CN1181386A - 金属茂 - Google Patents
金属茂 Download PDFInfo
- Publication number
- CN1181386A CN1181386A CN97121273A CN97121273A CN1181386A CN 1181386 A CN1181386 A CN 1181386A CN 97121273 A CN97121273 A CN 97121273A CN 97121273 A CN97121273 A CN 97121273A CN 1181386 A CN1181386 A CN 1181386A
- Authority
- CN
- China
- Prior art keywords
- indenyl
- tetrahydro indenyl
- metallocenes
- dimethylsilane
- bases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 title claims description 11
- 229910052751 metal Inorganic materials 0.000 title claims description 6
- 239000002184 metal Substances 0.000 title claims description 6
- -1 Siliciumatom Chemical group 0.000 claims description 102
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 claims description 68
- 238000005984 hydrogenation reaction Methods 0.000 claims description 47
- 239000002904 solvent Substances 0.000 claims description 20
- KUNZSLJMPCDOGI-UHFFFAOYSA-L [Cl-].[Cl-].[Hf+2] Chemical compound [Cl-].[Cl-].[Hf+2] KUNZSLJMPCDOGI-UHFFFAOYSA-L 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- 239000003054 catalyst Substances 0.000 claims description 13
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 9
- 229920000098 polyolefin Polymers 0.000 claims description 8
- 150000001721 carbon Chemical group 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 235000010290 biphenyl Nutrition 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- 229910052735 hafnium Inorganic materials 0.000 claims description 4
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims description 2
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 125000002577 pseudohalo group Chemical group 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- WNFNPZDRWHGMMV-UHFFFAOYSA-N 5-phenyl-6-propan-2-ylidenecyclohexa-1,3-diene Chemical compound CC(C)=C1C=CC=CC1C1=CC=CC=C1 WNFNPZDRWHGMMV-UHFFFAOYSA-N 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 33
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 18
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 16
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 14
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 13
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- 125000002524 organometallic group Chemical group 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- UCIKZESDXASJNG-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC=C2C([Zr+2])C=CC2=C1 Chemical class [Cl-].[Cl-].C1=CC=C2C([Zr+2])C=CC2=C1 UCIKZESDXASJNG-UHFFFAOYSA-L 0.000 description 8
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 8
- 150000003254 radicals Chemical group 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229910052763 palladium Inorganic materials 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical compound C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 4
- 239000003849 aromatic solvent Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 239000012442 inert solvent Substances 0.000 description 3
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- AFZZYIJIWUTJFO-UHFFFAOYSA-N 1,3-diethylbenzene Chemical compound CCC1=CC=CC(CC)=C1 AFZZYIJIWUTJFO-UHFFFAOYSA-N 0.000 description 2
- DSNHSQKRULAAEI-UHFFFAOYSA-N 1,4-Diethylbenzene Chemical compound CCC1=CC=C(CC)C=C1 DSNHSQKRULAAEI-UHFFFAOYSA-N 0.000 description 2
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 2
- JRLPEMVDPFPYPJ-UHFFFAOYSA-N 1-ethyl-4-methylbenzene Chemical compound CCC1=CC=C(C)C=C1 JRLPEMVDPFPYPJ-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- ZLCSFXXPPANWQY-UHFFFAOYSA-N 3-ethyltoluene Chemical compound CCC1=CC=CC(C)=C1 ZLCSFXXPPANWQY-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- HJYFEVJAUMKYSP-UHFFFAOYSA-L Cl[Zr]Cl.CCC1=CC2=C(C=CC=C2[CH]1)C1=CC=CC2=CC=CC=C12 Chemical class Cl[Zr]Cl.CCC1=CC2=C(C=CC=C2[CH]1)C1=CC=CC2=CC=CC=C12 HJYFEVJAUMKYSP-UHFFFAOYSA-L 0.000 description 2
- DZETZMSAJDMAKS-UHFFFAOYSA-L Cl[Zr]Cl.[CH]1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical class Cl[Zr]Cl.[CH]1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 DZETZMSAJDMAKS-UHFFFAOYSA-L 0.000 description 2
- PATLRDHGHBZQMP-UHFFFAOYSA-L Cl[Zr]Cl.[CH]1C(CC)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical class Cl[Zr]Cl.[CH]1C(CC)=CC2=C1C=CC=C2C1=CC=CC=C1 PATLRDHGHBZQMP-UHFFFAOYSA-L 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- VNVUTMPEJGCDNY-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC=C2C([Zr+2])C(CC)=CC2=C1 Chemical class [Cl-].[Cl-].C1=CC=C2C([Zr+2])C(CC)=CC2=C1 VNVUTMPEJGCDNY-UHFFFAOYSA-L 0.000 description 2
- DDDRMZMSFMQPPC-UHFFFAOYSA-L [Cl-].[Cl-].C1C=CC=C2C([Zr+2])CCC21 Chemical class [Cl-].[Cl-].C1C=CC=C2C([Zr+2])CCC21 DDDRMZMSFMQPPC-UHFFFAOYSA-L 0.000 description 2
- YKIOKAURTKXMSB-UHFFFAOYSA-N adams's catalyst Chemical compound O=[Pt]=O YKIOKAURTKXMSB-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000005695 dehalogenation reaction Methods 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- COSHNDIHSFYGTR-UHFFFAOYSA-L difluorozirconium Chemical class F[Zr]F COSHNDIHSFYGTR-UHFFFAOYSA-L 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 125000005574 norbornylene group Chemical group 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000012725 vapour phase polymerization Methods 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 1
- JPSHILHGDRCOQO-UHFFFAOYSA-L C1=CC=C2C([Hf](Cl)Cl)C=CC2=C1 Chemical compound C1=CC=C2C([Hf](Cl)Cl)C=CC2=C1 JPSHILHGDRCOQO-UHFFFAOYSA-L 0.000 description 1
- ZLCKIPYPLWPTHJ-UHFFFAOYSA-L CC(C)=[Hf](Cl)(Cl)(C1C=CC=C1)C1C=CC2=CC=CC=C12 Chemical compound CC(C)=[Hf](Cl)(Cl)(C1C=CC=C1)C1C=CC2=CC=CC=C12 ZLCKIPYPLWPTHJ-UHFFFAOYSA-L 0.000 description 1
- KPWMGUMUJVLSHH-UHFFFAOYSA-L CC(C)=[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC2=CC=CC=C12 Chemical compound CC(C)=[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC2=CC=CC=C12 KPWMGUMUJVLSHH-UHFFFAOYSA-L 0.000 description 1
- NHIBUQUQWHOPGV-UHFFFAOYSA-N CN(C)C.[Pb+2] Chemical compound CN(C)C.[Pb+2] NHIBUQUQWHOPGV-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical compound CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- PZJTWYQQMINEHH-UHFFFAOYSA-L [Cl-].[Cl-].C(C)C=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Hf+2] Chemical compound [Cl-].[Cl-].C(C)C=1C(C2=CC=CC(=C2C1)C1=CC=CC=C1)[Hf+2] PZJTWYQQMINEHH-UHFFFAOYSA-L 0.000 description 1
- FIKDKWMGFNSEMI-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC=C2C(C3=CC=CC4=C3C=C(C4[Zr+2])C)=CC=CC2=C1 Chemical class [Cl-].[Cl-].C1=CC=C2C(C3=CC=CC4=C3C=C(C4[Zr+2])C)=CC=CC2=C1 FIKDKWMGFNSEMI-UHFFFAOYSA-L 0.000 description 1
- IJWJAVHBOCRHSP-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC=C2C([Zr+2])C(C)=CC2=C1 Chemical compound [Cl-].[Cl-].C1=CC=C2C([Zr+2])C(C)=CC2=C1 IJWJAVHBOCRHSP-UHFFFAOYSA-L 0.000 description 1
- QWNLZLFPURFXNX-UHFFFAOYSA-L [Cl-].[Cl-].C1CCCC2=C1C([Zr+2])C=C2 Chemical compound [Cl-].[Cl-].C1CCCC2=C1C([Zr+2])C=C2 QWNLZLFPURFXNX-UHFFFAOYSA-L 0.000 description 1
- PCTAZFGBOWDFMH-UHFFFAOYSA-L [Cl-].[Cl-].CC1(C=CC=C1)[Zr+2]C1C(=CC2=CC=CC=C12)C Chemical compound [Cl-].[Cl-].CC1(C=CC=C1)[Zr+2]C1C(=CC2=CC=CC=C12)C PCTAZFGBOWDFMH-UHFFFAOYSA-L 0.000 description 1
- IOBGXXQUZFZDNL-UHFFFAOYSA-L [Cl-].[Cl-].CC1=Cc2ccccc2C1[Hf++] Chemical compound [Cl-].[Cl-].CC1=Cc2ccccc2C1[Hf++] IOBGXXQUZFZDNL-UHFFFAOYSA-L 0.000 description 1
- VEJIZCSMDMOWNM-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC2=CC=CC=C12)[Hf+2] Chemical compound [Cl-].[Cl-].CC=1C(C2=CC=CC(=C2C1)C1=CC=CC2=CC=CC=C12)[Hf+2] VEJIZCSMDMOWNM-UHFFFAOYSA-L 0.000 description 1
- QTGOARPMGWBLFG-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C=2CCCCC=2C=1)[Hf+2] Chemical compound [Cl-].[Cl-].CC=1C(C=2CCCCC=2C=1)[Hf+2] QTGOARPMGWBLFG-UHFFFAOYSA-L 0.000 description 1
- MPOPEWWQMXWSJQ-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(C=2CCCCC=2C=1)[Zr+2] Chemical compound [Cl-].[Cl-].CC=1C(C=2CCCCC=2C=1)[Zr+2] MPOPEWWQMXWSJQ-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- SSLYIXHGTXGSJZ-UHFFFAOYSA-L cyclopentane;dichlorozirconium;indene Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.C1=CC=C[C]2[CH][CH][CH][C]21 SSLYIXHGTXGSJZ-UHFFFAOYSA-L 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 150000002362 hafnium Chemical class 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- DPUXQWOMYBMHRN-UHFFFAOYSA-N hexa-2,3-diene Chemical compound CCC=C=CC DPUXQWOMYBMHRN-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- SGZHLLQPCVCEDC-UHFFFAOYSA-L magnesium;bromide;chloride Chemical compound Cl[Mg]Br SGZHLLQPCVCEDC-UHFFFAOYSA-L 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical group CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910003446 platinum oxide Inorganic materials 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Substances C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19644039.4 | 1996-10-31 | ||
| DE19644039A DE19644039A1 (de) | 1996-10-31 | 1996-10-31 | Metallocene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1181386A true CN1181386A (zh) | 1998-05-13 |
Family
ID=7809754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97121273A Pending CN1181386A (zh) | 1996-10-31 | 1997-10-30 | 金属茂 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6153549A (enExample) |
| EP (2) | EP1325926B1 (enExample) |
| JP (1) | JP4361975B2 (enExample) |
| KR (1) | KR19980033355A (enExample) |
| CN (1) | CN1181386A (enExample) |
| AT (2) | ATE256136T1 (enExample) |
| BR (1) | BR9705187A (enExample) |
| DE (3) | DE19644039A1 (enExample) |
| ES (1) | ES2213193T3 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509060A (zh) * | 2012-06-27 | 2014-01-15 | 大林产业株式会社 | 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法 |
| CN109071701A (zh) * | 2017-01-25 | 2018-12-21 | Lg化学株式会社 | 负载型混杂催化剂 |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19922020A1 (de) * | 1999-05-12 | 2000-11-16 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| KR100425633B1 (ko) * | 1999-11-16 | 2004-04-03 | 리서치 인스티튜트 오브 페트롤리움 프로세싱, 시노펙. | 메탈로센 부가물, 이의 제조 방법 및 올레핀중합반응에서의 이의 용도 |
| EP1298148A1 (en) * | 2001-09-27 | 2003-04-02 | Atofina Research S.A. | Catalyst component comprising a metallocene with two tetrahydroindenyl ligands for producing a polyolefin |
| EP1319665B1 (de) * | 2001-12-11 | 2004-09-22 | Crompton GmbH | Verfahren zur Hydrierung von ungesättigten Übergangsmetallverbindungen |
| EP2261292B1 (en) | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7176158B2 (en) | 2002-10-25 | 2007-02-13 | Exxonmobil Chemical Patents Inc. | Polymerization catalyst composition |
| EP1464657A1 (en) * | 2003-03-06 | 2004-10-06 | ATOFINA Research | Hydrogenated metallocene catalyst |
| JP5175575B2 (ja) * | 2007-02-26 | 2013-04-03 | 三井化学株式会社 | 遷移金属化合物及び該遷移金属化合物を含んでなる重合用触媒 |
| MX362816B (es) | 2009-06-16 | 2019-02-15 | Chevron Phillips Chemical Co Lp | Oligomerizacion de alfa olefinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes. |
| US20110082323A1 (en) * | 2009-10-06 | 2011-04-07 | Chevron Phillips Chemical Company Lp | Oligomerization of olefin waxes using metallocene-based catalyst systems |
| RU2510646C2 (ru) * | 2012-06-26 | 2014-04-10 | Дэлим Индастриал Ко, Лтд. | Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина |
| KR102028063B1 (ko) * | 2014-12-22 | 2019-10-02 | 주식회사 엘지화학 | 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀 중합체의 제조 방법 |
| US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
| US9932423B2 (en) | 2015-09-24 | 2018-04-03 | Exxonmobil Chemical Patents Inc. | Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such |
| KR101924198B1 (ko) | 2015-12-23 | 2018-11-30 | 주식회사 엘지화학 | 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체 |
| EP3312201B1 (en) * | 2016-01-27 | 2019-12-25 | LG Chem, Ltd. | Supported hybrid catalyst and method for preparing olefin polymer using the same |
| KR101950462B1 (ko) | 2016-02-24 | 2019-02-20 | 주식회사 엘지화학 | 올레핀 중합체 및 이의 제조 방법 |
| US9758600B1 (en) | 2016-05-25 | 2017-09-12 | Chevron Phillips Chemical Company Lp | Bicyclic bridged metallocene compounds and polymers produced therefrom |
| US9758540B1 (en) | 2016-05-25 | 2017-09-12 | Chevron Phillips Chemical Company Lp | Bicyclic bridged metallocene compounds and polymers produced therefrom |
| JP7536447B2 (ja) | 2016-08-30 | 2024-08-20 | ダブリュー・アール・グレース・アンド・カンパニー－コーン | 低灰含量を有するポリオレフィン及び同ポリオレフィンを作製する方法 |
| WO2018117408A1 (ko) * | 2016-12-22 | 2018-06-28 | 주식회사 엘지화학 | 올레핀 중합체 및 이의 제조 방법 |
| KR102140260B1 (ko) * | 2016-12-22 | 2020-07-31 | 주식회사 엘지화학 | 올레핀 중합체 및 이의 제조 방법 |
| KR102204962B1 (ko) * | 2016-12-26 | 2021-01-18 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 올레핀계 중합체의 제조 방법 |
| WO2018139874A1 (ko) * | 2017-01-25 | 2018-08-02 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| KR102612917B1 (ko) * | 2018-11-28 | 2023-12-12 | 주식회사 엘지화학 | 혼성 담지 촉매 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5024675A (en) * | 1987-08-03 | 1991-06-18 | Chloride Silent Power Limited | Apparatus for filling and sealing alkali metal electrode containers for alkali metal energy conversion devices and method of filling alkali metal electrode containers for alkali metal energy conversion devices |
| US5017714A (en) * | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5120867A (en) * | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| IL89525A0 (en) * | 1988-03-21 | 1989-09-10 | Exxon Chemical Patents Inc | Silicon-bridged transition metal compounds |
| ES2090209T3 (es) * | 1990-11-12 | 1996-10-16 | Hoechst Ag | Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores. |
| DE4039451A1 (de) * | 1990-12-11 | 1992-06-17 | Hoechst Ag | Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren |
| EP0538749B1 (en) † | 1991-10-21 | 1995-01-11 | Mitsubishi Petrochemical Co., Ltd. | Propylene copolymer composition |
| JP3293927B2 (ja) * | 1993-02-19 | 2002-06-17 | 三菱化学株式会社 | α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法 |
| IT1273420B (it) * | 1994-04-06 | 1997-07-08 | Spherilene Srl | Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| IT1272923B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
-
1996
- 1996-10-31 DE DE19644039A patent/DE19644039A1/de not_active Withdrawn
-
1997
- 1997-10-27 ES ES97118616T patent/ES2213193T3/es not_active Expired - Lifetime
- 1997-10-27 AT AT97118616T patent/ATE256136T1/de not_active IP Right Cessation
- 1997-10-27 DE DE59711103T patent/DE59711103D1/de not_active Expired - Lifetime
- 1997-10-27 DE DE59712813T patent/DE59712813D1/de not_active Expired - Lifetime
- 1997-10-27 EP EP03005762A patent/EP1325926B1/de not_active Expired - Lifetime
- 1997-10-27 AT AT03005762T patent/ATE353333T1/de not_active IP Right Cessation
- 1997-10-27 EP EP97118616A patent/EP0839823B2/de not_active Expired - Lifetime
- 1997-10-30 BR BR9705187-0A patent/BR9705187A/pt not_active Application Discontinuation
- 1997-10-30 CN CN97121273A patent/CN1181386A/zh active Pending
- 1997-10-31 JP JP30086297A patent/JP4361975B2/ja not_active Expired - Lifetime
- 1997-10-31 KR KR1019970056779A patent/KR19980033355A/ko not_active Withdrawn
- 1997-10-31 US US08/962,383 patent/US6153549A/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103509060A (zh) * | 2012-06-27 | 2014-01-15 | 大林产业株式会社 | 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法 |
| CN103509060B (zh) * | 2012-06-27 | 2016-08-10 | 大林产业株式会社 | 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法 |
| CN109071701A (zh) * | 2017-01-25 | 2018-12-21 | Lg化学株式会社 | 负载型混杂催化剂 |
| US10865260B2 (en) | 2017-01-25 | 2020-12-15 | Lg Chem, Ltd. | Supported hybrid catalyst |
| CN109071701B (zh) * | 2017-01-25 | 2021-01-19 | Lg化学株式会社 | 负载型混杂催化剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0839823B2 (de) | 2008-01-09 |
| EP0839823A2 (de) | 1998-05-06 |
| DE59712813D1 (de) | 2007-03-22 |
| EP1325926A3 (de) | 2003-07-16 |
| DE19644039A1 (de) | 1998-05-07 |
| JP4361975B2 (ja) | 2009-11-11 |
| DE59711103D1 (de) | 2004-01-22 |
| ATE256136T1 (de) | 2003-12-15 |
| EP1325926B1 (de) | 2007-02-07 |
| EP1325926A2 (de) | 2003-07-09 |
| US6153549A (en) | 2000-11-28 |
| BR9705187A (pt) | 1999-12-14 |
| JPH10158287A (ja) | 1998-06-16 |
| KR19980033355A (ko) | 1998-07-25 |
| ES2213193T3 (es) | 2004-08-16 |
| ATE353333T1 (de) | 2007-02-15 |
| EP0839823A3 (de) | 1999-03-31 |
| EP0839823B1 (de) | 2003-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1181386A (zh) | 金属茂 | |
| CN1053673C (zh) | 负载催化剂体系、它的制备及其在烯烃聚合中的应用 | |
| CN1176093C (zh) | 双环戊二烯基二烯配合物 | |
| CN1068332C (zh) | 金属茂化合物 | |
| CN1169997A (zh) | 过渡金属化合物 | |
| CN1116314C (zh) | 烯烃聚合的催化剂及方法 | |
| CN1098869C (zh) | 弹性体ep(d)m共聚物的制备方法 | |
| CN1113899C (zh) | 用于烯烃聚合的催化剂及方法 | |
| CN1068329C (zh) | 金属茂化合物 | |
| CN1042340C (zh) | 制备乙烯共聚物的方法 | |
| CN1243763C (zh) | 茂金属化合物的制备方法 | |
| CN1092668C (zh) | 包含第13族金属化合物的烯烃聚合催化剂组合物及利用其的聚合方法 | |
| CN1210280C (zh) | 用于制备二烯配合物的联合法 | |
| CN1216996A (zh) | 金属茂助催化剂 | |
| CN1099426C (zh) | 用于α－烯烃聚合的催化剂 | |
| CN1198835C (zh) | 用于烯烃（共）聚合的桥连金属茂配合物 | |
| CN1105674A (zh) | 乙烯聚合物的制备方法以及由乙烯聚合物制得的产物 | |
| CN1093092A (zh) | 用于制备控制立构规正度的聚合α-烯烃的离子催化剂 | |
| CN1374973A (zh) | 用于烯烃聚合的催化剂体系及方法 | |
| CN1270595A (zh) | 改性铝氧烷催化剂活化剂 | |
| CN1878805A (zh) | 用于制备多相丙烯共聚物的多步法 | |
| CN1211996A (zh) | 载体催化剂体系 | |
| CN1062271C (zh) | 金属茂化合物 | |
| CN1101051A (zh) | 环烯烃共聚物的制备方法 | |
| CN1291986A (zh) | 双(四氢茚基)金属茂作为烯烃聚合催化剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |