KR102706325B1 - 산소 빈자리를 불소 처리하는 igzo 부동화 방법 - Google Patents
산소 빈자리를 불소 처리하는 igzo 부동화 방법 Download PDFInfo
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- KR102706325B1 KR102706325B1 KR1020187023363A KR20187023363A KR102706325B1 KR 102706325 B1 KR102706325 B1 KR 102706325B1 KR 1020187023363 A KR1020187023363 A KR 1020187023363A KR 20187023363 A KR20187023363 A KR 20187023363A KR 102706325 B1 KR102706325 B1 KR 102706325B1
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- Prior art keywords
- metal oxide
- layer
- fluorine
- oxide layer
- oxide semiconductor
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- 238000000034 method Methods 0.000 title claims abstract description 58
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 37
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 239000001301 oxygen Substances 0.000 title claims abstract description 36
- 238000002161 passivation Methods 0.000 title description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 167
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 167
- 239000011737 fluorine Substances 0.000 claims abstract description 111
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 111
- 239000007789 gas Substances 0.000 claims abstract description 100
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 83
- 239000010410 layer Substances 0.000 claims description 271
- 239000000758 substrate Substances 0.000 claims description 71
- 238000000151 deposition Methods 0.000 claims description 39
- 239000004065 semiconductor Substances 0.000 claims description 27
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 claims description 18
- 238000000137 annealing Methods 0.000 claims description 13
- 238000005530 etching Methods 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000011229 interlayer Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 5
- 238000005240 physical vapour deposition Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 229910052814 silicon oxide Inorganic materials 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 230000008021 deposition Effects 0.000 description 7
- 238000009832 plasma treatment Methods 0.000 description 7
- 238000004544 sputter deposition Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000005477 sputtering target Methods 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000005546 reactive sputtering Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 238000004299 exfoliation Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- -1 polyethylene terephthalate Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
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- General Chemical & Material Sciences (AREA)
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Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662278955P | 2016-01-14 | 2016-01-14 | |
| US62/278,955 | 2016-01-14 | ||
| US15/359,325 | 2016-11-22 | ||
| US15/359,325 US10134878B2 (en) | 2016-01-14 | 2016-11-22 | Oxygen vacancy of IGZO passivation by fluorine treatment |
| PCT/US2017/012872 WO2017123552A1 (en) | 2016-01-14 | 2017-01-10 | Oxygen vacancy of igzo passivation by fluorine treatment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20180095115A KR20180095115A (ko) | 2018-08-24 |
| KR102706325B1 true KR102706325B1 (ko) | 2024-09-12 |
Family
ID=59311423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020187023363A Active KR102706325B1 (ko) | 2016-01-14 | 2017-01-10 | 산소 빈자리를 불소 처리하는 igzo 부동화 방법 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US10134878B2 (enExample) |
| JP (2) | JP6916186B2 (enExample) |
| KR (1) | KR102706325B1 (enExample) |
| CN (1) | CN108475620B (enExample) |
| WO (1) | WO2017123552A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10224432B2 (en) * | 2017-03-10 | 2019-03-05 | Applied Materials, Inc. | Surface treatment process performed on devices for TFT applications |
| CN108281509B (zh) * | 2018-01-30 | 2020-03-17 | 电子科技大学 | 氧化物半导体基光电探测器及提高其性能的方法 |
| JP7153499B2 (ja) * | 2018-08-08 | 2022-10-14 | 東京エレクトロン株式会社 | 酸素含有被処理体の処理方法及び処理装置 |
| KR102760140B1 (ko) | 2019-02-11 | 2025-01-24 | 삼성디스플레이 주식회사 | 표시 장치 |
| KR102885296B1 (ko) | 2019-08-30 | 2025-11-12 | 삼성디스플레이 주식회사 | 표시 장치 |
| GB201913533D0 (en) | 2019-09-19 | 2019-11-06 | Univ Southampton | Optical thin films and fabrication thereof |
| US11430898B2 (en) | 2020-03-13 | 2022-08-30 | Applied Materials, Inc. | Oxygen vacancy of amorphous indium gallium zinc oxide passivation by silicon ion treatment |
| KR102752707B1 (ko) | 2020-05-29 | 2025-01-13 | 삼성디스플레이 주식회사 | 표시 장치 및 그 제조 방법 |
| TWI750902B (zh) * | 2020-11-18 | 2021-12-21 | 友達光電股份有限公司 | 薄膜電晶體及其形成方法 |
| CN113764282B (zh) * | 2021-09-03 | 2023-09-05 | 深圳市华星光电半导体显示技术有限公司 | 一种背沟道蚀刻型的薄膜电晶体及其制作方法 |
| CN114093889A (zh) * | 2021-11-02 | 2022-02-25 | Tcl华星光电技术有限公司 | 阵列基板及制备方法和显示面板 |
| CN114203556B (zh) * | 2021-12-08 | 2023-05-23 | 中山大学 | 一种用于调控氧化镓半导体表层电导的方法及半导体晶圆 |
| CN115188827B (zh) * | 2021-12-09 | 2025-05-30 | 友达光电股份有限公司 | 半导体装置及其制造方法 |
| CN114551608A (zh) * | 2022-03-09 | 2022-05-27 | 浙江理工大学 | 一种等离子处理氧化镓基日盲紫外探测器及其制备方法 |
| KR20250145032A (ko) * | 2023-02-10 | 2025-10-13 | 램 리써치 코포레이션 | 할로겐화된 유전체 산화물의 증착에서 평탄대 전압의 제어 |
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| US8143093B2 (en) * | 2008-03-20 | 2012-03-27 | Applied Materials, Inc. | Process to make metal oxide thin film transistor array with etch stopping layer |
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| WO2012083220A2 (en) * | 2010-12-16 | 2012-06-21 | The Regents Of The University Of California | Generation of highly n-type, defect passivated transition metal oxides using plasma fluorine insertion |
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| US20150140836A1 (en) * | 2013-11-18 | 2015-05-21 | Intermolecular, Inc. | Methods to Control SiO2 Etching During Fluorine Doping of Si/SiO2 Interface |
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| US10008611B2 (en) | 2014-06-26 | 2018-06-26 | Joled Inc. | Thin film transistor and organic EL display device |
| US20160155849A1 (en) * | 2014-12-02 | 2016-06-02 | Semiconductor Energy Laboratory Co., Ltd. | Semiconductor device, method for manufacturing semiconductor device, module, and electronic device |
| KR20160137843A (ko) * | 2015-05-22 | 2016-12-01 | 엘지디스플레이 주식회사 | 고신뢰성 금속 산화물 반도체 물질을 포함하는 박막 트랜지스터 기판 |
| CN105572990B (zh) * | 2015-12-21 | 2019-07-12 | 武汉华星光电技术有限公司 | 阵列基板及其制造方法、液晶显示面板 |
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| CN108475620A (zh) | 2018-08-31 |
| JP2021182630A (ja) | 2021-11-25 |
| JP2019508883A (ja) | 2019-03-28 |
| US10134878B2 (en) | 2018-11-20 |
| WO2017123552A1 (en) | 2017-07-20 |
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