KR19980033355A - 메탈로센 - Google Patents

메탈로센 Download PDF

Info

Publication number
KR19980033355A
KR19980033355A KR1019970056779A KR19970056779A KR19980033355A KR 19980033355 A KR19980033355 A KR 19980033355A KR 1019970056779 A KR1019970056779 A KR 1019970056779A KR 19970056779 A KR19970056779 A KR 19970056779A KR 19980033355 A KR19980033355 A KR 19980033355A
Authority
KR
South Korea
Prior art keywords
tetrahydroindenyl
zirconium dichloride
metallocene
dichloride
dimethylsilanediylbis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
KR1019970056779A
Other languages
English (en)
Korean (ko)
Inventor
휘브셔에리히
젠크롤란트
Original Assignee
아울미히게르하르트
훽스트아크티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7809754&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR19980033355(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 아울미히게르하르트, 훽스트아크티엔게젤샤프트 filed Critical 아울미히게르하르트
Publication of KR19980033355A publication Critical patent/KR19980033355A/ko
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1019970056779A 1996-10-31 1997-10-31 메탈로센 Withdrawn KR19980033355A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19644039A DE19644039A1 (de) 1996-10-31 1996-10-31 Metallocene
DE19644039.4 1996-10-31

Publications (1)

Publication Number Publication Date
KR19980033355A true KR19980033355A (ko) 1998-07-25

Family

ID=7809754

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970056779A Withdrawn KR19980033355A (ko) 1996-10-31 1997-10-31 메탈로센

Country Status (9)

Country Link
US (1) US6153549A (enExample)
EP (2) EP0839823B2 (enExample)
JP (1) JP4361975B2 (enExample)
KR (1) KR19980033355A (enExample)
CN (1) CN1181386A (enExample)
AT (2) ATE256136T1 (enExample)
BR (1) BR9705187A (enExample)
DE (3) DE19644039A1 (enExample)
ES (1) ES2213193T3 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100425633B1 (ko) * 1999-11-16 2004-04-03 리서치 인스티튜트 오브 페트롤리움 프로세싱, 시노펙. 메탈로센 부가물, 이의 제조 방법 및 올레핀중합반응에서의 이의 용도
KR20180075317A (ko) * 2016-12-26 2018-07-04 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 올레핀계 중합체의 제조 방법
KR20200064245A (ko) * 2018-11-28 2020-06-08 주식회사 엘지화학 혼성 담지 촉매
US10865260B2 (en) 2017-01-25 2020-12-15 Lg Chem, Ltd. Supported hybrid catalyst

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
EP1298148A1 (en) * 2001-09-27 2003-04-02 Atofina Research S.A. Catalyst component comprising a metallocene with two tetrahydroindenyl ligands for producing a polyolefin
DE50201084D1 (de) * 2001-12-11 2004-10-28 Crompton Gmbh Verfahren zur Hydrierung von ungesättigten Übergangsmetallverbindungen
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7176158B2 (en) 2002-10-25 2007-02-13 Exxonmobil Chemical Patents Inc. Polymerization catalyst composition
EP1464657A1 (en) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenated metallocene catalyst
JP5175575B2 (ja) * 2007-02-26 2013-04-03 三井化学株式会社 遷移金属化合物及び該遷移金属化合物を含んでなる重合用触媒
JP5620986B2 (ja) 2009-06-16 2014-11-05 シェブロン フィリップス ケミカル カンパニー エルピー メタロセン−ssa触媒系を用いたアルファオレフィンのオリゴマー化および得られたポリアルファオレフィンの潤滑剤ブレンドを製造するための使用
US20110082323A1 (en) * 2009-10-06 2011-04-07 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems
RU2510646C2 (ru) * 2012-06-26 2014-04-10 Дэлим Индастриал Ко, Лтд. Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина
CN103509060B (zh) * 2012-06-27 2016-08-10 大林产业株式会社 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法
KR102028063B1 (ko) * 2014-12-22 2019-10-02 주식회사 엘지화학 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀 중합체의 제조 방법
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
US9932423B2 (en) 2015-09-24 2018-04-03 Exxonmobil Chemical Patents Inc. Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such
KR101924198B1 (ko) 2015-12-23 2018-11-30 주식회사 엘지화학 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체
EP3312201B1 (en) * 2016-01-27 2019-12-25 LG Chem, Ltd. Supported hybrid catalyst and method for preparing olefin polymer using the same
KR101950462B1 (ko) * 2016-02-24 2019-02-20 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
US9758600B1 (en) 2016-05-25 2017-09-12 Chevron Phillips Chemical Company Lp Bicyclic bridged metallocene compounds and polymers produced therefrom
US9758540B1 (en) 2016-05-25 2017-09-12 Chevron Phillips Chemical Company Lp Bicyclic bridged metallocene compounds and polymers produced therefrom
WO2018045020A1 (en) 2016-08-30 2018-03-08 W.R. Grace & Co. - Conn Catalyst system for the production of polyolefins and method of making and using same
KR102140260B1 (ko) * 2016-12-22 2020-07-31 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
WO2018117408A1 (ko) * 2016-12-22 2018-06-28 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
WO2018139874A1 (ko) * 2017-01-25 2018-08-02 주식회사 엘지화학 혼성 담지 촉매

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02500870A (ja) * 1987-08-04 1990-03-22 クローライド サイレント パワー リミテッド アルカリ金属エネルギ変換装置の為のアルカリ金属電極容器を充填して封止する装置及びアルカリ金属エネルギ変換装置の為のアルカリ金属電極容器を充填する方法
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
EP0485821B1 (de) * 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
DE69201180T2 (de) 1991-10-21 1995-06-14 Mitsubishi Petrochemical Co Propylencopolymerzusammensetzung.
JP3293927B2 (ja) * 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT1272923B (it) * 1995-01-23 1997-07-01 Spherilene Srl Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100425633B1 (ko) * 1999-11-16 2004-04-03 리서치 인스티튜트 오브 페트롤리움 프로세싱, 시노펙. 메탈로센 부가물, 이의 제조 방법 및 올레핀중합반응에서의 이의 용도
KR20180075317A (ko) * 2016-12-26 2018-07-04 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 올레핀계 중합체의 제조 방법
US10865260B2 (en) 2017-01-25 2020-12-15 Lg Chem, Ltd. Supported hybrid catalyst
KR20200064245A (ko) * 2018-11-28 2020-06-08 주식회사 엘지화학 혼성 담지 촉매

Also Published As

Publication number Publication date
ATE256136T1 (de) 2003-12-15
BR9705187A (pt) 1999-12-14
DE19644039A1 (de) 1998-05-07
ATE353333T1 (de) 2007-02-15
EP0839823B1 (de) 2003-12-10
EP1325926B1 (de) 2007-02-07
EP1325926A3 (de) 2003-07-16
DE59712813D1 (de) 2007-03-22
DE59711103D1 (de) 2004-01-22
EP0839823A2 (de) 1998-05-06
EP1325926A2 (de) 2003-07-09
EP0839823B2 (de) 2008-01-09
ES2213193T3 (es) 2004-08-16
CN1181386A (zh) 1998-05-13
EP0839823A3 (de) 1999-03-31
US6153549A (en) 2000-11-28
JPH10158287A (ja) 1998-06-16
JP4361975B2 (ja) 2009-11-11

Similar Documents

Publication Publication Date Title
US6153549A (en) Metallocenes
JP4371573B2 (ja) メタロセンの合成方法
US5532396A (en) Metallocene compound
US5543373A (en) Metallocene compound
US6218489B1 (en) Polymerization process using a monocyclopentadienyl compound as a catalyst component
JP3402473B2 (ja) オレフィン重合用触媒
US6242544B1 (en) Metallocenes containing aryl-substituted indenyl ligands and their use as catalysts
DE60226010T2 (de) Mehrkerniger metallocenkatalysator
EP0604908B1 (en) Process for the polymerisation of alpha-olefins using metallocene compounds having ligands of fluorenylic type
JPH05345793A (ja) ブリッジのあるキラルなメタロセン、その製造方法およびそれの触媒としての用途
US5840947A (en) Organometallic compound
JP4165720B2 (ja) メタロセン化合物
JP3751361B2 (ja) 有機金属化合物
EP0553491B1 (en) Catalyst for polymerization of olefins and process for production of olefin polymers
JP4145964B2 (ja) 遷移金属化合物
US5880302A (en) Organometallic compound
JPH09132584A (ja) メタロセン化合物
JPH08231573A (ja) メタロセン化合物及び触媒成分としてのその使用
RU2161621C2 (ru) Способ получения металлоценов с мостиковыми связями
US6319874B1 (en) Method for producing metallocenes
US6281153B1 (en) Catalysts based on fulvene metal complexes
US6537943B1 (en) Catalyst system composed of metallocenes comprising substituents containing fluorine
KR19980032830A (ko) 입체강성 메탈로센 화합물
RU2156253C2 (ru) Каталитическая композиция, металлоценовый комплекс и способ полимеризации олефинов
JP2000502678A (ja) 遷移金属化合物、その調製法及び触媒成分としてのその使用法

Legal Events

Date Code Title Description
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19971031

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid