KR880007586A - 불소화된 폴리우레탄의 분산수용액 및 섬유의 전면공정을 위한 이들의 용도 - Google Patents
불소화된 폴리우레탄의 분산수용액 및 섬유의 전면공정을 위한 이들의 용도 Download PDFInfo
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- KR880007586A KR880007586A KR1019870015475A KR870015475A KR880007586A KR 880007586 A KR880007586 A KR 880007586A KR 1019870015475 A KR1019870015475 A KR 1019870015475A KR 870015475 A KR870015475 A KR 870015475A KR 880007586 A KR880007586 A KR 880007586A
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- 239000006185 dispersion Substances 0.000 title claims 12
- 238000000034 method Methods 0.000 title claims 7
- 239000007864 aqueous solution Substances 0.000 title claims 5
- 239000004814 polyurethane Substances 0.000 title claims 5
- 229920002635 polyurethane Polymers 0.000 title claims 5
- 239000000835 fiber Substances 0.000 title claims 2
- 229920001228 polyisocyanate Polymers 0.000 claims 7
- 239000005056 polyisocyanate Substances 0.000 claims 7
- 239000000243 solution Substances 0.000 claims 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
- -1 2-hydroxyethyl- Chemical group 0.000 claims 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 125000003010 ionic group Chemical group 0.000 claims 3
- 125000000129 anionic group Chemical group 0.000 claims 2
- 150000001450 anions Chemical class 0.000 claims 2
- 125000002091 cationic group Chemical group 0.000 claims 2
- 150000001768 cations Chemical class 0.000 claims 2
- 125000005442 diisocyanate group Chemical group 0.000 claims 2
- 150000002009 diols Chemical class 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 229920005862 polyol Polymers 0.000 claims 2
- 150000003077 polyols Chemical class 0.000 claims 2
- 229920002994 synthetic fiber Polymers 0.000 claims 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- 229920003043 Cellulose fiber Polymers 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 241000208202 Linaceae Species 0.000 claims 1
- 235000004431 Linum usitatissimum Nutrition 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229920006397 acrylic thermoplastic Polymers 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000004745 nonwoven fabric Substances 0.000 claims 1
- 230000035699 permeability Effects 0.000 claims 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 229920003009 polyurethane dispersion Polymers 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 claims 1
- 239000012209 synthetic fiber Substances 0.000 claims 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 210000002268 wool Anatomy 0.000 claims 1
- 239000002759 woven fabric Substances 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
- C08G18/5015—Polyethers having heteroatoms other than oxygen having halogens having fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- 그들의 고분자내에 음이온 및 양이온성의 친수성 이온기를 함유하고, 다음 공정에 따라서 제조되는 불소화된 폴리우레탄의 안정한 분산수용액 : (a) 이온화될 수 있는 기를 함유하는 디올 및(폴리올과 적어도 l중량 %의 하나 또는 그 이상의 히드록시-및/또는 카르복시-결합된 플루오로폴리에테르로써 이루어지는)매크로글리콜로 구성되는 혼합물을, 유기디이소시아네이트와 반응시켜서 불소화된 폴리이소시안 폴리이소시아네이트를 제조하고 : (b) 이온화될 수 있는 기를 친수성 양이온 또는 음이온으로 전환시키기 위하여, 이와같이 해서 얻어진 불소화된 폴리이소시아네이트를 염화하고 : 그리고 (c) 염화된 불소화 폴리이소시아네이트를 물에 분산시켜서 완료함.
- 제1항에 있어서, 히드록시기의 합에 대한 이소시안기의 몰비율이 0.2 내지 2 되는 것을 특징으로 하는 분산수용액.
- 제2항에 있어서, 히드록시기의 합에 대한 이소시안기의 몰비율이 1.5임을 특징으로 하는 분산수용액.
- 상기항 중의 어느항에 있어서, 매크로글리콜이 하나 또는 그 이상의 히드록시-및/또는 카르복시-결합된 플루오로 폴리에테프로 이루어짐을 특징으로 하는 분산수용액.
- 상기항중의 어느항에 있어서, 히드록시 -및/또는 카르복시 -결합된 플로오로폴리에테르의 분자량이 500 내지 7,000, 바람직하게는 1,000내지 2,500 됨을 특징으로 하는 분산수용액.
- 상기항중의 어느항에 있어서, 히드록시-및/또는 카르복시-결합된 플루오로폴리에테르가 다음 일반식(Ⅰ) 내지 (Ⅸ)로 부터 선택되어짐을 특징으로 하는 분산수용액 :상기식에서 R1은 -(CH2)x-, -(CH2O)yCH2-, -(CH2)xOCH2-,로부터 선택되어지며,및는 1내지 4의 정수이고 ;및은 m/n 비율이 0.2내지 2, 바람직하게는 0.5내지 1.2인 정수이고 : Rf는 퍼플루오로알켄기이며 : X는 -F또는 -CF3이고 : Y는-OH, 및/또는 -COOH기를 나타내며 : 는 위에서 언급한 분자량이 얻어지는 것이 가능해지는 정수이다.
- 제6항에 있어서, 히드록시 -및/또는 카르복시 -결합된 플로오로폴리에테르가 평군분자량이 2,000되는 α·W-비스-(히드록시메틸)-폴리옥시퍼플루오로알켄 및 α·w-(폴리옥시퍼플루오로알칸)-디오익산임을 특징으로 하는 분산수용액.
- 그들의 고분자내에 음이온 또는 양이온성의 친수성 이온기를 함유하며, 다음 공정에 의해서 제조되는 불소화된 폴리우레탄의 안정한 분산수용액:(ⅰ) 이온화될 수 있는 디올 및(폴리올과 적어도 1중량%의 하나 또는 그이상의 히드록시-및/또는 카르복시-결합된 플루오로폴리에테르로 이루어지는)매크로글리콜로 구성되는 혼합물을, 유기디이소시아네이트와 반응시켜서 불소화원 폴리이소시안 프레폴리머를 제조하고: (ⅱ)이소시안기와 반응성이었는, 다음 일반식(X)를 갖는 히드록시-알킬-아크릴레이트 또는 메타아크릴레이트로 부터 선택된, 히드록시기를 함유하는 화합물과 반응시켜서 불소화된 폴리이소시안 프레폴리머를 불포화된 비닐말단기를 가지는 올리고우레탄으로 전환하고:상기식에서 R2는 수소 또는 (C1-C4)-알킬기이고 W는 히드록시알킬기이며: (ⅲ) 이온화될 수 있는 기를 친수성의 양이온 또는 음이온으로 전환하기 위하여, 얻어진 위와 같은 올리고우레탄으로 염화시키고 : (ⅳ) 얻어진 올리고우레탄을 물에 분산시키고 : 그리고 (ⅴ) 물에 분산된 올리고우레탄의 불포화원 기를 중합함.
- 제8항에 있어서, 히드록시알킬아크릴레이트 또는 메타아클릴레이트가, R이 수소 또는 메틸기이고, W가 2-히드록시에틸-, 2-히드록시프로필-, 3-히드록시프로필- 및 4-히드록시부틸기 임을 특징으로 하는 분산수용액.
- 제8 또는 9항에 있어서, 히드록시알킬 아크릴레이트 또는 메타아크릴레이트가, 폴리이소시안프레폴리머내에 존재하는 유리이소시안기에 대한 NCO-eq/OH-eq 비율이 0.5 내지 1·1의 범위내, 바람직하게는 1이 되도록 사용되어짐을 특징으로 하는 분산수용액.
- 상기항중의 어느항에 있어서, 고체함량이 20중량%이상, 바람직하게는 30내지 50중량%의 범위에 있음을 특징으로 하는 분산수용액.
- 상기항중의 어느항에 있어서, 불소화된 폴리우레탄이 그들의 고분자내에, 100g의 건성중합체당 10내지 60밀리당량, 바람직하게는 100g의 건성중합체당 20내지 40밀리당량의 이온기를 함유함을 특징으로 하는 분산수용액.
- 상기항에 따르는 불소화된 폴리우레탄의 분산수용액에 의해서 섬유제품을 처리하는 것으로 이루어지는 직포 및 부직포 섬유제품을 제조하기 위한 공정.
- 제13항에 있어서, 불소화된 폴리우레탄의 분산수용액이 20g/㎡ 이상, 바람직하게는 20내지 40g/㎡의 침착량수준이 전면가공에 의해 처리됨을 특징으로 하는 공정.
- 제13 또는 14항에 있어서, 섬유제품이, 모직, 비단, 면, 아마, 셀룰로오스섬유, 아크릴, 폴리에스테르, 폴리아미드섬유와 같은 천연, 인공 또는 합성섬유에 근거함을 특징으로 하는 공정.
- 수증기에 대한 침투성이 900내지 1,600의 범위에 있고, 물에 대한 불투과성이 2미터의 수압하에서 24시간이상되는, 높은 불투과성 및 통기성이 동시에 부여된 직포 및 부직포 섬유제품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019970003540A KR970007320B1 (ko) | 1986-12-30 | 1997-02-05 | 불소화 폴리우레탄 수성 분산액 및 이것을 사용하여 스프리딩 처리된 직물제품을 제조하는 방법 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT22883A/86 | 1986-12-30 | ||
| IT8622883A IT1213441B (it) | 1986-12-30 | 1986-12-30 | Dispersioni acquose di poliuretani e fluorurati e loro impiego per spalmature tessili. |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019970003540A Division KR970007320B1 (ko) | 1986-12-30 | 1997-02-05 | 불소화 폴리우레탄 수성 분산액 및 이것을 사용하여 스프리딩 처리된 직물제품을 제조하는 방법 |
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| Publication Number | Publication Date |
|---|---|
| KR880007586A true KR880007586A (ko) | 1988-08-27 |
| KR970004930B1 KR970004930B1 (ko) | 1997-04-10 |
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| KR1019870015475A KR970004930B1 (ko) | 1986-12-30 | 1987-12-30 | 불소화 폴리우레탄의 수성 분산액 및 이것을 스프리딩시킨 직물제품 |
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| Country | Link |
|---|---|
| US (2) | US4983666A (ko) |
| EP (1) | EP0273449B1 (ko) |
| JP (2) | JP2540572B2 (ko) |
| KR (1) | KR970004930B1 (ko) |
| CA (1) | CA1319220C (ko) |
| DE (1) | DE3777363D1 (ko) |
| ES (1) | ES2030048T3 (ko) |
| IT (1) | IT1213441B (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016052906A1 (ko) * | 2014-09-29 | 2016-04-07 | 코오롱인더스트리 주식회사 | 방오성을 가지는 스웨이드형 인공피혁 및 이의 제조방법 |
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| DE69017055T2 (de) * | 1989-01-11 | 1995-06-29 | Ciba Geigy Ag | Perfluorpolyalkylether- und Polyalkylether-Segmente enthaltende Vinylmakromere, daraus hergestellte Polymere, Interpolymere sowie ophthalmische Vorrichtungen. |
| IT1237788B (it) * | 1989-11-30 | 1993-06-17 | Syremont Spa | Poliuretani fluorurati idrodiluibili, procedimento per la loro preparazione e loro impiego per il trattamento di materiale lapideo e di intonaci |
| US5350795A (en) * | 1991-07-10 | 1994-09-27 | Minnesota Mining And Manufacturing Company | Aqueous oil and water repellent compositions which cure at ambient temperature |
| IT1251487B (it) * | 1991-09-17 | 1995-05-15 | Syremont Spa | Dispersioni acquose di poliuretani fluorurati |
| US5407728A (en) | 1992-01-30 | 1995-04-18 | Reeves Brothers, Inc. | Fabric containing graft polymer thereon |
| US5486210A (en) | 1992-01-30 | 1996-01-23 | Reeves Brothers, Inc. | Air bag fabric containing graft polymer thereon |
| DE4207851A1 (de) * | 1992-03-12 | 1993-09-16 | Bayer Ag | Mittel und verfahren zur ausruestung von textilien |
| US6391459B1 (en) | 1992-04-20 | 2002-05-21 | Dsm N.V. | Radiation curable oligomers containing alkoxylated fluorinated polyols |
| EP0605105B1 (en) * | 1992-12-30 | 1999-05-06 | Imperial Chemical Industries Plc | Process for rigid foams |
| IT1270213B (it) * | 1994-06-13 | 1997-04-29 | Ausimont Spa | Dispersioni acquose di poliuretani floururati |
| JPH11503768A (ja) * | 1995-01-30 | 1999-03-30 | デー エス エム エヌ．ヴェー． | フッ素化ウレタンオリゴマー含有放射線硬化性組成物 |
| US5725789A (en) * | 1995-03-31 | 1998-03-10 | Minnesota Mining And Manufacturing Company | Aqueous oil and water repellent compositions |
| IT1303808B1 (it) * | 1998-12-01 | 2001-02-23 | Ausimont Spa | Trattamenti di superfici con derivati bifunzionali diperfluoropolieteri. |
| IT1311977B1 (it) * | 1999-03-25 | 2002-03-22 | Ausimont Spa | Composizioni idro-oleo repellenti. |
| DE19933826A1 (de) * | 1999-07-20 | 2001-02-01 | Basf Ag | Wässrige Dispersion einer Mischung eines Polyurethans mit einem strahlungshärtbaren (Meth)acrylat-Präpolymer |
| IT1318558B1 (it) * | 2000-06-08 | 2003-08-27 | Ausimont Spa | Poliuretani a basso coefficiente di attrito. |
| US6482911B1 (en) | 2001-05-08 | 2002-11-19 | 3M Innovative Properties Company | Fluoroalkyl polymers containing a cationogenic segment |
| ITMI20011306A1 (it) * | 2001-06-21 | 2002-12-21 | Ausimont Spa | Poliuretani vulcanizzabili |
| ITMI20011424A1 (it) | 2001-07-05 | 2003-01-05 | Ausimont Spa | Dispersioni di polimeri fluorurati |
| ITMI20020029A1 (it) * | 2002-01-10 | 2003-07-10 | Ausimont Spa | Composizioni idro- oleo repellenti |
| DE10208567A1 (de) * | 2002-02-27 | 2003-09-11 | Degussa Construction Chem Gmbh | Wässriges fluormodifiziertes Polyurethansystem für Anti-Graffiti- und Anti-Soiling-Beschichtungen |
| ITMI20020803A1 (it) * | 2002-04-17 | 2003-10-17 | Ausimont Spa | Composizioni liquide per il trattamento di superfici metalliche |
| CN1304683C (zh) | 2002-05-24 | 2007-03-14 | 3M创新有限公司 | 用于处理纤维基底的含氟化合物组合物 |
| US7425279B2 (en) | 2002-05-24 | 2008-09-16 | 3M Innovative Properties Company | Fluorochemical composition for treatment of a fibrous substrate |
| CA2487004C (en) | 2002-05-24 | 2011-11-01 | 3M Innovative Properties Company | Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith |
| ITMI20021228A1 (it) * | 2002-06-06 | 2003-12-09 | Ausimont Spa | Composizioni di poliuretani reticolabili |
| US6923921B2 (en) | 2002-12-30 | 2005-08-02 | 3M Innovative Properties Company | Fluorinated polyether compositions |
| DE10331484A1 (de) * | 2003-07-11 | 2005-03-03 | Construction Research & Technology Gmbh | Polyurethan-Polymer-Hybrid-Dispersion mit verbesserten Oberflächeneigenschaften, Verfahren zu ihrer Herstellung sowie deren Verwendung |
| US7173081B2 (en) | 2003-08-12 | 2007-02-06 | Hexion Specialty Chemicals, Inc. | Processes to produce water-dispersible polyester stabilized fluoroalkyl compositions |
| WO2005019339A1 (en) * | 2003-08-12 | 2005-03-03 | Resolution Specialty Materials Llc | Water-dispersible polyester stabilized fluoroalkyl compositions |
| US7186769B2 (en) | 2003-08-12 | 2007-03-06 | Hexion Specialty Chemicals, Inc. | Water-dispersible polyester stabilized fluoroalkyl compositions |
| US7652115B2 (en) | 2003-09-08 | 2010-01-26 | 3M Innovative Properties Company | Fluorinated polyether isocyanate derived silane compositions |
| US20050058515A1 (en) * | 2003-09-12 | 2005-03-17 | Markusch Peter H. | Geotextile/polymer composite liners based on waterborne resins |
| US7141537B2 (en) | 2003-10-30 | 2006-11-28 | 3M Innovative Properties Company | Mixture of fluorinated polyethers and use thereof as surfactant |
| US7803894B2 (en) | 2003-12-05 | 2010-09-28 | 3M Innovatie Properties Company | Coating compositions with perfluoropolyetherisocyanate derived silane and alkoxysilanes |
| US7759447B2 (en) | 2005-11-17 | 2010-07-20 | Bayer Materialscience Llc | Low surface energy, ethylenically unsaturated polyisocyanate addition compounds and their use in coating compositions |
| WO2010028226A2 (en) * | 2008-09-05 | 2010-03-11 | Arrowstar, Llc | Compositions and methods for imparting water and oil repellency to fibers and articles thereof |
| TWI520977B (zh) | 2010-04-21 | 2016-02-11 | 首威索勒希斯股份有限公司 | 氟化的聚胺基甲酸酯組成物 |
| US20130023171A1 (en) | 2011-07-19 | 2013-01-24 | Brown Harold M | Composition and Method For Improving Adhesion of Textile Substrates to Rubber and Articles Resulting Therefrom |
| CN102899897B (zh) * | 2011-07-26 | 2014-12-10 | 台氟科技股份有限公司 | 氟素拨水拨油剂 |
| EP2607397A1 (en) | 2011-12-21 | 2013-06-26 | Clariant International Ltd. | Fluorochemical composition and use thereof |
| US8716396B2 (en) | 2012-04-19 | 2014-05-06 | Arrowstar Llc | Nonfluorinated polyurethanes and methods of making and using thereof |
| WO2013158138A1 (en) | 2012-04-19 | 2013-10-24 | Arrowstar, Llc | Nonfluorinated polyurethanes and methods of making and using thereof |
| CN102911342B (zh) * | 2012-10-31 | 2015-07-01 | 黎明化工研究设计院有限责任公司 | 一种含氟水性聚氨酯固化剂及其制备方法 |
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| US3242218A (en) * | 1961-03-29 | 1966-03-22 | Du Pont | Process for preparing fluorocarbon polyethers |
| US3250808A (en) * | 1963-10-31 | 1966-05-10 | Du Pont | Fluorocarbon ethers derived from hexafluoropropylene epoxide |
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| US3810874A (en) * | 1969-03-10 | 1974-05-14 | Minnesota Mining & Mfg | Polymers prepared from poly(perfluoro-alkylene oxide) compounds |
| US3988278A (en) * | 1970-08-17 | 1976-10-26 | Minnesota Mining And Manufacturing Company | Stable polymer latex and process for making same |
| BE789363A (fr) * | 1971-09-27 | 1973-03-27 | Fmc Corp | Composes fluores utilisables comme agents antitaches pour textiles |
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| US4046944A (en) * | 1976-04-06 | 1977-09-06 | Ciba-Geigy Corporation | Fluorinated condensation polymers and their use as soil release agents |
| CA1131376A (en) * | 1976-10-04 | 1982-09-07 | David G. Hangauer, Jr. | Aqueous urea-urethane dispersions |
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| US4523039A (en) * | 1980-04-11 | 1985-06-11 | The University Of Texas | Method for forming perfluorocarbon ethers |
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| US4408008A (en) * | 1981-07-24 | 1983-10-04 | Mobay Chemical Corporation | Stable, colloidal, aqueous dispersions of cross-linked urea-urethane polymers and their method of production |
| IT1153000B (it) * | 1982-07-01 | 1987-01-14 | Resem Spa | Dispersioni acquose di poliuretani da oligouretani aventi gruppi terminali insaturi |
| DE3230851A1 (de) * | 1982-08-19 | 1984-02-23 | Basf Farben + Fasern Ag, 2000 Hamburg | Waessrige dispersion auf der basis eines polyurethankunstharzes |
| EP0148482B1 (en) * | 1983-12-26 | 1992-03-25 | Daikin Industries, Limited | Process for preparing halogen-containing polyether |
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| DE3407362A1 (de) * | 1984-02-29 | 1985-08-29 | Bayer Ag, 5090 Leverkusen | Waessrige dispersionen von pfropfpolymerisaten oder -copolymerisaten, ein verfahren zu ihrer herstellung und ihre verwendung als hydrophobierungs- und oleophobierungsmittel fuer textilien |
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| DE3438563A1 (de) * | 1984-10-20 | 1986-04-24 | Bayer Ag, 5090 Leverkusen | Waessrige loesungen oder dispersionen von polyisocyanat-additionsprodukten, ein verfahren zu ihrer herstellung, sowie ihre verwendung als beschichtungsmittel oder als leimungsmittel fuer papier |
| DE3523856A1 (de) * | 1985-07-04 | 1987-01-08 | Bayer Ag | Waessrige loesungen oder dispersionen von polyisocyanat-additionsprodukten, ein verfahren zu ihrer herstellung, sowie ihre verwendung als beschichtungsmittel oder als leimungsmittel fuer papier |
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| IT1201498B (it) * | 1985-11-20 | 1989-02-02 | Ausimont Spa | Perfluoropolieteri funzionalizzati e procedimento per la loro preparazione |
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-
1986
- 1986-12-30 IT IT8622883A patent/IT1213441B/it active
-
1987
- 1987-12-23 JP JP62324226A patent/JP2540572B2/ja not_active Expired - Lifetime
- 1987-12-29 ES ES198787119332T patent/ES2030048T3/es not_active Expired - Lifetime
- 1987-12-29 CA CA000555530A patent/CA1319220C/en not_active Expired - Fee Related
- 1987-12-29 DE DE8787119332T patent/DE3777363D1/de not_active Expired - Lifetime
- 1987-12-29 EP EP87119332A patent/EP0273449B1/en not_active Expired - Lifetime
- 1987-12-30 KR KR1019870015475A patent/KR970004930B1/ko not_active IP Right Cessation
-
1990
- 1990-01-22 US US07/467,342 patent/US4983666A/en not_active Expired - Lifetime
- 1990-10-12 US US07/596,824 patent/US5068135A/en not_active Expired - Lifetime
-
1996
- 1996-02-06 JP JP8019977A patent/JP2618617B2/ja not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016052906A1 (ko) * | 2014-09-29 | 2016-04-07 | 코오롱인더스트리 주식회사 | 방오성을 가지는 스웨이드형 인공피혁 및 이의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR970004930B1 (ko) | 1997-04-10 |
| JP2618617B2 (ja) | 1997-06-11 |
| JPH08325951A (ja) | 1996-12-10 |
| ES2030048T3 (es) | 1992-10-16 |
| EP0273449A1 (en) | 1988-07-06 |
| DE3777363D1 (de) | 1992-04-16 |
| US4983666A (en) | 1991-01-08 |
| EP0273449B1 (en) | 1992-03-11 |
| IT1213441B (it) | 1989-12-20 |
| US5068135A (en) | 1991-11-26 |
| CA1319220C (en) | 1993-06-15 |
| JPS63295616A (ja) | 1988-12-02 |
| JP2540572B2 (ja) | 1996-10-02 |
| IT8622883A0 (it) | 1986-12-30 |
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