KR970027111A - 탈중합화된 천연 고무의 제조 방법 - Google Patents

탈중합화된 천연 고무의 제조 방법 Download PDF

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Publication number
KR970027111A
KR970027111A KR1019960052891A KR19960052891A KR970027111A KR 970027111 A KR970027111 A KR 970027111A KR 1019960052891 A KR1019960052891 A KR 1019960052891A KR 19960052891 A KR19960052891 A KR 19960052891A KR 970027111 A KR970027111 A KR 970027111A
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South Korea
Prior art keywords
natural rubber
carbonyl compound
depolymerized
radical
radical former
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KR1019960052891A
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English (en)
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KR100473902B1 (ko
Inventor
야스유키 다나카
도시아키 사카키
아쓰코 가와사키
마사하루 하야시
에이지 가나마루
가즈히코 시바타
Original Assignee
사이토 나오토
스미토모고무고교 가부시키가이샤
도키와 후미가쓰
가오 가부시키가이샤
야마모토 히데키
닛토덴코 가부시키가이샤
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Application filed by 사이토 나오토, 스미토모고무고교 가부시키가이샤, 도키와 후미가쓰, 가오 가부시키가이샤, 야마모토 히데키, 닛토덴코 가부시키가이샤 filed Critical 사이토 나오토
Publication of KR970027111A publication Critical patent/KR970027111A/ko
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Publication of KR100473902B1 publication Critical patent/KR100473902B1/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C1/00Treatment of rubber latex
    • C08C1/02Chemical or physical treatment of rubber latex before or during concentration
    • C08C1/04Purifying; Deproteinising
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/08Depolymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/22Compounds containing nitrogen bound to another nitrogen atom
    • C08K5/23Azo-compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 분자량 분포가 좁은 액체 형태의 탈중합화된 천연 고무를 높은 반응 효율로 수득하는 탈중합화된 천연 고무의 제조 방법: 및 천연 고무 특유의 냄새 또는 착색이 없고 단백질로부터 유래된 즉시형 알레르기의 위험이 없는 탈중합화된 천연 고무의 제조 방법에 관한 것이다.
본 발명에 따른 방법은 카보닐 화합물을 천연 고무 라텍스에 첨가하고 생성되는 천연 고무를 라디칼 형성제의 존재하에서 공기 산화시키는 단계, 또는 카보닐 화합물을 탈단백질화된 천연 고무에 첨가하고 탈단백질화된 천연 고무를 라디칼 형성제의 존재 또는 부재하에서 공기 산화시키는 단계를 포함한다.

Description

탈중합화된 천연 고무의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 카보닐 화합물을 천연 고무 라텍스에 첨가하고 생성되는 천연 고무를 라디칼 형성제의 존재하에서 공기 산화시키는 단계를 포함하여, 탈중합화된 천연 고무를 제조하는 방법.
  2. 제1항에 있어서, 라디칼 형성제가 퍼옥사이드계 라디칼 형성제, 산화환원제 라디칼 형성제 및 아조계 라디칼 형성제중에서 선택되는 방법.
  3. 카보닐 화합물을 탈단백질화된 천연 고무의 라텍스에 첨가하고 생성되는 탈단백질화된 천연 고무를 공기 산화시키는 단계를 포함하여, 탈중합화된 천연 고무를 제조하는 방법.
  4. 제3항에 있어서, 탈중합화된 천연 고무의 산화를 라디칼 형성제의 존재하에서 수행하는 방법.
  5. 제4항에 있어서, 탈단백질화된 천연 고무의 질소 함량이 0.1중량% 이하인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960052891A 1995-11-10 1996-11-08 해중합천연고무의제조방법 KR100473902B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP95-292907 1995-11-10
JP29290795A JP3517500B2 (ja) 1995-11-10 1995-11-10 解重合天然ゴムの製造方法

Publications (2)

Publication Number Publication Date
KR970027111A true KR970027111A (ko) 1997-06-24
KR100473902B1 KR100473902B1 (ko) 2005-06-08

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Application Number Title Priority Date Filing Date
KR1019960052891A KR100473902B1 (ko) 1995-11-10 1996-11-08 해중합천연고무의제조방법

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Country Link
US (1) US5856600A (ko)
EP (1) EP0773230B1 (ko)
JP (1) JP3517500B2 (ko)
KR (1) KR100473902B1 (ko)
AU (1) AU716117B2 (ko)
DE (1) DE69606495T2 (ko)
MY (1) MY113535A (ko)

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WO2001029121A1 (de) * 1999-10-22 2001-04-26 Ket Kunststoff- Und Elasttechnik Gmbh Liegau-August Usbad Devulkanisat aus gummiabfällen, devulkanisatcompound, verfahren zu deren herstellung und verwendung zum wiedereinsatz in frischmischungen und zur herstellung von spritzgussformteilen
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JP6087177B2 (ja) * 2013-03-07 2017-03-01 東洋ゴム工業株式会社 シリカマスターバッチ及びその製造方法
JP6100030B2 (ja) * 2013-03-07 2017-03-22 東洋ゴム工業株式会社 変性ポリマーの製造方法及びジエン系ポリマー
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US9938771B2 (en) 2014-11-03 2018-04-10 Baker Hughes, A Ge Company, Llc Initiator nanoconstituents for elastomer crosslinking and related methods
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Also Published As

Publication number Publication date
DE69606495D1 (de) 2000-03-09
DE69606495T2 (de) 2000-06-21
AU7066296A (en) 1997-05-15
MY113535A (en) 2002-03-30
EP0773230B1 (en) 2000-02-02
JPH09136903A (ja) 1997-05-27
EP0773230A1 (en) 1997-05-14
JP3517500B2 (ja) 2004-04-12
KR100473902B1 (ko) 2005-06-08
US5856600A (en) 1999-01-05
AU716117B2 (en) 2000-02-17

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