KR960700983A - 디플루오로메탄 제조방법(production of difluoromethane) - Google Patents
디플루오로메탄 제조방법(production of difluoromethane) Download PDFInfo
- Publication number
- KR960700983A KR960700983A KR1019950704055A KR19950704055A KR960700983A KR 960700983 A KR960700983 A KR 960700983A KR 1019950704055 A KR1019950704055 A KR 1019950704055A KR 19950704055 A KR19950704055 A KR 19950704055A KR 960700983 A KR960700983 A KR 960700983A
- Authority
- KR
- South Korea
- Prior art keywords
- zinc
- range
- difluoromethane
- metal
- fluoride
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
Abstract
본 발명은 아연 또는 화합물 및 금속 산화물, 금속 풀루오르화물 또는 금속 옥시플루오르화물로 구성되는 디플루오로메탄의 제조방법에 관한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 아연 또는 아연 화합물 및 금속 플루오르화물 또는 금속 옥시플루오르화물로 구성되는 풀루오르화 촉매의 존재하에 디클로로메탄올 플루오르화수소와 접촉시키는 단계로 구성되는 디플루오로메탄의 제조방법
- 제1항에 있어서 촉매가 아연 또는 아연 화합물 및 크로미아, 크롬 플루오라이드 또는 크롬 옥시플루오라이드로 구성되는 방법
- 제1항 또는 제2항에 있어서 온도가 약 240-약320°C의 범위내인 방법
- 제1항 또는 제2항에 있어서 플루오르화수소와 디클로로메탄의 몰비가 약5:1-약25:1의 범위내인 방법
- 제1항에 있어서 촉매의 중량을 기준한 아연의 중량%가 약0.5-약 30%인 범위내인 방법※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9306072.1 | 1993-03-24 | ||
GB939306072A GB9306072D0 (en) | 1993-03-24 | 1993-03-24 | Production of difluoromethane |
GB939306089A GB9306089D0 (en) | 1993-03-24 | 1993-03-24 | Production of difluoromethane |
GB9306089.5 | 1993-03-24 | ||
PCT/GB1994/000498 WO1994021580A1 (en) | 1993-03-24 | 1994-03-14 | Production of difluoromethane |
Publications (2)
Publication Number | Publication Date |
---|---|
KR960700983A true KR960700983A (ko) | 1996-02-24 |
KR100323102B1 KR100323102B1 (ko) | 2002-11-07 |
Family
ID=26302637
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950704055A KR100323102B1 (ko) | 1993-03-24 | 1994-03-14 | 디플루오로메탄제조방법 |
KR1019950704025A KR100323101B1 (ko) | 1993-03-24 | 1994-03-14 | 디플루오로메탄제조방법 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950704025A KR100323101B1 (ko) | 1993-03-24 | 1994-03-14 | 디플루오로메탄제조방법 |
Country Status (15)
Country | Link |
---|---|
US (2) | US5763704A (ko) |
EP (2) | EP0690832B1 (ko) |
JP (2) | JP3631753B2 (ko) |
KR (2) | KR100323102B1 (ko) |
CN (2) | CN1044227C (ko) |
AU (2) | AU691486B2 (ko) |
BR (2) | BR9406201A (ko) |
CA (2) | CA2157878C (ko) |
DE (2) | DE69410455T2 (ko) |
ES (2) | ES2116586T3 (ko) |
GB (2) | GB9404703D0 (ko) |
RU (2) | RU2127246C1 (ko) |
TW (1) | TW290531B (ko) |
UA (2) | UA40612C2 (ko) |
WO (2) | WO1994021579A1 (ko) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2736050B1 (fr) | 1995-06-29 | 1997-08-01 | Atochem Elf Sa | Procede de fabrication du difluoromethane |
US5763708A (en) * | 1995-09-20 | 1998-06-09 | Allied Signal Inc. | Process for the production of difluoromethane |
FR2748022B1 (fr) * | 1996-04-29 | 1998-07-24 | Atochem Elf Sa | Procede de fabrication du difluoromethane |
BE1010626A3 (fr) * | 1996-09-16 | 1998-11-03 | Solvay | Procede pour la preparation de difluoromethane. |
US5800682A (en) * | 1996-10-08 | 1998-09-01 | Alliedsignal Inc. | Process for the production of difluoromethane |
BE1012227A3 (fr) * | 1998-10-12 | 2000-07-04 | Solvay | Catalyseur et procede d'hydrofluoration. |
ATE421497T1 (de) * | 2002-07-10 | 2009-02-15 | Srf Ltd | Verfahren zur herstellung von difluormethan |
WO2004007410A1 (en) * | 2002-07-10 | 2004-01-22 | Srf Limited | A process for the production of difluoromethane |
KR100512845B1 (ko) * | 2002-11-21 | 2005-09-07 | 울산화학주식회사 | 디플르오로메탄의 제조 방법 |
TW200516068A (en) * | 2003-09-10 | 2005-05-16 | Showa Denko Kk | Process for production of hydrofluorocarbons, products thereof and use of the products |
US7371905B2 (en) * | 2003-10-17 | 2008-05-13 | Honeywell International Inc. | Method of producing hydrofluorocarbons |
US7112708B2 (en) | 2004-04-01 | 2006-09-26 | Honeywell International Inc. | Method of making difluoromethane, 1,1,1-trifluoroethane and 1,1-difluoroethane |
MX2011002366A (es) * | 2008-09-05 | 2011-06-27 | Mexichen Amanco Holding Sa De Capital Variable | Catalizador de fluoracion y proceso para producir hidrocarburos fluorados. |
BR112014008902B1 (pt) * | 2011-10-12 | 2020-03-10 | Bayer Intellectual Property Gmbh | Fluoração catalítica em fase gasosa de 1,1,2-tricloroetano e/ou 1,2-dicloroeteno para produzir 1-clor0-2,2-difluoroetano |
JP2014221727A (ja) * | 2013-05-13 | 2014-11-27 | 昭和電工株式会社 | ジクロロメタンの精製方法およびそれを用いるジフルオロメタンの製造方法 |
CN114425275B (zh) * | 2020-09-18 | 2023-08-15 | 中国石油化工股份有限公司 | 甲烷氧化偶联反应器及其应用 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2744148A (en) * | 1952-02-04 | 1956-05-01 | Dow Chemical Co | Process for fluorination of haloalkanes using a hydrogen fluoride activated catalyst containing alumina, a metal fluoride and basic aluminum fluoride |
US2745886A (en) * | 1955-01-31 | 1956-05-15 | Dow Chemical Co | Process for fluorinating aliphatic halohydrocarbons with a chromium fluoride catalyst and process for preparing the catalyst |
EP0128510A3 (en) * | 1983-06-07 | 1985-05-15 | Showa Denko Kabushiki Kaisha | Process for producing difluoromethane |
GB9104775D0 (en) * | 1991-03-07 | 1991-04-17 | Ici Plc | Fluorination catalyst and process |
US5300710A (en) * | 1991-03-20 | 1994-04-05 | E. I. Du Pont De Nemours And Company | Process for the manufacture of 2-chloro-1,1,1,2-tetrafluoroethane and pentafluoroethane |
US5208395A (en) * | 1992-04-06 | 1993-05-04 | Elf Atochem North America, Inc. | Manufacture of hydrofluorocarbons |
ES2111207T3 (es) * | 1993-06-18 | 1998-03-01 | Showa Denko Kk | Catalizador de fluoracion y procedimiento de fluoracion. |
KR960022411A (ko) * | 1994-12-28 | 1996-07-18 | 남경희 | 디플루오로메탄의 제조방법 |
-
1994
- 1994-03-10 GB GB9404703A patent/GB9404703D0/en active Pending
- 1994-03-10 GB GB9404715A patent/GB9404715D0/en active Pending
- 1994-03-14 BR BR9406201A patent/BR9406201A/pt not_active IP Right Cessation
- 1994-03-14 CA CA002157878A patent/CA2157878C/en not_active Expired - Fee Related
- 1994-03-14 EP EP94909203A patent/EP0690832B1/en not_active Expired - Lifetime
- 1994-03-14 US US08/522,241 patent/US5763704A/en not_active Expired - Fee Related
- 1994-03-14 KR KR1019950704055A patent/KR100323102B1/ko not_active IP Right Cessation
- 1994-03-14 DE DE69410455T patent/DE69410455T2/de not_active Expired - Fee Related
- 1994-03-14 ES ES94909204T patent/ES2116586T3/es not_active Expired - Lifetime
- 1994-03-14 JP JP52076394A patent/JP3631753B2/ja not_active Expired - Fee Related
- 1994-03-14 DE DE69410456T patent/DE69410456T2/de not_active Expired - Fee Related
- 1994-03-14 UA UA95094235A patent/UA40612C2/uk unknown
- 1994-03-14 WO PCT/GB1994/000497 patent/WO1994021579A1/en active IP Right Grant
- 1994-03-14 CN CN94191526A patent/CN1044227C/zh not_active Expired - Fee Related
- 1994-03-14 RU RU95121816A patent/RU2127246C1/ru not_active IP Right Cessation
- 1994-03-14 WO PCT/GB1994/000498 patent/WO1994021580A1/en active IP Right Grant
- 1994-03-14 RU RU95118158A patent/RU2116288C1/ru not_active IP Right Cessation
- 1994-03-14 BR BR9406236A patent/BR9406236A/pt not_active IP Right Cessation
- 1994-03-14 UA UA95094274A patent/UA35612C2/uk unknown
- 1994-03-14 AU AU62133/94A patent/AU691486B2/en not_active Ceased
- 1994-03-14 JP JP6520764A patent/JPH08508029A/ja not_active Ceased
- 1994-03-14 ES ES94909203T patent/ES2115940T3/es not_active Expired - Lifetime
- 1994-03-14 CN CN94191525A patent/CN1057750C/zh not_active Expired - Fee Related
- 1994-03-14 EP EP94909204A patent/EP0690833B1/en not_active Expired - Lifetime
- 1994-03-14 KR KR1019950704025A patent/KR100323101B1/ko not_active IP Right Cessation
- 1994-03-14 US US08/507,429 patent/US5672786A/en not_active Expired - Fee Related
- 1994-03-14 AU AU62134/94A patent/AU691487B2/en not_active Ceased
- 1994-03-14 CA CA002157528A patent/CA2157528C/en not_active Expired - Fee Related
- 1994-03-18 TW TW083102380A patent/TW290531B/zh active
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