KR950034874A - 금속-절연체-반도체 게이트 구조를 갖는 불휘발성 반도체 기억 장치 - Google Patents
금속-절연체-반도체 게이트 구조를 갖는 불휘발성 반도체 기억 장치 Download PDFInfo
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- KR950034874A KR950034874A KR1019950013797A KR19950013797A KR950034874A KR 950034874 A KR950034874 A KR 950034874A KR 1019950013797 A KR1019950013797 A KR 1019950013797A KR 19950013797 A KR19950013797 A KR 19950013797A KR 950034874 A KR950034874 A KR 950034874A
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- Prior art keywords
- insulating film
- film
- semiconductor memory
- memory device
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- 239000004065 semiconductor Substances 0.000 title claims abstract 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000000203 mixture Substances 0.000 claims abstract 2
- 229910052710 silicon Inorganic materials 0.000 claims abstract 2
- 239000010703 silicon Substances 0.000 claims abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 5
- 229910052814 silicon oxide Inorganic materials 0.000 claims 5
- 239000011810 insulating material Substances 0.000 claims 3
- 229910044991 metal oxide Inorganic materials 0.000 claims 3
- 150000004706 metal oxides Chemical class 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 239000006104 solid solution Substances 0.000 claims 3
- 229910052454 barium strontium titanate Inorganic materials 0.000 claims 2
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 229910052581 Si3N4 Inorganic materials 0.000 claims 1
- VNSWULZVUKFJHK-UHFFFAOYSA-N [Sr].[Bi] Chemical compound [Sr].[Bi] VNSWULZVUKFJHK-UHFFFAOYSA-N 0.000 claims 1
- 229910002113 barium titanate Inorganic materials 0.000 claims 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims 1
- 229910002115 bismuth titanate Inorganic materials 0.000 claims 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 claims 1
- 229910052451 lead zirconate titanate Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000004767 nitrides Chemical class 0.000 claims 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/788—Field effect transistors with field effect produced by an insulated gate with floating gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66833—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a charge trapping gate insulator, e.g. MNOS transistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/401—Multistep manufacturing processes
- H01L29/4011—Multistep manufacturing processes for data storage electrodes
- H01L29/40117—Multistep manufacturing processes for data storage electrodes the electrodes comprising a charge-trapping insulator
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/78391—Field effect transistors with field effect produced by an insulated gate the gate comprising a layer which is used for its ferroelectric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/788—Field effect transistors with field effect produced by an insulated gate with floating gate
- H01L29/7881—Programmable transistors with only two possible levels of programmation
- H01L29/7883—Programmable transistors with only two possible levels of programmation charging by tunnelling of carriers, e.g. Fowler-Nordheim tunnelling
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/792—Field effect transistors with field effect produced by an insulated gate with charge trapping gate insulator, e.g. MNOS-memory transistors
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- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- Non-Volatile Memory (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
- Semiconductor Memories (AREA)
Abstract
본 발명은 반도체의 불휘발성 기억 소자에 있어서, 그 기입 소거 동작의 저전압화와 저소비 전력화, 이 동작의 회수의 증가를 실현하고, 플래쉬 메모리와 같은 불휘발성 반도체 기억 장치의 성능 향상을 도모하는 것을 목적으로 한다.
MIS형 반도체 불휘발성 기억 소자에 있어서, 제1절연막과 제2절연막의 2층의 절연막으로 형성된 게이트 절연막 중, 상기 제2절연막을 고유전율막으로 형성함과 동시에, 이 고유전율막의 조성을 연속적 또는 불연속적으로 바꾸거나 또는 상기 제1절연막과 제2절연막 사이에 실리콘 미립자를 형성한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 제1실시예를 설명하기 위한 개략 단면도, 제2도는 본 발명의 MIS 구조의 등가 회로도.
Claims (7)
- MIS(금속-절연체-반도체) 구조의 트랜지스터에서, 반도체 기판의 주면에 제1절연막이 형성되고, 상기 제1절연막에 적층하여 제2절연막이 형성되며, 상기 제1절연막과 제2절연막의 2층 절연막에서 MIS구조 트랜지스터의 게이트 절연막이 형성되고, 상기 제1절연막의 막 두께 및 비유전율을 t1, ε1로하고, 상기 제2절연막의 막 두께 및 비유절율을 t2, ε2로 하여, ε2/ε1이 20≤ε2/ε1의 관계와 t2/t1≤ε2/ε1의 관계를 만족하는 것을 특징으로 하는 반도체 기억 장치.
- 제1항에 있어서, 상기 제1절연막이 실리콘 산화물, 실리콘 질화물 또는 실리콘 산화막의 질화물로 형성되고, 상기 제2절연막이 티탄산 스트롬튬, 티탄산 발륨 스트론튬, 티탄산 지르콘산납, 티탄산 비스무스 또는 탄탈산 비스무스 스트론튬의 금속 산화물로 형성되는 것을 특징으로 한 반도체 기억 장치.
- 제1항에 있어서, 상기 제2절연막이 2종류의 금속 산화물 고용체(固溶體)의 절연 물질로 형성되고, 상기 고용체의 절연 물질의 조성이 그 막 두께 방향에서 상이하도록 형성되어 있는 것을 특징으로 하는 반도체 기억 장치.
- 제3항에 있어서, 상기 2종류의 금속 산화물이 티탄산 스트롬튬 및 티탄산 발륨이고, 상기 고용체의 절연물질이 티탄산 발륨 스트론튬인 것을 특징으로 하는 반도체 기억 장치.
- 제1항에 있어서, 상기 제2절연막이 적층되는 2종류의 산화막으로 형성되어 있는 것을 특징으로 하는 반도체 기억 장치.
- 제1, 2, 3, 4또는 5항에 있어서, 상기 제1절연막과 상기 제2절연막의 계면 영역에 실리콘 원자의 집합체를 상기 집합체가 서로 이산되어 형성되는 것을 특징으로 하는 반도체 기억 장치.
- 실리콘 반도체 기판의 주면에 실리콘 산화막을 형성하는 공정, 상기 실리콘 산화막의 표면에 실리콘 원자의 복수의 집합체를 이들 집합체가 서로 이산하도록 형성하는 공정 및 상기 실리콘 산화막 및 상기 집합체를 피복하도록 상기 제2절연막을 형성하는 공정을 포함하는 것을 특징으로 하는 제6항 기재의 반도체 기억 장치의 제조 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP94-116394 | 1994-05-30 | ||
JP6116394A JP2643833B2 (ja) | 1994-05-30 | 1994-05-30 | 半導体記憶装置及びその製造方法 |
Publications (2)
Publication Number | Publication Date |
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KR950034874A true KR950034874A (ko) | 1995-12-28 |
KR100190158B1 KR100190158B1 (ko) | 1999-06-01 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019950013797A KR100190158B1 (ko) | 1994-05-30 | 1995-05-30 | 금속-절연체-반도체 게이트 구조를 갖는 불휘발성 반도체 기억 장치 |
Country Status (3)
Country | Link |
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US (1) | US5596214A (ko) |
JP (1) | JP2643833B2 (ko) |
KR (1) | KR100190158B1 (ko) |
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-
1994
- 1994-05-30 JP JP6116394A patent/JP2643833B2/ja not_active Expired - Lifetime
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1995
- 1995-05-30 KR KR1019950013797A patent/KR100190158B1/ko not_active IP Right Cessation
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KR100190158B1 (ko) | 1999-06-01 |
JP2643833B2 (ja) | 1997-08-20 |
JPH07326681A (ja) | 1995-12-12 |
US5596214A (en) | 1997-01-21 |
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