KR880011057A - 촉매의 존재하에 히드로플루오르화에 의한1,1.1-트리플루오로-2,2-디클로로에탄의 제조방법 - Google Patents

촉매의 존재하에 히드로플루오르화에 의한1,1.1-트리플루오로-2,2-디클로로에탄의 제조방법 Download PDF

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Publication number
KR880011057A
KR880011057A KR1019880002430A KR880002430A KR880011057A KR 880011057 A KR880011057 A KR 880011057A KR 1019880002430 A KR1019880002430 A KR 1019880002430A KR 880002430 A KR880002430 A KR 880002430A KR 880011057 A KR880011057 A KR 880011057A
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South Korea
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catalyst
range
alf
trifluoro
dichloroethane
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KR1019880002430A
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KR960001696B1 (ko
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카르 멜로 디에그
구글리엘모 기오르기오
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원본미기재
오시몬트 에이.페.아.
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00—Acyclic saturated compounds containing halogen atoms
    • C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

촉매의 존재하에 히드로플루오르화에 의한 1,1,1-트리플루오로-2,2-디클로로에탄의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 감마 및/또는 베타 형태의 AlF3에 지지된 Cr2O3로 구성되는 촉매의 존재하에 기체상태에서 퍼클로로에틸렌과 HF를 반응시킴을 특징으로 하는 1,1,1-트리플루오로-2,2-디클로로에탄의 연속적인 제조방법.
  2. 제1항에 있어서, Cr2O3의 양이 촉매위에 크롬으로서 계산된 1 내지 15중량 %의 범위인 방법.
  3. 제1항에 있어서, AlF3의 표면적이 15 내지 30m2/g의 범위인 방법.
  4. 제1항에 있어서, AlF3가 20 내지 200?? 범위의 입자크기를 갖는 분말의 형태인 방법.
  5. 제1항에 있어서, 지지된 AlF3는 30중량%이하의 델타상을 더욱 함유할 수 있는 방법.
  6. 제1항에 있어서, 상기 촉매는 : a) 용해되는 크롬염의 용액에 AlF3을 함침시키고 : b) 촉매를 건조시키고 : c) 200℃ 내지 600℃의 온도범위에서 공기 및 질소와 더불어 촉매를 활성화시키는 단계에 의해 제조된 방법.
  7. 제6항에 있어서, 활성화 단계가 스팀의 존재하에 수행되는 방법.
  8. 제6항에 있어서, 활성화 온도가 330℃ 내지 500℃ 범위인 방법.
  9. 제1항에 있어서, 더욱더 반응온도가 300℃ 내지 400℃의 범위인 방법.
  10. 제1항에 있어서, 더욱더 시약과 촉매 덩어리 사이의 접촉시간이 1초 내지 30초의 범위인 방법.
  11. 제1항에 있어서, 더욱더 시약 HF와 C2Cl4사이의 몰비가 적어도 3 : 1인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880002430A 1987-03-09 1988-03-09 촉매의 존재하에 히드로플루오르화에 의한 1,1,1-트리플루오로-2,2-디클로로에탄의 제조방법 KR960001696B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT19622A/87 1987-03-09
IT19622/87A IT1202652B (it) 1987-03-09 1987-03-09 Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori

Publications (2)

Publication Number Publication Date
KR880011057A true KR880011057A (ko) 1988-10-26
KR960001696B1 KR960001696B1 (ko) 1996-02-03

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KR1019880002430A KR960001696B1 (ko) 1987-03-09 1988-03-09 촉매의 존재하에 히드로플루오르화에 의한 1,1,1-트리플루오로-2,2-디클로로에탄의 제조방법

Country Status (16)

Country Link
US (2) US4967023A (ko)
EP (1) EP0282005B1 (ko)
JP (1) JP2557936B2 (ko)
KR (1) KR960001696B1 (ko)
AR (1) AR244193A1 (ko)
AU (1) AU603188B2 (ko)
BR (1) BR8800992A (ko)
CA (1) CA1290351C (ko)
DE (1) DE3866558D1 (ko)
ES (1) ES2039488T3 (ko)
HU (1) HU200151B (ko)
IT (1) IT1202652B (ko)
PL (1) PL162267B1 (ko)
SU (1) SU1706385A3 (ko)
UA (1) UA7138A1 (ko)
ZA (1) ZA881535B (ko)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5262574A (en) * 1987-03-09 1993-11-16 Ausimont S.P.A. Process for preparing 1,1,1-trifluoro-2,2-dichloroethane by hydrofluorination in the presence of catalysts
US5276224A (en) * 1987-03-09 1994-01-04 Ausimont S.P.A. Process for preparing 1,1,1-trifluoro-2,2-dichloroethane by hydrofluorination in the presence of catalysts
US4766260A (en) * 1987-07-07 1988-08-23 E. I. Du Pont De Nemours And Company Gas-phase fluorination process
US4843181A (en) * 1987-10-22 1989-06-27 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1-trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane
IN170774B (ko) * 1988-05-23 1992-05-16 Du Pont
IT1230780B (it) * 1989-07-12 1991-10-29 Ausimont Srl Procedimento per la preparazione di 1,2 dicloro 1,1,2 trifluoroetano.
FR2652573B1 (fr) * 1989-10-03 1991-12-13 Atochem Procede de fabrication du 1,1,1-chlorodifluoroethane.
DE4005945A1 (de) * 1990-02-26 1991-08-29 Kali Chemie Ag Verfahren zur herstellung von aethanderivaten
JP2797652B2 (ja) * 1990-05-25 1998-09-17 旭硝子株式会社 トリクロロジフルオロエタンのフッ素化法
US5300711A (en) * 1991-03-20 1994-04-05 E. I. Du Pont De Nemours And Company Process for the manufacture of 2,2-dichloro-1,1,1-trifluoroethane, 2-chloro-1,1,1,2-tetrafluoroethane and pentafluoroethane
US5321170A (en) * 1991-03-20 1994-06-14 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2-tetrafluoroethane
DE69212821T2 (de) * 1991-03-20 1996-12-19 Du Pont Verfahren zur herstellung von 2-chlor-1,1,1-trifluorethan
US5300710A (en) * 1991-03-20 1994-04-05 E. I. Du Pont De Nemours And Company Process for the manufacture of 2-chloro-1,1,1,2-tetrafluoroethane and pentafluoroethane
US5155082A (en) * 1991-04-12 1992-10-13 Allied-Signal Inc. Catalyst for the manufacture of chlorofluorocarbons, hydrochlorofluorocarbons and hydrofluorocarbons
IT1251957B (it) * 1991-10-18 1995-05-27 Ausimont Spa Procedimento per isomerizzare 1,1,2-trifluoro-1,2-dicloroetano a 1,1,1- trifluoro-2,2,-dicloroetano
IT1251951B (it) * 1991-10-18 1995-05-27 Ausimont Spa Procedimento per purificare 1,1,1-trifluoro-,2,2 dicloroetano dall`isomero 1,1,2-trifluoro-1,2-dicloroetano.
IT1255781B (it) * 1992-08-14 1995-11-15 Ausimont Spa Procedimento per preparare 1,1,1-trifluoro-2-cloroetano
IT1256631B (it) * 1992-12-10 1995-12-12 Ausimont Spa Procedimento per la separazione di hf da sue miscele con gli idroclorofluorcarburi 123 e/o 124
US6180840B1 (en) 1993-03-05 2001-01-30 Daiken Industries Ltd. Method of producing 1,1,1,2,2-pentafluoroethane a method of producing 2,-2,-diohloro-1,1,1-trifluorethane and a method of purifying 1,1,1,2 pentafluoroethane
EP0687660B2 (en) * 1993-03-05 2006-05-17 Daikin Industries, Limited Process for producing 1,1,1,2,2-pentafluoroethane, process for producing 2,2-dichloro-1,1,1-trifluoroethane, and method of purifying 1,1,1,2,2-pentafluoroethane
IT1270959B (it) * 1993-08-13 1997-05-26 Ausimont Spa Processo per la preparazione di pentafluoroetano
WO1995011875A1 (en) * 1993-10-28 1995-05-04 Alliedsignal Inc. Process for purifying 1,1-dichloro-2,2,2-trifluoroethane and 1-chloro-1,2,2,2-tetrafluoroethane
IT1265223B1 (it) * 1993-11-25 1996-10-31 Ausimont Spa Processo per la preparazione di polimeri del vinilidenfluoruro
US5417954A (en) * 1994-03-02 1995-05-23 E. I. Du Pont De Nemours And Company Phases of NH4 AlF4 and AlF3
US5545778A (en) * 1994-05-25 1996-08-13 Alliedsignal Inc. Single stage process for producing hydrofluorocarbons from perchloroethylene
US5569794A (en) * 1994-05-24 1996-10-29 Alliedsignal Inc. Vapor phase process for producing hydroflourocarbons from perchloroethylene having a phenolic inhibitor
US5981813A (en) * 1996-05-22 1999-11-09 Ausimont S.P.A. Fluorination process of halogenated organic compounds
IT1291758B1 (it) 1997-05-22 1999-01-21 Ausimont Spa Processo per la preparazione di fluoruro di alluminio
IT1292007B1 (it) 1997-05-27 1999-01-25 Ausimont Spa Processo per la preparazione di hcfc-123
IT1303074B1 (it) 1998-05-07 2000-10-23 Ausimont Spa Catalizzatore per la fluorurazione di composti organici alogenati
IT1303073B1 (it) 1998-05-07 2000-10-23 Ausimont Spa Processo per la preparazione di fluoruro di alluminio
US6417413B1 (en) 1999-11-03 2002-07-09 Alliedsignal Inc. Process for the preparation of halogenated ethanes
FR2828193B1 (fr) * 2001-08-03 2004-04-02 Atofina Nouveau procede de preparation du 1,1,1,-trifluoro-2,2-dichloroethane
US20070032688A1 (en) * 2002-08-02 2007-02-08 Beatrice Boussand Process for preparing 1,1,1-trifluoro-2, 2-dichloroethane
WO2004060805A1 (en) * 2003-01-03 2004-07-22 Solvay Solexis S.P.A. Aluminium fluoride
GB0525700D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525701D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525699D0 (en) 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525702D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
US8931682B2 (en) 2007-06-04 2015-01-13 Ethicon Endo-Surgery, Inc. Robotically-controlled shaft based rotary drive systems for surgical instruments
CN101402546B (zh) * 2008-11-13 2012-02-29 山东华安新材料有限公司 一种二氯三氟乙烷的制法
WO2016104085A1 (ja) * 2014-12-24 2016-06-30 ダイキン工業株式会社 反応に用いた触媒の取り出し方法
CN108299148B (zh) * 2016-10-18 2020-09-29 福州绿航环保技术服务有限公司 一种联产制备五氟乙烷和1,2‐二氯‐1,1,2‐三氟乙烷的方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3258500A (en) * 1959-08-17 1966-06-28 Du Pont Process for fluorinating halohydro-carbons
NL274475A (ko) * 1962-02-07
GB1000485A (en) * 1962-02-07 1965-08-04 Sicedison Spa Improvements in or relating to the fluorination of halo-olefines
US3178484A (en) * 1962-11-08 1965-04-13 Du Pont Process for preparing vinyl fluoride and 1, 1-difluoroethane
DE1224732B (de) * 1962-11-08 1966-09-15 Du Pont Verfahren zur Herstellung von Vinylfluorid und 1, 1-Difluoraethan
GB1048899A (en) * 1963-12-30 1966-11-23 Dow Chemical Co Method of preparing halogenated hydrocarbons
SE361134B (ko) * 1968-07-25 1973-10-22 Montedison Spa
NL173393C (nl) * 1968-10-10 1984-01-16 Montedison Spa Werkwijze voor het bereiden van volledig ge(chloor)fluoreerd ethaan met symmetrische verdeling van de fluoratomen over de koolstofatomen.
GB1307224A (en) * 1969-06-27 1973-02-14 Ici Ltd Chromium oxide catalyst
NL171235C (nl) * 1970-06-10 1983-03-01 Montedison Spa Werkwijze voor het bereiden van katalysatoren die in hoofdzaak uit aluminiumfluoride bestaan en werkwijze voor het bereiden van gefluoreerde of gechloorfluoreerde koolwaterstoffen met behulp van een dergelijke katalysator.
US4088704A (en) * 1977-01-21 1978-05-09 Allied Chemical Corporation Production of fluorocarbons employing two catalyst zones
US4147733A (en) * 1978-05-22 1979-04-03 The Dow Chemical Company Fluorination of chlorinated hydrocarbons
US4843181A (en) * 1987-10-22 1989-06-27 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1-trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane

Also Published As

Publication number Publication date
ZA881535B (en) 1988-08-24
UA7138A1 (uk) 1995-06-30
PL162267B1 (pl) 1993-09-30
AU603188B2 (en) 1990-11-08
US5091601A (en) 1992-02-25
HU200151B (en) 1990-04-28
JPS63295521A (ja) 1988-12-01
EP0282005A1 (en) 1988-09-14
IT8719622A0 (it) 1987-03-09
BR8800992A (pt) 1988-10-11
SU1706385A3 (ru) 1992-01-15
ES2039488T3 (es) 1993-10-01
EP0282005B1 (en) 1991-12-04
KR960001696B1 (ko) 1996-02-03
AR244193A1 (es) 1993-10-29
AU1274888A (en) 1988-09-08
US4967023A (en) 1990-10-30
HUT46638A (en) 1988-11-28
JP2557936B2 (ja) 1996-11-27
CA1290351C (en) 1991-10-08
DE3866558D1 (de) 1992-01-16
IT1202652B (it) 1989-02-09
PL271065A1 (en) 1988-12-08

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