KR101763224B1 - 알칼리 금속 노출을 통해 탄소 나노튜브로부터 제조된 그래핀 나노리본 - Google Patents

알칼리 금속 노출을 통해 탄소 나노튜브로부터 제조된 그래핀 나노리본 Download PDF

Info

Publication number
KR101763224B1
KR101763224B1 KR1020127001075A KR20127001075A KR101763224B1 KR 101763224 B1 KR101763224 B1 KR 101763224B1 KR 1020127001075 A KR1020127001075 A KR 1020127001075A KR 20127001075 A KR20127001075 A KR 20127001075A KR 101763224 B1 KR101763224 B1 KR 101763224B1
Authority
KR
South Korea
Prior art keywords
graphene nanoribbons
functionalized graphene
alkali metal
carbon nanotubes
nanoribbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020127001075A
Other languages
English (en)
Korean (ko)
Other versions
KR20120039634A (ko
Inventor
제임스 엠 투어
드미트리 브이 코신킨
Original Assignee
윌리엄 마쉬 라이스 유니버시티
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 윌리엄 마쉬 라이스 유니버시티 filed Critical 윌리엄 마쉬 라이스 유니버시티
Publication of KR20120039634A publication Critical patent/KR20120039634A/ko
Application granted granted Critical
Publication of KR101763224B1 publication Critical patent/KR101763224B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20—Polycyclic condensed hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/19—Preparation by exfoliation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/194—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/06—Multi-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/06—Graphene nanoribbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/895—Manufacture, treatment, or detection of nanostructure having step or means utilizing chemical property
    • Y10S977/896—Chemical synthesis, e.g. chemical bonding or breaking

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
KR1020127001075A 2009-06-15 2010-06-11 알칼리 금속 노출을 통해 탄소 나노튜브로부터 제조된 그래핀 나노리본 Expired - Fee Related KR101763224B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US18713009P 2009-06-15 2009-06-15
US61/187,130 2009-06-15
PCT/US2010/038368 WO2010147860A1 (en) 2009-06-15 2010-06-11 Graphene nanoribbons prepared from carbon nanotubes via alkali metal exposure

Publications (2)

Publication Number Publication Date
KR20120039634A KR20120039634A (ko) 2012-04-25
KR101763224B1 true KR101763224B1 (ko) 2017-07-31

Family

ID=43356694

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020127001075A Expired - Fee Related KR101763224B1 (ko) 2009-06-15 2010-06-11 알칼리 금속 노출을 통해 탄소 나노튜브로부터 제조된 그래핀 나노리본

Country Status (10)

Country Link
US (1) US8992881B2 (enExample)
EP (1) EP2443062A4 (enExample)
JP (1) JP5613230B2 (enExample)
KR (1) KR101763224B1 (enExample)
CN (1) CN102666378B (enExample)
BR (1) BRPI1016033A2 (enExample)
CA (1) CA2765492C (enExample)
MX (1) MX2011013545A (enExample)
SG (2) SG10201403233XA (enExample)
WO (1) WO2010147860A1 (enExample)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9193879B2 (en) 2010-02-17 2015-11-24 Baker Hughes Incorporated Nano-coatings for articles
CA2813944A1 (en) 2010-10-06 2012-04-12 M-I L.L.C. Graphene-based material for shale stabilization and method of use
KR101300765B1 (ko) 2011-04-29 2013-08-29 한국교통대학교산학협력단 가용성 그라핀 용액의 제조방법
US9040013B2 (en) * 2011-08-04 2015-05-26 Baker Hughes Incorporated Method of preparing functionalized graphene
US9428383B2 (en) 2011-08-19 2016-08-30 Baker Hughes Incorporated Amphiphilic nanoparticle, composition comprising same and method of controlling oil spill using amphiphilic nanoparticle
WO2013040356A1 (en) * 2011-09-14 2013-03-21 William Marsh Rice University Solvent-based methods for production of graphene nanoribbons
KR102514830B1 (ko) 2011-09-30 2023-03-30 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극, 리튬 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전기 기기
CN104303320A (zh) 2011-10-21 2015-01-21 犹他大学研究基金会 均质多带隙装置
US9550678B2 (en) 2011-12-20 2017-01-24 Basf Se Polymeric precursors for producing graphene nanoribbons and methods for preparing them
US9441462B2 (en) 2012-01-11 2016-09-13 Baker Hughes Incorporated Nanocomposites for absorption tunable sandscreens
CN104204131A (zh) * 2012-01-27 2014-12-10 威廉马什莱斯大学 并入了磁性碳纳米带和磁性功能化碳纳米带的井筒流体和其使用方法
CN102616770B (zh) * 2012-03-28 2013-08-07 福州大学 一种水蒸气刻蚀碳纳米管制备石墨烯纳米带的方法
EP2832688A4 (en) * 2012-03-31 2015-11-25 Oceans King Lighting Science PROCESS FOR PREPARING GRAPHENE PAPER
JP6077347B2 (ja) 2012-04-10 2017-02-08 株式会社半導体エネルギー研究所 非水系二次電池用正極の製造方法
US9527043B2 (en) 2012-05-17 2016-12-27 Samsung Electronics Co., Ltd. Gas separation membrane and method of preparing the same
KR101920716B1 (ko) * 2012-05-17 2019-02-13 삼성전자주식회사 기체 분리막 및 그 제조방법
US20140004327A1 (en) * 2012-06-29 2014-01-02 The University Of Kentucky Research Foundation Few-layer graphene nanoribbon and a method of making the same
CN102757043B (zh) * 2012-08-10 2014-07-02 中国科学院苏州纳米技术与纳米仿生研究所 一种制备定向石墨烯纳米带阵列的方法
JP6207923B2 (ja) 2012-08-27 2017-10-04 株式会社半導体エネルギー研究所 二次電池用正極の製造方法
TW201431902A (zh) * 2012-11-16 2014-08-16 巴斯夫歐洲公司 用以生產石墨烯奈米帶之聚合前驅物，以及適用於製備彼等之寡伸苯基單體
CN103833023B (zh) * 2012-11-27 2015-10-28 海洋王照明科技股份有限公司 石墨烯纳米带及其制备方法
US8580658B1 (en) 2012-12-21 2013-11-12 Solan, LLC Methods for fabricating graphene device topography and devices formed therefrom
US10468152B2 (en) * 2013-02-21 2019-11-05 Global Graphene Group, Inc. Highly conducting and transparent film and process for producing same
US20140272308A1 (en) * 2013-03-15 2014-09-18 Solan, LLC Graphite-Based Devices Incorporating A Graphene Layer With A Bending Angle
US9059013B2 (en) 2013-03-21 2015-06-16 International Business Machines Corporation Self-formation of high-density arrays of nanostructures
TWI529128B (zh) * 2013-08-19 2016-04-11 長庚大學 連續微波製作石墨烯奈米帶之系統
JP6825781B2 (ja) * 2014-06-12 2021-02-03 センター ナショナル デ ラ レシェルシェ サイエンティフィック（シーエヌアールエス）Ｃｅｎｔｒｅ Ｎａｔｉｏｎａｌ Ｄｅ Ｌａ Ｒｅｃｈｅｒｃｈｅ Ｓｃｉｅｎｔｉｆｉｑｕｅ（Ｃｎｒｓ） 剥離ナノカーボン材料の水性および有機懸濁液、その作製方法及びその使用
US9840418B2 (en) 2014-06-16 2017-12-12 William Marsh Rice University Production of graphene nanoplatelets by oxidative anhydrous acidic media
CA2968886A1 (en) * 2014-11-26 2016-08-24 William Marsh Rice University Laser induced graphene hybrid materials for electronic devices
US11772975B2 (en) * 2015-12-03 2023-10-03 Global Graphene Group, Inc. Chemical-free production of graphene materials
CN105543991B (zh) * 2016-01-13 2018-06-01 郑州大学 一种螺旋结构石墨烯纤维及其制备方法和应用
CN106115675B (zh) * 2016-06-24 2018-04-17 中国科学院电工研究所 一种制备介孔石墨烯的方法
US11246962B2 (en) 2016-08-22 2022-02-15 William Marsh Rice University Neuronal scaffold-water soluble graphene for treatment of severed spinal cords and neuronal repair
US10707524B2 (en) 2016-10-19 2020-07-07 Semiconductor Energy Laboratory Co., Ltd. Graphene compound and manufacturing method thereof, electrolyte, and power storage device
JP6839355B2 (ja) * 2017-02-08 2021-03-10 富士通株式会社 グラフェンナノリボン、グラフェンナノリボンの製造方法及び半導体装置
CN107200947B (zh) * 2017-05-22 2019-08-20 成都新柯力化工科技有限公司 一种石墨烯微片导电母料及其制备方法
KR102170675B1 (ko) * 2017-06-23 2020-10-27 주식회사 엘지화학 탄소 나노튜브 섬유 집합체의 인장강도 향상 방법
US10465291B2 (en) * 2017-09-26 2019-11-05 California Institute Of Technology Method and system for growth of graphene nanostripes by plasma enhanced chemical vapor deposition
CN108190959B (zh) * 2018-01-23 2020-05-08 福州大学 一种基于熔融碱金属液插入剥离制备单层硫化钼的方法
CN108117064B (zh) * 2018-03-01 2021-07-09 上海理工大学 一种褶皱石墨烯的制备方法
CN108383110B (zh) * 2018-04-18 2020-01-10 天津大学 一种氟化石墨烯纳米带的制备方法
CN109835884B (zh) * 2019-03-27 2022-07-19 王奉瑾 一种利用液态金属碱制备石墨烯的方法
CN111039284A (zh) * 2020-01-17 2020-04-21 中山大学 一种超窄石墨烯纳米带的制备方法
CN115650213A (zh) * 2022-06-28 2023-01-31 重庆大学 一种高单晶纯单层石墨烯纳米带阵列及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008515654A (ja) 2004-10-12 2008-05-15 ナノシス・インク． 導電性ポリマー及び半導体ナノワイヤに基づいてプラスチック電子部品を製造するための完全に集積化された有機層プロセス
US8481421B2 (en) * 2007-07-25 2013-07-09 California Institute Of Technology Functional anchors connecting graphene-like carbon to metal
TW201012749A (en) * 2008-08-19 2010-04-01 Univ Rice William M Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
D. Kosynkin et al. Nature. 2009, Vol. 458, pp. 872-875 (2009.04.)*

Also Published As

Publication number Publication date
CN102666378A (zh) 2012-09-12
EP2443062A4 (en) 2016-04-20
US8992881B2 (en) 2015-03-31
CA2765492A1 (en) 2010-12-23
US20120197051A1 (en) 2012-08-02
WO2010147860A1 (en) 2010-12-23
KR20120039634A (ko) 2012-04-25
SG10201403233XA (en) 2014-10-30
JP2012530044A (ja) 2012-11-29
CA2765492C (en) 2018-01-02
JP5613230B2 (ja) 2014-10-22
SG176826A1 (en) 2012-01-30
CN102666378B (zh) 2017-03-01
EP2443062A1 (en) 2012-04-25
BRPI1016033A2 (pt) 2016-05-10
MX2011013545A (es) 2012-05-08

Similar Documents

Publication Publication Date Title
KR101763224B1 (ko) 알칼리 금속 노출을 통해 탄소 나노튜브로부터 제조된 그래핀 나노리본
KR101999866B1 (ko) 나노플레이트-나노튜브 복합체, 그의 생산 방법 및 그로부터 수득한 생성물
US9991391B2 (en) Pristine and functionalized graphene materials
KR101883023B1 (ko) 향상된 용해도를 나타내는 작용기화된 탄소 나노튜브 및 상기 나노튜브를 제조하는 방법
US8287699B2 (en) Production of chemically functionalized nano graphene materials
CN106660800B (zh) 剥离的纳米碳材料的水性和有机悬浮液、其制备方法及其用途
US20120295091A1 (en) Processes for fabricating films of graphene, carbon nanotubes, and other carbon nanostructures on various types of substrates
JP2016166122A (ja) 剥離したカーボンナノチューブ、その製造方法およびそれから得られる生成物
JP2005502792A (ja) 整列した単層カーボンナノチューブの繊維及びその製造方法
JP2016538228A (ja) 制御された触媒酸化による穴の多い炭素同素体の大量調製
Hu et al. One-step functionalization of graphene by cycloaddition of diarylcarbene and its application as reinforcement in epoxy composites
You et al. Green and mild oxidation: An efficient strategy toward water-dispersible graphene
Dao et al. Direct covalent modification of thermally exfoliated graphene forming functionalized graphene stably dispersible in water and poly (vinyl alcohol)
Park et al. Controlled assembly of graphene oxide nanosheets within one-dimensional polymer nanostructure
Li et al. Thermally stable and highly conductive free-standing hybrid films based on reduced graphene oxide
Maity et al. Amorphous carbon nanotube–polyaniline core–shell nanostructures for efficient cold cathode applications
ALKALI c12) United States Patent
Brozena Chemical functionalization of carbon nanotubes for controlled optical, electrical and dispersion properties
KR20160024245A (ko) 산화된 나노탄소 기반의 투명 전도성 필름의 제조방법
KR101383084B1 (ko) 기능기가 도입된 탄소나노튜브 및 그 제조방법
Moayeri Development of graphene-based polymer nanocomposites for electrical conductors and supercapacitors
Oyer Exfoliation and Chemical Modifications of Natural Flake Graphite
Rasenthiram Synthesis of Graphene Fibers for use in Supercapacitors
Cha Synthesis and Modification of Carbon Nanomaterials for Potential Device Applications
Nezakati et al. Functionalization Methods of Carbon-Based Nanomaterials

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20200726

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20200726