KR920702731A - 망간 및 마그네슘 함유 아연 포스페이트 코팅의 형성방법 - Google Patents

망간 및 마그네슘 함유 아연 포스페이트 코팅의 형성방법

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Publication number
KR920702731A
KR920702731A KR1019910701931A KR910701931A KR920702731A KR 920702731 A KR920702731 A KR 920702731A KR 1019910701931 A KR1019910701931 A KR 1019910701931A KR 910701931 A KR910701931 A KR 910701931A KR 920702731 A KR920702731 A KR 920702731A
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KR
South Korea
Prior art keywords
ions
aqueous solution
ion
magnesium
zinc
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KR1019910701931A
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English (en)
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KR0171219B1 (ko
Inventor
리에소프 죄르그
고트왈드 카알-헤인즈
롤란트 울프-아킴
Original Assignee
요한 글라슬, 호르스트 헤를레
헨켈코만디트 게젤샤프트 아우프 아크티엔
호르스트 헤를레
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Publication of KR920702731A publication Critical patent/KR920702731A/ko
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Publication of KR0171219B1 publication Critical patent/KR0171219B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/368—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing magnesium cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/18—Orthophosphates containing manganese cations
    • C23C22/188—Orthophosphates containing manganese cations containing also magnesium cations

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  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Dental Preparations (AREA)
  • Glass Compositions (AREA)
  • Materials For Medical Uses (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음

Description

망간 및 마그네슘 함유 아연 포스페이트 코팅의 형성방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 아연(II)이온 0.2∼1.0g/ℓ, 망간(II)이온 0.2∼2.0g/ℓ, 마그네슘(II)이온 0.5∼2.0g/ℓ, 포스페이트 이온 10.0∼20.0g/ℓ, 플루오라이드 이온 0.0∼ 1.0g/ℓ, 니트레이트 이온 0.2∼10.0g/ℓ 및, 촉진제로서 니트라이트 이온 0.02∼0.2g/ℓ, 및/또는 클로레이트 이온 0.4∼1g/ℓ 및/또는 유기 산화제 0.2∼1.0g/ℓ를 함유하고 유리산의 함량이 0.6∼1.8포인트이며, 산의 총함량이 15∼30 포인트이고, 유리산을 조절하는데 필요한 양의 Na+가 존재하고 있는 수용액을 사용하여 이를 분무, 분무-침액 및/또는 침액함으로써, 강철, 아연, 알루미늄 및/또는 이들의 합금상에 망간 및 마그네슘 함유 아연 포스페이프 코팅을 형성하는 방법.
  2. 제1항에 있어서, 수용액이 아연(II)이온 0.4∼0.6g/ℓ, 망간(II)이온 0.9∼1.1g/ℓ, 마그네슘(II) 이온 1.4∼1.6g/ℓ, 포스페이트이온 12.0∼16.0g/ℓ, 니트레이트 이온 1.0∼5.0g/ℓ 및 플루오라이드 이온 0.4∼0.6g/ℓ을 함유함을 특징으로 하는 방법.
  3. 제1항 또는 2항에 있어서, 수용액이 니켈(II) 이온 0.2∼0.8g/ℓ을 함유함을 특징으로 하는 방법.
  4. 제1항 또는 2항에 있어서, 수용액이 니켈(II) 이온 0.25∼0.5g/ℓ을 함유함을 특징으로 하는 방법.
  5. 제1항 내지 4항중 어느 한 항에 있어서, 3-니트로벤젠술폰산을 유기 산화제로서 사용함을 특징으로 하는 방법.
  6. 제5항에 있어서, 3-니트로벤젠술폰산의 나트륨염을 사용함을 특징으로 하는 방법.
  7. 제1항 내지 6항중 어느 한 항에 있어서, 포스페이트화 조작을 40~70℃ 범위의 온도에서 수행함을 특징으로 하는 방법.
  8. 제1항 내지 7항중 어느 한 항에 있어서, 강철, 아연 도금 강철, 알루미늄의 표면 및/또는 각각의 합금-개질된 표면을 1~5분을 동안 포스페이트화하여 층을 형성함을 특징으로 하는 방법.
  9. 금속 표면상에 페인팅, 특히 전기-집 코우팅을 형성하는 방법으로서, 제1항 내지 8항중 어느 한항에 따른 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019910701931A 1989-06-21 1990-06-12 망간 및 마그네슘 함유 아연 포스페이트 코팅의 형성방법 KR0171219B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP3920296.8 1989-06-21
DEP39202968 1989-06-21
DE3920296A DE3920296A1 (de) 1989-06-21 1989-06-21 Verfahren zur herstellung von mangan- und magnesiumhaltigen zinkphosphatueberzuegen

Publications (2)

Publication Number Publication Date
KR920702731A true KR920702731A (ko) 1992-10-06
KR0171219B1 KR0171219B1 (ko) 1999-02-18

Family

ID=6383236

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910701931A KR0171219B1 (ko) 1989-06-21 1990-06-12 망간 및 마그네슘 함유 아연 포스페이트 코팅의 형성방법

Country Status (12)

Country Link
US (1) US5207840A (ko)
EP (1) EP0478648B1 (ko)
JP (1) JPH04506233A (ko)
KR (1) KR0171219B1 (ko)
AT (1) ATE117381T1 (ko)
BR (1) BR9007437A (ko)
CA (1) CA2062952A1 (ko)
DE (2) DE3920296A1 (ko)
ES (1) ES2067031T3 (ko)
PT (1) PT94426B (ko)
WO (1) WO1990015889A1 (ko)
ZA (1) ZA904795B (ko)

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Publication number Priority date Publication date Assignee Title
DE4210513A1 (de) 1992-03-31 1993-10-07 Henkel Kgaa Nickel-freie Phosphatierverfahren
WO1995007370A1 (de) * 1993-09-06 1995-03-16 Henkel Kommanditgesellschaft Auf Aktien Nickelfreies phosphatierverfahren
DE4440300A1 (de) * 1994-11-11 1996-05-15 Metallgesellschaft Ag Verfahren zum Aufbringen von Phosphatüberzügen
DE19500927A1 (de) * 1995-01-16 1996-07-18 Henkel Kgaa Lithiumhaltige Zinkphosphatierlösung
DE19511573A1 (de) * 1995-03-29 1996-10-02 Henkel Kgaa Verfahren zur Phosphatierung mit metallhaltiger Nachspülung
US5900073A (en) * 1996-12-04 1999-05-04 Henkel Corporation Sludge reducing zinc phosphating process and composition
DE19740953A1 (de) * 1997-09-17 1999-03-18 Henkel Kgaa Verfahren zur Phosphatierung von Stahlband
JP3828675B2 (ja) * 1998-04-23 2006-10-04 新日本製鐵株式会社 耐食性、加工性に優れた表面処理鋼板およびその製造方法
DE19834796A1 (de) 1998-08-01 2000-02-03 Henkel Kgaa Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung
US6607844B1 (en) * 1999-03-15 2003-08-19 Kobe Steel, Ltd. Zn-Mg electroplated metal sheet and fabrication process therefor
US6322906B1 (en) 1999-07-08 2001-11-27 Kawasaki Steel Corporation Perforative corrosion resistant galvanized steel sheet
CN1245535C (zh) * 1999-09-17 2006-03-15 杰富意钢铁株式会社 表面处理钢板及其制造方法
DE10109480A1 (de) * 2001-02-28 2002-09-05 Volkswagen Ag Verfahren zur Beschichtung einer Aluminiumoberfläche
JP4233565B2 (ja) 2002-07-10 2009-03-04 ヒェメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング 金属表面を被覆する方法
DE10320313B4 (de) * 2003-05-06 2005-08-11 Chemetall Gmbh Verfahren zum Beschichten von metallischen Körpern mit einer Phosphatierungslösung, Phosphatierungslösung und die Verwendung des beschichteten Gegenstandes
DE10323305B4 (de) * 2003-05-23 2006-03-30 Chemetall Gmbh Verfahren zur Beschichtung von metallischen Oberflächen mit einer Wasserstoffperoxid enthaltenden Phosphatierungslösung, Phosphatierlösung und Verwendung der behandelten Gegenstände
US7815751B2 (en) * 2005-09-28 2010-10-19 Coral Chemical Company Zirconium-vanadium conversion coating compositions for ferrous metals and a method for providing conversion coatings
DE102008004728A1 (de) 2008-01-16 2009-07-23 Henkel Ag & Co. Kgaa Phosphatiertes Stahlblech sowie Verfahren zur Herstellung eines solchen Blechs
US10442480B2 (en) * 2017-06-30 2019-10-15 Caterpillar Inc. Coating for seal assembly

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US3676224A (en) * 1970-10-16 1972-07-11 Lubrizol Corp Phosphating solution with scale suppressing characteristics
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US4681641A (en) * 1982-07-12 1987-07-21 Ford Motor Company Alkaline resistant phosphate conversion coatings
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DE3711931A1 (de) * 1987-04-09 1988-10-20 Metallgesellschaft Ag Verfahren zur bestimmung von zink in phosphatierbaedern
DE3712339A1 (de) * 1987-04-11 1988-10-20 Metallgesellschaft Ag Verfahren zur phosphatierung vor der elektrotauchlackierung

Also Published As

Publication number Publication date
JPH04506233A (ja) 1992-10-29
WO1990015889A1 (de) 1990-12-27
DE59008322D1 (de) 1995-03-02
EP0478648B1 (de) 1995-01-18
US5207840A (en) 1993-05-04
KR0171219B1 (ko) 1999-02-18
EP0478648A1 (de) 1992-04-08
ATE117381T1 (de) 1995-02-15
BR9007437A (pt) 1992-04-14
DE3920296A1 (de) 1991-01-10
PT94426B (pt) 1997-02-28
CA2062952A1 (en) 1990-12-22
PT94426A (pt) 1991-02-08
ZA904795B (en) 1991-02-27
ES2067031T3 (es) 1995-03-16

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