KR102036398B1 - 부타다이엔을 생성하기 위한, 저공해 산화 탈수소화 방법 - Google Patents

부타다이엔을 생성하기 위한, 저공해 산화 탈수소화 방법 Download PDF

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KR102036398B1
KR102036398B1 KR1020147030264A KR20147030264A KR102036398B1 KR 102036398 B1 KR102036398 B1 KR 102036398B1 KR 1020147030264 A KR1020147030264 A KR 1020147030264A KR 20147030264 A KR20147030264 A KR 20147030264A KR 102036398 B1 KR102036398 B1 KR 102036398B1
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butadiene
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리아나 카치울라
조셉 지 더프
엘리자베쓰 발라드
마크 포터
시리샤 차다
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티피씨 그룹 엘엘씨
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/187—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147030264A 2012-03-29 2013-03-28 부타다이엔을 생성하기 위한, 저공해 산화 탈수소화 방법 Active KR102036398B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261617535P 2012-03-29 2012-03-29
US201261617506P 2012-03-29 2012-03-29
US61/617,506 2012-03-29
US61/617,535 2012-03-29
PCT/US2013/034205 WO2013148908A1 (en) 2012-03-29 2013-03-28 Low emissions oxidative dehydrogenation process for producing butadiene

Publications (2)

Publication Number Publication Date
KR20140147875A KR20140147875A (ko) 2014-12-30
KR102036398B1 true KR102036398B1 (ko) 2019-10-24

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KR1020147030267A Active KR102051168B1 (ko) 2012-03-29 2013-03-28 부타다이엔을 생성하기 위한, 제어성이 개선된 산화 탈수소화 방법
KR1020147030264A Active KR102036398B1 (ko) 2012-03-29 2013-03-28 부타다이엔을 생성하기 위한, 저공해 산화 탈수소화 방법

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US (3) US9908097B2 (enExample)
EP (2) EP2831021B1 (enExample)
JP (2) JP6157585B2 (enExample)
KR (2) KR102051168B1 (enExample)
CN (2) CN104507894B (enExample)
CA (2) CA2867635A1 (enExample)
MX (2) MX366150B (enExample)
MY (1) MY166545A (enExample)
RU (2) RU2619114C2 (enExample)
SG (2) SG11201405984TA (enExample)
WO (2) WO2013148908A1 (enExample)

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CA2867635A1 (en) 2012-03-29 2013-10-03 Tpc Group Llc Low emissions oxidative dehydrogenation process for producing butadiene
KR101676531B1 (ko) * 2013-11-21 2016-11-15 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
US10035136B2 (en) 2014-03-25 2018-07-31 Tpc Group Llc Catalyst for reduced nitrogen oxide (NOx) emissions in an oxodehydrogenation process
KR101784047B1 (ko) 2014-07-02 2017-10-10 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101782675B1 (ko) * 2014-07-02 2017-09-27 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101782674B1 (ko) * 2014-07-02 2017-09-27 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101784046B1 (ko) * 2014-07-02 2017-10-10 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
WO2016151008A1 (de) * 2015-03-26 2016-09-29 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
FR3040703B1 (fr) * 2015-09-03 2017-10-06 Ifp Energies Now Procede integre de production de butadiene a partir de butanol
RU2674664C1 (ru) * 2015-09-25 2018-12-12 Юоп Ллк Способы и установки для производства бутадиена
KR102088494B1 (ko) * 2015-11-06 2020-03-13 유오피 엘엘씨 부타디엔 제조 목적으로 알데히드를 스트리핑하기 위한 c4 흡수기 오버헤드의 사용
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WO2018095776A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wässrige wäsche des c4-produktgasstroms
WO2018095856A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine methacrolein-abtrennung bei der aufarbeitung
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KR102224278B1 (ko) 2017-04-12 2021-03-08 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법
US10543470B2 (en) * 2017-04-28 2020-01-28 Intramicron, Inc. Reactors and methods for processes involving partial oxidation reactions
WO2018234158A1 (de) 2017-06-19 2018-12-27 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wäsche des c4-produktgasstroms
JP7137920B2 (ja) * 2017-11-02 2022-09-15 旭化成株式会社 ブタジエンの製造方法
KR102262896B1 (ko) * 2017-11-30 2021-06-09 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 부타디엔 제조용 반응기 및 1,3-부타디엔의 제조방법
CN110066212B (zh) * 2018-01-22 2022-04-01 惠生工程（中国）有限公司 一种甲醇制烯烃工艺副产碳四烯烃氧化脱氢制丁二烯工艺
KR102564959B1 (ko) * 2018-08-23 2023-08-07 주식회사 엘지화학 1,3-부타디엔의 제조방법
CN110237788B (zh) * 2019-05-28 2020-05-05 宁波浙铁江宁化工有限公司 一种顺酐反应系统在线检测工艺及设备

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