KR910015602A - 수용성 저분자량 공중합체 및 그 제조방법 - Google Patents
수용성 저분자량 공중합체 및 그 제조방법 Download PDFInfo
- Publication number
- KR910015602A KR910015602A KR1019900016576A KR900016576A KR910015602A KR 910015602 A KR910015602 A KR 910015602A KR 1019900016576 A KR1019900016576 A KR 1019900016576A KR 900016576 A KR900016576 A KR 900016576A KR 910015602 A KR910015602 A KR 910015602A
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- KR
- South Korea
- Prior art keywords
- acid
- monoethylenically unsaturated
- monomers
- copolymer
- polymerization
- Prior art date
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- 229920001577 copolymer Polymers 0.000 title claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title 1
- 239000000178 monomer Substances 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims 14
- 239000003599 detergent Substances 0.000 claims 7
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 5
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 4
- 150000001879 copper Chemical class 0.000 claims 4
- 150000003839 salts Chemical class 0.000 claims 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 239000003999 initiator Substances 0.000 claims 3
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- -1 alkali metal salts Chemical class 0.000 claims 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims 2
- 150000008064 anhydrides Chemical class 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 230000003472 neutralizing effect Effects 0.000 claims 2
- 229920005646 polycarboxylate Polymers 0.000 claims 2
- 239000003505 polymerization initiator Substances 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 239000011591 potassium Substances 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims 1
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 claims 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 claims 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- WIVTXBIFTLNVCZ-UHFFFAOYSA-N CC(=C)C(=O)OCCP(=O)=O Chemical compound CC(=C)C(=O)OCCP(=O)=O WIVTXBIFTLNVCZ-UHFFFAOYSA-N 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- 239000004641 Diallyl-phthalate Substances 0.000 claims 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical class OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 claims 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- 239000002671 adjuvant Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 125000005907 alkyl ester group Chemical group 0.000 claims 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims 1
- 229940018557 citraconic acid Drugs 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims 1
- 239000003623 enhancer Substances 0.000 claims 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 claims 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 claims 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 claims 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 claims 1
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- 235000007686 potassium Nutrition 0.000 claims 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical class [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims 1
- 229940048086 sodium pyrophosphate Drugs 0.000 claims 1
- 235000019832 sodium triphosphate Nutrition 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical class [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims 1
- 239000001577 tetrasodium phosphonato phosphate Chemical class 0.000 claims 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 claims 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Detergent Compositions (AREA)
- Polymerisation Methods In General (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Graft Or Block Polymers (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 말레산 및 아크릴산의 단량체 유니트로부터 합성된 공중합체의 분자량 vs. 단량체 총중량을 기준으로 한 말레산 wt%의 그래프이다. 본 그래프는 두가지의 플롯을 포함하는데, 하나는 구리없이 행한 공중합체 합성의 결과이고, 다른 하나는 중합조절제로서 구리를 사용한 공중합체 합성의 결과이다.
Claims (19)
- 모노에틸렌계 불포화 디카르복시산, 모노에틸렌계 불포화 모노카르복시산, 및 카르복시기가 없는 모노에틸렌계 불포화 단량체들로 된 단량체 유니트로부터 유도되며, 중량 평균 분자량이 25,000이하이고, 공중합체의 모노에틸렌계 불포화 티카르복시산 함량이 단량체 유니트 총량을 기준으로 25wt%인 수용성 저분자량 공중합체.
- 제1항에 있어서, 상기 모노에틸렌계 불포화 디카르복시산이 말레산이고 상기 모노에틸렌계 불포화 모노카르복시산이 아크릴산인 것을 특징으로 하는 공중합체.
- 음이온성세제, 비이온성 세제, 즈비터이온성 세제, 양쪽성세제 및 그 혼합물로 구성된 군으로부터 선택된 세제 화합물; 카르복시메틸옥시숙신산과 옥시디아세트산의 알칼리금속염류, 피로인산사나트륨, 피로인산사칼륨, 트리폴리인산오나트륨, 트리폴리인산오칼륨, 에테르 폴리카르복실레이트, 시트레이트, 폴리카르복실레이트로부터 유도된 전분 또는 셀룰로우즈, 및 폴리아크릴산으로 구성된 군으로부터 선택된 증진제; 보조제; 및 35wt%이하의 청구범위 1항의 공중합체 구성되는 세제 조성물.
- 제3항에 있어서, 상기 제1항의 공중합체의 수준이 0.1-20wt%인 것을 특징으로 하는 세제 조성물.
- 제3항에 있어서, 상기 제1항의 공중합체의 수준이 0.5-5.0wt%인 것을 특징으로 하는 세제 조성물.
- 수용성 중합 개시제, 구리염 중합조절제 및 중화제 존재하고 온에서, 단량체 총량을 기준으로 3-25wt%의 단량체 분자당 4-6개의 탄소 원자를 함유하는 하나 이상의 모노에틸렌계 불포화 디카르복시산 및, 단량체 총량을 기준으로 75-97wt%의, 단량체 분자당 3-6개의 탄소원자를 함유하는 모노에틸렌계 불포화 모노카르복시산 및 카르복시기가 없는 모노에틸렌계 불포화단량체들로부터 선택된 하나 이상의 공단량체를 중합시키고, 중합완료 후 공중합체를 회수함을 특징으로 하는 수용성 공중합체의 제조방법.
- 제6항에 있어서, 상기 방법이 최초에 모노에틸렌계 불포화 디카르복시산이 반응조에 채워지고 구리염 중합조절제는 이 최초 장입물내에 함유되며, 모노에틸렌계 불포화 모노카르복시산, 카르복시기가 없는 모노에틸렌계 불포화 단량체들, 수용성 개시제 및 중화제는 각각의 용액으로 또는 혼합용액으로 1-6시간에 걸쳐 반응조에 첨가되는 배치공정; 및 최초에 물이 반응조에 채워지고 구리염 중합 조절제는 이 최초 장입물내에 포함될 수 있으며, 상기 단량체들, 중합개시제 및 중화제는 별도의 스트림들로서 또는 혼합물로서 중합 반응조에 균일한 속도로 서서히 첨가되는 공동공급 공정으로 구성된 군으로부터 선택된 공정으로 행하여짐을 특징으로 하는 방법.
- 제6항에 있어서, 상기 구리염이 중합 단량체들 총중량 기준으로 1-200ppm의 양으로 존재함을 특징으로 하는 방법.
- 제6항에 있어서, 상기 모노에틸렌계 불포화 디카르복시산의 농도가 단량체들 총량을 기준으로 5-23wt% 범위인 것을 특징으로 하는 방법.
- 제6항에 있어서, 상기 모노에틸렌계 불포화 디카르복시간이 말레산, 이타콘산, 메사콘산, 푸마르산, 시트라콘산, 그들의 염, 그들의 무수물 및 금 혼합물들로 구성된 군으로 부터 선택된 것임을 특징으로 하는 방법.
- 제6항에 있어서, 상기 모노에틸렌계 불포화 디카르복시산이 말레산, 그 염 및 그 무수물인 것을 특징으로 하는 방법.
- 제6항에 있어서, 중합이 20-80%의 고체함량 수준에서 행하여 짐을 특징으로 하는 방법.
- 제6항에 있어서, 중합이 30-65%의 고체함량 수준에서 행하여 짐을 특징으로 하는 방법.
- 제6항에 있어서, 상기 모노에틸렌계 불포화 모노카르복시산이 아크릴산, 메타크릴산, 비닐아세트산, 크로톤산 및 아크릴 옥시프로피온산으로 구성된 군으로부터 선택된 것임을 특징으로 하는 방법.
- 제6항에 있어서, 상기 모노에틸렌계 불포화 모노카르복시산이 아클릴산인 것을 특징으로 하는 방법.
- 제6항에 있어서, 상기 카르복시기가 없는 모노에틸렌계 불포화 단량체가 메틸 아크릴레이트, 에티 아크릴레이트, 부틸아크릴레이트, 메틸 메타크릴레이트, 에틸 메타크릴레이트, 부틸 메타크릴레이트 및 이소부틸 메타크릴레이트와 같은 아크릴산 또는 메타크릴산의 알킬 에스테르, 히드록시에틸 아크릴레이트, 히드록시프로필 아크릴레이트, 히드록시에틸 메타크릴레이트 및 히드록시프로필 메타크릴레이트와 같은 아크릴산 또는 메타크릴산의 히드록시알킬에스테르, 아크릴아미드, 메타크릴아미드, N-tert-부틸 아크릴아미드, N-메틸 아크릴 아미드, N, N-디메틸아크릴아미드, 아크릴로니트릴, 메타크릴로니트릴, 알릴 알코올, 알릴 술폰산, 알킬 포스폰산, 비닐포스폰산, 디메틸아미노에틸 메타크릴레이트, 포스포에틸 메타크릴레이트, N-비닐 피롤리돈, N-비닐 포름아미드, N-비닐이미다졸, 에틸렌 글리콜 디아크릴레이트, 트리메틸올프로판 트리아크릴레이트, 디알릴 프탈레이트, 비닐 아세테이트, 스티렌, 비닐 술폰산과 그 염, 및 2-아크릴아미도-2-메틸프로판 술폰산(AMPS)과 그 염으로 구성된 군으로부터 선택된 것임을 특징으로 하는 방법.
- 제6항에 있어서, 개시제가 과산화수소, t-부틸 과산화수소, 과황산나트륨, 과황산 칼륨, 과황산암모늄, 과인산나트륨, 과인산암모늄, 과인산칼륨 및 2, 2-아조비스(시아노발레르산)으로 구성된 군으로부터 선택되며, 그 농도 범위는 단량체들 총중량 기준으로 0.5-20wt%인 것을 특징으로 하는 방법.
- 제6항에 있어서, 개시제 농도 범위가 단량체들 총중량 기준으로 1-10wt%인 것을 특징으로 하는 방법.
- 제6항에 있어서, 단량체 혼합물의 산함향을 기준으로 30-80 당량퍼센트의 염기를 첨가함에 의하여 중합 pH를 4-6의 범위내에서 유지시키는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/475,580 US5055540A (en) | 1990-02-06 | 1990-02-06 | Process for efficient molecular weight control in copolymerization |
| US475,580 | 1990-02-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR910015602A true KR910015602A (ko) | 1991-09-30 |
| KR100190513B1 KR100190513B1 (ko) | 1999-06-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900016576A KR100190513B1 (ko) | 1990-02-06 | 1990-10-18 | 수용성 저분자량 공중합체 및 그 제조방법 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US5055540A (ko) |
| EP (1) | EP0441022B1 (ko) |
| JP (1) | JP3054873B2 (ko) |
| KR (1) | KR100190513B1 (ko) |
| CN (2) | CN1030322C (ko) |
| AT (1) | ATE123297T1 (ko) |
| AU (1) | AU644803B2 (ko) |
| BR (1) | BR9003959A (ko) |
| CA (1) | CA2022705C (ko) |
| DD (1) | DD296692A5 (ko) |
| DE (1) | DE69019814T2 (ko) |
| DK (1) | DK0441022T3 (ko) |
| ES (1) | ES2073532T3 (ko) |
| IE (1) | IE902758A1 (ko) |
| NZ (2) | NZ243407A (ko) |
| PH (1) | PH27560A (ko) |
| PT (1) | PT94976A (ko) |
| ZA (1) | ZA906080B (ko) |
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| KR100626552B1 (ko) * | 2005-04-06 | 2006-09-22 | 김수동 | 잔류단량제와 개시제 잔류물이 적게 함유된폴리아크릴아마이드 공중합체의 제조 |
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| US5866012A (en) * | 1993-01-26 | 1999-02-02 | National Starch And Chemical Investment Holding Corporation | Multifunctional maleate polymers |
| EP0682693B1 (de) * | 1993-02-05 | 1998-04-01 | Henkel Kommanditgesellschaft auf Aktien | Gerüststoff für wasch- oder reinigungsmittel |
| US5431846A (en) * | 1993-05-20 | 1995-07-11 | Lever Brothers Company, Division Of Conopco, Inc. | Copolymers and detergent compositions containing them |
| ES2072812B1 (es) * | 1993-05-28 | 1996-02-16 | Derypol S A | Procedimiento para la preparacion de copolimeros de acidos dicarboxilicos |
| EP0630965A1 (en) * | 1993-06-23 | 1994-12-28 | The Procter & Gamble Company | Concentrated liquid hard surface detergent compositions containing maleic acid-olefin copolymers |
| EP0874008B1 (en) * | 1993-07-20 | 2001-10-31 | Nippon Shokubai Co., Ltd. | Maleic acid copolymer, process for producing the same and uses thereof |
| DE4405621A1 (de) * | 1994-02-22 | 1995-08-24 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten aus Vinylestern und monoethylenisch ungesättigten Carbonsäuren und ihre Verwendung |
| US6335404B1 (en) * | 1994-04-05 | 2002-01-01 | Rohm And Haas Company | Aqueous process for preparing aqueous weight carboxyl containing polymers |
| CA2151112A1 (en) * | 1994-06-13 | 1995-12-14 | Michael Bennett Freeman | High temperature polymerization process and products therefrom |
| DE4420920A1 (de) * | 1994-06-16 | 1995-12-21 | Basf Ag | Vinylformiateinheiten enthaltende Copolymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung in Wasch- und Reinigungsmitteln |
| JP2001081108A (ja) * | 1999-09-16 | 2001-03-27 | Sekisui Chem Co Ltd | ビニル系低分子量重合体の製造方法及びビニル系低分子量重合体、並びに、トナー用バインダー樹脂組成物及びトナー |
| TWI236483B (en) | 2000-07-07 | 2005-07-21 | Nippon Catalytic Chem Ind | Low molecular weight (methyl) acrylic acid (acrylate) polymer and preparation process and use thereof |
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| MXPA05008644A (es) * | 2003-02-24 | 2005-10-18 | Basf Ag | Polimeros que contienen carboxilato para el tratamiento de superficies metalicas. |
| CN100389137C (zh) * | 2004-12-30 | 2008-05-21 | 中国石油化工股份有限公司 | 一种丁烯二酸聚合物的制备方法 |
| CN100509683C (zh) * | 2006-09-30 | 2009-07-08 | 江苏博特新材料有限公司 | 一种低分子量共聚物分散剂及其制备方法 |
| CA2704568C (en) * | 2007-11-09 | 2016-01-26 | The Procter & Gamble Company | Cleaning compositions with monocarboxylic acid monomers, dicarboxylic monomers, and monomers comprising sulfonic acid groups |
| US8389458B2 (en) | 2008-03-31 | 2013-03-05 | The Procter & Gamble Company | Automatic dishwashing composition containing a sulfonated copolymer |
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| DE3426368A1 (de) * | 1984-07-18 | 1986-01-23 | Basf Ag, 6700 Ludwigshafen | Copolymerisate fuer wasch- und reinigungsmittel |
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| DE3716544A1 (de) * | 1987-05-16 | 1988-11-24 | Basf Ag | Verwendung von wasserloeslichen copolymerisaten, die monomere mit mindestens zwei ethylenisch ungesaettigten doppelbindungen einpolymerisiert enthalten, in wasch- und reinigungsmitteln |
| DE3716543A1 (de) * | 1987-05-16 | 1988-11-24 | Basf Ag | Verwendung von wasserloeslichen copolymerisaten, die monomere mit mindestens zwei ethylenisch ungesaettigten doppelbindungen einpolymerisiert enthalten, in wasch- und reinigungsmitteln |
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| US5244988A (en) * | 1989-05-17 | 1993-09-14 | Rohm And Haas Company | Maleate polymerization process |
-
1990
- 1990-02-06 US US07/475,580 patent/US5055540A/en not_active Expired - Lifetime
- 1990-07-30 IE IE275890A patent/IE902758A1/en unknown
- 1990-07-31 ES ES90308429T patent/ES2073532T3/es not_active Expired - Lifetime
- 1990-07-31 AT AT90308429T patent/ATE123297T1/de active
- 1990-07-31 DD DD90343179A patent/DD296692A5/de not_active IP Right Cessation
- 1990-07-31 NZ NZ243407A patent/NZ243407A/en unknown
- 1990-07-31 EP EP90308429A patent/EP0441022B1/en not_active Expired - Lifetime
- 1990-07-31 NZ NZ234722A patent/NZ234722A/xx unknown
- 1990-07-31 DK DK90308429.1T patent/DK0441022T3/da active
- 1990-07-31 AU AU60044/90A patent/AU644803B2/en not_active Ceased
- 1990-07-31 PH PH40932A patent/PH27560A/en unknown
- 1990-07-31 DE DE69019814T patent/DE69019814T2/de not_active Expired - Fee Related
- 1990-08-02 ZA ZA906080A patent/ZA906080B/xx unknown
- 1990-08-03 CA CA002022705A patent/CA2022705C/en not_active Expired - Fee Related
- 1990-08-10 BR BR909003959A patent/BR9003959A/pt not_active IP Right Cessation
- 1990-08-13 PT PT94976A patent/PT94976A/pt not_active Application Discontinuation
- 1990-10-03 JP JP2266140A patent/JP3054873B2/ja not_active Expired - Fee Related
- 1990-10-18 KR KR1019900016576A patent/KR100190513B1/ko not_active IP Right Cessation
-
1991
- 1991-02-06 CN CN91100772A patent/CN1030322C/zh not_active Expired - Fee Related
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1994
- 1994-08-01 CN CN94114814A patent/CN1100134A/zh active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100626552B1 (ko) * | 2005-04-06 | 2006-09-22 | 김수동 | 잔류단량제와 개시제 잔류물이 적게 함유된폴리아크릴아마이드 공중합체의 제조 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2022705C (en) | 2001-05-29 |
| EP0441022A2 (en) | 1991-08-14 |
| BR9003959A (pt) | 1991-11-12 |
| CN1100134A (zh) | 1995-03-15 |
| EP0441022B1 (en) | 1995-05-31 |
| ZA906080B (en) | 1991-10-30 |
| JPH03234713A (ja) | 1991-10-18 |
| IE902758A1 (en) | 1991-08-14 |
| DE69019814T2 (de) | 1995-12-07 |
| AU644803B2 (en) | 1993-12-23 |
| PT94976A (pt) | 1991-09-30 |
| JP3054873B2 (ja) | 2000-06-19 |
| ES2073532T3 (es) | 1995-08-16 |
| CA2022705A1 (en) | 1991-08-07 |
| NZ243407A (en) | 1994-01-26 |
| DE69019814D1 (de) | 1995-07-06 |
| DK0441022T3 (da) | 1995-07-24 |
| AU6004490A (en) | 1991-08-08 |
| DD296692A5 (de) | 1991-12-12 |
| CN1030322C (zh) | 1995-11-22 |
| KR100190513B1 (ko) | 1999-06-01 |
| PH27560A (en) | 1993-08-18 |
| CN1053925A (zh) | 1991-08-21 |
| EP0441022A3 (en) | 1991-10-16 |
| NZ234722A (en) | 1994-01-26 |
| ATE123297T1 (de) | 1995-06-15 |
| US5055540A (en) | 1991-10-08 |
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