends of ionomer with propylene copolymer and articles |
| JPS60141702A (ja) * | 1983-12-29 | 1985-07-26 | Nippon Synthetic Chem Ind Co Ltd:The | エチレン−酢酸ビニル共重合体の連続ケン化方法 |
| US4557852A (en) * | 1984-04-09 | 1985-12-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
| US4654395A (en) * | 1984-04-09 | 1987-03-31 | S. C. Johnson & Son, Inc. | Water-soluble polymer sheet for delivering laundry care additive and laundry care product formed from same |
| DE3415880A1 (de) * | 1984-04-28 | 1985-10-31 | Henkel KGaA, 4000 Düsseldorf | Waschzusatz |
| JPS6157700A (ja) * | 1984-08-29 | 1986-03-24 | 花王株式会社 | 水溶性フイルムを用いた単位包装洗剤製品 |
| JPS6197348A (ja) * | 1984-10-17 | 1986-05-15 | Kao Corp | 耐湿、防湿性に優れた水溶性フイルム |
| US4602062A (en) * | 1984-12-24 | 1986-07-22 | Texaco Inc. | Conversion of polyvinyl alcohol to acrylic acid polymer |
| DE3540833A1 (de) * | 1985-11-18 | 1987-05-21 | Henkel Kgaa | Verfahren zum umhuellen von textilpflegemitteln |
| JPH0627205B2 (ja) * | 1986-12-27 | 1994-04-13 | 日本合成化学工業株式会社 | アルカリ性物質包装用のポリビニルアルコ−ルフイルム |
| US4747976A (en) * | 1987-05-14 | 1988-05-31 | The Clorox Company | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
| JP3197636B2 (ja) * | 1992-11-19 | 2001-08-13 | 保土谷化学工業株式会社 | ウレタン組成物 |
| JPH06197348A (ja) * | 1992-12-25 | 1994-07-15 | Aiphone Co Ltd | テレビインターホン装置 |
-
1988
- 1988-03-31 US US07/175,778 patent/US4885105A/en not_active Ceased
- 1988-04-27 DE DE88303799T patent/DE3885507T2/de not_active Revoked
- 1988-04-27 ES ES88303799T patent/ES2059512T3/es not_active Expired - Lifetime
- 1988-04-27 EP EP88303799A patent/EP0291198B1/en not_active Revoked
- 1988-05-02 AR AR88310736A patent/AR245748A1/es active
- 1988-05-02 MX MX011345A patent/MX166114B/es unknown
- 1988-05-05 CA CA000566038A patent/CA1309924C/en not_active Expired - Lifetime
- 1988-05-12 AU AU16082/88A patent/AU604890B2/en not_active Ceased
- 1988-05-12 BR BR8802311A patent/BR8802311A/pt not_active Application Discontinuation
- 1988-05-13 JP JP63115041A patent/JPS6414244A/ja active Pending
-
1991
- 1991-12-04 US US07/803,297 patent/USRE34988E/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU1608288A (en) | 1988-11-17 |
| ES2059512T3 (es) | 1994-11-16 |
| JPS6414244A (en) | 1989-01-18 |
| DE3885507D1 (de) | 1993-12-16 |
| DE3885507T2 (de) | 1994-03-03 |
| US4885105A (en) | 1989-12-05 |
| USRE34988E (en) | 1995-07-04 |
| AU604890B2 (en) | 1991-01-03 |
| AR245748A1 (es) | 1994-02-28 |
| EP0291198A3 (en) | 1990-03-28 |
| EP0291198A2 (en) | 1988-11-17 |
| EP0291198B1 (en) | 1993-11-10 |
| CA1309924C (en) | 1992-11-10 |
| BR8802311A (pt) | 1988-12-13 |
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