KR970028879A - 규소계 전하 전송 재료의 제조방법 - Google Patents
규소계 전하 전송 재료의 제조방법 Download PDFInfo
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- KR970028879A KR970028879A KR1019960052205A KR19960052205A KR970028879A KR 970028879 A KR970028879 A KR 970028879A KR 1019960052205 A KR1019960052205 A KR 1019960052205A KR 19960052205 A KR19960052205 A KR 19960052205A KR 970028879 A KR970028879 A KR 970028879A
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- charge transfer
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/08—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/062—Acyclic or carbocyclic compounds containing non-metal elements other than hydrogen, halogen, oxygen or nitrogen
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0612—Acyclic or carbocyclic compounds containing nitrogen
- G03G5/0614—Amines
- G03G5/06142—Amines arylamine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0612—Acyclic or carbocyclic compounds containing nitrogen
- G03G5/0614—Amines
- G03G5/06142—Amines arylamine
- G03G5/06144—Amines arylamine diamine
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0612—Acyclic or carbocyclic compounds containing nitrogen
- G03G5/0614—Amines
- G03G5/06142—Amines arylamine
- G03G5/06144—Amines arylamine diamine
- G03G5/061443—Amines arylamine diamine benzidine
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0612—Acyclic or carbocyclic compounds containing nitrogen
- G03G5/0614—Amines
- G03G5/06142—Amines arylamine
- G03G5/06147—Amines arylamine alkenylarylamine
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0601—Acyclic or carbocyclic compounds
- G03G5/0612—Acyclic or carbocyclic compounds containing nitrogen
- G03G5/0614—Amines
- G03G5/06142—Amines arylamine
- G03G5/06147—Amines arylamine alkenylarylamine
- G03G5/061473—Amines arylamine alkenylarylamine plural alkenyl groups linked directly to the same aryl group
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Photoreceptors In Electrophotography (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
본 발명은 폴리실록산 수지에 전하 전송 특성을 부여할 수 있는 용매 가용성 전하 전송 재료의 제조방법에 관한 것이다. 이들 물질은 다음 화학식(1)을 갖는다.
A-[R1SiR2 3-nQn]p(1)
상기 식에서, A는 3급 아민 및 전하 전송 특성을 가지며 이온화 포텐셜이 4.5 내지 6.2eV인 화합물로부터 유도되는 유기 그룹이고, R1은 탄소수 1 내지 18의 알킬렌 그룹이고, R2는 탄소수 1 내지 15의 1가 탄화수소 그룹 또는 할로겐-치환된 1가 탄화수소 그룹이고, Q는 -OR3과 같은 가수분해 가능한 그룹(여기서, R3은 탄소수 1 내지 6의 알킬 그룹이다)이고, n 및 p는 각각 1 내지 3이다. 이러한 규소계 전하 전송 재료는 다수의 방향족 그룹 및 이러한 방향족 환내에 탄화수소 그룹을 통해 도입되는 알콕시실릴 그룹을 갖는 방향족 치환된 3급 아민이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- 전하 전송 특성을 가지며 이온화 포텐셜이 4.5 내지 6.2eV인 화합물의 하나 이상의 방향족 그룹의 방향족 환내에 실릴 그룹을 탄화수소 그룹에 의해 도입시킴을 포함하는, 가수분해 가능한 그룹 Q를 함유하는 실릴 그룹과 함께 다수의 방향족 그룹을 갖는 방향족 치환된 3급 아민에 의해 나타내어짐을 특징으로 하는 화학식(1)의 규소계 전하 전송 재료의 제조방법.A-[R1SiR2 3-nQn]p(1)상기 식에서, A는 다수의 방향족 그룹을 갖는 방향족 치환된 3급 아민이며 또한 전하 전송 특성을 가지며 이온화 포텐셜이 4.5 내지 6.2eV인 화합물로부터 유도되는 유기 그룹이고, R1은 탄소수 1 내지 18의 알킬렌 그룹이고, R2는 탄소수 1 내지 15의 1가 탄화수소 그룹 또는 할로겐-치환된 1가 탄화수소 그룹이고, Q는 가수분해 가능한 그룹이고, n 및 p는 각각 1 내지 3이다.
- 제1항에 있어서, 가수분해 가능한 그룹 Q가 알콕시 그룹인 방법.
- 제2항에 있어서, 전하 전송 특성을 갖는 화합물의 방향족 그룹의 전부 또는 일부가 불포화 탄화수소 그룹 형태의 치환체를 가지며, 치환체가 알콕시 실란과 하이드로실릴화 반응하여 화학식(1)인 A-[R1SiR2 3-nQn]p의 규소계 전하 전송 재료를 수득하는 방법.
- 제1항에 따른 방법에 따라 제조된 규소계 전하 전송 재료.
- 방향족 환상에 치환된 비닐 그룹을 함유하는 전하 전송 특성을 갖는 화합물의 방향족 환과, 규소에 결합된 수소원자를 갖는 유기 규소 화합뭍의 규소원자 사이에 탄화수소 그룹을 하이드로실릴화에 의해 도입시킴을 포함하는, 화학식(1)의 규소계 전하 전송 재료의 제조방법.A-[R1SiR2 3-nQn]p(1)상기 식에서, A는 다수의 방향족 그룹을 갖는 방향족 치환된 3급 아민이며 또한 전하 전송 특성을 가지며 이온화 포텐셜이 4.5 내지 6.2eV인 화합물로부터 유도되는 유기 그룹이고, R1은 탄소수 1 내지 18의 알킬렌 그룹이고, R2는 탄소수 1 내지 15의 1가 탄화수소 그룹 또는 할로겐-치환된 1가 탄화수소 그룹이고, Q는 가수분해 가능한 그룹이고, n 및 p는 각각 1 내지 3이다.
- 제5항에 따른 방법에 따라 수득할 수 있는 규소계 전하 전송 재료.※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP95-287634 | 1995-11-06 | ||
JP7287634A JPH09127710A (ja) | 1995-11-06 | 1995-11-06 | ケイ素系正孔輸送材の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970028879A true KR970028879A (ko) | 1997-06-24 |
KR100494208B1 KR100494208B1 (ko) | 2005-11-11 |
Family
ID=17719775
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019960052205A KR100494208B1 (ko) | 1995-11-06 | 1996-11-06 | 규소계정공전송재의제조방법및당해방법에의해제조된규소계정공전송재 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5824443A (ko) |
EP (1) | EP0771806B1 (ko) |
JP (1) | JPH09127710A (ko) |
KR (1) | KR100494208B1 (ko) |
CN (1) | CN1156850A (ko) |
AU (1) | AU708183B2 (ko) |
DE (1) | DE69619464T2 (ko) |
TW (1) | TW348230B (ko) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100387746B1 (ko) * | 1995-03-01 | 2003-09-29 | 다카사고코료코교가부시키가이샤 | 트리페닐아민유도체,이를이용한전하수송재료및전자사진감광체 |
JP4158204B2 (ja) * | 1995-04-10 | 2008-10-01 | 住友化学株式会社 | ポリシラン化合物、その製造方法およびその原料 |
JP3267519B2 (ja) * | 1995-11-06 | 2002-03-18 | キヤノン株式会社 | 電子写真感光体、該電子写真感光体を有するプロセスカートリッジ及び画像形成装置 |
JP3640444B2 (ja) * | 1995-11-06 | 2005-04-20 | ダウ コーニング アジア株式会社 | ポリシロキサン系正孔輸送材料の製造方法 |
JP3614222B2 (ja) * | 1995-11-06 | 2005-01-26 | ダウ コーニング アジア株式会社 | ケイ素系正孔輸送材の製造方法 |
KR100273180B1 (ko) * | 1997-01-28 | 2000-12-01 | 이마이 기요스케 | 전자사진 광수용체 |
JPH1135687A (ja) * | 1997-07-17 | 1999-02-09 | Sumitomo Chem Co Ltd | ポリシラン共重合体、その製造方法、それを用いた有機エレクトロルミネッセンス素子及び電子写真感光体 |
TW558561B (en) | 1997-07-22 | 2003-10-21 | Sumitomo Chemical Co | Hole transporting polymer and organic electroluminescence device using the same |
US6187491B1 (en) | 1999-02-08 | 2001-02-13 | Eastman Kodak Company | Electrophotographic charge generating element containing acid scavenger in overcoat |
US6265122B1 (en) * | 1999-02-22 | 2001-07-24 | Konica Corporation | Electrophotographic photoreceptor and an image forming apparatus and a process cartridge using the same |
US6319645B1 (en) * | 2001-02-26 | 2001-11-20 | Xerox Corporation | Imaging members |
US6517984B1 (en) | 2001-03-27 | 2003-02-11 | Heidelberger Druckmaschinen Ag | Silsesquioxane compositions containing tertiary arylamines for hole transport |
EP1380596B1 (en) * | 2002-07-08 | 2007-12-05 | Eastman Kodak Company | Organic charge transporting polymers including charge transport mojeties and silane groups, and silsesquioxane compositions prepared therefrom |
CN102219700A (zh) * | 2011-04-22 | 2011-10-19 | 南京邮电大学 | 一种基于芴苯胺结构的有机光电材料 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5595953A (en) * | 1979-01-11 | 1980-07-21 | Ricoh Co Ltd | Electrophotographic photoreceptor |
JPS61238062A (ja) * | 1985-04-16 | 1986-10-23 | Canon Inc | 電子写真感光体 |
JPH071400B2 (ja) | 1985-11-05 | 1995-01-11 | 三菱化成株式会社 | 電子写真感光体 |
EP0224784A3 (de) * | 1985-11-21 | 1988-09-28 | BASF Aktiengesellschaft | Carbazolsubstituierte Polysiloxane, daraus hergestellte feste, fotoleitfähige Schichten und diese enthaltende elektrofotographische Aufzeichnungsmaterialien |
US5187310A (en) * | 1990-03-14 | 1993-02-16 | Kao Corporation | Organic silicon compound, method of its production, and photoreceptor for electrophotography incorporating it |
US5290963A (en) * | 1990-05-12 | 1994-03-01 | Kao Corporation | Organic silicon compound, method of its production, and photoreceptor for electrophotography incorporating it |
US5272029A (en) * | 1991-02-28 | 1993-12-21 | Canon Kabushiki Kaisha | Image-bearing member and apparatus including same |
JPH04273252A (ja) | 1991-02-28 | 1992-09-29 | Canon Inc | 像保持部材及びそれを用いた装置 |
JPH04346356A (ja) * | 1991-05-24 | 1992-12-02 | Matsushita Electric Ind Co Ltd | 電子写真感光体 |
US5326661A (en) * | 1991-11-13 | 1994-07-05 | Hoechst Celanese Corp. | Photorefractive polymers containing discrete photoconductive and electrooptical units |
US5232801A (en) * | 1991-12-23 | 1993-08-03 | Eastman Kodak Company | Hole-transport liquid crystalline polymeric compounds, electrophotographic elements comprising same, and electrophotographic process |
US5230976A (en) * | 1991-12-27 | 1993-07-27 | Xerox Corporation | Polymeric arylamine silane compounds and imaging members incorporating same |
US5436099A (en) * | 1993-12-21 | 1995-07-25 | Xerox Corporation | Photoreceptor with low surface energy overcoat |
JP3614222B2 (ja) * | 1995-11-06 | 2005-01-26 | ダウ コーニング アジア株式会社 | ケイ素系正孔輸送材の製造方法 |
-
1995
- 1995-11-06 JP JP7287634A patent/JPH09127710A/ja active Pending
-
1996
- 1996-11-04 US US08/743,265 patent/US5824443A/en not_active Expired - Lifetime
- 1996-11-04 AU AU70593/96A patent/AU708183B2/en not_active Ceased
- 1996-11-06 CN CN96121687A patent/CN1156850A/zh active Pending
- 1996-11-06 DE DE69619464T patent/DE69619464T2/de not_active Expired - Fee Related
- 1996-11-06 EP EP96117733A patent/EP0771806B1/en not_active Expired - Lifetime
- 1996-11-06 KR KR1019960052205A patent/KR100494208B1/ko not_active IP Right Cessation
- 1996-11-13 TW TW085113885A patent/TW348230B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU708183B2 (en) | 1999-07-29 |
EP0771806B1 (en) | 2002-02-27 |
CN1156850A (zh) | 1997-08-13 |
US5824443A (en) | 1998-10-20 |
DE69619464D1 (de) | 2002-04-04 |
AU7059396A (en) | 1997-05-15 |
KR100494208B1 (ko) | 2005-11-11 |
DE69619464T2 (de) | 2002-10-17 |
JPH09127710A (ja) | 1997-05-16 |
EP0771806A1 (en) | 1997-05-07 |
TW348230B (en) | 1998-12-21 |
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