MX363244B - Procedimiento de deshidrogenación oxidativa de bajas emisiones para producir butadieno. - Google Patents

Procedimiento de deshidrogenación oxidativa de bajas emisiones para producir butadieno.

Info

Publication number
MX363244B
MX363244B MX2014011658A MX2014011658A MX363244B MX 363244 B MX363244 B MX 363244B MX 2014011658 A MX2014011658 A MX 2014011658A MX 2014011658 A MX2014011658 A MX 2014011658A MX 363244 B MX363244 B MX 363244B
Authority
MX
Mexico
Prior art keywords
oxidative dehydrogenation
butadiene
dehydrogenation process
low emissions
purposes
Prior art date
Application number
MX2014011658A
Other languages
English (en)
Other versions
MX2014011658A (es
Inventor
Joseph G Duff
Liana Caciula
Elizabeth Ballard
Mark Potter
Sirisha Chada
Original Assignee
Tpc Group Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tpc Group Llc filed Critical Tpc Group Llc
Publication of MX2014011658A publication Critical patent/MX2014011658A/es
Publication of MX363244B publication Critical patent/MX363244B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
    • C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/187—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

El butadieno se forma por medio de la deshidrogenación de butenos que se mezclan con vapor y oxígeno y después se convierten en butadieno por medio de deshidrogenación oxidativa sobre un catalizador de óxido ferrítico, en donde el calor sensible en el producto de reacción de deshidrogenación oxidativa se utiliza junto con el calor producido por medio de la oxidación térmica de productos volátiles de valor bajo formados para reducir los requerimientos de energía y las emisiones de CO2 el calor sensible se utiliza a alta temperatura para propósitos de supercalentar la alimentación a temperaturas de algún modo inferiores para propósitos de vaporizar la alimentación en ubicaciones secuenciales en el procedimiento.
MX2014011658A 2012-03-29 2013-03-28 Procedimiento de deshidrogenación oxidativa de bajas emisiones para producir butadieno. MX363244B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261617506P 2012-03-29 2012-03-29
US201261617535P 2012-03-29 2012-03-29
PCT/US2013/034205 WO2013148908A1 (en) 2012-03-29 2013-03-28 Low emissions oxidative dehydrogenation process for producing butadiene

Publications (2)

Publication Number Publication Date
MX2014011658A MX2014011658A (es) 2014-10-24
MX363244B true MX363244B (es) 2019-03-14

Family

ID=49261226

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2014011658A MX363244B (es) 2012-03-29 2013-03-28 Procedimiento de deshidrogenación oxidativa de bajas emisiones para producir butadieno.
MX2014011659A MX366150B (es) 2012-03-29 2013-03-28 Procedimiento de deshidrogenacion oxidativa de controlabilidad mejorada para producir butadieno.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2014011659A MX366150B (es) 2012-03-29 2013-03-28 Procedimiento de deshidrogenacion oxidativa de controlabilidad mejorada para producir butadieno.

Country Status (12)

Country Link
US (3) US9908097B2 (es)
EP (2) EP2831022B1 (es)
JP (2) JP6157585B2 (es)
KR (2) KR102036398B1 (es)
CN (2) CN104507894B (es)
CA (2) CA2867635A1 (es)
HK (1) HK1204321A1 (es)
MX (2) MX363244B (es)
MY (1) MY166545A (es)
RU (2) RU2619114C2 (es)
SG (2) SG11201405984TA (es)
WO (2) WO2013148908A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11201405984TA (en) 2012-03-29 2014-10-30 Tpc Group Llc Low emissions oxidative dehydrogenation process for producing butadiene
KR101676531B1 (ko) * 2013-11-21 2016-11-15 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
US10035136B2 (en) 2014-03-25 2018-07-31 Tpc Group Llc Catalyst for reduced nitrogen oxide (NOx) emissions in an oxodehydrogenation process
KR101784047B1 (ko) 2014-07-02 2017-10-10 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101784046B1 (ko) * 2014-07-02 2017-10-10 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101782674B1 (ko) * 2014-07-02 2017-09-27 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
KR101782675B1 (ko) * 2014-07-02 2017-09-27 주식회사 엘지화학 부타디엔 제조 공정 내 에너지 재활용 방법
EP3274320B1 (de) * 2015-03-26 2019-02-27 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
FR3040703B1 (fr) * 2015-09-03 2017-10-06 Ifp Energies Now Procede integre de production de butadiene a partir de butanol
RU2674664C1 (ru) * 2015-09-25 2018-12-12 Юоп Ллк Способы и установки для производства бутадиена
CA3001739C (en) 2015-11-06 2020-08-11 Uop Llc Use of c4 absorber for stripping aldehydes
WO2017079633A1 (en) * 2015-11-06 2017-05-11 Uop Llc Heat recovery in the process of production of butadiene
EP3323797A1 (de) 2016-11-22 2018-05-23 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine saure wäsche des c4-produktgasstroms
WO2018095776A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wässrige wäsche des c4-produktgasstroms
WO2018095856A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine methacrolein-abtrennung bei der aufarbeitung
KR102224278B1 (ko) 2017-04-12 2021-03-08 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 산화적 탈수소화용 반응기 및 산화적 탈수소화 방법
US10543470B2 (en) * 2017-04-28 2020-01-28 Intramicron, Inc. Reactors and methods for processes involving partial oxidation reactions
WO2018234158A1 (de) 2017-06-19 2018-12-27 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wäsche des c4-produktgasstroms
JP7137920B2 (ja) * 2017-11-02 2022-09-15 旭化成株式会社 ブタジエンの製造方法
KR102262896B1 (ko) * 2017-11-30 2021-06-09 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 시스템, 이를 포함하는 부타디엔 제조용 반응기 및 1,3-부타디엔의 제조방법
CN110066212B (zh) * 2018-01-22 2022-04-01 惠生工程（中国）有限公司 一种甲醇制烯烃工艺副产碳四烯烃氧化脱氢制丁二烯工艺
KR102564959B1 (ko) * 2018-08-23 2023-08-07 주식회사 엘지화학 1,3-부타디엔의 제조방법
CN110237788B (zh) * 2019-05-28 2020-05-05 宁波浙铁江宁化工有限公司 一种顺酐反应系统在线检测工艺及设备

Family Cites Families (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2444035A (en) * 1943-12-31 1948-06-29 Koppers Co Inc Process for dehydrogenating hydrocarbons using as catalyst calcium oxide on calcium carbonate
US3159588A (en) * 1960-06-15 1964-12-01 Union Oil Co Silica-zirconia-titania hydrocracking catalyst
US3207805A (en) 1960-06-17 1965-09-21 Petro Tex Chem Corp Dehydrogenation in the presence of oxygen and an ammonium halide
BE615317A (es) * 1961-03-22
US3110746A (en) * 1961-05-26 1963-11-12 Shell Oil Co Oxidative dehydrogenation of monoolefins
US3320330A (en) * 1962-04-25 1967-05-16 Standard Oil Co Process for the catalytic oxidative dehydrogenation of olefins to diolefins
US3284536A (en) 1964-01-02 1966-11-08 Petro Tex Chem Corp Dehydrogenation with magnesium ferrite
US4658074A (en) 1965-05-28 1987-04-14 Petro-Tex Chemical Corporation Catalytic oxidative dehydrogenation process
US3322847A (en) * 1965-09-02 1967-05-30 Standard Oil Co Oxidative dehydrogenation of monoolefins
US3496070A (en) 1967-11-09 1970-02-17 Petro Tex Chem Corp Purification of unsaturated hydrocarbons by extractive distillation with addition of liquid solvent to stripper overhead
US3937746A (en) 1969-09-19 1976-02-10 Petro-Tex Chemical Corporation Sulfur promoted oxidative dehydrogenation
US3925498A (en) * 1970-05-27 1975-12-09 Petro Tex Chem Corp Oxidative dehydrogenation process
US3849511A (en) * 1970-10-07 1974-11-19 Petro Tex Chem Corp Oxidative dehydrogenation with manganese ferrite catalyst
US3745194A (en) 1970-10-16 1973-07-10 Phillips Petroleum Co Oxidative dehydrogenation of paraffinic hydrocarbons
US3674887A (en) * 1970-12-24 1972-07-04 Phillips Petroleum Co Oxidative dehydrogenation process
JPS495321B1 (es) * 1970-12-25 1974-02-06
US3801670A (en) 1970-12-25 1974-04-02 Sumitomo Chemical Co Catalytic process for the production of diolefins
US3828202A (en) 1971-07-06 1974-08-06 Burroughs Corp Logic circuit using a current switch to compensate for signal deterioration
US3828101A (en) * 1971-08-26 1974-08-06 Petro Tex Chem Corp Method of preparation of ferrite catalysts
BE794908A (fr) 1972-02-03 1973-08-02 Petro Tex Chem Corp Purification de composes insatures
US3900525A (en) * 1972-05-16 1975-08-19 Petro Tex Chem Corp Manganese ferrite catalyzed oxidative dehydrogenation
US3801671A (en) 1972-05-30 1974-04-02 Phillips Petroleum Co Oxidative dehydrogenation of organic compounds
US4021500A (en) * 1972-09-13 1977-05-03 Phillips Petroleum Company Oxidative dehydrogenation system
US3887631A (en) 1973-05-14 1975-06-03 Texaco Inc Oxidative dehydrogenation of hydrocarbons
CA1034148A (en) * 1974-02-19 1978-07-04 Petro-Tex Chemical Corporation Acetylene removal process
US4644088A (en) * 1974-02-19 1987-02-17 Petro-Tex Chemical Corporation Acetylene removal process
US4658080A (en) 1974-02-19 1987-04-14 Petro-Tex Chemical Corporation Acetylene removal process
US3943185A (en) 1974-05-28 1976-03-09 Petro-Tex Chemical Corporation Diolefin production and purification
US3960767A (en) * 1974-09-03 1976-06-01 Petro-Tex Chemical Corporation Modified zinc ferrite oxidative dehydrogenation catalysts
US3953370A (en) 1974-10-16 1976-04-27 Petro-Tex Chemical Corporation Method of activating zinc ferrite oxidative dehydrogenation catalysts
US4083884A (en) * 1976-07-19 1978-04-11 Petro-Tex Chemical Corporation Calcium oxide modified zinc ferrite oxidative dehydrogenation catalysts and use
US4067921A (en) * 1976-12-06 1978-01-10 The Dow Chemical Company Primary adjunct, continuous diene process
FR2444019A1 (fr) * 1978-12-15 1980-07-11 Inst Neftekhimicheskikh Prot Procede de preparation de butadiene-1,3
US4266086A (en) 1980-02-12 1981-05-05 The B. F. Goodrich Company Process for removing α-acetylenes from diolefins
JPS5879932A (ja) * 1981-11-06 1983-05-13 Japan Synthetic Rubber Co Ltd ブタジエン又はイソプレンの精製方法
US4479025A (en) * 1982-11-22 1984-10-23 Uop Inc. Alkylaromatic hydrocarbon dehydrogenation process
US4595788A (en) * 1983-11-25 1986-06-17 Nippon Zeon Co. Ltd. Process for producing butadiene
JPS60126235A (ja) * 1983-12-14 1985-07-05 Nippon Zeon Co Ltd ブタジエンの製造方法
SU1216938A1 (ru) * 1984-08-13 1999-10-20 А.Л. Цайлингольд Способ получения бутадиена
US4740334A (en) 1987-05-29 1988-04-26 Norton Company Tower packing element with embossed surfaces
FR2630662A1 (fr) 1988-04-29 1989-11-03 Shell Int Research Catalyseur pour la deshydrogenation de composes organiques, procede pour sa preparation et son utilisation
US4973793A (en) 1989-06-08 1990-11-27 Texas Petrochemicals Corporation Oxidative dehydrogenation of amylenes
JP3371112B2 (ja) 1990-09-18 2003-01-27 ダイヤニトリックス株式会社 鉄・アンチモン含有金属酸化物触媒組成物およびその製法
US5214225A (en) * 1991-12-05 1993-05-25 Hall Stephen G Dehydrogenation process with improved heat recovery
US5772898A (en) 1994-12-21 1998-06-30 Uop Llc Hydrocarbon conversion process using novel metallo manganese oxides
US6403523B1 (en) 2000-09-18 2002-06-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the oxidative dehydrogenation of hydrocarbons
TWI262820B (en) 2002-10-03 2006-10-01 Koch Glitsch Lp Packing element for an exchange column, the method of fabrication and use thereof
US7402720B2 (en) 2002-12-19 2008-07-22 Exxonmobil Chemical Patents Inc. Distillation process for removal of methyl acetylene and/or propadiene from an olefin stream
US7205447B2 (en) 2002-12-23 2007-04-17 Exxonmobil Chemical Patents Inc. Process for removing aldehydes and/or ketones from an olefinic stream
DE10361822A1 (de) 2003-12-30 2005-08-11 Basf Ag Verfahren zur Herstellung von Butadien
DE102004061514A1 (de) * 2004-12-21 2006-07-06 Basf Ag Verfahren zur Herstellung von Butadien aus n-Butan
DE102005002127A1 (de) * 2005-01-17 2006-07-20 Basf Ag Verfahren zur Herstellung von Butadien aus n-Butan
DE102006029790A1 (de) * 2006-06-27 2008-01-03 Basf Ag Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung wenigstens eines zu dehydrierenden Kohlenwasserstoffs
KR100847206B1 (ko) 2007-05-10 2008-07-17 에스케이에너지 주식회사 아연 페라이트 촉매, 이의 제조방법 및 이를 이용한1,3-부타디엔의 제조방법
KR101508776B1 (ko) * 2008-03-28 2015-04-10 에스케이이노베이션 주식회사 연속 흐름식 2중 촉매 반응 장치를 이용하여노르말-부텐으로부터 1,3-부타디엔을 제조하는 방법
CN102046568A (zh) * 2008-04-09 2011-05-04 国际壳牌研究有限公司 改进脱氢工艺的方法
US20110245568A1 (en) * 2008-07-22 2011-10-06 Fina Technology, Inc. Dehydrogenation Reactions of N-Butene to Butadiene
JP5272657B2 (ja) * 2008-10-31 2013-08-28 三菱化学株式会社 プレート式反応器を用いた反応生成物の製造方法
KR20120015300A (ko) * 2009-04-10 2012-02-21 유니버시티 오브 써던 캘리포니아 천연 가스를 환경적으로 이산화탄소 중립 연료와 재생 탄소 공급원으로 만드는 방법
KR20120026049A (ko) * 2009-05-29 2012-03-16 미쓰비시 가가꾸 가부시키가이샤 공액 디엔의 제조 방법
JP5652151B2 (ja) * 2009-12-21 2015-01-14 三菱化学株式会社 共役ジエンの製造方法
KR101713328B1 (ko) 2010-07-20 2017-03-08 에스케이이노베이션 주식회사 혼성 망간 페라이트가 코팅된 촉매, 이의 제조방법 및 이를 이용한 1,3-부타디엔의 제조방법
SG11201405984TA (en) 2012-03-29 2014-10-30 Tpc Group Llc Low emissions oxidative dehydrogenation process for producing butadiene

Also Published As

Publication number Publication date
RU2628519C2 (ru) 2017-08-17
EP2831021A1 (en) 2015-02-04
EP2831021A4 (en) 2015-11-18
CN104507894A (zh) 2015-04-08
HK1204321A1 (en) 2015-11-13
JP6157586B2 (ja) 2017-07-05
US20170216811A1 (en) 2017-08-03
CA2870209A1 (en) 2013-10-03
EP2831022A1 (en) 2015-02-04
RU2014143514A (ru) 2016-05-20
CN104321294B (zh) 2018-03-13
KR102051168B1 (ko) 2019-12-02
MX366150B (es) 2019-06-28
US9650316B2 (en) 2017-05-16
US20150080627A1 (en) 2015-03-19
EP2831022A4 (en) 2015-11-25
KR20140147875A (ko) 2014-12-30
JP2015512417A (ja) 2015-04-27
RU2619114C2 (ru) 2017-05-12
WO2013148913A1 (en) 2013-10-03
WO2013148908A1 (en) 2013-10-03
EP2831021B1 (en) 2019-11-27
US10052608B2 (en) 2018-08-21
JP6157585B2 (ja) 2017-07-05
SG11201405986VA (en) 2014-10-30
RU2014143515A (ru) 2016-05-20
EP2831022B1 (en) 2018-11-14
US20150073184A1 (en) 2015-03-12
KR102036398B1 (ko) 2019-10-24
CN104507894B (zh) 2016-06-01
US9908097B2 (en) 2018-03-06
SG11201405984TA (en) 2014-10-30
CN104321294A (zh) 2015-01-28
MY166545A (en) 2018-07-16
JP2015514092A (ja) 2015-05-18
MX2014011659A (es) 2014-10-24
CA2867635A1 (en) 2013-10-03
MX2014011658A (es) 2014-10-24
KR20140147876A (ko) 2014-12-30

Similar Documents

Publication Publication Date Title
MX363244B (es) Procedimiento de deshidrogenación oxidativa de bajas emisiones para producir butadieno.
BR112016030951A2 (pt) Método para preparar grafeno poroso
AR075072A1 (es) Proceso para formar etileno a partir de acido acetico de manera selectiva
AR075172A1 (es) Reactor adiabatico para producir olefinas
MX2015006893A (es) Reactores y metodos para producir materiales de carbono solido.
BR112014004222A2 (pt) sistemas e métodos de torrefação que incluem oxidação catalítica e/ou reutilização de gases de combustão diretamente em um reator de torrefação, refrigerador e/ou secador/preaquecedor
AR095144A1 (es) Procedimiento para la gasificación de una materia prima carbonosa
IN2014DN00122A (es)
MY171598A (en) Externally heated microwave plasma gasifier and synthesis gas production method
WO2012009110A3 (en) Method for quenching paraffin dehydrogenation reaction in counter-current reactor
MY182262A (en) Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
WO2015004042A3 (de) Verfahren zur oxidativen dehydrierung von n-butenen zu butadien
UA116465C2 (uk) Спосіб карбонілювання
EA201690024A1 (ru) Горизонтальная система сублимации
PH12014502279B1 (en) Activated carbon manufacturing system
MY168436A (en) Apparatuses and methods for deoxygenating biomass-derived pyrolysis oil
TR201902672T4 (tr) Olefin üretimi için kimyasal dönüştürme için ısı sağlama usulü ve usulün kullanıldığı bir işlem ve sistem.
WO2011130612A3 (en) System and method for the generation of hydrogen fuel product
AR090024A1 (es) Reduccion catalitica selectiva de nox y proceso de control y aparato
PH12020500235A1 (en) Compositions, methods, and apparatuses for catalytic combustion
WO2014184287A3 (en) Process for converting a solid biomass material
WO2014122421A3 (en) Reactor and reaction method for reacting carbon monoxide and hydrogen in the presence of a carrier liquid to form a hydrocarbon product
WO2014101900A3 (zh) 一种低碳脂加氢制备乙醇的方法
WO2013159884A3 (en) Solar energy based countinuous process and reactor system for the production of an alkene by dehydrogenation of the corresponding alkane
BR112017007039A2 (pt) reator para hidrólise enzimática de um material.