KR950700358A - 가교결합성 표면 피복물(Crosslinkable surface coatings) - Google Patents

가교결합성 표면 피복물(Crosslinkable surface coatings)

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Publication number
KR950700358A
KR950700358A KR1019940702765A KR19940702765A KR950700358A KR 950700358 A KR950700358 A KR 950700358A KR 1019940702765 A KR1019940702765 A KR 1019940702765A KR 19940702765 A KR19940702765 A KR 19940702765A KR 950700358 A KR950700358 A KR 950700358A
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polymeric
aqueous
functional
phenyl
carbon atoms
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KR1019940702765A
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English (en)
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에써 리카르트 요트
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로버스 씨. 하르
에스. 씨. 존슨 앤드 썬. 인코포레이티드
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Publication of KR950700358A publication Critical patent/KR950700358A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31688—Next to aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y10T428/31692—Next to addition polymer from unsaturated monomers
    • Y10T428/31699—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31895—Paper or wood
    • Y10T428/31906—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31935—Ester, halide or nitrile of addition polymer

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Organic Insulating Materials (AREA)

Abstract

수성 캐리어, 산작용성 팬던트 잔기와 아세토아세톡시 작용성 팬던트 잔기를 모두 갖는 하나 이상의 중합체성 성분, 두개 이상의 아민 작용성 잔기를 갖는 비중합체성 다작용성 아민 및 염기를 포함하는 신규한 저장 안정성이 있는 가교결합 가능한 중합체성 수성 배합물에 관한 것이다. 배합물내에 함유된 염기의 양은 겔화 방지에 유효하며, 그렇지 않으면 아세토아세톡시 작용성 잔기와 아민 작용성 잔기 사이에 가교결합이 일어난다.

Description

가교결합성 표면 피복물(Crosslinkable surface coating)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 증발가능한 수성 캐리어(carrier); 산작용성 팬던트 잔기와 아세토아세톡시 작용성 팬던트 잔기를 갖는, 수성 담체내에 함유된 하나 이상의 중합체성 성분; 2개 이상의 아민 작용성 잔기를 갖는, 수성 담체내에 함유된 다작용성 비중합체성 아민; 및 아세토아세톡시 작용성 잔기와 아민 작용성 잔기(이때, 이들 두 잔기는 수성 캐리어 중에 함유되어 있다) 사이의 가교결합 결과로서 발생하는 겔화를 억제하기에 유효한 양의, 수성 담체중의 염기를 포함함을 특징으로 하는, 연장된 기간 동안 싱글-패키지(single-packange)로 패키징시킬 수 있는 가교 결합 가능한 중합체성 수성 배합물.
  2. 증발가능한 수성 캐리어; 둘중 하나의 중합체성 성분은 산작용성 잔기를 갖고 나머지 하나의 중합체성 성분은 아세토아세톡시 작용선 팬던트 잔기를 갖는, 수성 캐리어내에 함유된 2개 이상의 중합체성 성분; 2개 이상의 아민 작용성 잔기를 갖는, 수성 캐리어내에 함유된 다작용성 비중합체성 아민; 및 아세토아세톡시 작용성 잔기와 아민 작용성 잔기(이때, 이들 두 잔기는 수성 캐리어내에 함유된다) 사이의 가교결합의 결과로서 발생하는 겔화를 억제하기에 유효한 양의, 수성 캐리어중의 염기를 포함함을 특징으로 하는, 연장된 기간동안 싱글-패키지로 패키징될 수 있는 가교결합가능한 중합체성 수성 배합물.
  3. 제 1 항에 있어서, 염기가 암모니아 또는 휘발성 아민인 중합체성 수성 배합물.
  4. 제 1 항에 있어서, 다작용성 비중합체성 아민의 화학식량이 약 2,000g/mol 미만인 중합체성 수성 배합물.
  5. 제 1 항에 있어서, 증발가능한 캐리어가 물과 실온에서 증발할 수 있는 하나 이상의 휘발성 액체 유기 화합물을 포함하고, 배합물중의 휘발성 유기 화합물의 총 양이 제형 1ℓ당 200g을 초과하지 않는 중합체성 수성 배합물.
  6. 제 1 항 또는 제 2 항에 있어서, 아세토아세톡시 작용성 팬던트 잔기를 갖는 중합체성 성분이 하기 일반식으로 표시될 수 있는 중합체성 수성 배합물.
    상기 식에서, R1은 H, 탄소수 1 내지 10의 알킬또는 페닐이고, A는
    R2
    또는
    H
    R2
    H
    (여기서, R2는 H, 탄소수 1 내지 10의 알킬, 페닐, 치환된 페닐, 할로, CO2CH3또는 CN이고, R3은 H, 탄소수 1 내지 10의 알킬, 페닐, 치환된 페닐 또는 할로이며, R4는 탄소수 1 내지 10의 알킬렌, 페닐렌 또는 치환된 페닐렌이고, ,R5는 알킬렌 또는 치환된 알킬렌이며, a,m,n 및 q는 각각 0 또는 1이고, X 및 Y는 각각 -NH- 또는 -O-이다)이며, B는 A, 탄소수 1 내지 10의 알킬, 페닐, 치환된 페닐 또는 헤테로사이클릭이다.
  7. 제 1 항에 있어서, 12개월이상 동안 안정하게 저장되는 중합체성 수성 배합물.
  8. 증발 가능한 수성 캐리어중에서 산 작용성 팬던트 잔기와 아세토아세톡시 작용성 팬던트 잔기를 모두 갖는 하나 이상의 중합체성 성분, 2개 이상의 아민 작용성 잔기를 갖는 다작용성 비중합체성 아민, 및 아세토아세톡시 작용성 잔기와 아민 작용성 잔기 사이의 가교결합의 결과로서 발생하는 겔화를 억제하기에 유효한 양의, 수성 캐리어중의 염기를 혼합하여 반응 혼합물을 제조하는 단계; 및 당해 반응 혼합물을 미리 설정한 반응 온도에서 미리 결정한 시간동안 정지시켜 중합체성 수성 배합물을 제조하는 단계를 포함함을 특징으로 하여, 연장된 기간 동안 싱글-페키지로 패키징될 수 있는 가교결합가능한 중합체성 수성 배합물을 제조하는 방법.
  9. 증발가능한 수성 캐리어중에서 둘중 하나의 중합체성 성분은 산 작용성 팬던트 잔기를 갖고 다른 하나의 중합체성 성분은 아세토아세톡시 작용성 팬던트 잔기를 갖는 2개 이상의 중합체성 성분, 2개 이상의 아민 작용성 잔기를 갖는 다작용성 비중합체성 아민, 및 아세토아세톡시 작용성 잔기와 아민 작용성 잔기사이의 가교결합의 결과로서 발생하는 겔화를 억제하기에 유효한 양의, 수성 캐리어중의 염기를 혼합하여 반응 혼합물을 제조하는 단계; 및 당해 반응 혼합물을 미리 설정한 반응 온도에서 미리 결정한 시간동안 정지시켜 중합체성 수성 배합물을 제조하는 단계를 포함함을 특징으로 하여, 연장된 기간동안 싱글 패키지로 패키징될 수 있는 가교결합가능한 중합체성 수성 배합물을 제조하는 방법.
  10. 제 8 항에 있어서, 이와 같이 제조된 중합체성 수성 배합물의 적어도 일부분을 후속적인 유화 중반 반응에서 하나의 성분으로서 사용하는 단계를 추가로 포함하는 방법.
  11. 제 8 항에 있어서, 아세토아세톡시 작용성 팬던트 잔기를 갖는 중합체성 성분이 하기 일반식으로 표시될 수 있는 방법.
    상기 식에서, R1은 H, 탄소수 1 내지 10의 알킬 또는 페닐이고, A는
    R2
    또는
    H
    R2
    H
    (여기서, R2는 H, 탄소수 1 내지 10의 알킬, 페닐, 치환된 페닐, 할로, CO2CH3또는 CN이고, R3은 H, 탄소수 1 내지 10의 알킬, 페닐, 치환된 페닐 또는 할로이며, R4는 탄소수 1 내지 10의 알킬렌, 페닐렌 또는 치환된 페닐렌이고, ,R5는 알킬렌 또는 치환된 알킬렌이며, a,m,n 및 q는 각각 0 또는 1이고, X 및 Y는 각각 -NH- 또는 -O-이다)이며, B는 A, 탄소수 1 내지 10의 알킬, 페닐, 치환된 페닐 또는 헤테로사이클릭이다
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940702765A 1992-02-10 1993-02-09 가교결합성 표면 피복물(Crosslinkable surface coatings) KR950700358A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US83325092A 1992-02-10 1992-02-10
US07/833,250 1992-02-10
PCT/US1993/001133 WO1993016133A2 (en) 1992-02-10 1993-02-09 Crosslinkable surface coatings

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KR950700358A true KR950700358A (ko) 1995-01-16

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KR1019940702765A KR100276375B1 (ko) 1992-02-10 1993-02-09 수성중합체성 조성물 및 이의 제조방법
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KR20007003366A KR100282110B1 (ko) 1992-02-10 2000-03-29

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AT (1) ATE156503T1 (ko)
AU (1) AU661126B2 (ko)
CA (2) CA2216303C (ko)
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Families Citing this family (130)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5296530A (en) * 1992-07-28 1994-03-22 Rohm And Haas Company Method for light-assisted curing of coatings
US5270380A (en) † 1992-10-13 1993-12-14 Rohm And Haas Company Method for extending the open time of an aqueous coating composition
US5525662A (en) * 1993-07-14 1996-06-11 Rohm And Haas Company Functionalization of polymers via enamine of acetoacetate
US5534310A (en) * 1994-08-17 1996-07-09 Rohm And Haas Company Method of improving adhesive of durable coatings on weathered substrates
US5939482A (en) * 1994-11-29 1999-08-17 Vianova Resins Aktiengesellschaft Method for the two-stage preparation of aqueous autocrosslinking copolymer dispersions and their use for coating materials
DE69523019T2 (de) * 1994-12-09 2002-02-07 Fuji Photo Film Co Ltd Feine Polymerpartikel mit heterogener Phasenstruktur, photographisches lichtempfindliches Silberhalogenidmaterial feine Polymerpartikel enthaltend und Bilderzeugungsverfahren
US5519087A (en) * 1995-04-28 1996-05-21 Rohm And Haas Company Binders for ceramic products
US5872297A (en) * 1995-08-24 1999-02-16 S. C. Johnson Commercial Markets, Inc. Ethylenically-unsaturated 1,3-diketoamide functional compounds
AU720104B2 (en) * 1995-12-04 2000-05-25 Rohm And Haas Company Waterborne crosslinkable coating compositions
US5681883A (en) * 1996-03-05 1997-10-28 Advanced Ceramics Corporation Enhanced boron nitride composition and polymer based high thermal conductivity molding compound
US5772988A (en) * 1996-05-10 1998-06-30 Revlon Consumer Products Corporation Nail enamel compositions from acetoacetoxy methacrylate copolymer
US5998543A (en) * 1996-05-28 1999-12-07 Eastman Chemical Company Stable amino-containing polymer latex blends
US6028155A (en) * 1997-05-21 2000-02-22 Eastman Chemical Company Surfactant-containing acetoacetoxy-functional and enamine-functional polymers
US6417267B1 (en) 1996-05-28 2002-07-09 Eastman Chemical Company Adhesive compositions containing stable amino-containing polymer latex blends
US5891950A (en) * 1996-05-28 1999-04-06 Eastman Chemical Company Use of stable amino-functional latexes in water-based inks
CA2212407A1 (en) * 1996-08-20 1998-02-20 Theodore Tysak Aqueaous polish compositions containing acid-amine latexes
US5763012A (en) * 1996-10-16 1998-06-09 Basf Aktiengesellschaft Coating of substrates
US5962556A (en) * 1996-10-22 1999-10-05 Eastman Chemical Company Functional latexes resistant to hydrolysis
US6512042B1 (en) 1996-12-18 2003-01-28 Rohm And Haas Company Waterborne crosslinkable coating compositions
US6262169B1 (en) 1998-05-14 2001-07-17 Eastman Chemical Company Protonated amines for controlled crosslinking of latex polymers
WO1998052980A1 (en) * 1997-05-21 1998-11-26 Eastman Chemical Company Process for preparing reactive latex blends which are chemically and physically stable until film formation
US6090882A (en) * 1997-05-30 2000-07-18 S. C. Johnson Commercial Markets, Inc. Crosslinkable surface coatings and process of preparation
US6329016B1 (en) * 1997-09-03 2001-12-11 Velcro Industries B.V. Loop material for touch fastening
US6649679B1 (en) 1997-09-18 2003-11-18 Eastman Chemical Company Stable waterborne polymer compositions containing poly(alkylenimines)
US6005035A (en) * 1997-09-18 1999-12-21 Eastman Chemical Company Stable waterborne polymer compositions containing poly(alkylenimines)
US5990224A (en) * 1997-09-18 1999-11-23 Eastman Chemical Company Stable low foam waterborne polymer compositions containing poly(alkyleneimines)
US6201048B1 (en) 1997-09-18 2001-03-13 Eastman Chemical Company Stable waterborne polymer compositions containing poly(alkyleneimines)
EP1042410A1 (en) * 1997-11-06 2000-10-11 The Edgington Company Coating composition
US6277358B1 (en) 1997-12-15 2001-08-21 Revlon Consumer Products Corporation Cosmetic compositions containing crosslinkable polymers
US6037390A (en) * 1997-12-31 2000-03-14 E. I. Du Pont De Nemours And Company Smear resistant pigmented ink jet inks containing β-diketone or ureido dispersants
US6060410A (en) * 1998-04-22 2000-05-09 Gillberg-Laforce; Gunilla Elsa Coating of a hydrophobic polymer substrate with a nonstoichiometric polyelectrolyte complex
JP2002515533A (ja) 1998-05-19 2002-05-28 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ペンダントのアセトアセテート部分を含むポリアクリル樹脂
CA2348895C (en) 1998-11-20 2005-04-12 The Sherwin-Williams Company Curable compositions comprising acetoacetoxy and imine functionality
US6174960B1 (en) 1999-01-08 2001-01-16 National Starch And Chemical Investmnent Holding Corporation Coating compositions prepared with an acrylic modified ethylene-vinyl acetate polymer
CA2292166A1 (en) 1999-01-13 2000-07-13 Kent B. Godsted Chemically coated fasteners having improved penetration and withdrawal resistance
US6086305A (en) * 1999-01-13 2000-07-11 Illinois Tool Works Inc. Nails having selected heat treatment and hardening
US6109851A (en) * 1999-01-13 2000-08-29 Illinois Tool Works Inc. Screws having selected heat treatment and hardening
US6437059B1 (en) 1999-02-11 2002-08-20 Reichhold, Inc. Composition of epoxy, urethane polyacrylate and polyamine
US6117492A (en) * 1999-03-30 2000-09-12 Air Products And Chemicals, Inc. Polymers having dual crosslinkable functionality and process for forming high performance nonwoven webs
US6723200B1 (en) * 1999-08-18 2004-04-20 Meadwestvaco Corporation Method for releasing laminated materials
US6369189B1 (en) 1999-12-07 2002-04-09 Reichhold, Inc. Hindered amine adducts for polyurea systems
US6355720B1 (en) 2000-05-12 2002-03-12 Johnson Polymer, Inc. Latex formulations with reduced yellowing
US6521715B1 (en) 2000-08-22 2003-02-18 E. I. Du Pont De Nemours And Company Graft copolymer pigment dispersants
US20020103278A1 (en) * 2000-09-15 2002-08-01 Krajnik John M. Waterborne coating composition
US6420479B1 (en) 2000-12-29 2002-07-16 National Starch And Chemical Investment Holding Corporation Star polymer colloidal stabilizers
CA2371096C (en) * 2001-02-07 2006-10-31 The Hill And Griffith Company Concrete form release compositions
US6960367B2 (en) * 2001-02-07 2005-11-01 The Hill And Griffith Company Sandcasting pattern coating compositions
US6646058B1 (en) * 2001-02-21 2003-11-11 The Sherwin-Williams Company Water-borne paint composition having improved hiding and scrub-resistance
US6911493B2 (en) * 2002-04-12 2005-06-28 Resolution Specialty Materials Llc Acrylate-functionalized alkyd compositions for fast-dry coatings
US6794049B2 (en) * 2002-04-12 2004-09-21 Eastman Chemical Company Fast-dry, high solids coating compositions based on acetoacetate-functionalized alkyd resins
US6780523B2 (en) 2002-04-12 2004-08-24 Eastman Chemical Company Waterborne acetoacetate-functionalized alkyd coating compositions
US7060745B2 (en) 2002-04-12 2006-06-13 Resolution Specialty Materials Llc Waterborne acrylate-functionalized alkyd coating compositions
US6893722B2 (en) * 2002-04-29 2005-05-17 Exxonmobil Oil Corporation Cationic, amino-functional, adhesion-promoting polymer for curable inks and other plastic film coatings, and plastic film comprising such polymer
US7195818B2 (en) 2002-05-01 2007-03-27 Exxonmobil Oil Corporation Sealable multi-layer opaque film
US6946509B2 (en) * 2002-09-20 2005-09-20 Resolution Specialty Materials Llc Acrylate-functional alkyd resins having improved dry time
US20040105994A1 (en) * 2002-12-03 2004-06-03 Pang-Chia Lu Thermoplastic film structures with a low melting point outer layer
US6683132B1 (en) 2002-12-19 2004-01-27 Eastman Chemical Company Self-crosslinking aqueous acetoacetate-functionalized sulfonated alkyd systems
KR20100022127A (ko) 2003-06-12 2010-02-26 발스파 소싱 인코포레이티드 반응성 희석제를 함유하는 코팅 조성물 및 코팅 방법
US7728068B2 (en) 2003-06-12 2010-06-01 Valspar Sourcing, Inc. Coating compositions containing reactive diluents and methods
US20050104488A1 (en) * 2003-11-14 2005-05-19 Hunt Stacy A. Dishwaser with electrocoated dish rack
US20050245636A1 (en) * 2004-04-29 2005-11-03 Ashland Inc. Radiation-curable coatings for wood substrates from multifunctional acrylate oligomers
US20060046005A1 (en) * 2004-08-24 2006-03-02 Mcgee Dennis E Coating for polymeric labels
US7470751B2 (en) * 2004-09-21 2008-12-30 Basf Corporation Stabilized water-borne polymer compositions for use as water-based coatings
BRPI0518334A2 (pt) 2004-11-22 2008-11-11 Valspar Sourcing Inc composiÇço de revestimento, mÉtodo de revestimento, revestimento, e, mÉtodo para preparar uma composiÇço de revestimento
MX279192B (es) † 2004-12-17 2010-09-22 Valspar Sourcing Inc Composiciones acuosas de recubrimiento que contienen polimeros funcionales de acetoacetilo, recubrimientos, y metodos.
US8609762B2 (en) 2004-12-17 2013-12-17 Valspar Sourcing, Inc. Aqueous coating compositions containing acetoacetyl-functional polymers, coatings, and methods
JP2007169449A (ja) * 2005-12-21 2007-07-05 Nippon Paint Co Ltd 水性硬化型防汚塗料組成物、防汚性塗膜、水中構造物及び水中摩擦低減方法
JP2006182955A (ja) * 2004-12-28 2006-07-13 Nippon Paint Co Ltd 水性硬化型防汚塗料組成物、防汚性塗膜及び水中構造物
EP2000489B1 (en) * 2006-02-24 2010-07-28 Kansai Paint Co., Ltd. Curable aqueous composition
JP2009535159A (ja) * 2006-05-01 2009-10-01 アボット ラボラトリーズ 医療デバイスの保持を改善する表面相互作用
US20080135058A1 (en) * 2006-12-08 2008-06-12 Ted Calvin Germroth Tobacco smoke filter and method for removal of aldehydes from tobacco smoke
US7855261B2 (en) 2006-12-08 2010-12-21 Eastman Chemical Company Aldehyde removal
US20080134893A1 (en) * 2006-12-08 2008-06-12 Thauming Kuo Particulate filter media
GB2445748A (en) * 2007-01-18 2008-07-23 Arjobex Ltd Coating composition
US20090118397A1 (en) * 2007-10-30 2009-05-07 Archer-Daniels-Midland Company Waterborne Film-Forming Compositions Containing Reactive Surfactants and/or Humectants
US20090276974A1 (en) * 2008-03-14 2009-11-12 David Khalil Cordless Hand-Held Rechargeable Vacuum Cleaner and Charger Unit Therefore
US20100062169A1 (en) * 2008-09-08 2010-03-11 JN Machinery Coating high temperature parts with polymer
US7906571B2 (en) * 2008-10-28 2011-03-15 Archer Daniels Midland Company Waterborne film-forming compositions containing reactive surfactants and/or humectants
CN102115513B (zh) * 2009-12-30 2014-05-28 罗门哈斯公司 低气味苯乙烯系聚合物分散体系
US9279022B1 (en) 2014-09-08 2016-03-08 Sirrus, Inc. Solution polymers including one or more 1,1-disubstituted alkene compounds, solution polymerization methods, and polymer compositions
US9249265B1 (en) 2014-09-08 2016-02-02 Sirrus, Inc. Emulsion polymers including one or more 1,1-disubstituted alkene compounds, emulsion methods, and polymer compositions
US10414839B2 (en) 2010-10-20 2019-09-17 Sirrus, Inc. Polymers including a methylene beta-ketoester and products formed therefrom
US9828324B2 (en) 2010-10-20 2017-11-28 Sirrus, Inc. Methylene beta-diketone monomers, methods for making methylene beta-diketone monomers, polymerizable compositions and products formed therefrom
US8809446B2 (en) 2010-12-15 2014-08-19 Eastman Chemical Company Substituted 3-oxopentanoates and their uses in coating compositions
US8809447B2 (en) 2010-12-15 2014-08-19 Eastman Chemical Company Acetoacetate-functional monomers and their uses in coating compositions
US9029451B2 (en) 2010-12-15 2015-05-12 Eastman Chemical Company Waterborne coating compositions that include 2,2,4-trimethyl-3-oxopentanoate esters as reactive coalescents
US9102848B2 (en) 2011-02-28 2015-08-11 Basf Se Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same
EP2508555B1 (en) 2011-03-21 2015-05-13 Electrolux Home Products Corporation N.V. Process for producing pre-expandable plastic beads and beads obtainable according to said process
WO2012134695A1 (en) 2011-03-29 2012-10-04 Exxonmobil Oil Corporation Film coatings based on polyalkylimine condensation polymers
CN102964898B (zh) 2011-08-05 2016-05-25 罗门哈斯公司 具有改进的亲水污渍排斥性的水性涂料组合物
US20130084437A1 (en) 2011-09-29 2013-04-04 Dennis E. McGee Film Coatings Based on Polyalkylimine Condensation Polymers
US8748504B2 (en) * 2011-10-11 2014-06-10 Yale University Polymeric composites having oriented nanomaterials and methods of making the same
US9512058B2 (en) 2011-10-19 2016-12-06 Sirrus Inc. Multifunctional monomers, methods for making multifunctional monomers, polymerizable compostions and products formed thereform
CA2869115A1 (en) 2012-03-30 2013-10-03 Bioformix Inc. Ink and coating formulations and polymerizable systems for producing the same
CA2869112A1 (en) 2012-03-30 2013-10-03 Bioformix Inc. Composite and laminate articles and polymerizable systems for producing the same
EP2748237A1 (en) 2012-05-01 2014-07-02 Jindal Films Americas, LLC Epoxylated polyalkyleneimine film coatings
US10047192B2 (en) 2012-06-01 2018-08-14 Sirrus, Inc. Optical material and articles formed therefrom
US11535762B2 (en) 2012-09-18 2022-12-27 Ennis Flint Fast drying aqueous amine free coating composition(s)
US9816002B2 (en) 2012-10-12 2017-11-14 Dow Global Technologies Llc Aqueous coating composition with improved viscosity stability
WO2014078689A1 (en) 2012-11-16 2014-05-22 Bioformix Inc. Plastics bonding systems and methods
EP2926368B1 (en) 2012-11-30 2020-04-08 Sirrus, Inc. Electronic assembly
CN105008321A (zh) 2013-01-11 2015-10-28 瑟拉斯公司 经过双(羟甲基)丙二酸酯的途径获得亚甲基丙二酸酯的方法
US10053597B2 (en) 2013-01-18 2018-08-21 Basf Se Acrylic dispersion-based coating compositions
WO2014201674A1 (en) 2013-06-21 2014-12-24 Dow Global Technologies Llc An aqueous coating composition
EP3154929B1 (en) 2014-04-21 2020-09-16 Firestone Building Products Company, LLC Method of preparing a foam
US9416091B1 (en) 2015-02-04 2016-08-16 Sirrus, Inc. Catalytic transesterification of ester compounds with groups reactive under transesterification conditions
US9315597B2 (en) 2014-09-08 2016-04-19 Sirrus, Inc. Compositions containing 1,1-disubstituted alkene compounds for preparing polymers having enhanced glass transition temperatures
US10501400B2 (en) 2015-02-04 2019-12-10 Sirrus, Inc. Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions
EP3085713A1 (en) * 2015-04-21 2016-10-26 Rohm And Haas Company Co2 abating latex coating composition
US9334430B1 (en) 2015-05-29 2016-05-10 Sirrus, Inc. Encapsulated polymerization initiators, polymerization systems and methods using the same
US9217098B1 (en) 2015-06-01 2015-12-22 Sirrus, Inc. Electroinitiated polymerization of compositions having a 1,1-disubstituted alkene compound
US10717800B2 (en) 2015-09-17 2020-07-21 Ennis Paint, Inc. Controlled crosslinking of latex polymers with polyfunctional amines
US10450475B2 (en) 2015-11-17 2019-10-22 Ennis Paint, Inc. Traffic marking compositions containing polyfunctional amines
US9796873B2 (en) 2016-02-02 2017-10-24 Ennis Paint, Inc. Linear polyglycidyl amine additives for controlled crosslinking of latex polymers
EP3430065A1 (de) 2016-03-18 2019-01-23 Basf Se Feinteilige wässrige mehrstufige polymerisatdispersion, verfahren zu deren herstellung und deren verwendung als bindemittel
US9518001B1 (en) 2016-05-13 2016-12-13 Sirrus, Inc. High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation
US10196481B2 (en) 2016-06-03 2019-02-05 Sirrus, Inc. Polymer and other compounds functionalized with terminal 1,1-disubstituted alkene monomer(s) and methods thereof
US9567475B1 (en) 2016-06-03 2017-02-14 Sirrus, Inc. Coatings containing polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
US9617377B1 (en) 2016-06-03 2017-04-11 Sirrus, Inc. Polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
US10428177B2 (en) 2016-06-03 2019-10-01 Sirrus, Inc. Water absorbing or water soluble polymers, intermediate compounds, and methods thereof
CN112469741A (zh) 2018-07-05 2021-03-09 巴斯夫欧洲公司 制备水性聚合物分散体的方法
AU2020230424A1 (en) 2019-03-07 2021-09-02 Allnex Netherlands Aqueous coating composition
ES2946660T3 (es) 2019-05-08 2023-07-24 Basf Se Látex polimérico acuoso
CN111718484B (zh) * 2020-07-07 2021-10-12 四川大学 基于乙烯基酰肼键的高性能动态交联聚合物及制备方法
KR20230041759A (ko) 2020-07-20 2023-03-24 바스프 에스이 수계 코팅 조성물에서 결합제로서 적합한 필름-형성 공중합체의 수성 중합체 라텍스
KR102263874B1 (ko) 2020-12-22 2021-06-10 고한덕 음료컵 포장용 종이 대지
EP4284844A1 (en) 2021-01-26 2023-12-06 Basf Se Aqueous polymer latex
AU2022321978A1 (en) 2021-08-04 2024-02-08 Basf Se Process for modifying an aqueous polymer latex
CN118055984A (zh) 2021-10-04 2024-05-17 巴斯夫欧洲公司 水性聚合物组合物作为多孔材料的着色剂的用途
WO2024105095A1 (en) 2022-11-18 2024-05-23 Basf Se Aqueous polymer latex of film-forming copolymers suitable as binder in waterborne coating compositions

Family Cites Families (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA610432A (en) * 1955-03-03 1960-12-13 Graulich Wilhelm Process for the production of two dimensional bodies from aqueous emulsions of copolymers
US3401272A (en) * 1965-08-30 1968-09-10 Westinghouse Electric Corp Ferroresonant transient suppression system
US3554987A (en) * 1965-12-20 1971-01-12 Eastman Kodak Co Novel compounds and photographic materials containing said compounds
DE1644760A1 (de) * 1966-12-24 1971-03-04 Huels Chemische Werke Ag Verfahren zum Herstellen von UEberzuegen
DE1644988B2 (de) * 1967-06-28 1973-09-06 Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen Ueberzugs- und verklebungsmittel auf basis von gemischen von acetylacetatgruppen aufweisenden polymerisaten aethylenisch ungesaettigterverbindungen, acetoacetaten mehrwertiger metalle und verduennungsmittel
GB1241226A (en) * 1967-11-25 1971-08-04 Basf Ag Air-drying coating materials and impregnants and production of coatings and impregnations therefrom
DE1965740C3 (de) * 1969-12-31 1979-11-22 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von pulverisierbaren Acryl-Harzen
US3673168A (en) * 1970-01-22 1972-06-27 Burke Oliver W Jun Polymerization process
US3668183A (en) * 1970-11-03 1972-06-06 Union Carbide Corp Production of polyenamines
US3832217A (en) * 1970-12-15 1974-08-27 Mitsubishi Rayon Co Process for forming exterior finish coating films for automobile bodies
GB1445345A (en) * 1972-12-21 1976-08-11 Mullard Ltd Positive-working electron resists
AU473121B2 (en) * 1973-02-01 1976-06-10 Bayer Aktiengesellschaft Pulverizable acrylic resins
JPS5442035B2 (ko) * 1974-02-04 1979-12-12
US3915921A (en) * 1974-07-02 1975-10-28 Goodrich Co B F Unsaturated carboxylic acid-long chain alkyl ester copolymers and tri-polymers water thickening agents and emulsifiers
GB1517276A (en) * 1974-08-21 1978-07-12 Ici Ltd Preparation of polymer film
ES450388A1 (es) * 1975-08-08 1977-12-01 Hoechst Ag Procedimiento para obtener dispersiones de plastico.
DE2535372C3 (de) * 1975-08-08 1986-07-10 Hoechst Ag, 6230 Frankfurt Verfahren zum Herstellen von wäßrigen Kunststoff-Dispersionen
DE2626174A1 (de) * 1976-06-11 1977-12-22 Bayer Ag Vernetzbare acrylnitrilcopolymerisate
DE2626172A1 (de) * 1976-06-11 1977-12-22 Bayer Ag Vernetzbare polyacrylnitril-copolymere
DE2636863A1 (de) * 1976-08-17 1978-02-23 Texaco Ag Kaltvernetzende dispersionskleber
US4190562A (en) * 1977-04-04 1980-02-26 The B. F. Goodrich Company Improved water absorbent copolymers of copolymerizable carboxylic acids and acrylic or methacrylic esters
GB1588978A (en) * 1977-07-19 1981-05-07 Ici Ltd Coating processes
DE2749386A1 (de) * 1977-11-04 1979-05-10 Roehm Gmbh Dispersionen hydrophiler acrylharze
US4251597A (en) * 1978-12-01 1981-02-17 Rohm And Haas Company Coating, impregnating and adhesive compositions curable at ambient temperature, and methods of using them
US4250070A (en) * 1978-01-26 1981-02-10 Basf Aktiengesellschaft Aqueous dispersions, containing hydrazine derivatives, of carbonyl-containing copolymers
US4371669A (en) * 1979-02-12 1983-02-01 Desoto, Inc. Polymers having improved water resistance and monomers for same
US4275229A (en) * 1979-02-12 1981-06-23 Desoto, Inc. Polymers having improved water resistance and monomers for same
DE2927932A1 (de) * 1979-07-11 1981-02-05 Hoechst Ag Vinylpolymer mit acetylacetoxygruppen, verfahren zu seiner herstellung und daraus erhaltenes mittel
US4258079A (en) * 1979-12-13 1981-03-24 International Business Machines Corporation Preparation of continuous films of diacetylenic polymers
US4325856A (en) * 1980-01-02 1982-04-20 The Dow Chemical Company Sequential emulsion polymerization process
US4342815A (en) * 1980-03-06 1982-08-03 Permacel Pressure-sensitive adhesive tape having a release coating
US4414370A (en) * 1981-01-09 1983-11-08 S. C. Johnson & Son, Inc. Process for continuous bulk copolymerization of vinyl monomers
US4751263A (en) * 1981-07-01 1988-06-14 Union Carbide Corporation Curable molding compositions containing a poly(acrylate)
DE3145714A1 (de) * 1981-11-19 1983-05-26 Basf Farben + Fasern Ag, 2000 Hamburg Hitzehaertbare bindemittelmischung
US4547409A (en) * 1982-04-29 1985-10-15 Basf Farben & Fasenn A.G. Self-crosslinking heat-curable binder
US4529787A (en) * 1982-06-15 1985-07-16 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
US4408018A (en) * 1982-10-29 1983-10-04 Rohm And Haas Company Acetoacetate functionalized polymers and monomers useful for crosslinking formulations
US4523003A (en) * 1984-01-04 1985-06-11 American Cyanamid Company Storage stable, one package, heat curable polyurea/urethane coating compositions and method of preparation
US4554018A (en) * 1984-02-01 1985-11-19 Allied Colloids Limited Production of polymeric thickeners and their use in printing
US4487789A (en) * 1984-02-09 1984-12-11 Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha Process for forming film of hydrolyzed ethylene-vinyl acetate copolymer
US4631320A (en) * 1984-02-17 1986-12-23 American Cyanamid Company Coating compositions containing polyurethane or polyurea polymers and amino resins
US4546160A (en) * 1984-02-29 1985-10-08 S. C. Johnson & Son, Inc. Bulk polymerization process for preparing high solids and uniform copolymers
EP0199087B2 (en) * 1985-03-29 1993-11-10 Akzo N.V. A liquid coating composition and a process for coating a substrate with such coating composition
JPS61296078A (ja) * 1985-06-25 1986-12-26 Kanebo N S C Kk 室温硬化型接着剤
AT384029B (de) * 1986-04-30 1987-09-25 Vianova Kunstharz Ag 2-komponenten -acrylat-bindemittel
US5185212A (en) * 1986-05-02 1993-02-09 Rohm And Haas Company Acetoacetoxy-alkyl acrylate-containing pressure sensitive adhesives manufactured articles
US5122567A (en) * 1986-05-02 1992-06-16 Union Oil Company Of California Pressure sensitive adhesives of acetoacetoxy-alkyl acrylate polymers
US4908403A (en) * 1986-05-02 1990-03-13 Union Oil Of California Pressure sensitive adhesives of acetoacetoxy-alkyl acrylate polymers
US4855349A (en) * 1986-09-04 1989-08-08 Union Oil Company Of California Mastic and caulking compositions and composite articles
ES2021017B3 (es) * 1986-09-24 1991-10-16 Akzo Nv Composicion de recubrimiento acuosa y proceso para recubrir un sustrato con tal composicion de recubrimiento
ATE62920T1 (de) * 1986-09-24 1991-05-15 Akzo Nv Waesserige ueberzugszusammensetzung und verfahren zum ueberziehen eines substrats damit.
DE3700534A1 (de) * 1987-01-10 1988-07-21 Basf Ag Waessrige polymerdispersionen fuer die holzbeschichtung
DE3779090D1 (de) * 1987-01-16 1992-06-17 Kuraray Co Geformte gegenstaende aus methacrylsaeureesterharzen und verfahren zu deren herstellung.
US4772491A (en) * 1987-08-13 1988-09-20 Eastman Kodak Company Coating process
DE3737630A1 (de) * 1987-11-05 1989-05-18 Henkel Kgaa Waessriger kontaktkleber auf basis von eva-copolymeren
NL8702858A (nl) * 1987-11-28 1989-06-16 Dsm Resins Bv Kamerhardende bekledingsmiddelen.
JPH0757863B2 (ja) * 1987-12-29 1995-06-21 日本合成化学工業株式会社 感圧性接着剤組成物
ATE87320T1 (de) * 1988-02-01 1993-04-15 Rohm & Haas Verfahren zum reagieren von zwei komponenten, zusammensetzungen, beschichtungszusammensetzungen und verwendung davon.
US4894397A (en) * 1988-04-21 1990-01-16 S. C. Johnson & Son, Inc. Stable emulsion polymers and methods of preparing same
GB8811436D0 (en) * 1988-05-13 1988-06-15 Polyvinyl Chemie Holland Bv Aqueous coating compositions
ES2067547T3 (es) * 1988-08-26 1995-04-01 Nippon Oils & Fats Co Ltd Agente dispersante de pigmento.
US5055510A (en) * 1988-08-31 1991-10-08 Union Oil Company Of California Extended polymer compositions and textile materials manufactured therewith
US4906684A (en) * 1988-12-09 1990-03-06 Rtz Chemicals, Ltd. Ambient temperature curing polymer compositions containing acetoacetoxyethyl methacrylate, glycidyl methacrylate and a polymerizable acid
GB9005838D0 (en) * 1989-03-29 1990-05-09 Ici Plc Aqueous coating compositions
US4987177A (en) * 1989-07-18 1991-01-22 E. I. Du Pont De Nemours And Company Coating composition of an acrylic polymer containing glycidyl groups and acetoacetoxy groups and an amino ester acrylic polymer
US5202375A (en) * 1989-07-28 1993-04-13 Rohm And Haas Company Water-resistant polymeric emulsions
NL8902135A (nl) * 1989-08-24 1991-03-18 Stamicarbon Harssamenstelling op basis van een primair amine- of geblokkeerd primair aminefunctioneel urethaan- en/of ureumgroepen bevattend polymeer en een kruisvernetter.
US5157071A (en) * 1989-08-29 1992-10-20 Union Oil Company Of California Paints and polymers for use therein
US5227423A (en) * 1989-08-29 1993-07-13 Rohm And Haas Company Paints and binders for use therein
US5064719A (en) * 1989-09-26 1991-11-12 E. I. Du Pont De Nemours And Company Coating composition of acrylic polymers containing reactive groups and an epoxy organosilane
US4988759A (en) * 1989-09-26 1991-01-29 E. I. Du Pont De Nemours And Company Coating composition of acrylic polymers containing reactive groups and an epoxy organosilane
DE3935137A1 (de) * 1989-10-21 1991-04-25 Hoechst Ag Urethangruppen enthaltende copolymerisate auf der basis von ethylenisch ungesaettigten monomeren, verfahren zu ihrer herstellung und ihre verwendung
US5194527A (en) * 1989-10-31 1993-03-16 The Dow Chemical Company Preparation of ketone containing photodegradable polymers
DE4026346A1 (de) * 1989-11-01 1991-05-02 Linck Masch Gatterlinck Verfahren zum spanlosen aufteilen eines kantholzes in bretter gleicher dicke
US5574090A (en) * 1990-01-16 1996-11-12 Rohm And Haas Company Metal free emulsion polymers for high performance aqueous coatings
US5221581A (en) * 1990-12-18 1993-06-22 E. I. Du Pont De Nemours And Company Coating composition of a glycidyl acrylic polymer, an aminoester acrylic polymer and a polyester or a polyesterurethane
SG45329A1 (en) * 1990-12-21 1998-01-16 Rohm & Haas Air curing polymer composition

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AU661126B2 (en) 1995-07-13
ES2107658T3 (es) 1997-12-01
CA2216303C (en) 2001-07-24
AU3659893A (en) 1993-09-03
DE69312908D1 (de) 1997-09-11
WO1993016133A3 (en) 1993-09-30
KR100282110B1 (ko) 2001-02-15
CA2129822C (en) 2000-10-17
US5605722A (en) 1997-02-25
US5391624A (en) 1995-02-21
DE69312908T2 (de) 1997-11-20
CA2129822A1 (en) 1993-08-19
WO1993016133A2 (en) 1993-08-19
US5952407A (en) 1999-09-14
US5498659A (en) 1996-03-12
US5609965A (en) 1997-03-11
US5605952A (en) 1997-02-25
CA2216303A1 (en) 1993-08-19
US5605953A (en) 1997-02-25
DK0625999T3 (da) 1998-03-23
KR100276375B1 (ko) 2001-03-02
EP0625999B1 (en) 1997-08-06
EP0625999A4 (ko) 1995-01-04
JPH07503753A (ja) 1995-04-20
ATE156503T1 (de) 1997-08-15
EP0625999A1 (en) 1994-11-30

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