DE19644039A1 - Metallocene - Google Patents

Metallocene

Info

Publication number
DE19644039A1
DE19644039A1 DE19644039A DE19644039A DE19644039A1 DE 19644039 A1 DE19644039 A1 DE 19644039A1 DE 19644039 A DE19644039 A DE 19644039A DE 19644039 A DE19644039 A DE 19644039A DE 19644039 A1 DE19644039 A1 DE 19644039A1
Authority
DE
Germany
Prior art keywords
tetrahydroindenyl
zirconium dichloride
dichloride
dimethylsilanediylbis
metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19644039A
Other languages
German (de)
English (en)
Inventor
Erich Dipl Ing Huebscher
Roland Dr Zenk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7809754&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE19644039(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to DE19644039A priority Critical patent/DE19644039A1/de
Priority to AT97118616T priority patent/ATE256136T1/de
Priority to EP03005762A priority patent/EP1325926B1/de
Priority to DE59712813T priority patent/DE59712813D1/de
Priority to ES97118616T priority patent/ES2213193T3/es
Priority to AT03005762T priority patent/ATE353333T1/de
Priority to EP97118616A priority patent/EP0839823B2/de
Priority to DE59711103T priority patent/DE59711103D1/de
Priority to BR9705187-0A priority patent/BR9705187A/pt
Priority to CN97121273A priority patent/CN1181386A/zh
Priority to US08/962,383 priority patent/US6153549A/en
Priority to JP30086297A priority patent/JP4361975B2/ja
Priority to KR1019970056779A priority patent/KR19980033355A/ko
Publication of DE19644039A1 publication Critical patent/DE19644039A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE19644039A 1996-10-31 1996-10-31 Metallocene Withdrawn DE19644039A1 (de)

Priority Applications (13)

Application Number Priority Date Filing Date Title
DE19644039A DE19644039A1 (de) 1996-10-31 1996-10-31 Metallocene
DE59711103T DE59711103D1 (de) 1996-10-31 1997-10-27 Metallocene
EP97118616A EP0839823B2 (de) 1996-10-31 1997-10-27 Metallocene
EP03005762A EP1325926B1 (de) 1996-10-31 1997-10-27 Metallocene
DE59712813T DE59712813D1 (de) 1996-10-31 1997-10-27 Metallocene
ES97118616T ES2213193T3 (es) 1996-10-31 1997-10-27 Metalocenos.
AT03005762T ATE353333T1 (de) 1996-10-31 1997-10-27 Metallocene
AT97118616T ATE256136T1 (de) 1996-10-31 1997-10-27 Metallocene
CN97121273A CN1181386A (zh) 1996-10-31 1997-10-30 金属茂
BR9705187-0A BR9705187A (pt) 1996-10-31 1997-10-30 Metalocenos.
US08/962,383 US6153549A (en) 1996-10-31 1997-10-31 Metallocenes
JP30086297A JP4361975B2 (ja) 1996-10-31 1997-10-31 メタロセン
KR1019970056779A KR19980033355A (ko) 1996-10-31 1997-10-31 메탈로센

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19644039A DE19644039A1 (de) 1996-10-31 1996-10-31 Metallocene

Publications (1)

Publication Number Publication Date
DE19644039A1 true DE19644039A1 (de) 1998-05-07

Family

ID=7809754

Family Applications (3)

Application Number Title Priority Date Filing Date
DE19644039A Withdrawn DE19644039A1 (de) 1996-10-31 1996-10-31 Metallocene
DE59711103T Expired - Lifetime DE59711103D1 (de) 1996-10-31 1997-10-27 Metallocene
DE59712813T Expired - Lifetime DE59712813D1 (de) 1996-10-31 1997-10-27 Metallocene

Family Applications After (2)

Application Number Title Priority Date Filing Date
DE59711103T Expired - Lifetime DE59711103D1 (de) 1996-10-31 1997-10-27 Metallocene
DE59712813T Expired - Lifetime DE59712813D1 (de) 1996-10-31 1997-10-27 Metallocene

Country Status (9)

Country Link
US (1) US6153549A (enExample)
EP (2) EP1325926B1 (enExample)
JP (1) JP4361975B2 (enExample)
KR (1) KR19980033355A (enExample)
CN (1) CN1181386A (enExample)
AT (2) ATE256136T1 (enExample)
BR (1) BR9705187A (enExample)
DE (3) DE19644039A1 (enExample)
ES (1) ES2213193T3 (enExample)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
KR100425633B1 (ko) * 1999-11-16 2004-04-03 리서치 인스티튜트 오브 페트롤리움 프로세싱, 시노펙. 메탈로센 부가물, 이의 제조 방법 및 올레핀중합반응에서의 이의 용도
EP1298148A1 (en) * 2001-09-27 2003-04-02 Atofina Research S.A. Catalyst component comprising a metallocene with two tetrahydroindenyl ligands for producing a polyolefin
EP1319665B1 (de) * 2001-12-11 2004-09-22 Crompton GmbH Verfahren zur Hydrierung von ungesättigten Übergangsmetallverbindungen
EP2261292B1 (en) 2002-10-15 2014-07-23 ExxonMobil Chemical Patents Inc. Polyolefin adhesive compositions
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7176158B2 (en) 2002-10-25 2007-02-13 Exxonmobil Chemical Patents Inc. Polymerization catalyst composition
EP1464657A1 (en) * 2003-03-06 2004-10-06 ATOFINA Research Hydrogenated metallocene catalyst
JP5175575B2 (ja) * 2007-02-26 2013-04-03 三井化学株式会社 遷移金属化合物及び該遷移金属化合物を含んでなる重合用触媒
MX362816B (es) 2009-06-16 2019-02-15 Chevron Phillips Chemical Co Lp Oligomerizacion de alfa olefinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
US20110082323A1 (en) * 2009-10-06 2011-04-07 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems
RU2510646C2 (ru) * 2012-06-26 2014-04-10 Дэлим Индастриал Ко, Лтд. Металлоценовое соединение, включающая его композиция катализатора и использующий его способ полимеризации олефина
CN103509060B (zh) * 2012-06-27 2016-08-10 大林产业株式会社 茂金属化合物、包含茂金属化合物的催化剂组合物以及使用茂金属化合物的烯烃聚合方法
KR102028063B1 (ko) * 2014-12-22 2019-10-02 주식회사 엘지화학 전이 금속 화합물, 이를 포함하는 촉매 조성물 및 이를 이용하는 올레핀 중합체의 제조 방법
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
US9932423B2 (en) 2015-09-24 2018-04-03 Exxonmobil Chemical Patents Inc. Hydrogenation of annulated cyclopentadienyl metal complexes and metallocene catalysts comprising such
KR101924198B1 (ko) 2015-12-23 2018-11-30 주식회사 엘지화학 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체
EP3312201B1 (en) * 2016-01-27 2019-12-25 LG Chem, Ltd. Supported hybrid catalyst and method for preparing olefin polymer using the same
KR101950462B1 (ko) 2016-02-24 2019-02-20 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
US9758600B1 (en) 2016-05-25 2017-09-12 Chevron Phillips Chemical Company Lp Bicyclic bridged metallocene compounds and polymers produced therefrom
US9758540B1 (en) 2016-05-25 2017-09-12 Chevron Phillips Chemical Company Lp Bicyclic bridged metallocene compounds and polymers produced therefrom
JP7536447B2 (ja) 2016-08-30 2024-08-20 ダブリュー・アール・グレース・アンド・カンパニー－コーン 低灰含量を有するポリオレフィン及び同ポリオレフィンを作製する方法
WO2018117408A1 (ko) * 2016-12-22 2018-06-28 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
KR102140260B1 (ko) * 2016-12-22 2020-07-31 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
KR102204962B1 (ko) * 2016-12-26 2021-01-18 주식회사 엘지화학 혼성 담지 메탈로센 촉매 및 이를 이용한 올레핀계 중합체의 제조 방법
KR102065719B1 (ko) 2017-01-25 2020-01-13 주식회사 엘지화학 혼성 담지 촉매
WO2018139874A1 (ko) * 2017-01-25 2018-08-02 주식회사 엘지화학 혼성 담지 촉매
KR102612917B1 (ko) * 2018-11-28 2023-12-12 주식회사 엘지화학 혼성 담지 촉매

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5024675A (en) * 1987-08-03 1991-06-18 Chloride Silent Power Limited Apparatus for filling and sealing alkali metal electrode containers for alkali metal energy conversion devices and method of filling alkali metal electrode containers for alkali metal energy conversion devices
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
ES2090209T3 (es) * 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
DE4039451A1 (de) * 1990-12-11 1992-06-17 Hoechst Ag Metallocene mit bicyclischen cyclopentadienderivaten als liganden, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren
EP0538749B1 (en) † 1991-10-21 1995-01-11 Mitsubishi Petrochemical Co., Ltd. Propylene copolymer composition
JP3293927B2 (ja) * 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
IT1272923B (it) * 1995-01-23 1997-07-01 Spherilene Srl Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Also Published As

Publication number Publication date
EP0839823B2 (de) 2008-01-09
EP0839823A2 (de) 1998-05-06
DE59712813D1 (de) 2007-03-22
EP1325926A3 (de) 2003-07-16
JP4361975B2 (ja) 2009-11-11
CN1181386A (zh) 1998-05-13
DE59711103D1 (de) 2004-01-22
ATE256136T1 (de) 2003-12-15
EP1325926B1 (de) 2007-02-07
EP1325926A2 (de) 2003-07-09
US6153549A (en) 2000-11-28
BR9705187A (pt) 1999-12-14
JPH10158287A (ja) 1998-06-16
KR19980033355A (ko) 1998-07-25
ES2213193T3 (es) 2004-08-16
ATE353333T1 (de) 2007-02-15
EP0839823A3 (de) 1999-03-31
EP0839823B1 (de) 2003-12-10

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Legal Events

Date Code Title Description
8127 New person/name/address of the applicant

Owner name: TARGOR GMBH, 55116 MAINZ, DE

8127 New person/name/address of the applicant

Owner name: BASELL POLYOLEFINE GMBH, 77694 KEHL, DE

8127 New person/name/address of the applicant

Owner name: BASELL POLYOLEFINE GMBH, 50389 WESSELING, DE

8141 Disposal/no request for examination