KR102051168B1 - 부타다이엔을 생성하기 위한, 제어성이 개선된 산화 탈수소화 방법 - Google Patents

부타다이엔을 생성하기 위한, 제어성이 개선된 산화 탈수소화 방법 Download PDF

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KR102051168B1
KR102051168B1 KR1020147030267A KR20147030267A KR102051168B1 KR 102051168 B1 KR102051168 B1 KR 102051168B1 KR 1020147030267 A KR1020147030267 A KR 1020147030267A KR 20147030267 A KR20147030267 A KR 20147030267A KR 102051168 B1 KR102051168 B1 KR 102051168B1
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oxidative dehydrogenation
butadiene
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KR20140147876A (ko
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리아나 카치울라
조셉 지 더프
시리샤 차다
엘리자베쓰 발라드
세실 지 맥파랜드
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티피씨 그룹 엘엘씨
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/187—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147030267A 2012-03-29 2013-03-28 부타다이엔을 생성하기 위한, 제어성이 개선된 산화 탈수소화 방법 Active KR102051168B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261617506P 2012-03-29 2012-03-29
US201261617535P 2012-03-29 2012-03-29
US61/617,535 2012-03-29
US61/617,506 2012-03-29
PCT/US2013/034215 WO2013148913A1 (en) 2012-03-29 2013-03-28 Improved controllability oxidative dehydrogenation process for producing butadiene

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KR20140147876A KR20140147876A (ko) 2014-12-30
KR102051168B1 true KR102051168B1 (ko) 2019-12-02

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KR1020147030267A Active KR102051168B1 (ko) 2012-03-29 2013-03-28 부타다이엔을 생성하기 위한, 제어성이 개선된 산화 탈수소화 방법

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EP (2) EP2831021B1 (enExample)
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KR (2) KR102036398B1 (enExample)
CN (2) CN104321294B (enExample)
CA (2) CA2867635A1 (enExample)
MX (2) MX363244B (enExample)
MY (1) MY166545A (enExample)
RU (2) RU2619114C2 (enExample)
SG (2) SG11201405986VA (enExample)
WO (2) WO2013148908A1 (enExample)

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KR102036398B1 (ko) * 2012-03-29 2019-10-24 티피씨 그룹 엘엘씨 부타다이엔을 생성하기 위한, 저공해 산화 탈수소화 방법
KR101676531B1 (ko) * 2013-11-21 2016-11-15 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
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KR101782675B1 (ko) * 2014-07-02 2017-09-27 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101784046B1 (ko) * 2014-07-02 2017-10-10 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101782674B1 (ko) * 2014-07-02 2017-09-27 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101784047B1 (ko) 2014-07-02 2017-10-10 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
US10421700B2 (en) * 2015-03-26 2019-09-24 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
FR3040703B1 (fr) * 2015-09-03 2017-10-06 Ifp Energies Now Procede integre de production de butadiene a partir de butanol
MY184740A (en) * 2015-09-25 2021-04-20 Uop Llc Processes and apparatuses for production of butadiene
RU2693490C1 (ru) * 2015-11-06 2019-07-03 Юоп Ллк Использование абсорбера с4 для отпаривания альдегидов
CN108349846B (zh) * 2015-11-06 2021-05-25 环球油品公司 丁二烯生产方法中的热回收
WO2018095776A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wässrige wäsche des c4-produktgasstroms
EP3323797A1 (de) 2016-11-22 2018-05-23 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine saure wäsche des c4-produktgasstroms
WO2018095856A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine methacrolein-abtrennung bei der aufarbeitung
KR102224278B1 (ko) 2017-04-12 2021-03-08 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법
US10543470B2 (en) * 2017-04-28 2020-01-28 Intramicron, Inc. Reactors and methods for processes involving partial oxidation reactions
WO2018234158A1 (de) 2017-06-19 2018-12-27 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wäsche des c4-produktgasstroms
JP7137920B2 (ja) * 2017-11-02 2022-09-15 旭化成株式会社 ブタジエンの製造方法
KR102262896B1 (ko) * 2017-11-30 2021-06-09 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 부타디엔 제조용 반응기 및 1,3-부타디엔의 제조방법
CN110066212B (zh) * 2018-01-22 2022-04-01 惠生工程（中国）有限公司 一种甲醇制烯烃工艺副产碳四烯烃氧化脱氢制丁二烯工艺
KR102564959B1 (ko) * 2018-08-23 2023-08-07 주식회사 엘지화학 1,3-부타디엔의 제조방법
CN110237788B (zh) * 2019-05-28 2020-05-05 宁波浙铁江宁化工有限公司 一种顺酐反应系统在线检测工艺及设备

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