KR20020006705A - 3차원 물품 광제조용 수지조성물 - Google Patents
3차원 물품 광제조용 수지조성물 Download PDFInfo
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
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- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
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- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
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- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/16—Cyclic ethers having four or more ring atoms
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- C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
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- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/075—Silicon-containing compounds
- G03F7/0757—Macromolecular compounds containing Si-O, Si-C or Si-N bonds
Abstract
Description
성분 | 실시예 | 비교 실시예 | |||||||||||
1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 1 | 2 | 3 | 4 | ||
A | 옥세탄 화합물*1 | 50 | 40 | 30 | 50 | 30 | 30 | 40 | 30 | 90 | 50 | - | 15 |
옥세탄 화합물*2 | - | - | - | - | - | 10 | - | - | - | - | - | - | |
B | 에폭시시클로헥산*6 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 8 | 38 | 60 | 14 |
에폭시시클로헥산*7 | - | 10 | 15 | 10 | 15 | 10 | 5 | - | - | - | 15 | - | |
1,6-헥산디올디글리시딜 에테르 | 10 | 10 | 15 | - | - | - | 10 | - | - | 10 | 15 | - | |
네오펜틸 글리콜글리시딜 에테르 | - | - | - | - | 15 | 10 | - | 15 | - | - | - | - | |
C | 광산 발생제 *3 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 |
D | 탄성중합체 입자200㎚ *4 | 8 | 8 | 8 | 8 | - | 8 | 6 | 8 | - | - | 8 | 8 |
탄성중합체 입자50㎚ *5 | - | - | - | - | 8 | - | - | - | - | - | - | - | |
E | 프로필렌 옥시드-변형 글리세롤 *8 | - | - | - | - | - | - | 5 | - | - | - | - | - |
F | 트리메틸롤프로판트리아크릴레이트 | - | - | - | - | - | - | - | 14 | - | - | - | 60 |
G | 1-히드록시 페닐케톤 | - | - | - | - | - | - | - | 1 | - | - | - | 1 |
성질 | |||||||||||||
경화성 | 우수 | 우수 | 우수 | 우수 | 우수 | 우수 | 우수 | 우수 | 나쁨 | 우수 | 나쁨 | 우수 | |
탄성 계수(1일 후) | 160 | 150 | 155 | 170 | 157 | 150 | 153 | 150 | 110 | 172 | 182 | 195 | |
탄성 계수(30일 후) | 155 | 146 | 150 | 165 | 152 | 146 | 148 | 154 | 120 | 165 | 170 | 210 | |
접힘 내구성 | O | O | O | O | O | O | ⊙ | O | O | X | X | X | |
제품의 뒤틀림 양 | 좋음 | 우수 | 우수 | 양호 | 우수 | 우수 | 우수 | 우수 | 미형성 | 양호 | 미형성 | 나쁨 | |
제조 정확성 | O | ⊙ | ⊙ | O | ⊙ | ⊙ | ⊙ | ⊙ | 미형성 | O | 미형성 | X |
Claims (9)
- (A)옥세탄 화합물 5-80중량부,(B)에폭시 화합물 5-80중량부,(C)광산 발생제 0.1-10중량부,(D)평균입자직경이 10-700㎚인 탄성중합체 입자 1-35중량부,(E)폴리올 화합물 0-35중량부,(F)에틸렌계 불포화 단량체 0-45중량부 및(G)라디칼 광중합화 개시제 0-10중량부로 이루어진 3차원 물품 광제조용 광경화성 수지조성물.
- 제 1 항에 있어서,상기 옥세탄 화합물 (A)는 2개의 옥세탄 고리를 함유하는 것을 특징으로 하는 광경화성 수지조성물.
- 제 1 항 또는 제 2 항에 있어서,상기 에폭시 화합물 (B)는 에폭시시클로헥실기 또는 글리시딜기를 함유하는 것을 특징으로 하는 광경화성 수지조성물.
- 제 1 항 내지 제 3 항 중 어느 한 항에 있어서,상기 광산 발생제는 방향족 오늄염인 것을 특징으로 하는 광경화성 수지조성물.
- 제 1 항 내지 제 4 항 중 어느 한 항에 있어서,상기 입자 (D)는 일부 가교된 폴리부타디엔, 폴리이소프렌, 스티렌/부타디엔 공중합체, 스티렌/이소프렌 공중합체, 부타디엔/(메트)아크릴레이트 공중합체, 스티렌/부타디엔 블록 공중합체 및 스티렌/이소프렌 블록 공중합체의 코어가 메틸 메타크릴레이트 중합체 또는 메틸 메타크릴레이트/글리시딜 메타크릴레이트 공중합체에 의해 코팅되는 탄성중합체 입자를 포함하는 것을 특징으로 하는 광경화성 수지조성물.
- 제 1 항 내지 제 5 항 중 어느 한 항에 있어서,폴리올 (E)은 2 내지 6개의 히드록실기를 함유하는 것을 특징으로 하는 광경화성 수지조성물.
- 3차원 물품을 광제조하는데 사용되는 것을 특징으로 하는 제 1 항 내지 제 6 항 중 어느 한 항의 광경화성 수지조성물의 용도.
- 제 1 항 내지 제 6 항 중 어느 한 항의 광경화성 수지조성물을 광제조함으로써 수득할 수 있는 3차원 물품.
- 디자인 모델 및 기계부품용 원형에 사용되는 것을 특징으로 하는 제 8 항의 3차원 물품의 용도.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP11144599A JP4350832B2 (ja) | 1999-04-19 | 1999-04-19 | 立体造形用光硬化性樹脂組成物およびこれを硬化してなる造形物 |
JPJP-P-1999-00111445 | 1999-04-19 |
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KR20020006705A true KR20020006705A (ko) | 2002-01-24 |
KR100735409B1 KR100735409B1 (ko) | 2007-07-04 |
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KR1020017013335A KR100735409B1 (ko) | 1999-04-19 | 2000-04-19 | 입체 형상물의 광조형용 수지조성물 |
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US (3) | US20020132872A1 (ko) |
EP (1) | EP1171502B2 (ko) |
JP (1) | JP4350832B2 (ko) |
KR (1) | KR100735409B1 (ko) |
CN (1) | CN1234049C (ko) |
AT (1) | ATE364649T1 (ko) |
DE (1) | DE60035189T3 (ko) |
ES (1) | ES2288849T5 (ko) |
HK (1) | HK1046006B (ko) |
WO (1) | WO2000063272A1 (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20160044192A (ko) * | 2014-10-15 | 2016-04-25 | 동우 화인켐 주식회사 | 입체 조형용 광경화성 수지 조성물 |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4350832B2 (ja) † | 1999-04-19 | 2009-10-21 | Jsr株式会社 | 立体造形用光硬化性樹脂組成物およびこれを硬化してなる造形物 |
GB9921779D0 (en) | 1999-09-16 | 1999-11-17 | Ciba Sc Holding Ag | UV-Curable compositions |
WO2001095030A2 (en) * | 2000-06-09 | 2001-12-13 | Dsm N.V. | Resin composition and three-dimensional object |
US6794451B2 (en) | 2001-02-13 | 2004-09-21 | Toagosei Co., Ltd. | Cationically polymerizable liquid composition and tacky polymer |
JP3986060B2 (ja) * | 2001-12-28 | 2007-10-03 | キヤノン株式会社 | インクジェット記録ヘッドの流路構成部材及びインクジェット記録ヘッドの製造方法 |
US20030198824A1 (en) * | 2002-04-19 | 2003-10-23 | Fong John W. | Photocurable compositions containing reactive polysiloxane particles |
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- 2000-04-19 EP EP00921184.8A patent/EP1171502B2/en not_active Expired - Lifetime
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KR20160044192A (ko) * | 2014-10-15 | 2016-04-25 | 동우 화인켐 주식회사 | 입체 조형용 광경화성 수지 조성물 |
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EP1171502B1 (en) | 2007-06-13 |
US20020132872A1 (en) | 2002-09-19 |
EP1171502B2 (en) | 2017-07-05 |
JP2000302964A (ja) | 2000-10-31 |
ATE364649T1 (de) | 2007-07-15 |
DE60035189D1 (de) | 2007-07-26 |
ES2288849T3 (es) | 2008-02-01 |
HK1046006B (zh) | 2006-08-25 |
CN1234049C (zh) | 2005-12-28 |
JP4350832B2 (ja) | 2009-10-21 |
KR100735409B1 (ko) | 2007-07-04 |
DE60035189T2 (de) | 2008-02-21 |
ES2288849T5 (es) | 2017-11-17 |
US20070043138A1 (en) | 2007-02-22 |
US20050171255A1 (en) | 2005-08-04 |
CN1354763A (zh) | 2002-06-19 |
WO2000063272A1 (en) | 2000-10-26 |
EP1171502A1 (en) | 2002-01-16 |
DE60035189T3 (de) | 2017-10-26 |
HK1046006A1 (en) | 2002-12-20 |
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