MX166114B - Peliculas de alcohol polivinilico modificadas con comonomeros anionicos no hidrolizables - Google Patents
Peliculas de alcohol polivinilico modificadas con comonomeros anionicos no hidrolizablesInfo
- Publication number
- MX166114B MX166114B MX011345A MX1134588A MX166114B MX 166114 B MX166114 B MX 166114B MX 011345 A MX011345 A MX 011345A MX 1134588 A MX1134588 A MX 1134588A MX 166114 B MX166114 B MX 166114B
- Authority
- MX
- Mexico
- Prior art keywords
- film
- cleaning composition
- resin
- unsaturated
- butanoic
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La presente invención se refiere a una combinación de película polimérica soluble en agua y composición limpiadora, caracterizada porque comprende: a) una película soluble en agua, con un espesor de aproximadamente 25.4-127 micras, formada a partir de una resina copolimérica de alcohol vinílico que tiene aproximadamente 0-10 por ciento molar de grupos acetato residuales y aproximadamente 1-6 por ciento molar de un comonómero aniónico no hidrolizable, convertido del grupo de comonómeros que consisten de: (i) ácidos insaturados, tales como ácido acrílico, metacrílico, cis-2-butanoico, 3-butanoico, cinámico, fenilcinámico, pentenoico, metilenmalónico, sus sales de metal alcalino y de amonio y sus derivados halogenuro de acilo; (ii) ésteres insaturados, amidas y halogenuros de acilo de la siguiente estructura I: (v) ácidos sulfónicos insaturados y sus derivados; (vi) mezclas de los mismos: polimerizándose la resina a un grado que dé por resultado una viscosidad de resina, cuando se disuelve en agua a 25 grados C, a un nivel aproximado de 4 por ciento de entre aproximadamente 4-35 cPs, incluyendo la película una cantidad efectiva plastificadora de un plastificante; y (b) una composición limpiadora alcalina o que contiene borato, por lo menos parcialmente encerrada por la película, en donde la película se disolverá cuando se coloca en un medio acuoso, liberando la composición limpiadora.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/050,260 US4747976A (en) | 1987-05-14 | 1987-05-14 | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
US07/175,778 US4885105A (en) | 1987-05-14 | 1988-03-31 | Films from PVA modified with nonhydrolyzable anionic comonomers |
Publications (1)
Publication Number | Publication Date |
---|---|
MX166114B true MX166114B (es) | 1992-12-21 |
Family
ID=26728073
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX011345A MX166114B (es) | 1987-05-14 | 1988-05-02 | Peliculas de alcohol polivinilico modificadas con comonomeros anionicos no hidrolizables |
Country Status (10)
Country | Link |
---|---|
US (2) | US4885105A (es) |
EP (1) | EP0291198B1 (es) |
JP (1) | JPS6414244A (es) |
AR (1) | AR245748A1 (es) |
AU (1) | AU604890B2 (es) |
BR (1) | BR8802311A (es) |
CA (1) | CA1309924C (es) |
DE (1) | DE3885507T2 (es) |
ES (1) | ES2059512T3 (es) |
MX (1) | MX166114B (es) |
Families Citing this family (101)
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US5222595A (en) * | 1990-07-18 | 1993-06-29 | Rhone-Poulenc Ag Company | Bag in a bag for containerization of toxic or hazardous material |
US5328025A (en) * | 1990-07-18 | 1994-07-12 | Rhone-Poulenc Inc. | Containerization system for agrochemicals and the like |
US5224601A (en) * | 1990-07-18 | 1993-07-06 | Rhone-Poulenc Ag Company | Water soluble package |
US5248038A (en) * | 1990-07-18 | 1993-09-28 | Rhone-Poulenc Inc. | Containerization system for agrochemicals and the like |
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AU655282B2 (en) * | 1991-06-14 | 1994-12-15 | Rhone-Poulenc Agro | New aqueous formulations |
CA2090016A1 (en) * | 1991-06-20 | 1992-12-21 | Toshio Sasaki | Packaging material and methods of manufacturing and disposing of said material |
US5439683A (en) * | 1992-10-09 | 1995-08-08 | Rhone-Poulenc Inc. | Paddy rice treatment |
JP3262406B2 (ja) * | 1993-06-01 | 2002-03-04 | 花王株式会社 | 水溶性フィルムによる液体包装体 |
US6124036A (en) * | 1993-08-06 | 2000-09-26 | Milliken & Company | Aqueous colorant composition in water-soluble package |
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GB9906171D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
GB9906169D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
GB9906176D0 (en) * | 1999-03-17 | 1999-05-12 | Unilever Plc | Process for producing a water soluble package |
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DE19934254A1 (de) * | 1999-07-21 | 2001-01-25 | Henkel Kgaa | Wasch- oder Reinigungsmittel-Portion mit neuer Verpackung und Verpackung für Wasch- oder Reinigungsmittel |
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DE60102582T2 (de) | 2000-05-15 | 2004-08-05 | Unilever N.V. | Flüssiges reinigungsmittel |
US20020094942A1 (en) * | 2000-09-06 | 2002-07-18 | The Procter & Gamble Company | Fabric additive articles and package therefor |
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CN109312275B (zh) | 2016-06-13 | 2021-03-02 | 宝洁公司 | 由不同膜的组合制成且含有家庭护理组合物的水溶性单位剂量制品 |
US10907117B2 (en) | 2016-06-13 | 2021-02-02 | Monosol, Llc | Use of a first film and a second film to improve seal strength of a water-soluble unit dose article |
JP7133475B2 (ja) | 2016-06-13 | 2022-09-08 | モノソル リミテッド ライアビリティ カンパニー | 異なるフィルムの組み合わせから作製された水溶性単位用量物品 |
CN109153950A (zh) | 2016-06-13 | 2019-01-04 | 宝洁公司 | 由不同膜的组合制成的且含有家用护理组合物的水溶性单位剂量制品 |
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FR2421928A1 (fr) * | 1978-02-13 | 1979-11-02 | Rhone Poulenc Ind | Composition polymere de revetement et son emploi pour la fabrication d'emballages stratifies |
US4388442A (en) * | 1979-10-13 | 1983-06-14 | Denki Kagaku Kogyo Kabushiki Kaisha | Stabilizer or dispersing agent for use in a suspension polymerization of a vinyl compound comprising a modified and partially hydrolyzed anionic polyvinyl alcohol |
US4359440A (en) * | 1980-11-24 | 1982-11-16 | Gulf Oil Corporation | Coextrusion process for preparing a composite polymer film construction |
NZ199130A (en) * | 1980-12-15 | 1985-07-31 | Colgate Palmolive Co | Water-soluble film;mixture of polyvinyl alcohol and polyacrylic acid |
CA1230795A (en) * | 1981-11-10 | 1987-12-29 | Edward J. Kaufmann | Borate solution soluble polyvinyl alcohol films |
US4626372A (en) * | 1981-11-10 | 1986-12-02 | The Clorox Company | Borate solution soluble polyvinyl alcohol films |
US4539263A (en) * | 1983-08-22 | 1985-09-03 | E. I. Du Pont De Nemours And Company | Blends of ionomer with propylene copolymer and articles |
US4550141A (en) * | 1983-08-22 | 1985-10-29 | E. I. Du Pont De Nemours And Company | Blends of ionomer with propylene copolymer |
JPS60141702A (ja) * | 1983-12-29 | 1985-07-26 | Nippon Synthetic Chem Ind Co Ltd:The | エチレン−酢酸ビニル共重合体の連続ケン化方法 |
US4557852A (en) * | 1984-04-09 | 1985-12-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
US4654395A (en) * | 1984-04-09 | 1987-03-31 | S. C. Johnson & Son, Inc. | Water-soluble polymer sheet for delivering laundry care additive and laundry care product formed from same |
DE3415880A1 (de) * | 1984-04-28 | 1985-10-31 | Henkel KGaA, 4000 Düsseldorf | Waschzusatz |
JPS6157700A (ja) * | 1984-08-29 | 1986-03-24 | 花王株式会社 | 水溶性フイルムを用いた単位包装洗剤製品 |
JPS6197348A (ja) * | 1984-10-17 | 1986-05-15 | Kao Corp | 耐湿、防湿性に優れた水溶性フイルム |
US4602062A (en) * | 1984-12-24 | 1986-07-22 | Texaco Inc. | Conversion of polyvinyl alcohol to acrylic acid polymer |
DE3540833A1 (de) * | 1985-11-18 | 1987-05-21 | Henkel Kgaa | Verfahren zum umhuellen von textilpflegemitteln |
JPH0627205B2 (ja) * | 1986-12-27 | 1994-04-13 | 日本合成化学工業株式会社 | アルカリ性物質包装用のポリビニルアルコ−ルフイルム |
US4747976A (en) * | 1987-05-14 | 1988-05-31 | The Clorox Company | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
JP3197636B2 (ja) * | 1992-11-19 | 2001-08-13 | 保土谷化学工業株式会社 | ウレタン組成物 |
JPH06197348A (ja) * | 1992-12-25 | 1994-07-15 | Aiphone Co Ltd | テレビインターホン装置 |
-
1988
- 1988-03-31 US US07/175,778 patent/US4885105A/en not_active Ceased
- 1988-04-27 EP EP88303799A patent/EP0291198B1/en not_active Revoked
- 1988-04-27 DE DE88303799T patent/DE3885507T2/de not_active Revoked
- 1988-04-27 ES ES88303799T patent/ES2059512T3/es not_active Expired - Lifetime
- 1988-05-02 AR AR88310736A patent/AR245748A1/es active
- 1988-05-02 MX MX011345A patent/MX166114B/es unknown
- 1988-05-05 CA CA000566038A patent/CA1309924C/en not_active Expired - Lifetime
- 1988-05-12 BR BR8802311A patent/BR8802311A/pt not_active Application Discontinuation
- 1988-05-12 AU AU16082/88A patent/AU604890B2/en not_active Ceased
- 1988-05-13 JP JP63115041A patent/JPS6414244A/ja active Pending
-
1991
- 1991-12-04 US US07/803,297 patent/USRE34988E/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4885105A (en) | 1989-12-05 |
BR8802311A (pt) | 1988-12-13 |
AU604890B2 (en) | 1991-01-03 |
EP0291198A3 (en) | 1990-03-28 |
JPS6414244A (en) | 1989-01-18 |
AU1608288A (en) | 1988-11-17 |
CA1309924C (en) | 1992-11-10 |
AR245748A1 (es) | 1994-02-28 |
DE3885507T2 (de) | 1994-03-03 |
DE3885507D1 (de) | 1993-12-16 |
ES2059512T3 (es) | 1994-11-16 |
EP0291198B1 (en) | 1993-11-10 |
EP0291198A2 (en) | 1988-11-17 |
USRE34988E (en) | 1995-07-04 |
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