KR910012128A - 정전기 방지성 용이 접착성 필름, 그의 제조방법 및 그를 사용하는 자기 카드 - Google Patents

정전기 방지성 용이 접착성 필름, 그의 제조방법 및 그를 사용하는 자기 카드 Download PDF

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KR910012128A
KR910012128A KR1019900020628A KR900020628A KR910012128A KR 910012128 A KR910012128 A KR 910012128A KR 1019900020628 A KR1019900020628 A KR 1019900020628A KR 900020628 A KR900020628 A KR 900020628A KR 910012128 A KR910012128 A KR 910012128A
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weight
compound
easily adhesive
copolymerizing
hydrogen atom
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마사유끼 후꾸다
사다요시 미우라
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이따가끼 히로시
데이진 가부시끼가이샤
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Abstract

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Description

정전기 방지성 용이 접착성 필름, 그의 제조방법 및 그를 사용하는 자기 카드
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 이차 전이온도(Tg) 10∼80℃를 가지며, (a) 하기식 (Ⅰ)의 화합물 70∼99중량%, (b) N-메틸올(메트)아크릴아미드 1∼10중량%, (c) 분자중에 카르복시기를 갖는 에틸렌성 화합물 (화합(a) 제외) 0∼5중량%, 및 (d)화합물 (a)∼(c)와 공중합가능한 기타 화합물 0∼29중량% ((a)∼(d)의 총량은 100중량%임)을 공중합함으써 수득되는 공중합체 (A); 및 분자량 5,000이상을 가지며, (e) 하기식 (Ⅱ)의 화합물 30∼100중량%, (f)화합물 (e)와 공중합가능한 기타 화합물 0∼70중량% ((e) 및 (f)의 총량은 100중량%임)을 중합하거나 공중합함으로서 수득되는 중합체(B)를 95:5∼50:50중량비로 함유하는, 폴리에스테르 필름의 적어도 1면에 제공되는 정전기 방지성 용이 접착성층 및 폴리에스테르 필름을 함유함을 특징으로 하는 정전기 방지성 용이 접착성 필름.
    [상기식중, R1은 수소원자 또는 메틸기이고; R2은 -COOR3(식중, R3은 탄소수 1∼20의 직쇄 또는 측쇄알킬기이다).또는 -C≡N 이며 ; R4, R5및 R6은 각각 수소원자 또는 저급 알킬기이고; R7은 2가 유기기이며; X은 알칼리 금속 또는 -NH(R8)3(식중, R8은 수소원자 또는 저급 알킬기이다)이고; n은 0또는 1이다]
  2. 제1항에 있어서, 정전기 방지성 용이 접착성 층이 화합물 (a)75∼95중량%, N-메틸올(메트)아크릴아미드 (b)3∼6중량%, 에틸렌성 화합물 (c)0.5∼3중량% 및 화합물 (d)0∼29중량%을 공중합함으로써 수득되는 공중합체 (A), 및 화합물 (e)30∼80중량% 및 화합물 (f) 20∼70중량%을 공중합함으로서 수득되는 중합체 (B)를 90:10∼70:30 중량비로 함유하는 정전기 방지성 용이 접착성 필름.
  3. 제2항에 있어서, 중합체 (B)가 화합물 (e)50∼80중량% 및 화합물(f) 20∼50중량%을 공중합함으로써 수득되는 정전지방지성 용이 접착성 필름.
  4. 제2항에 있어서, 화합물(e)가 메탈릴술폰산 나트륨 또는 비닐술폰산 나트륨인 정전기 방지성 용이 접착성 필름.
  5. 제3항에 있어서, 화합물(e)가 메탈릴술폰산나트륨인 정전기 방지성 용이 접착성 필름.
  6. 이차 전이온도(Tg)10∼80℃를 가지며, (a) 하기식(Ⅰ)의 화합물 70∼99중량%, (b)N-메틸올(메트)아크릴아미드 1∼10중량5, (c)분자중에 카르복시기를 갖는 에틸렌성 화합물(화합물 (a)제외) 0∼5중량%, 및 (d)화합물 (a)∼(c)와 공중합 가능한 기타 화합물 0∼29중량% ((a)∼(d)의 총량은 100중량%임)을 공중합함으로써 수득되는 공중합체 (A); 및 분자량 5,000이상을 가지며, (e) 하기식 (Ⅱ)의 화합물 30∼100중량%, 및 (f)화합물 (e)와 공중합 가능한 기타 화합물 0∼70중량% ((e)및 (f)의 총량은 100중량%임)을 중합하거나 공중합함으로써 수득되는 중합체 (B)를 95:5∼50:50 중량비로 함유하는 수성 분산액을 배열화 및 결정화가 완결되지 않은 폴리에스테르 필름의 적어도 1면에 피복시킨후, 피복된 폴리에스테르 필름을 건조, 신장 및 열고정시켜서 결정화및 배열화를 완결시킴을 특징으로 하는 정전기 방지성 용이 접착성 필름의 제조방법.
    [상기식중, R1은 수소원자 또는 메틸기이고; R2은 -COOR3(식중, R3은 탄소수 1∼20의 직쇄 또는 측쇄 알킬기이다).또는 -C≡N 이며 ; R4, R5및 R6은 각각 수소원자 또는 저급 알킬기이고; R7은 2가 유기기이며; X은 알칼리 금속 또는 -NH(R2)3(식중, R6은 수소원자 또는 저급 알킬기이다)이고; n은 0 또는 1이다]
  7. 제6항에 있어서, 폴리에스테르 필름을 세로방향 신장시키고, 생성 폴리에스테르 필름을 공중합체 (A) 및 중합체 (B)를 함유하는 수성 분산액으로 피복시킨후, 피복된 폴리에스테르 필름을 건조, 가로방향 신장 및 열고정 시키는 방법.
  8. 제1항의 정전기 방지성 용이 접착성 필름, 자외선 경화 잉크로 이루어진 잉크충, 및 자기층(두층은 모두 필름상에 제공됨)을 함유함을 특징으로 하는 자기 카트.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR90020628A 1989-12-14 1990-12-14 Antistatic highly adhesive film, process for producing the said film and magnetic card using the said film KR960008483B1 (en)

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JP1324262A JPH03183545A (ja) 1989-12-14 1989-12-14 制電易接着性フイルム、その製造方法及びそれを用いた磁気カード
JP324262/1989 1989-12-14

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