CN102666378B - 用碳纳米管通过接触碱金属制备的石墨烯纳米带 - Google Patents

用碳纳米管通过接触碱金属制备的石墨烯纳米带 Download PDF

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CN102666378B
CN102666378B CN201080034953.XA CN201080034953A CN102666378B CN 102666378 B CN102666378 B CN 102666378B CN 201080034953 A CN201080034953 A CN 201080034953A CN 102666378 B CN102666378 B CN 102666378B
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methods
graphene nanoribbons
metal
alkali metal
functionalized
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CN102666378A (zh
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J·M·图尔
D·V·科森金
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William Marsh Rice University
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20—Polycyclic condensed hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/19—Preparation by exfoliation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/194—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/06—Multi-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2204/00—Structure or properties of graphene
    • C01B2204/06—Graphene nanoribbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/895—Manufacture, treatment, or detection of nanostructure having step or means utilizing chemical property
    • Y10S977/896—Chemical synthesis, e.g. chemical bonding or breaking

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
CN201080034953.XA 2009-06-15 2010-06-11 用碳纳米管通过接触碱金属制备的石墨烯纳米带 Expired - Fee Related CN102666378B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US18713009P 2009-06-15 2009-06-15
US61/187,130 2009-06-15
PCT/US2010/038368 WO2010147860A1 (en) 2009-06-15 2010-06-11 Graphene nanoribbons prepared from carbon nanotubes via alkali metal exposure

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CN102666378B true CN102666378B (zh) 2017-03-01

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US (1) US8992881B2 (enExample)
EP (1) EP2443062A4 (enExample)
JP (1) JP5613230B2 (enExample)
KR (1) KR101763224B1 (enExample)
CN (1) CN102666378B (enExample)
BR (1) BRPI1016033A2 (enExample)
CA (1) CA2765492C (enExample)
MX (1) MX2011013545A (enExample)
SG (2) SG10201403233XA (enExample)
WO (1) WO2010147860A1 (enExample)

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US9040013B2 (en) * 2011-08-04 2015-05-26 Baker Hughes Incorporated Method of preparing functionalized graphene
US9428383B2 (en) 2011-08-19 2016-08-30 Baker Hughes Incorporated Amphiphilic nanoparticle, composition comprising same and method of controlling oil spill using amphiphilic nanoparticle
WO2013040356A1 (en) * 2011-09-14 2013-03-21 William Marsh Rice University Solvent-based methods for production of graphene nanoribbons
KR102514830B1 (ko) 2011-09-30 2023-03-30 가부시키가이샤 한도오따이 에네루기 켄큐쇼 양극, 리튬 이차 전지, 전기 자동차, 하이브리드 자동차, 이동체, 시스템, 및 전기 기기
CN104303320A (zh) 2011-10-21 2015-01-21 犹他大学研究基金会 均质多带隙装置
US9550678B2 (en) 2011-12-20 2017-01-24 Basf Se Polymeric precursors for producing graphene nanoribbons and methods for preparing them
US9441462B2 (en) 2012-01-11 2016-09-13 Baker Hughes Incorporated Nanocomposites for absorption tunable sandscreens
CN104204131A (zh) * 2012-01-27 2014-12-10 威廉马什莱斯大学 并入了磁性碳纳米带和磁性功能化碳纳米带的井筒流体和其使用方法
CN102616770B (zh) * 2012-03-28 2013-08-07 福州大学 一种水蒸气刻蚀碳纳米管制备石墨烯纳米带的方法
EP2832688A4 (en) * 2012-03-31 2015-11-25 Oceans King Lighting Science PROCESS FOR PREPARING GRAPHENE PAPER
JP6077347B2 (ja) 2012-04-10 2017-02-08 株式会社半導体エネルギー研究所 非水系二次電池用正極の製造方法
US9527043B2 (en) 2012-05-17 2016-12-27 Samsung Electronics Co., Ltd. Gas separation membrane and method of preparing the same
KR101920716B1 (ko) * 2012-05-17 2019-02-13 삼성전자주식회사 기체 분리막 및 그 제조방법
US20140004327A1 (en) * 2012-06-29 2014-01-02 The University Of Kentucky Research Foundation Few-layer graphene nanoribbon and a method of making the same
CN102757043B (zh) * 2012-08-10 2014-07-02 中国科学院苏州纳米技术与纳米仿生研究所 一种制备定向石墨烯纳米带阵列的方法
JP6207923B2 (ja) 2012-08-27 2017-10-04 株式会社半導体エネルギー研究所 二次電池用正極の製造方法
TW201431902A (zh) * 2012-11-16 2014-08-16 巴斯夫歐洲公司 用以生產石墨烯奈米帶之聚合前驅物，以及適用於製備彼等之寡伸苯基單體
CN103833023B (zh) * 2012-11-27 2015-10-28 海洋王照明科技股份有限公司 石墨烯纳米带及其制备方法
US8580658B1 (en) 2012-12-21 2013-11-12 Solan, LLC Methods for fabricating graphene device topography and devices formed therefrom
US10468152B2 (en) * 2013-02-21 2019-11-05 Global Graphene Group, Inc. Highly conducting and transparent film and process for producing same
US20140272308A1 (en) * 2013-03-15 2014-09-18 Solan, LLC Graphite-Based Devices Incorporating A Graphene Layer With A Bending Angle
US9059013B2 (en) 2013-03-21 2015-06-16 International Business Machines Corporation Self-formation of high-density arrays of nanostructures
TWI529128B (zh) * 2013-08-19 2016-04-11 長庚大學 連續微波製作石墨烯奈米帶之系統
JP6825781B2 (ja) * 2014-06-12 2021-02-03 センター ナショナル デ ラ レシェルシェ サイエンティフィック（シーエヌアールエス）Ｃｅｎｔｒｅ Ｎａｔｉｏｎａｌ Ｄｅ Ｌａ Ｒｅｃｈｅｒｃｈｅ Ｓｃｉｅｎｔｉｆｉｑｕｅ（Ｃｎｒｓ） 剥離ナノカーボン材料の水性および有機懸濁液、その作製方法及びその使用
US9840418B2 (en) 2014-06-16 2017-12-12 William Marsh Rice University Production of graphene nanoplatelets by oxidative anhydrous acidic media
CA2968886A1 (en) * 2014-11-26 2016-08-24 William Marsh Rice University Laser induced graphene hybrid materials for electronic devices
US11772975B2 (en) * 2015-12-03 2023-10-03 Global Graphene Group, Inc. Chemical-free production of graphene materials
CN105543991B (zh) * 2016-01-13 2018-06-01 郑州大学 一种螺旋结构石墨烯纤维及其制备方法和应用
CN106115675B (zh) * 2016-06-24 2018-04-17 中国科学院电工研究所 一种制备介孔石墨烯的方法
US11246962B2 (en) 2016-08-22 2022-02-15 William Marsh Rice University Neuronal scaffold-water soluble graphene for treatment of severed spinal cords and neuronal repair
US10707524B2 (en) 2016-10-19 2020-07-07 Semiconductor Energy Laboratory Co., Ltd. Graphene compound and manufacturing method thereof, electrolyte, and power storage device
JP6839355B2 (ja) * 2017-02-08 2021-03-10 富士通株式会社 グラフェンナノリボン、グラフェンナノリボンの製造方法及び半導体装置
CN107200947B (zh) * 2017-05-22 2019-08-20 成都新柯力化工科技有限公司 一种石墨烯微片导电母料及其制备方法
KR102170675B1 (ko) * 2017-06-23 2020-10-27 주식회사 엘지화학 탄소 나노튜브 섬유 집합체의 인장강도 향상 방법
US10465291B2 (en) * 2017-09-26 2019-11-05 California Institute Of Technology Method and system for growth of graphene nanostripes by plasma enhanced chemical vapor deposition
CN108190959B (zh) * 2018-01-23 2020-05-08 福州大学 一种基于熔融碱金属液插入剥离制备单层硫化钼的方法
CN108117064B (zh) * 2018-03-01 2021-07-09 上海理工大学 一种褶皱石墨烯的制备方法
CN108383110B (zh) * 2018-04-18 2020-01-10 天津大学 一种氟化石墨烯纳米带的制备方法
CN109835884B (zh) * 2019-03-27 2022-07-19 王奉瑾 一种利用液态金属碱制备石墨烯的方法
CN111039284A (zh) * 2020-01-17 2020-04-21 中山大学 一种超窄石墨烯纳米带的制备方法
CN115650213A (zh) * 2022-06-28 2023-01-31 重庆大学 一种高单晶纯单层石墨烯纳米带阵列及其制备方法

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CN102666378A (zh) 2012-09-12
EP2443062A4 (en) 2016-04-20
US8992881B2 (en) 2015-03-31
CA2765492A1 (en) 2010-12-23
US20120197051A1 (en) 2012-08-02
WO2010147860A1 (en) 2010-12-23
KR20120039634A (ko) 2012-04-25
SG10201403233XA (en) 2014-10-30
JP2012530044A (ja) 2012-11-29
CA2765492C (en) 2018-01-02
JP5613230B2 (ja) 2014-10-22
SG176826A1 (en) 2012-01-30
EP2443062A1 (en) 2012-04-25
BRPI1016033A2 (pt) 2016-05-10
KR101763224B1 (ko) 2017-07-31
MX2011013545A (es) 2012-05-08

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