KR101575385B1 - 하이브리드 나노 입자 tfc 멤브레인 - Google Patents
하이브리드 나노 입자 tfc 멤브레인 Download PDFInfo
- Publication number
- KR101575385B1 KR101575385B1 KR1020107025647A KR20107025647A KR101575385B1 KR 101575385 B1 KR101575385 B1 KR 101575385B1 KR 1020107025647 A KR1020107025647 A KR 1020107025647A KR 20107025647 A KR20107025647 A KR 20107025647A KR 101575385 B1 KR101575385 B1 KR 101575385B1
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- membrane
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- nanoparticles
- flux
- solution
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
- B01D67/00793—Dispersing a component, e.g. as particles or powder, in another component
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
- B01D69/1251—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction by interfacial polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/0213—Silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/028—Molecular sieves
- B01D71/0281—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/48—Antimicrobial properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/56—Polyamides, e.g. polyester-amides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Dispersion Chemistry (AREA)
- Nanotechnology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (54)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4524708P | 2008-04-15 | 2008-04-15 | |
| US4526208P | 2008-04-15 | 2008-04-15 | |
| US4523408P | 2008-04-15 | 2008-04-15 | |
| US4524908P | 2008-04-15 | 2008-04-15 | |
| US4523708P | 2008-04-15 | 2008-04-15 | |
| US4525208P | 2008-04-15 | 2008-04-15 | |
| US61/045,262 | 2008-04-15 | ||
| US61/045,249 | 2008-04-15 | ||
| US61/045,237 | 2008-04-15 | ||
| US61/045,234 | 2008-04-15 | ||
| US61/045,252 | 2008-04-15 | ||
| US61/045,247 | 2008-04-15 | ||
| US7979408P | 2008-07-10 | 2008-07-10 | |
| US61/079,794 | 2008-07-10 | ||
| US8866608P | 2008-08-13 | 2008-08-13 | |
| US61/088,666 | 2008-08-13 | ||
| US10490508P | 2008-10-13 | 2008-10-13 | |
| US61/104,905 | 2008-10-13 | ||
| US12234808P | 2008-12-12 | 2008-12-12 | |
| US12234408P | 2008-12-12 | 2008-12-12 | |
| US12235208P | 2008-12-12 | 2008-12-12 | |
| US12234208P | 2008-12-12 | 2008-12-12 | |
| US12234608P | 2008-12-12 | 2008-12-12 | |
| US12234308P | 2008-12-12 | 2008-12-12 | |
| US12234108P | 2008-12-12 | 2008-12-12 | |
| US12234708P | 2008-12-12 | 2008-12-12 | |
| US12235508P | 2008-12-12 | 2008-12-12 | |
| US12235008P | 2008-12-12 | 2008-12-12 | |
| US12235408P | 2008-12-12 | 2008-12-12 | |
| US12234508P | 2008-12-12 | 2008-12-12 | |
| US12235108P | 2008-12-12 | 2008-12-12 | |
| US61/122,344 | 2008-12-12 | ||
| US61/122,350 | 2008-12-12 | ||
| US61/122,348 | 2008-12-12 | ||
| US61/122,342 | 2008-12-12 | ||
| US61/122,341 | 2008-12-12 | ||
| US61/122,354 | 2008-12-12 | ||
| US61/122,347 | 2008-12-12 | ||
| US61/122,346 | 2008-12-12 | ||
| US61/122,355 | 2008-12-12 | ||
| US61/122,352 | 2008-12-12 | ||
| US61/122,351 | 2008-12-12 | ||
| US61/122,345 | 2008-12-12 | ||
| US61/122,343 | 2008-12-12 | ||
| US12235808P | 2008-12-13 | 2008-12-13 | |
| US12235708P | 2008-12-13 | 2008-12-13 | |
| US61/122,357 | 2008-12-13 | ||
| US61/122,358 | 2008-12-13 | ||
| US15639409P | 2009-02-27 | 2009-02-27 | |
| US15638809P | 2009-02-27 | 2009-02-27 | |
| US61/156,394 | 2009-02-27 | ||
| US61/156,388 | 2009-02-27 | ||
| US16403109P | 2009-03-27 | 2009-03-27 | |
| US61/164,031 | 2009-03-27 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020157019571A Division KR101570028B1 (ko) | 2008-04-15 | 2009-04-15 | 하이브리드 나노 입자 tfc 멤브레인 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20110011626A KR20110011626A (ko) | 2011-02-08 |
| KR101575385B1 true KR101575385B1 (ko) | 2015-12-08 |
Family
ID=41199721
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020107025647A Active KR101575385B1 (ko) | 2008-04-15 | 2009-04-15 | 하이브리드 나노 입자 tfc 멤브레인 |
| KR1020157019571A Active KR101570028B1 (ko) | 2008-04-15 | 2009-04-15 | 하이브리드 나노 입자 tfc 멤브레인 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020157019571A Active KR101570028B1 (ko) | 2008-04-15 | 2009-04-15 | 하이브리드 나노 입자 tfc 멤브레인 |
Country Status (8)
| Country | Link |
|---|---|
| EP (3) | EP3144054B1 (enExample) |
| JP (2) | JP5856479B2 (enExample) |
| KR (2) | KR101575385B1 (enExample) |
| CN (2) | CN105457508B (enExample) |
| AU (1) | AU2009236162B2 (enExample) |
| CA (1) | CA2720673C (enExample) |
| ES (1) | ES2639212T3 (enExample) |
| WO (1) | WO2009129354A2 (enExample) |
Families Citing this family (85)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US8177978B2 (en) | 2008-04-15 | 2012-05-15 | Nanoh20, Inc. | Reverse osmosis membranes |
| US8286803B2 (en) * | 2009-06-18 | 2012-10-16 | The Boeing Company | Methods and systems for incorporating carbon nanotubes into thin film composite reverse osmosis membranes |
| CA2766352C (en) | 2009-06-29 | 2018-09-18 | NanoH2O Inc. | Improved hybrid tfc ro membranes with nitrogen additives |
| US10350553B2 (en) * | 2010-02-16 | 2019-07-16 | Nitto Denko Corporation | Composite separation membrane and separation membrane element using the same |
| GB2492677B (en) * | 2010-04-30 | 2018-07-25 | Woongjin Chemical Co Ltd | Forward osmosis membrane for seawater desalination, and method for manufacturing same |
| DK2621615T3 (da) * | 2010-09-30 | 2020-09-28 | Porifera Inc | Sammensatte tyndfilmmembraner til fremadrettet osmose og fremgangsmåder til fremstilling heraf |
| CA2817570C (en) * | 2010-11-10 | 2018-03-06 | Nanoh2O, Inc. | Improved hybrid tfc ro membranes with additives |
| JP5934253B2 (ja) | 2011-01-24 | 2016-06-15 | ダウ グローバル テクノロジーズ エルエルシー | 複合ポリアミド膜 |
| EP2632575B1 (en) | 2011-01-24 | 2016-04-27 | Dow Global Technologies LLC | Method for making a composite polyamide membrane |
| KR101920194B1 (ko) | 2011-01-24 | 2019-02-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 복합 폴리아미드 막 |
| US9216391B2 (en) | 2011-03-25 | 2015-12-22 | Porifera, Inc. | Membranes having aligned 1-D nanoparticles in a matrix layer for improved fluid separation |
| KR101440968B1 (ko) * | 2011-06-17 | 2014-09-17 | 주식회사 엘지화학 | 초친수성 보호층을 포함하는 역삼투막 및 이의 제조방법 |
| EP2722100A4 (en) * | 2011-06-20 | 2014-12-10 | Lg Chemical Ltd | REVERSE OSMOSEMEMBRANE WITH EXCELLENT SALT SUPPRESSION AND PERMEATE FLUID CHARACTERISTICS AND METHOD OF MANUFACTURING THEREOF |
| KR101401922B1 (ko) * | 2011-08-08 | 2014-06-02 | 고려대학교 산학협력단 | 해수담수화용 폴리에테르술폰계 역삼투막 제조용 코팅액 조성물 및 이를 이용한 폴리에테르술폰계 역삼투막의 제조방법 |
| CN103764264B (zh) | 2011-08-31 | 2016-11-16 | 陶氏环球技术有限责任公司 | 源自包含胺反应性官能团和含磷官能团的单体的复合聚酰胺膜 |
| WO2013048763A1 (en) * | 2011-09-29 | 2013-04-04 | Dow Global Technologies Llc | Method for solubilizing carboxylic acid-containing compound in hydrocarbon solvent |
| IN2014CN02212A (enExample) * | 2011-09-29 | 2015-06-12 | Dow Global Technologies Llc | |
| US9227360B2 (en) | 2011-10-17 | 2016-01-05 | Porifera, Inc. | Preparation of aligned nanotube membranes for water and gas separation applications |
| KR101407445B1 (ko) * | 2011-12-08 | 2014-06-17 | 주식회사 엘지화학 | 은 나노 와이어층을 포함하는 역삼투막 및 그 제조 방법 |
| US20130146530A1 (en) * | 2011-12-08 | 2013-06-13 | General Electric Company | Membrane, water treatment system, and method of making |
| KR101907106B1 (ko) | 2011-12-16 | 2018-12-05 | 삼성전자주식회사 | 나노다공체를 포함하는 반투성 필름과 분리막 및 이들의 제조방법 |
| EP2776146B1 (en) | 2012-01-06 | 2020-05-13 | DDP Specialty Electronic Materials US, Inc. | Method of preparation of a composite polyamide membrane |
| JP5879161B2 (ja) * | 2012-03-09 | 2016-03-08 | 旭化成ケミカルズ株式会社 | 水蒸気分離膜及びその製造方法 |
| CN103906561A (zh) * | 2012-06-08 | 2014-07-02 | Lg化学株式会社 | 包含经表面处理过的沸石的高渗透通量反渗透膜及其制备方法 |
| US9610542B2 (en) * | 2012-07-19 | 2017-04-04 | Dow Global Technologies Llc | Composite polyamide membrane with increased carboxylic acid functionality |
| US20150217238A1 (en) * | 2012-08-15 | 2015-08-06 | Nanyang Technological University | Reinforced membranes for producing osmotic power in pressure retarded osmosis |
| JP6191102B2 (ja) * | 2012-08-23 | 2017-09-06 | 三菱ケミカル株式会社 | 正浸透膜複合体 |
| FR2996780B1 (fr) * | 2012-10-16 | 2014-12-19 | Univ Claude Bernard Lyon | Procede et dispositif de production d'energie |
| CN104955552B (zh) | 2012-12-21 | 2017-03-08 | 波里费拉公司 | 用于利用堆叠隔膜及间隔件进行分离的分离系统、元件及方法 |
| CN105188889B (zh) | 2013-03-15 | 2018-01-19 | 波里费拉公司 | 包含低压控制的渗透驱动隔膜系统的发展 |
| PE20151711A1 (es) * | 2013-03-15 | 2015-11-18 | Oasys Water Inc | Modulos de membrana |
| US9051417B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | Method for solubilizing carboxylic acid-containing compound in hydrocarbon solvent |
| US9051227B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | In-situ method for preparing hydrolyzed acyl halide compound |
| US9289729B2 (en) | 2013-03-16 | 2016-03-22 | Dow Global Technologies Llc | Composite polyamide membrane derived from carboxylic acid containing acyl halide monomer |
| WO2015079442A1 (en) * | 2013-11-28 | 2015-06-04 | B. G. Negev Technologies And Applications Ltd | Fabrication and modification of polymer membranes using ink-jet printing |
| KR102213238B1 (ko) * | 2013-12-06 | 2021-02-05 | 동의대학교 산학협력단 | 반투막 및 그 제조 방법 |
| CN105899284A (zh) * | 2014-01-13 | 2016-08-24 | 陶氏环球技术有限责任公司 | 高溶胀性复合聚酰胺膜 |
| JP6614138B2 (ja) * | 2014-04-18 | 2019-12-04 | 三菱ケミカル株式会社 | 多孔質支持体−ゼオライト膜複合体の製造方法 |
| ES2704238T3 (es) * | 2014-05-14 | 2019-03-15 | Dow Global Technologies Llc | Membrana de poliamida de material compuesto sometida a tratamiento posterior con ácido nitroso |
| JP2016068019A (ja) * | 2014-09-30 | 2016-05-09 | 日東電工株式会社 | 複合半透膜及びその製造方法、スパイラル型分離膜エレメント |
| US10384169B2 (en) | 2014-10-31 | 2019-08-20 | Porifera, Inc. | Supported carbon nanotube membranes and their preparation methods |
| US9695065B2 (en) * | 2015-06-03 | 2017-07-04 | Lg Nanoh2O, Inc. | Combination of chemical additives for enhancement of water flux of a membrane |
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| ES2796605T5 (en) | 2015-06-24 | 2025-04-11 | Porifera Inc | Methods of dewatering of alcoholic solutions via forward osmosis |
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| CN105797595A (zh) * | 2016-05-13 | 2016-07-27 | 高学理 | 一种高水稳定性金属有机框架化合物材料的制备方法及其应用 |
| WO2018044298A1 (en) | 2016-08-31 | 2018-03-08 | South Dakota Board Of Regents | Multilayer thin film nanocomposite membranes prepared by molecular layer-by-layer assembly |
| CN106474944B (zh) * | 2016-11-08 | 2019-04-23 | 福建农林大学 | 一种抗菌纤维素平板纳滤膜的制备方法 |
| CN110290854A (zh) | 2016-12-23 | 2019-09-27 | 波里费拉公司 | 通过正向渗透除去醇溶液的组分和相关系统 |
| CN107349807B (zh) * | 2017-07-20 | 2020-05-22 | 浙江工业大学 | 一种Fe(BTC)镶嵌的大通量聚酰胺纳米复合膜及其制备方法和用途 |
| JP2018008270A (ja) * | 2017-08-08 | 2018-01-18 | 三菱ケミカル株式会社 | 正浸透膜 |
| CN107486028B (zh) * | 2017-09-21 | 2020-01-03 | 成都新柯力化工科技有限公司 | 一种用于废润滑油处理的高滤通膜及其制备方法 |
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| CN108837712A (zh) * | 2018-07-11 | 2018-11-20 | 佛山市高明区爪和新材料科技有限公司 | 一种反渗透膜的制备方法 |
| CN108911250A (zh) * | 2018-08-01 | 2018-11-30 | 苏州艾吉克膜科技有限公司 | 含氨废水的回用装置和含氨废水的回用装置工艺 |
| CN109433029A (zh) * | 2018-11-15 | 2019-03-08 | 山东大学 | 一种抗污型掺杂氧化铈与银纳米颗粒的反渗透膜的制备方法 |
| US12097471B2 (en) | 2018-11-21 | 2024-09-24 | Evoqua Water Technologies Llc | Nanoparticles for use in membranes |
| CN109925895A (zh) * | 2019-04-08 | 2019-06-25 | 河北工业大学 | 一种抗污染聚酰胺薄膜复合膜的制备方法 |
| CN111408286A (zh) * | 2019-06-24 | 2020-07-14 | 江苏久吾高科技股份有限公司 | 一种纳米二氧化钛聚哌嗪酰胺纳滤膜的制备方法 |
| CN110180402B (zh) * | 2019-07-08 | 2020-08-04 | 清华大学 | 一种基于界面聚合制备松散纳滤膜的方法 |
| CN110960987B (zh) * | 2019-12-11 | 2022-05-03 | 恩泰环保科技(常州)有限公司 | 一种高性能纳米杂化反渗透膜及其制备方法 |
| WO2022030572A1 (ja) * | 2020-08-07 | 2022-02-10 | 東レ株式会社 | ガス分離用複合分離膜、ガス分離用複合分離膜エレメント及びガス製造方法 |
| CN114471183B (zh) * | 2020-11-11 | 2023-03-14 | 沃顿科技股份有限公司 | 分离膜的制备方法和由此制备的分离膜 |
| CN112717720B (zh) * | 2020-12-25 | 2022-05-20 | 湖南澳维科技股份有限公司 | 一种耐污染聚酰胺复合膜及其制备方法 |
| WO2022152799A1 (en) * | 2021-01-13 | 2022-07-21 | Institut National De Recherche Pour L'agriculture, L'alimentation Et L'environnement | Detection of viral particles by an immuno-specific-mediated co-precipitation |
| CN112827369B (zh) * | 2021-01-18 | 2021-11-09 | 蓝星(杭州)膜工业有限公司 | 一种纳米杂化复合膜的制备方法 |
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| WO2006098872A2 (en) | 2005-03-09 | 2006-09-21 | The Regents Of The University Of California | Nanocomposite membranes and methods of making and using same |
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| US5371166A (en) * | 1993-12-22 | 1994-12-06 | The B. F. Goodrich Company | Polyurethane composition for use as a dispersing binder |
| JPH08182921A (ja) * | 1994-12-28 | 1996-07-16 | Mitsubishi Rayon Co Ltd | ポリオレフィン複合微多孔質膜 |
| US5919522A (en) * | 1995-03-31 | 1999-07-06 | Advanced Technology Materials, Inc. | Growth of BaSrTiO3 using polyamine-based precursors |
| US6337018B1 (en) * | 2000-04-17 | 2002-01-08 | The Dow Chemical Company | Composite membrane and method for making the same |
| KR100527898B1 (ko) * | 2004-01-27 | 2005-11-15 | 한국해양연구원 | 나노 입자 토르마린을 포함한 역삼투 복합막 및 이의제조방법 |
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| JP5050335B2 (ja) * | 2005-10-21 | 2012-10-17 | 東レ株式会社 | 複合半透膜の製造方法 |
| WO2008057842A2 (en) * | 2006-10-27 | 2008-05-15 | The Regents Of The University Of California | Micro-and nanocomposite support structures for reverse osmosis thin film membranes |
| US8231013B2 (en) * | 2006-12-05 | 2012-07-31 | The Research Foundation Of State University Of New York | Articles comprising a fibrous support |
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|---|---|
| CN105457508A (zh) | 2016-04-06 |
| JP2011516264A (ja) | 2011-05-26 |
| EP2276558A2 (en) | 2011-01-26 |
| EP2276558A4 (en) | 2012-12-12 |
| CN104906957A (zh) | 2015-09-16 |
| KR20110011626A (ko) | 2011-02-08 |
| CA2720673A1 (en) | 2009-10-22 |
| KR20150099806A (ko) | 2015-09-01 |
| ES2639212T8 (es) | 2021-02-11 |
| EP2276558B1 (en) | 2017-07-12 |
| EP3144052B1 (en) | 2022-08-31 |
| JP2015037788A (ja) | 2015-02-26 |
| CN105457508B (zh) | 2018-10-26 |
| WO2009129354A2 (en) | 2009-10-22 |
| AU2009236162B2 (en) | 2013-10-31 |
| EP3144054A1 (en) | 2017-03-22 |
| JP5974060B2 (ja) | 2016-08-23 |
| EP3144054B1 (en) | 2022-11-02 |
| JP5856479B2 (ja) | 2016-02-09 |
| WO2009129354A3 (en) | 2010-01-28 |
| CA2720673C (en) | 2017-08-08 |
| WO2009129354A4 (en) | 2010-04-01 |
| AU2009236162A1 (en) | 2009-10-22 |
| EP3144052A1 (en) | 2017-03-22 |
| KR101570028B1 (ko) | 2015-11-17 |
| ES2639212T3 (es) | 2017-10-25 |
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