KR940021761A - 냉간 가공 작업을 용이하게 하는 방법 - Google Patents

냉간 가공 작업을 용이하게 하는 방법 Download PDF

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KR940021761A
KR940021761A KR1019940003802A KR19940003802A KR940021761A KR 940021761 A KR940021761 A KR 940021761A KR 1019940003802 A KR1019940003802 A KR 1019940003802A KR 19940003802 A KR19940003802 A KR 19940003802A KR 940021761 A KR940021761 A KR 940021761A
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calculated
treatment solution
immersed
phosphate
ferrous material
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KR1019940003802A
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KR100324862B1 (ko
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니텔 클라우스-디이터
잔데르 카르하인쯔
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하인리히 괴츠, 하랄트 리이게르
메탈게젤샤후트 아크치엔게젤샤후트
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/368—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing magnesium cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations
    • C23C22/14—Orthophosphates containing zinc cations containing also chlorate anions
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
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  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Materials For Medical Uses (AREA)
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Abstract

인산염 코우팅을 가하여 제1철 물질의 비절단 냉간 가공을 용이하게 하는 방법에서, 제1철 물질은 주기율표 시스템의 제6아군의 원소가 없고 질소 화합물이 없고 바람직하게 또한 니켈이 없고 5-20g/ℓ아연, 1-15g/ℓ마그네슘, 10-26g/ℓ 인산염(P2O5로서 계산됨), 1-15g/ℓ 플루오로붕산염(BF4로서 계산됨), 1-7g/ℓ 염소산염(ClO3로서 계산됨) 및 바람직하게는 부가적으로 5-40g/ℓ 황산염(SO4로서 계산됨)을 함유하고, Zn : Mg : BF4의 중량비가 1 : (0.15-1) : (0.15-1)의 수치로 조정된 인산염 처리 용액내에 침지된다.

Description

냉간 가공 작업을 용이하게 하는 방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 주기율표 시스템의 제6아군의 원소가 없고 질소 화합물이 없고, 5-20g/ℓ 아연, 1-15g/ℓ 마그네슘, 10-26g/ℓ 인산염(P2O5로서 계산됨), 1-15g/ℓ 플루오로붕산염(BF4로서 계산됨), 1-7g/ℓ 염소산염(ClO3로서 계산됨)을 함유하고, Zn : Mg : BF4의 중량비가 1 : (0.15-1) : (0.15-1)의 수치로 조정되는 인산염 처리 용액에 제1철 물질을 침지시킴을 특징으로 하는, 아연 이온, Mg 이온 및 인산염 이온, 및 산화제를 함유하는 수성 산 인산염 처리 용액에 침지시킴으로써 인산염 코우팅을 가하여 제1철 물질의 비절단 냉간 가공을 용이하게 하는 방법.
  2. 제1항에 있어서, 6-17g/ℓ 아연, 2-5g/ℓ 마그네슘, 13-20g/ℓ 인산염(P2O5로서 계산됨), 2-5g/ℓ 플루오로붕산염(BF4로서 계산됨), 2-4g/ℓ 염소산염(ClO3로서 계산됨)을 함유하는 인산염 처리 용액에 제1철 물질을 침지시킴을 특징으로 하는 방법.
  3. 제1 또는 2항에 있어서, 1 : (0.23-0.46) : (0.23-0.46)로 Zn : Mg : BF4의 중량비를 갖도록 조정되는 인산염 처리 용액내에 제1철 물질을 침지시킴을 특징으로 하는 방법.
  4. 제1, 2 또는 3항에 있어서, 5-40g/ℓ 황산염(SO4로서 계산됨)을 함유하는 인산염 처리 용액내에 제1철 물질을 침지시킴을 특징으로 하는 방법.
  5. 제4항에 있어서, 10-30g/ℓ황산염(SO4로서 계산됨)을 함유하는 인산염 처리 용액내에 제1철 물질을 침지시킴을 특징으로 하는 방법.
  6. 제1-5항 중 어느 한 항에 있어서, 0.1-0.4의 산비를 갖는 인산염 처리 용액내에 제1철 물질을 침지시킴을 특징으로 하는 방법.
  7. 제1-6항 중 어느 한 항에 있어서, 니켈이 없는 인산염 처리 용액에 제1철 물질을 침지시킴을 특징으로 하는 방법.
  8. 제1-7항 중 어느 한 항에 있어서, 50-70℃로 온도가 조정된 인산염 처리 용액내에 제1철 물질을 침지시킴을 특징으로 하는 방법.
  9. 제1-8항 중 어느 한 항에 있어서, 3-15분간 인산염 처리 용액내에 제1철 물질을 침지시킴을 특징으로 하는 방법.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940003802A 1993-03-02 1994-02-28 제1철물질의비절단냉간가공을용이하게하는방법 KR100324862B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4306446A DE4306446A1 (de) 1993-03-02 1993-03-02 Verfahren zur Erleichterung der Kaltumformung
DEP4306446.9 1993-03-02

Publications (2)

Publication Number Publication Date
KR940021761A true KR940021761A (ko) 1994-10-19
KR100324862B1 KR100324862B1 (ko) 2002-06-20

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KR1019940003802A KR100324862B1 (ko) 1993-03-02 1994-02-28 제1철물질의비절단냉간가공을용이하게하는방법

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Country Link
US (1) US5415701A (ko)
EP (1) EP0613964B1 (ko)
JP (1) JPH06322550A (ko)
KR (1) KR100324862B1 (ko)
CN (1) CN1040779C (ko)
AT (1) ATE130052T1 (ko)
DE (2) DE4306446A1 (ko)
ES (1) ES2081224T3 (ko)
TW (1) TW270901B (ko)
ZA (1) ZA941457B (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4630326B2 (ja) * 1999-08-09 2011-02-09 新日本製鐵株式会社 加工性に優れたリン酸塩処理亜鉛系めっき鋼板の製造方法
CA2494559C (en) 2002-07-10 2011-09-20 Chemetall Gmbh Method for coating metallic surfaces
DE10320313B4 (de) * 2003-05-06 2005-08-11 Chemetall Gmbh Verfahren zum Beschichten von metallischen Körpern mit einer Phosphatierungslösung, Phosphatierungslösung und die Verwendung des beschichteten Gegenstandes
DE10323305B4 (de) * 2003-05-23 2006-03-30 Chemetall Gmbh Verfahren zur Beschichtung von metallischen Oberflächen mit einer Wasserstoffperoxid enthaltenden Phosphatierungslösung, Phosphatierlösung und Verwendung der behandelten Gegenstände
TWI457433B (zh) * 2008-01-30 2014-10-21 Chemetall Gmbh 將金屬表面施以一磷酸鹽層然後施以一潤滑劑層的方法
TWI457431B (zh) * 2008-01-30 2014-10-21 Chemetall Gmbh 將金屬表面施以一種潤滑劑組成物的方法
TWI457432B (zh) * 2008-01-30 2014-10-21 Chemetall Gmbh 將金屬表面施以一含蠟的潤滑劑組成物的方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1796102A1 (de) * 1968-08-31 1972-02-17 Metallgesellschaft Ag Verfahren zum Aufbringen eines Phosphatueberzuges auf Oberflaechen von Eisen und Stahl
FR2389683A1 (en) * 1977-05-03 1978-12-01 Parker Ste Continentale Phosphating soln. contg. boron fluoride - for phosphating ferrous and non-ferrous surfaces, e.g. steel, zinc and aluminium
GB2080835B (en) * 1980-07-25 1984-08-30 Pyrene Chemical Services Ltd Prevention of sludge in phosphating baths
DE3871031D1 (de) * 1987-08-19 1992-06-17 Metallgesellschaft Ag Verfahren zur phosphatierung von metallen.
JPH0696773B2 (ja) * 1989-06-15 1994-11-30 日本ペイント株式会社 金属表面のリン酸亜鉛皮膜形成方法
DE3927613A1 (de) * 1989-08-22 1991-02-28 Metallgesellschaft Ag Verfahren zur erzeugung von phosphatueberzuegen auf metalloberflaechen
JPH03107469A (ja) * 1989-09-21 1991-05-07 Nippon Parkerizing Co Ltd 裸耐食性に優れたりん酸塩化成皮膜を有する亜鉛系めっき材料

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Publication number Publication date
EP0613964B1 (de) 1995-11-08
KR100324862B1 (ko) 2002-06-20
JPH06322550A (ja) 1994-11-22
TW270901B (ko) 1996-02-21
EP0613964A1 (de) 1994-09-07
ZA941457B (en) 1995-09-04
CN1093416A (zh) 1994-10-12
ES2081224T3 (es) 1996-02-16
CN1040779C (zh) 1998-11-18
DE59400038D1 (de) 1995-12-14
DE4306446A1 (de) 1994-09-08
US5415701A (en) 1995-05-16
ATE130052T1 (de) 1995-11-15

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