KR20210030938A - 복분해 반응에서 n-킬레이트성 루테늄 착물의 용도 - Google Patents

복분해 반응에서 n-킬레이트성 루테늄 착물의 용도 Download PDF

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Publication number
KR20210030938A
KR20210030938A KR1020217001941A KR20217001941A KR20210030938A KR 20210030938 A KR20210030938 A KR 20210030938A KR 1020217001941 A KR1020217001941 A KR 1020217001941A KR 20217001941 A KR20217001941 A KR 20217001941A KR 20210030938 A KR20210030938 A KR 20210030938A
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South Korea
Prior art keywords
alkyl
aryl
formula
independently
alkoxy
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Korean (ko)
Inventor
라팔 가윈
패트릭 크라즈취
안나 가윈
크지슈토프 스코벌스키
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아페이론 신세시스 에스.아.
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • B01J31/2269Heterocyclic carbenes
    • B01J31/2273Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • B01J31/2278Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020217001941A 2018-07-12 2019-07-10 복분해 반응에서 n-킬레이트성 루테늄 착물의 용도 Ceased KR20210030938A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PL426318A PL426318A1 (pl) 2018-07-12 2018-07-12 Zastosowanie N-chelatujących kompleksów rutenu w reakcji metatezy
PLPL426318 2018-07-12
PCT/IB2019/055864 WO2020012370A1 (en) 2018-07-12 2019-07-10 Use of n-chelating ruthenium complexes in the metathesis reaction

Publications (1)

Publication Number Publication Date
KR20210030938A true KR20210030938A (ko) 2021-03-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020217001941A Ceased KR20210030938A (ko) 2018-07-12 2019-07-10 복분해 반응에서 n-킬레이트성 루테늄 착물의 용도

Country Status (7)

Country Link
US (1) US12251688B2 (https=)
EP (1) EP3820609B1 (https=)
JP (1) JP2021530432A (https=)
KR (1) KR20210030938A (https=)
CA (1) CA3096337A1 (https=)
PL (2) PL426318A1 (https=)
WO (1) WO2020012370A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102536751B1 (ko) * 2020-04-07 2023-05-24 주식회사 엘지화학 촉매 조성물, 이를 포함하는 세척액 조성물 및 이를 이용한 중합장치의 세척방법
PL246181B1 (pl) * 2020-08-17 2024-12-16 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu i ich zastosowanie w reakcji krzyżowej metatezy olefin

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5314753B2 (ja) * 2008-05-22 2013-10-16 リミテッド・ライアビリティ・カンパニー・”ユナイテッド・リサーチ・アンド・デベロップメント・センター” ジシクロペンタジエンのメタセシス重合触媒、その製造方法および重合方法
RU2402572C1 (ru) 2009-07-09 2010-10-27 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" Способ получения полидициклопентадиена и материалов на его основе
CN102596407B (zh) 2009-11-09 2014-09-03 埃克森美孚化学专利公司 复分解催化剂和其应用方法
WO2011079439A1 (en) * 2009-12-30 2011-07-07 Zannan Scitech Co., Ltd. Highly active metathesis catalysts selective for romp and rcm reactions
RU2451692C2 (ru) * 2010-08-13 2012-05-27 Закрытое Акционерное Общество "Сибур Холдинг" Способ очистки полимеризационного оборудования от труднорастворимых отложений высокомолекулярного полимера (варианты)
RU2462308C1 (ru) * 2011-10-04 2012-09-27 Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" Катализатор полимеризации дициклопентадиена и способ его получения
PL225024B1 (pl) * 2012-08-16 2017-02-28 Univ Warszawski Nowe kompleksy rutenu oraz ich zastosowanie
RU2523321C1 (ru) * 2013-05-15 2014-07-20 Открытое акционерное общество "Нефтяная компания "Роснефть" Материал для проппанта и способ его получения
RU2552750C1 (ru) * 2014-02-18 2015-06-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения микросфер полимерного проппанта из полимерной матрицы на основе метатезис-радикально сшитой смеси олигоциклопентадиенов
RU2577252C1 (ru) * 2015-02-26 2016-03-10 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ получения катализатора метатезисной полимеризации дициклопентадиена
PL238806B1 (pl) * 2015-09-30 2021-10-04 Apeiron Synthesis Spolka Akcyjna Kompleks rutenu i sposób jego wytwarzania, związek pośredni stosowany w tym sposobie oraz zastosowanie kompleksu rutenu i związku pośredniego w metatezie olefin
CN107233920A (zh) * 2016-03-29 2017-10-10 上海东杰高分子材料有限公司 一种钌络合物催化剂
WO2017185324A1 (en) * 2016-04-29 2017-11-02 Xia, Ling Group 8 transition metal catalysts and method for making same and process for use of same in olefin disproportionation reactions
PL241085B1 (pl) * 2016-11-10 2022-08-01 Apeiron Synthesis Spolka Akcyjna Zastosowanie kompleksów rutenu w reakcji metatezy olefin
PL243369B1 (pl) * 2018-04-16 2023-08-14 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu oraz ich zastosowanie w reakcjach metatezy olefin
US11291983B2 (en) * 2019-09-18 2022-04-05 Apeiron Synthesis S.A. Organoruthenium carbide complexes as precatalysts for olefin metathesis
PL246181B1 (pl) * 2020-08-17 2024-12-16 Apeiron Synthesis Spolka Akcyjna Nowe kompleksy rutenu i ich zastosowanie w reakcji krzyżowej metatezy olefin

Also Published As

Publication number Publication date
EP3820609A1 (en) 2021-05-19
PL426318A1 (pl) 2020-01-13
PL3820609T3 (pl) 2023-10-16
JP2021530432A (ja) 2021-11-11
US20210237045A1 (en) 2021-08-05
CA3096337A1 (en) 2020-01-16
WO2020012370A1 (en) 2020-01-16
EP3820609B1 (en) 2023-06-28
US12251688B2 (en) 2025-03-18

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