KR940014735A - 시각에 의해 칼라가 결정되는 안료, 그 제조방법 및 그 사용 - Google Patents
시각에 의해 칼라가 결정되는 안료, 그 제조방법 및 그 사용 Download PDFInfo
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- KR940014735A KR940014735A KR1019930025716A KR930025716A KR940014735A KR 940014735 A KR940014735 A KR 940014735A KR 1019930025716 A KR1019930025716 A KR 1019930025716A KR 930025716 A KR930025716 A KR 930025716A KR 940014735 A KR940014735 A KR 940014735A
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- pigment
- liquid crystal
- crystal structure
- pigments
- Prior art date
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- 239000000049 pigment Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims 4
- 238000004132 cross linking Methods 0.000 claims abstract 7
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract 7
- 239000000463 material Substances 0.000 claims abstract 7
- 125000003118 aryl group Chemical group 0.000 claims abstract 4
- 238000000034 method Methods 0.000 claims abstract 2
- 229920005989 resin Polymers 0.000 claims 8
- 239000011347 resin Substances 0.000 claims 8
- -1 polypropylene Polymers 0.000 claims 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 6
- 239000004743 Polypropylene Substances 0.000 claims 3
- 239000000975 dye Substances 0.000 claims 3
- 230000002496 gastric effect Effects 0.000 claims 3
- 229920001155 polypropylene Polymers 0.000 claims 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- 239000004793 Polystyrene Substances 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 229920003023 plastic Polymers 0.000 claims 2
- 239000004033 plastic Substances 0.000 claims 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims 2
- 229920002223 polystyrene Polymers 0.000 claims 2
- 210000002784 stomach Anatomy 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- ZVKPGHYZRCHUJO-UHFFFAOYSA-N 4-ethenoxycarbonylbenzoic acid Chemical compound OC(=O)C1=CC=C(C(=O)OC=C)C=C1 ZVKPGHYZRCHUJO-UHFFFAOYSA-N 0.000 claims 1
- 239000004925 Acrylic resin Substances 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 229920000180 alkyd Polymers 0.000 claims 1
- 229920003180 amino resin Polymers 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 239000005018 casein Substances 0.000 claims 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims 1
- 235000021240 caseins Nutrition 0.000 claims 1
- 229920006218 cellulose propionate Polymers 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000004040 coloring Methods 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 claims 1
- 239000011243 crosslinked material Substances 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- 239000000976 ink Substances 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 125000005375 organosiloxane group Chemical group 0.000 claims 1
- 239000003973 paint Substances 0.000 claims 1
- 229920001568 phenolic resin Polymers 0.000 claims 1
- 239000005011 phenolic resin Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920001748 polybutylene Polymers 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 229920005749 polyurethane resin Polymers 0.000 claims 1
- 229920002689 polyvinyl acetate Polymers 0.000 claims 1
- 239000011118 polyvinyl acetate Substances 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 229920006337 unsaturated polyester resin Polymers 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 241001416181 Axis axis Species 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0295—Liquid crystals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/40—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen or sulfur, e.g. silicon, metals
- C09K19/406—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen or sulfur, e.g. silicon, metals containing silicon
- C09K19/408—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- Crystallography & Structural Chemistry (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Liquid Crystal Substances (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Investigating Or Analysing Biological Materials (AREA)
- Electroluminescent Light Sources (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Cosmetics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
이 발명은 시각에 따른 칼라가 결정되는 안료, 그 제조방법 및 사용에 관한 것이다.
이들의 안료는 키랄상(chiral phase)을 가진 액정구조이 방향성 3차원 가교물질과 필요할 경우 또드란 염료와 안료를 구성하며, 그 또다른 염료의 안료는 존재할 경우 키탈상을 가진 액정구조의 방향성 3차원 가교물질의 기재(base)로서 작용하지 않는다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도면은 이발명에 의한 안료함유래커로 코팅한 표면에 대한 실시예 7의 사용설명도.
Claims (10)
- 시각(viewing angle)에 따라 칼라가 결정되는 안료에 있어서, 키탈상(chiral phase)을 가진 액정구조의 방향성 3차원 가교물질(oriented three-dimensionally crosslinked substances)와, 필요할 경우 또다른 염료와 안료를 구성성하며, 그 또다른 염료와 안료는 존재할 경우 키랄상을 가진 액정구조의 방향성 3차원 가교물질의 기래(bere)로서 작용하지 아니한 위 안료.
- 제1항에 있어서, 키랄상을 가진 액정구조의 방향성 3차원 가교물질로서 중합할수 있는 그룹(groups)의 수가 적어도 2종인 오르가노 폴리실록산을 포함함을 특징으로 하는 위 안료.
- 제2항에 있어서, 키랄상을 가진 액정구조의 방향성 3차원가교물질로서 적어도 2종의 오르가노 실록산을 포함함을 특징으로하는 위 안료.
- 제1항에 있어서, 또다른 안료로서 카본블랙을 포함함을 특징으로 하는 위 안료.
- 제1항에 있어서, 그 안료는 두께 1-100μm, 입자직경 1-100μm임을 특징으로하는 위 안료.
- 제1항 내지 제5항중 어느 한항의 안료의 제조방법에 있어서, 키랄상을 가진 액정구조의 방향성 3차원가교물질을 구성시켜 필요할 경우 또다른 안료 및/또는 염료를 혼가시킨후, 3차원적으로 가교결합성반응을 시켜 필요한 입자크기로 분해 시켰을 특징으로하는 위 제조방법.
- 제6항에 있어서, 그 방향성 3차원 가교물질은 배킹(backing)상에 처리하여 분쇄전에 다시 분리시킴을 특징으로하는 위 제조방법.
- 제1항 내지 제5항의 적어도 하나의 안료를 포함한 조성물에 있어서, 페놀수지, 아미노수지, 알키드수지, 폴리비닐 아세테이트수지, 에폭시수지, 폴리우레탄수지, 폴리에틸레수지, 클로리네이티드레버 수지, 시클로레버 수지, 클로리네이티드 폴리 프로필렌, 케톤수지, 아크릴레이트수지, 벨라민수지, 요소/포름알레히드수지, 페놀/포름알레히드수지로 구성되는 그룹에서 적어도 하나의 물질 또는 아크릴로디트릴/부타리엔/스티렌/코풀리머, 셀룰로오스 프로피오 네이트, 카제인 플라스틱, 폴리마이드, 폴리카드보네이트, 폴리에틸렌, 폴리부틸렌, 테레프탈 레이트, 폴리메틸메타크릴레이트, 폴리프로필렌, 폴리스티렌, 폴리테트라 플로오로에틸렌, 폴리비닐 테레프탈 레이트, 폴리메틸메타크릴레이트, 폴리프로필렌, 폴리스티렌, 폴리테트라 플로오로에틸렌, 폴리비닐 클로리드, 폴리비닐리렌 클로리드, 폴리우레탄, 스티렌/아크릴로 니트릴 코폴리며, 불포화 폴리에스테르 수지로 구성되는 그룹에서 적어도 하나의 물질을 추가로 구성함을 특징으로하는 위 조성물.
- 페인트 및 코팅, 플라스틱, 섬유원료, 프린팅잉크의 또는 발색(coloring)용 화장품 제조용으로 청구범위 제1항 내지 제5항의 안료의 사용.
- 보안표시(security marking)로서 청구범위 제1항 내지 제5항의 안료의 사용.※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4240743A DE4240743A1 (de) | 1992-12-03 | 1992-12-03 | Pigmente mit vom Betrachtungswinkel abhängiger Farbigkeit, ihre Herstellung und Verwendung |
DE92-P4240743.5 | 1992-12-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940014735A true KR940014735A (ko) | 1994-07-19 |
KR0134948B1 KR0134948B1 (ko) | 1998-04-18 |
Family
ID=6474346
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930025716A KR0134948B1 (ko) | 1992-12-03 | 1993-11-29 | 시각(視角)에 의해 칼라가 결정되는 안료, 그 제조방법 및 그 사용 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5362315A (ko) |
EP (1) | EP0601483B1 (ko) |
JP (1) | JP2519018B2 (ko) |
KR (1) | KR0134948B1 (ko) |
AT (1) | ATE128481T1 (ko) |
CA (1) | CA2110099C (ko) |
DE (2) | DE4240743A1 (ko) |
DK (1) | DK0601483T3 (ko) |
ES (1) | ES2077462T3 (ko) |
Families Citing this family (112)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4418075C2 (de) * | 1994-05-24 | 2000-06-29 | Daimler Chrysler Ag | Effektlack bzw. Effektlackierung, insbesondere für Fahrzeugkarosserien, unter Verwendung von flüssigkristallinen Interferenzpigmenten |
DE59501081D1 (de) * | 1994-04-30 | 1998-01-15 | Wacker Chemie Gmbh | Wässriges überzugsmittel und verfahren zur herstellung von mehrschichtlackierungen mit vom betrachtungswinkel abhängigem farbeindruck |
DE4416191A1 (de) | 1994-05-06 | 1995-11-09 | Consortium Elektrochem Ind | Interferenzpigmente aus in cholesterischer Anordnung fixierten Molekülen sowie deren Verwendung |
DE4416993C2 (de) * | 1994-05-13 | 2002-12-12 | Daimler Chrysler Ag | Thermisch farb-beinflußbare Lackierung |
DE4418490C2 (de) * | 1994-05-27 | 1997-05-28 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Effektmehrschichtlackierungen |
DE4419239A1 (de) * | 1994-06-01 | 1995-12-07 | Consortium Elektrochem Ind | Optische Elemente mit farb- und polarisationsselektiver Reflexion enthaltend LC-Pigmente sowie Herstellung dieser Elemente |
DE4430919A1 (de) * | 1994-08-31 | 1996-03-07 | Daimler Benz Ag | Lack, insbsondere Pulverlack zum Lackieren der Oberflächen von Substraten, insbesondere von Fahrzeugkarosserien |
DE4441651A1 (de) * | 1994-11-23 | 1996-04-25 | Basf Ag | Verfahren zur oberflächlichen Beschichtung von Substraten |
DE19502413B4 (de) | 1995-01-26 | 2009-06-10 | Sicpa Holding S.A. | Pigment mit vom Betrachtungswinkel abhängiger Farbigkeit, dessen Herstellung sowie Verwendung in einem Lack, insbesondere für Kraftfahrzeuge |
DE19549872B4 (de) * | 1995-01-26 | 2017-05-18 | Sicpa Holding Sa | Lack enthaltend ein Pigment mit vom Betrachtungswinkel abhängiger Farbigkeit, sowie dessen Verwendung |
DE19504913A1 (de) * | 1995-02-15 | 1996-08-22 | Basf Ag | Neue chiral neumatische Polyester |
DE19505161A1 (de) * | 1995-02-16 | 1996-08-22 | Daimler Benz Ag | Effektlack bzw. Effektlackierung, insbesondere für Kraftfahrzeugkarosserien |
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DE3110048A1 (de) * | 1981-03-16 | 1982-09-30 | Consortium für elektrochemische Industrie GmbH, 8000 München | "fluessigkristalline phasen aufweisende zusammensetzungen auf basis cyclischer organopolysiloxane, ihre herstellung und deren verwendung" |
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ES2060921T3 (es) * | 1989-02-13 | 1994-12-01 | Akzo Nobel Nv | Pigmento de cristal liquido, metodo de producirlo y uso en revestimientos. |
-
1992
- 1992-12-03 DE DE4240743A patent/DE4240743A1/de not_active Withdrawn
-
1993
- 1993-11-22 US US08/155,353 patent/US5362315A/en not_active Expired - Fee Related
- 1993-11-26 CA CA002110099A patent/CA2110099C/en not_active Expired - Fee Related
- 1993-11-29 KR KR1019930025716A patent/KR0134948B1/ko not_active IP Right Cessation
- 1993-12-01 JP JP5302021A patent/JP2519018B2/ja not_active Expired - Lifetime
- 1993-12-02 DK DK93119438.5T patent/DK0601483T3/da active
- 1993-12-02 ES ES93119438T patent/ES2077462T3/es not_active Expired - Lifetime
- 1993-12-02 EP EP93119438A patent/EP0601483B1/de not_active Revoked
- 1993-12-02 DE DE59300677T patent/DE59300677D1/de not_active Revoked
- 1993-12-02 AT AT93119438T patent/ATE128481T1/de not_active IP Right Cessation
Also Published As
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---|---|
CA2110099C (en) | 1997-02-04 |
ATE128481T1 (de) | 1995-10-15 |
US5362315A (en) | 1994-11-08 |
EP0601483B1 (de) | 1995-09-27 |
CA2110099A1 (en) | 1994-06-04 |
DE59300677D1 (de) | 1995-11-02 |
JP2519018B2 (ja) | 1996-07-31 |
EP0601483A1 (de) | 1994-06-15 |
KR0134948B1 (ko) | 1998-04-18 |
JPH06220350A (ja) | 1994-08-09 |
DE4240743A1 (de) | 1994-06-09 |
ES2077462T3 (es) | 1995-11-16 |
DK0601483T3 (da) | 1995-12-04 |
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