KR101806758B1 - 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름 - Google Patents
내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름 Download PDFInfo
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- KR101806758B1 KR101806758B1 KR1020167018937A KR20167018937A KR101806758B1 KR 101806758 B1 KR101806758 B1 KR 101806758B1 KR 1020167018937 A KR1020167018937 A KR 1020167018937A KR 20167018937 A KR20167018937 A KR 20167018937A KR 101806758 B1 KR101806758 B1 KR 101806758B1
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- South Korea
- Prior art keywords
- polyethylene
- catalyst
- fraction
- polymerization
- radicals
- Prior art date
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- 239000000203 mixture Substances 0.000 title description 50
- -1 polyethylene Polymers 0.000 claims abstract description 228
- 239000004698 Polyethylene Substances 0.000 claims abstract description 130
- 229920000573 polyethylene Polymers 0.000 claims abstract description 129
- 239000003054 catalyst Substances 0.000 claims description 115
- 238000000034 method Methods 0.000 claims description 54
- 238000006116 polymerization reaction Methods 0.000 claims description 49
- 238000009826 distribution Methods 0.000 claims description 35
- 239000000654 additive Substances 0.000 claims description 29
- 229910052723 transition metal Inorganic materials 0.000 claims description 25
- 150000003624 transition metals Chemical class 0.000 claims description 25
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 23
- 239000005977 Ethylene Substances 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 6
- 238000010094 polymer processing Methods 0.000 claims description 6
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract description 32
- 238000001125 extrusion Methods 0.000 abstract description 13
- 230000003287 optical effect Effects 0.000 abstract description 10
- 150000003254 radicals Chemical class 0.000 description 79
- 125000004432 carbon atom Chemical group C* 0.000 description 65
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 60
- 229920000642 polymer Polymers 0.000 description 59
- 150000001875 compounds Chemical class 0.000 description 43
- 229910052757 nitrogen Inorganic materials 0.000 description 40
- 239000001257 hydrogen Substances 0.000 description 34
- 229910052739 hydrogen Inorganic materials 0.000 description 34
- 239000000047 product Substances 0.000 description 34
- 229910052736 halogen Inorganic materials 0.000 description 30
- 150000002367 halogens Chemical group 0.000 description 30
- 229910052799 carbon Inorganic materials 0.000 description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 27
- 150000002431 hydrogen Chemical class 0.000 description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 125000000217 alkyl group Chemical group 0.000 description 23
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 22
- 229910052698 phosphorus Inorganic materials 0.000 description 21
- 238000012545 processing Methods 0.000 description 21
- 125000003118 aryl group Chemical group 0.000 description 20
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 20
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 20
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 18
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 18
- 239000000460 chlorine Substances 0.000 description 18
- 229910052801 chlorine Inorganic materials 0.000 description 18
- 238000000113 differential scanning calorimetry Methods 0.000 description 18
- 125000000623 heterocyclic group Chemical group 0.000 description 17
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 16
- 150000005840 aryl radicals Chemical class 0.000 description 16
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 16
- 229910052794 bromium Inorganic materials 0.000 description 16
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 16
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 16
- 229910052731 fluorine Inorganic materials 0.000 description 16
- 239000011737 fluorine Substances 0.000 description 16
- 229910001701 hydrotalcite Inorganic materials 0.000 description 16
- 229960001545 hydrotalcite Drugs 0.000 description 16
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 15
- 125000002877 alkyl aryl group Chemical group 0.000 description 15
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- 239000003446 ligand Substances 0.000 description 15
- 229920000092 linear low density polyethylene Polymers 0.000 description 15
- 239000000843 powder Substances 0.000 description 15
- 239000004707 linear low-density polyethylene Substances 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 13
- 229910052742 iron Inorganic materials 0.000 description 13
- 239000012968 metallocene catalyst Substances 0.000 description 13
- 239000011574 phosphorus Substances 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 125000004429 atom Chemical group 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- 125000001424 substituent group Chemical group 0.000 description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 12
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 229910052717 sulfur Inorganic materials 0.000 description 11
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 10
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 10
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 10
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 10
- 239000002841 Lewis acid Substances 0.000 description 10
- 150000001336 alkenes Chemical class 0.000 description 10
- 150000001450 anions Chemical class 0.000 description 10
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 10
- 150000004698 iron complex Chemical class 0.000 description 10
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
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- 239000002184 metal Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- 238000011068 loading method Methods 0.000 description 9
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 239000012190 activator Substances 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
- IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical compound [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 8
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000005227 gel permeation chromatography Methods 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 8
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 8
- 239000000155 melt Substances 0.000 description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 8
- 102200078752 rs201827340 Human genes 0.000 description 8
- 239000000741 silica gel Substances 0.000 description 8
- 229910002027 silica gel Inorganic materials 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
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- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 6
- 239000006057 Non-nutritive feed additive Substances 0.000 description 6
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- 239000004708 Very-low-density polyethylene Substances 0.000 description 6
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 6
- 150000007517 lewis acids Chemical class 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 229920001866 very low density polyethylene Polymers 0.000 description 6
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 125000004122 cyclic group Chemical group 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 230000000737 periodic effect Effects 0.000 description 5
- 229920002959 polymer blend Polymers 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 5
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 102220517591 Methyl-CpG-binding domain protein 3-like 2B_R11C_mutation Human genes 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
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- 235000010290 biphenyl Nutrition 0.000 description 4
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- 239000011651 chromium Substances 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000010096 film blowing Methods 0.000 description 4
- 238000012685 gas phase polymerization Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 150000008040 ionic compounds Chemical class 0.000 description 4
- 229920002521 macromolecule Polymers 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 4
- 125000001624 naphthyl group Chemical group 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 102200160920 rs35304565 Human genes 0.000 description 4
- 239000011593 sulfur Chemical group 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 3
- 125000006163 5-membered heteroaryl group Chemical group 0.000 description 3
- 125000006164 6-membered heteroaryl group Chemical group 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000000041 C6-C10 aryl group Chemical group 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- XJONFIGVOQMBIP-UHFFFAOYSA-L Cl[Zr](Cl)C1C=CC=C1 Chemical compound Cl[Zr](Cl)C1C=CC=C1 XJONFIGVOQMBIP-UHFFFAOYSA-L 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007983 Tris buffer Substances 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 3
- 229910000085 borane Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
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- 238000013329 compounding Methods 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 125000000392 cycloalkenyl group Chemical group 0.000 description 3
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 125000006547 cyclononyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 3
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 3
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 description 3
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- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
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- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 2
- QPFMBZIOSGYJDE-QDNHWIQGSA-N 1,1,2,2-tetrachlorethane-d2 Chemical compound [2H]C(Cl)(Cl)C([2H])(Cl)Cl QPFMBZIOSGYJDE-QDNHWIQGSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
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- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 125000000590 4-methylphenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 2
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- 125000004008 6 membered carbocyclic group Chemical group 0.000 description 2
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- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
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- 239000007848 Bronsted acid Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08016904.8 | 2008-09-25 | ||
| EP08016904 | 2008-09-25 | ||
| PCT/EP2009/006840 WO2010034463A1 (fr) | 2008-09-25 | 2009-09-22 | Composition de lldpe à résistance au choc et films fabriqués à partir de ladite composition |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| KR1020117006931A Division KR20110061584A (ko) | 2008-09-25 | 2009-09-22 | 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름 |
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| KR20160086992A KR20160086992A (ko) | 2016-07-20 |
| KR101806758B1 true KR101806758B1 (ko) | 2017-12-07 |
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| KR1020117006931A KR20110061584A (ko) | 2008-09-25 | 2009-09-22 | 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름 |
| KR1020167018937A KR101806758B1 (ko) | 2008-09-25 | 2009-09-22 | 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름 |
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| KR1020117006931A KR20110061584A (ko) | 2008-09-25 | 2009-09-22 | 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8957158B2 (fr) |
| EP (1) | EP2361281B1 (fr) |
| JP (4) | JP2012503687A (fr) |
| KR (2) | KR20110061584A (fr) |
| CN (1) | CN102165005B (fr) |
| BR (1) | BRPI0919740B1 (fr) |
| CA (1) | CA2736413A1 (fr) |
| MX (1) | MX349957B (fr) |
| RU (1) | RU2517166C2 (fr) |
| WO (1) | WO2010034463A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210144438A (ko) * | 2020-05-22 | 2021-11-30 | 한화토탈 주식회사 | 폴리에틸렌 수지 조성물 및 이로부터 제조된 이차전지용 분리막 |
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| RU2509782C2 (ru) | 2008-09-25 | 2014-03-20 | Базелль Полиолефине Гмбх | Ударопрочная композиция лпэнп и полученные из нее пленки |
| US8957158B2 (en) | 2008-09-25 | 2015-02-17 | Basell Polyolefine Gmbh | Impact resistant LLDPE composition and films made thereof |
| EP2337811A1 (fr) * | 2008-09-25 | 2011-06-29 | Basell Polyolefine GmbH | Composition de lldpe à résistance au choc et films fabriqués à partir de ladite composition |
| CA2800056A1 (fr) * | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Compositions de melange de polyethylene |
| KR101617870B1 (ko) * | 2014-09-05 | 2016-05-03 | 주식회사 엘지화학 | 가공성이 우수한 올레핀계 중합체 |
| KR101747401B1 (ko) | 2014-12-08 | 2017-06-14 | 주식회사 엘지화학 | 가공성이 우수한 에틸렌/알파-올레핀 공중합체 |
| US10066716B2 (en) | 2015-01-28 | 2018-09-04 | Thk Co., Ltd. | Screw device |
| ES2703602T3 (es) | 2016-03-03 | 2019-03-11 | Dow Global Technologies Llc | Composición de polietileno, método para fabricar la misma, y películas fabricadas a partir de la misma |
| CN109562634A (zh) * | 2016-08-31 | 2019-04-02 | 富士胶片株式会社 | 固化性组合物、平版印刷版原版及平版印刷版的制造方法 |
| WO2018089194A1 (fr) | 2016-11-08 | 2018-05-17 | Univation Technologies, Llc | Composition de polyéthylène |
| CN109890855B (zh) | 2016-11-08 | 2022-08-09 | 尤尼威蒂恩技术有限责任公司 | 聚乙烯组合物 |
| US10543667B2 (en) * | 2016-12-30 | 2020-01-28 | Toray Plastics (America), Inc. | Easy opening metalized hermetic films and methods to manufacture the same |
| AR113247A1 (es) * | 2017-07-02 | 2020-03-11 | Braskem Sa | COPOLÍMEROS DE ETILENO a-OLEFINA CON DISTRIBUCIONES MULTIMODALES DE COMONÓMEROS Y PROCESOS PARA OBTENERLOS |
| SG11202002090SA (en) | 2017-09-11 | 2020-04-29 | Univation Tech Llc | Carbon black-containing bimodal polyethylene composition |
| EP3692079B1 (fr) | 2017-10-06 | 2024-09-04 | ExxonMobil Chemical Patents Inc. | Extrudés de polyéthylène et leur procédé de fabrication |
| WO2019124805A1 (fr) * | 2017-12-18 | 2019-06-27 | 주식회사 엘지화학 | Polymère d'oléfine, son procédé de préparation et film l'utilisant |
| KR102133030B1 (ko) * | 2017-12-18 | 2020-07-10 | 주식회사 엘지화학 | 올레핀 중합체, 이의 제조 방법, 그리고 이를 이용한 필름 |
| BR112020018814B1 (pt) | 2018-03-28 | 2023-12-12 | Univation Technologies, Llc | Composição de polietileno bimodal, método para produzir uma composição de polietileno bimodal, artigo fabricado e tampa ou fecho de garrafa |
| US20220033549A1 (en) * | 2019-01-08 | 2022-02-03 | Exxonmobil Chemical Patents Inc. | Olefin Polymerization Processes Featuring In Situ Blending of an Oil Extension |
| EP3953130B1 (fr) * | 2019-04-11 | 2024-08-14 | The Procter & Gamble Company | Article moulé par soufflage avec effets visuels |
| MX2020008168A (es) | 2019-08-06 | 2021-02-08 | Dow Global Technologies Llc | Composiciones de polietileno. |
| MX2022001400A (es) | 2019-08-06 | 2022-05-19 | Dow Global Technologies Llc | Películas multicapa que incluyen al menos cinco capas y métodos para producirlas. |
| EP4126998A1 (fr) | 2020-04-01 | 2023-02-08 | Dow Global Technologies LLC | Copolymère de polyéthylène basse densité linéaire bimodal |
| US11492429B2 (en) * | 2020-06-05 | 2022-11-08 | Formosa Plastics Corporation, U.S.A. | Long-chain branched ethylene copolymer with novel composition distribution and films formed from the same |
| EP4029914A1 (fr) * | 2021-01-14 | 2022-07-20 | Borealis AG | Composition de polyoléfine hétérophasique |
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| EP2337811A1 (fr) | 2008-09-25 | 2011-06-29 | Basell Polyolefine GmbH | Composition de lldpe à résistance au choc et films fabriqués à partir de ladite composition |
| US8957158B2 (en) | 2008-09-25 | 2015-02-17 | Basell Polyolefine Gmbh | Impact resistant LLDPE composition and films made thereof |
| RU2509782C2 (ru) | 2008-09-25 | 2014-03-20 | Базелль Полиолефине Гмбх | Ударопрочная композиция лпэнп и полученные из нее пленки |
| CA2736410A1 (fr) | 2008-09-25 | 2010-04-01 | Basell Polyolefine Gmbh | Composition de lldpe a resistance aux chocs et films fabriques a partir de ladite composition |
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-
2009
- 2009-09-22 US US13/119,697 patent/US8957158B2/en active Active
- 2009-09-22 CA CA2736413A patent/CA2736413A1/fr not_active Abandoned
- 2009-09-22 RU RU2011116217/04A patent/RU2517166C2/ru not_active IP Right Cessation
- 2009-09-22 BR BRPI0919740A patent/BRPI0919740B1/pt not_active IP Right Cessation
- 2009-09-22 WO PCT/EP2009/006840 patent/WO2010034463A1/fr active Application Filing
- 2009-09-22 KR KR1020117006931A patent/KR20110061584A/ko active Application Filing
- 2009-09-22 MX MX2011003162A patent/MX349957B/es active IP Right Grant
- 2009-09-22 KR KR1020167018937A patent/KR101806758B1/ko active IP Right Grant
- 2009-09-22 EP EP09778655A patent/EP2361281B1/fr active Active
- 2009-09-22 JP JP2011528234A patent/JP2012503687A/ja active Pending
- 2009-09-22 CN CN200980137787.3A patent/CN102165005B/zh active Active
-
2014
- 2014-09-10 JP JP2014184065A patent/JP2015014001A/ja active Pending
-
2016
- 2016-04-27 JP JP2016089821A patent/JP2016156026A/ja active Pending
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2018
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007534822A (ja) * | 2004-04-26 | 2007-11-29 | バーゼル・ポリオレフィン・ゲーエムベーハー | ポリエチレンおよびポリエチレンを製造するための触媒組成物 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210144438A (ko) * | 2020-05-22 | 2021-11-30 | 한화토탈 주식회사 | 폴리에틸렌 수지 조성물 및 이로부터 제조된 이차전지용 분리막 |
| KR102358766B1 (ko) | 2020-05-22 | 2022-02-04 | 한화토탈 주식회사 | 폴리에틸렌 수지 조성물 및 이로부터 제조된 이차전지용 분리막 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010034463A8 (fr) | 2011-04-21 |
| BRPI0919740B1 (pt) | 2019-08-27 |
| RU2517166C2 (ru) | 2014-05-27 |
| CN102165005A (zh) | 2011-08-24 |
| BRPI0919740A2 (pt) | 2015-12-08 |
| US20110212283A1 (en) | 2011-09-01 |
| MX2011003162A (es) | 2011-05-19 |
| JP2016156026A (ja) | 2016-09-01 |
| WO2010034463A1 (fr) | 2010-04-01 |
| JP2015014001A (ja) | 2015-01-22 |
| RU2011116217A (ru) | 2012-10-27 |
| CA2736413A1 (fr) | 2010-04-01 |
| MX349957B (es) | 2017-08-21 |
| KR20110061584A (ko) | 2011-06-09 |
| KR20160086992A (ko) | 2016-07-20 |
| JP6649980B2 (ja) | 2020-02-19 |
| JP2018115345A (ja) | 2018-07-26 |
| EP2361281A1 (fr) | 2011-08-31 |
| JP2012503687A (ja) | 2012-02-09 |
| CN102165005B (zh) | 2014-09-10 |
| US8957158B2 (en) | 2015-02-17 |
| EP2361281B1 (fr) | 2012-11-21 |
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