KR920009747A - 1, 1, 1, 2-테트라플루오로에탄의 제조방법 - Google Patents
1, 1, 1, 2-테트라플루오로에탄의 제조방법 Download PDFInfo
- Publication number
- KR920009747A KR920009747A KR1019910020158A KR910020158A KR920009747A KR 920009747 A KR920009747 A KR 920009747A KR 1019910020158 A KR1019910020158 A KR 1019910020158A KR 910020158 A KR910020158 A KR 910020158A KR 920009747 A KR920009747 A KR 920009747A
- Authority
- KR
- South Korea
- Prior art keywords
- nickel
- chromium
- tetrafluoroethane
- seconds
- metal
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pyrrole Compounds (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 알루미늄 플루오라이드 또는 알루미늄 플루오라이드 및 알루미나의 혼합물로 이루어진 지지체상에 침착시킨 니첼 및 크롬 옥사이드, 할라이드 및/또는 옥시할라이드로 구성된 혼합 촉매를 사용함을 특징으로 하는, 가스상 플루오르화수소산을 첨가하여 1-클로로-2,2,2-트리플루오로에탄(F133a)의 촉매적 플루오르화 반응에 의한 1,1,2,2-테트라플루오로에탄(F134a)의 제조방법.
- 제1항에 있어서, 촉매속의 니켈 및 크롬의 중량 함량이 각각의 금속에 대해 0.5내지 20%이고, 니켈/크롬 원자비가 0.5내지 5, 바람직하게는 1에 가까움을 특징으로 하는 방법.
- 제2항에 있어서, 함량이 각각의 금속에 대해 2내지 10%임을 특징으로 하는 방법.
- 제1내지 3항중 어느 한 항에 있어서, 지지체가 나트륨을 1000ppm까지 함유할 수 있음을 특징으로 하는 방법.
- 제1내지 4항중 어느 한 항에 있어서, 반응온도가 300내지 420℃, 바람직하게는 330내지 410℃임을 특징으로 하는 방법.
- 제1내지 5항중 어느 한 항에 있어서, 작업 압력이 절대 압력 1내지 20bar, 바람직하게는 12내지 16bar임을 특징으로 하는 방법.
- 제1내지 6항중 어느 한 항에 있어서, HF/F133a 몰비가 1내지 20, 바람직하게는 2내지 5임을 특징으로 하는 방법.
- 제1내지 7항중 어느 한 항에 있어서, 접촉시간이 반응 조건하에서 계산하여 2내지 32초, 바람직하게는 5내지 25초임을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9014043A FR2669022B1 (fr) | 1990-11-13 | 1990-11-13 | Procede de fabrication du tetrafluoro-1,1,1,2-ethane. |
FR90-14043 | 1990-11-13 | ||
FR9014043 | 1990-11-13 | ||
US08/772,521 US5731481A (en) | 1990-11-13 | 1996-12-24 | Process for the manufacture of 1,1,1,2-Tetrafluoroethane |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920009747A true KR920009747A (ko) | 1992-06-25 |
KR950006521B1 KR950006521B1 (ko) | 1995-06-16 |
Family
ID=26228326
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910020158A KR950006521B1 (ko) | 1990-11-13 | 1991-11-13 | 1,1,1,2-테트라플루오로에탄의 제조방법 |
Country Status (17)
Country | Link |
---|---|
US (1) | US5731481A (ko) |
EP (1) | EP0486333B1 (ko) |
JP (1) | JPH0780796B2 (ko) |
KR (1) | KR950006521B1 (ko) |
AT (1) | ATE115532T1 (ko) |
AU (1) | AU641292B2 (ko) |
CA (1) | CA2055281C (ko) |
DE (1) | DE69105924T2 (ko) |
DK (1) | DK0486333T3 (ko) |
ES (1) | ES2066394T3 (ko) |
FI (1) | FI915341A (ko) |
FR (1) | FR2669022B1 (ko) |
GR (1) | GR3015222T3 (ko) |
IE (1) | IE913932A1 (ko) |
MX (1) | MX9102049A (ko) |
NO (1) | NO174096C (ko) |
PT (1) | PT99489A (ko) |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2661906B1 (fr) * | 1990-05-11 | 1993-10-01 | Atochem | Procede de fabrication du 1,1,1,2-tetrafluoro-chloroethane et du pentafluoroethane. |
FR2684567B1 (fr) * | 1991-12-09 | 1994-11-04 | Atochem | Catalyseurs massiques a base d'oxydes de chrome et de nickel, et leur application a la fluoration d'hydrocarbures halogenes. |
MX9303208A (es) * | 1992-06-17 | 1994-01-31 | Alliend Signal Inc | Mejoras en un proceso de fluorizacion en fase de vapor. |
US5629461A (en) * | 1992-12-29 | 1997-05-13 | Daikin Industries, Ltd. | Method of producing 1,1,2,2,3-pentafluoropropane |
FR2700770B1 (fr) * | 1993-01-27 | 1995-03-24 | Atochem Elf Sa | Procédé de fabrication du 1,1,1,2-tétrafluoro-2-chloroéthane et du pentafluoroéthane. |
FR2700766B1 (fr) * | 1993-01-27 | 1995-03-24 | Atochem Elf Sa | Procédé de fluoration de perchloréthylène ou du pentachloréthane. |
US5639924A (en) | 1994-11-29 | 1997-06-17 | Elf Atochem North America, Inc. | Process for the production of 1,1,1-trifluoroethane |
FR2736050B1 (fr) | 1995-06-29 | 1997-08-01 | Atochem Elf Sa | Procede de fabrication du difluoromethane |
FR2748022B1 (fr) | 1996-04-29 | 1998-07-24 | Atochem Elf Sa | Procede de fabrication du difluoromethane |
FR2757085B1 (fr) | 1996-12-13 | 1999-01-22 | Atochem Elf Sa | Catalyseurs massiques a base de chrome et de nickel pour la fluoration en phase gazeuse d'hydrocarbures halogenes |
FR2771027B1 (fr) * | 1997-11-20 | 2000-01-14 | Atochem Elf Sa | Catalyseur mixte de fluoration |
US6124510A (en) * | 1998-07-21 | 2000-09-26 | Elf Atochem North America, Inc. | 1234ze preparation |
US6386468B1 (en) * | 1999-11-29 | 2002-05-14 | Ceramoptec Industries, Inc. | Mechano-chemical flourination: improved method of fullerene fluorination |
FR2828193B1 (fr) | 2001-08-03 | 2004-04-02 | Atofina | Nouveau procede de preparation du 1,1,1,-trifluoro-2,2-dichloroethane |
ATE395025T1 (de) * | 2002-03-05 | 2008-05-15 | Hill Rom Services Inc | Griff für ein krankenhausbett |
EP1539347B1 (en) | 2002-08-22 | 2012-06-27 | E.I. Du Pont De Nemours And Company | Cobalt substituted chromium oxide compositions, their preparation and their use as catalysts and catalyst precursors |
WO2004060805A1 (en) * | 2003-01-03 | 2004-07-22 | Solvay Solexis S.P.A. | Aluminium fluoride |
EP1502906A1 (en) * | 2003-07-31 | 2005-02-02 | Solvay Solexis S.p.A. | Process for activation of AIF3 based catalysts and process for isomerising hydrochlorofluorocarbons |
US7608574B2 (en) * | 2006-08-17 | 2009-10-27 | Honeywell International Inc. | Azeotropic or azeotropic-like compositions of 1,1,1-trifuoroethane and 1-chloro-2,2,2-trifluoroethane |
KR101394583B1 (ko) | 2006-10-03 | 2014-05-12 | 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. | 탄소수 3-6의 (하이드로)플루오로알켄의 생성을 위한 탈수소할로겐화 방법 |
FR2911870B1 (fr) * | 2007-01-29 | 2009-03-20 | Arkema France | Procede de fabrication du 1,1-difluoroethane |
GB0706978D0 (en) * | 2007-04-11 | 2007-05-16 | Ineos Fluor Holdings Ltd | Process |
US8563789B2 (en) | 2007-06-27 | 2013-10-22 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
US8076521B2 (en) | 2007-06-27 | 2011-12-13 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
FR2929272B1 (fr) | 2008-03-28 | 2010-04-09 | Arkema France | Procede pour la preparation du 2,3,3,3-tetrafluoro-1-propene |
FR2929273B1 (fr) * | 2008-03-28 | 2017-05-26 | Arkema France | Procede de preparation de composes fluores. |
US8445736B2 (en) | 2008-06-26 | 2013-05-21 | Arkema Inc. | Catalytic gas phase fluorination of 1230xa to 1234yf |
WO2011077191A1 (en) | 2009-12-23 | 2011-06-30 | Arkema France | Catalytic gas phase fluorination of 1230xa to 1234yf |
CN102686543B (zh) | 2009-12-23 | 2015-04-15 | 阿克马法国公司 | 1230xa到1234yf的催化气相氟化 |
CN106316774A (zh) | 2009-12-23 | 2017-01-11 | 阿克马法国公司 | 1233xf到1234yf的催化气相氟化 |
EP2516367B1 (en) * | 2009-12-23 | 2015-10-07 | Arkema France | Catalytic gas phase fluorination of 243db to 1234yf |
WO2012098421A1 (en) | 2011-01-21 | 2012-07-26 | Arkema France | Catalytic gas phase fluorination |
EP2665693B1 (en) | 2011-01-21 | 2017-07-19 | Arkema France | Catalytic gas phase fluorination |
FR2975922B1 (fr) | 2011-06-06 | 2013-05-31 | Arkema France | Reacteur a plaques avec injection in situ |
GB201207666D0 (en) | 2012-05-02 | 2012-06-13 | Mexichem Amanco Holding Sa | Process |
ES2714752T3 (es) | 2014-08-14 | 2019-05-29 | Chemours Co Fc Llc | Procedimiento para la producción de E-1,3,3,3-tetrafluoropropeno (HFC-1234ZE) por deshidrofluoración |
EP3230240B1 (en) | 2014-12-11 | 2018-06-13 | Arkema France | Process for the preparation of 1-chloro-2,2-difluoroethane |
CN106179403B (zh) * | 2016-06-27 | 2018-12-21 | 巨化集团技术中心 | 一种合成2,3,3,3-四氟丙烯的方法 |
CN109476567B (zh) | 2016-07-27 | 2022-08-09 | 科慕埃弗西有限公司 | 用于生产卤化烯烃的方法 |
US11209196B2 (en) | 2018-10-26 | 2021-12-28 | The Chemours Company Fc, Llc | HFO-1234ZE, HFO-1225ZC and HFO-1234YF compositions and processes for producing and using the compositions |
BR112021022059A2 (pt) | 2018-10-26 | 2021-12-28 | Chemours Co Fc Llc | Composições de fluoropropeno, métodos de produção de uma mistura e de resfriamento, processos para transferência de calor, para tratamento de uma superfície e para formação de uma composição, sistema de refrigeração, aparelhos de refrigeração, uso da composição de fluoropropeno e método para substituição de um refrigerante |
WO2020086928A1 (en) | 2018-10-26 | 2020-04-30 | The Chemours Company Fc, Llc | Hfo-1234ze and hfo-1234yf compositions and processes for producing and using the compositions |
BR112021018315A2 (pt) | 2019-04-05 | 2021-11-23 | Chemours Co Fc Llc | Processos para produzir e-1,1,1,4,4,4-hexafluorobut-2-eno, para produzir 1,1,2,4,4-pentaclorobuta-1,3-dieno e para produzir z-1,1,1,4,4,4-hexafluorobut-2-eno e composições |
CA3162108A1 (en) | 2020-01-23 | 2021-07-29 | The Chemours Company Fc, Llc | Synthesis of (e)-1,1,1,4,5,5,5-heptafluoro-4-(trifluoromethyl)pent-2-ene |
JP2023516058A (ja) | 2020-03-04 | 2023-04-17 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | (z)-1,1,1,4,4,4-ヘキサフルオロ-2-ブテン及び中間体を生成するためのプロセス |
CN112588307A (zh) * | 2020-12-30 | 2021-04-02 | 山东华安新材料有限公司 | 一种气相氟化制备1,1,2,2-四氟乙烷的方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE361134B (ko) * | 1968-07-25 | 1973-10-22 | Montedison Spa | |
DE1796045C3 (de) * | 1968-08-20 | 1980-06-26 | Schering Ag, 1000 Berlin Und 4619 Bergkamen | Galvanisiertrommel zur Oberflächenbehandlung von Gegenständen |
NL173393C (nl) * | 1968-10-10 | 1984-01-16 | Montedison Spa | Werkwijze voor het bereiden van volledig ge(chloor)fluoreerd ethaan met symmetrische verdeling van de fluoratomen over de koolstofatomen. |
NL171235C (nl) * | 1970-06-10 | 1983-03-01 | Montedison Spa | Werkwijze voor het bereiden van katalysatoren die in hoofdzaak uit aluminiumfluoride bestaan en werkwijze voor het bereiden van gefluoreerde of gechloorfluoreerde koolwaterstoffen met behulp van een dergelijke katalysator. |
US4129603A (en) * | 1978-02-07 | 1978-12-12 | Imperial Chemical Industries Limited | Manufacture of halogenated compounds |
US4147733A (en) * | 1978-05-22 | 1979-04-03 | The Dow Chemical Company | Fluorination of chlorinated hydrocarbons |
JPS5527139A (en) * | 1978-08-14 | 1980-02-27 | Daikin Ind Ltd | Preparation of tetrafluoroethane |
IN172054B (ko) * | 1988-02-24 | 1993-03-27 | Du Pont | |
US4922037A (en) * | 1988-02-24 | 1990-05-01 | E. I. Du Pont De Nemours And Company | Gas-phase fluorination process |
WO1990008755A1 (en) * | 1989-02-03 | 1990-08-09 | E.I. Du Pont De Nemours And Company | Manufacture of 1,1,1,2-tetrafluoroethane |
FR2661906B1 (fr) * | 1990-05-11 | 1993-10-01 | Atochem | Procede de fabrication du 1,1,1,2-tetrafluoro-chloroethane et du pentafluoroethane. |
-
1990
- 1990-11-13 FR FR9014043A patent/FR2669022B1/fr not_active Expired - Lifetime
-
1991
- 1991-10-07 ES ES91402668T patent/ES2066394T3/es not_active Expired - Lifetime
- 1991-10-07 EP EP91402668A patent/EP0486333B1/fr not_active Expired - Lifetime
- 1991-10-07 DK DK91402668.7T patent/DK0486333T3/da active
- 1991-10-07 DE DE69105924T patent/DE69105924T2/de not_active Expired - Lifetime
- 1991-10-07 AT AT91402668T patent/ATE115532T1/de not_active IP Right Cessation
- 1991-10-18 NO NO914107A patent/NO174096C/no unknown
- 1991-11-12 AU AU87799/91A patent/AU641292B2/en not_active Ceased
- 1991-11-12 CA CA002055281A patent/CA2055281C/fr not_active Expired - Lifetime
- 1991-11-12 IE IE393291A patent/IE913932A1/en not_active Application Discontinuation
- 1991-11-12 FI FI915341A patent/FI915341A/fi unknown
- 1991-11-12 PT PT99489A patent/PT99489A/pt not_active Application Discontinuation
- 1991-11-13 MX MX9102049A patent/MX9102049A/es unknown
- 1991-11-13 KR KR1019910020158A patent/KR950006521B1/ko not_active IP Right Cessation
- 1991-11-13 JP JP3297480A patent/JPH0780796B2/ja not_active Expired - Lifetime
-
1995
- 1995-02-28 GR GR950400426T patent/GR3015222T3/el unknown
-
1996
- 1996-12-24 US US08/772,521 patent/US5731481A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2055281A1 (en) | 1992-05-14 |
CA2055281C (fr) | 1998-08-11 |
EP0486333A1 (fr) | 1992-05-20 |
FR2669022B1 (fr) | 1992-12-31 |
EP0486333B1 (fr) | 1994-12-14 |
FI915341A0 (fi) | 1991-11-12 |
GR3015222T3 (en) | 1995-05-31 |
ES2066394T3 (es) | 1995-03-01 |
AU641292B2 (en) | 1993-09-16 |
JPH0780796B2 (ja) | 1995-08-30 |
FI915341A (fi) | 1992-05-14 |
AU8779991A (en) | 1992-05-14 |
NO914107D0 (no) | 1991-10-18 |
MX9102049A (es) | 1992-07-08 |
NO174096B (no) | 1993-12-06 |
US5731481A (en) | 1998-03-24 |
JPH04288027A (ja) | 1992-10-13 |
DE69105924T2 (de) | 1995-07-27 |
DE69105924D1 (de) | 1995-01-26 |
FR2669022A1 (fr) | 1992-05-15 |
ATE115532T1 (de) | 1994-12-15 |
DK0486333T3 (da) | 1995-05-01 |
PT99489A (pt) | 1992-09-30 |
KR950006521B1 (ko) | 1995-06-16 |
NO914107L (no) | 1992-05-14 |
NO174096C (no) | 1994-03-16 |
IE913932A1 (en) | 1992-05-20 |
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