KR101415822B1 - 유기 태양 전지 및 이의 제조 방법 - Google Patents
유기 태양 전지 및 이의 제조 방법 Download PDFInfo
- Publication number
- KR101415822B1 KR101415822B1 KR1020100061620A KR20100061620A KR101415822B1 KR 101415822 B1 KR101415822 B1 KR 101415822B1 KR 1020100061620 A KR1020100061620 A KR 1020100061620A KR 20100061620 A KR20100061620 A KR 20100061620A KR 101415822 B1 KR101415822 B1 KR 101415822B1
- Authority
- KR
- South Korea
- Prior art keywords
- metal oxide
- metal
- anode
- organic solar
- solar cell
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 23
- 238000004519 manufacturing process Methods 0.000 title abstract description 16
- 229920000642 polymer Polymers 0.000 title abstract description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 105
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 105
- 239000002245 particle Substances 0.000 claims abstract description 71
- 239000010409 thin film Substances 0.000 claims abstract description 28
- 238000009826 distribution Methods 0.000 claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims description 38
- 239000002184 metal Substances 0.000 claims description 38
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 24
- 239000011259 mixed solution Substances 0.000 claims description 22
- 239000000654 additive Substances 0.000 claims description 19
- 230000000996 additive effect Effects 0.000 claims description 19
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- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 15
- 239000002244 precipitate Substances 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 12
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- -1 alcohol amines Chemical class 0.000 claims description 12
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- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 6
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- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 4
- 239000000908 ammonium hydroxide Substances 0.000 claims description 4
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 claims description 3
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims description 3
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Images
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/30—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains
- H10K30/353—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising bulk heterojunctions, e.g. interpenetrating networks of donor and acceptor material domains comprising blocking layers, e.g. exciton blocking layers
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/12—Deposition of organic active material using liquid deposition, e.g. spin coating
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/10—Transparent electrodes, e.g. using graphene
- H10K2102/101—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO]
- H10K2102/103—Transparent electrodes, e.g. using graphene comprising transparent conductive oxides [TCO] comprising indium oxides, e.g. ITO
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/10—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising heterojunctions between organic semiconductors and inorganic semiconductors
- H10K30/15—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2
- H10K30/152—Sensitised wide-bandgap semiconductor devices, e.g. dye-sensitised TiO2 the wide bandgap semiconductor comprising zinc oxide, e.g. ZnO
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/50—Photovoltaic [PV] devices
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
- H10K85/1135—Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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|---|---|---|---|
| KR1020100061620A KR101415822B1 (ko) | 2010-06-29 | 2010-06-29 | 유기 태양 전지 및 이의 제조 방법 |
| CN2011800329511A CN102971864A (zh) | 2010-06-29 | 2011-06-28 | 有机太阳能电池及其制备方法 |
| PCT/KR2011/004689 WO2012002694A2 (ko) | 2010-06-29 | 2011-06-28 | 유기 태양 전지 및 이의 제조 방법 |
| EP11801100.6A EP2590229A4 (en) | 2010-06-29 | 2011-06-28 | Organic solar cell and manufacturing method thereof |
| JP2013516510A JP5466790B2 (ja) | 2010-06-29 | 2011-06-28 | 有機太陽電池及びその製造方法 |
| US13/319,669 US9166183B2 (en) | 2010-06-29 | 2011-06-28 | Organic solar cell and method for producing the same |
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| KR1020100061620A KR101415822B1 (ko) | 2010-06-29 | 2010-06-29 | 유기 태양 전지 및 이의 제조 방법 |
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| KR20120001046A KR20120001046A (ko) | 2012-01-04 |
| KR101415822B1 true KR101415822B1 (ko) | 2014-07-09 |
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| EP (1) | EP2590229A4 (ja) |
| JP (1) | JP5466790B2 (ja) |
| KR (1) | KR101415822B1 (ja) |
| CN (1) | CN102971864A (ja) |
| WO (1) | WO2012002694A2 (ja) |
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| KR101371609B1 (ko) * | 2012-05-24 | 2014-03-07 | 서울대학교산학협력단 | 이중 계면층을 포함한 저분자 유기태양전지 |
| KR101445024B1 (ko) * | 2013-02-01 | 2014-09-26 | 경북대학교 산학협력단 | 수분제거막이 형성된 광활성층을 가지는 유기태양전지 및 이의 제조방법 |
| WO2015002285A1 (ja) * | 2013-07-05 | 2015-01-08 | 積水化学工業株式会社 | 半導体膜の製造方法、半導体膜製造用原料粒子、半導体膜、光電極および色素増感太陽電池 |
| JP6585595B2 (ja) * | 2013-12-12 | 2019-10-02 | アファンタマ アクチェンゲゼルシャフト | 溶液で処理できる金属酸化物バッファー層を含む電子機器 |
| KR101583055B1 (ko) * | 2014-05-08 | 2016-01-06 | 한국세라믹기술원 | 볼로미터용 저항 박막 제조방법 및 볼로미터 |
| WO2016081789A1 (en) * | 2014-11-20 | 2016-05-26 | Brown University | Methods of making coated substrates |
| KR101721565B1 (ko) * | 2015-06-25 | 2017-04-18 | 한국기계연구원 | 이중 주파수 전력 구동 유도결합 플라즈마 토치 및 이를 이용한 나노 입자 생성 장치 |
| CN105762283B (zh) * | 2016-05-05 | 2018-01-19 | 天津市职业大学 | 一种钙钛矿太阳电池光吸收层纳米溶胶镀膜液及制备方法 |
| WO2017217727A1 (ko) * | 2016-06-15 | 2017-12-21 | 코오롱인더스트리 주식회사 | 유기 태양전지 및 이의 제조 방법 |
| EP3602645B1 (en) * | 2017-03-31 | 2023-06-07 | Peafowl Plasmonics AB | Ultra-thin plasmonic solar cells, methods for their manufacture and use |
| CN109378386B (zh) * | 2018-10-16 | 2022-06-07 | 南京邮电大学 | 调控无铅钙钛矿太阳能电池形貌的方法及制备的电池器件 |
| CN110459681A (zh) * | 2019-07-31 | 2019-11-15 | 青岛大学 | 基于聚乙烯亚胺修饰的氧化锌电子传输层构建柔性结构的聚合物太阳能电池及其制备方法 |
| CN117809985B (zh) * | 2024-02-29 | 2024-05-10 | 山东恒嘉高纯铝业科技股份有限公司 | 一种含有六铝酸钙的薄膜电极及其制备方法和应用 |
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| KR20090123739A (ko) * | 2008-05-28 | 2009-12-02 | 광주과학기술원 | 유무기 태양전지 및 이의 제조 방법 |
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| JP4934770B2 (ja) * | 2003-04-15 | 2012-05-16 | 国立大学法人金沢大学 | 有機太陽電池 |
| US8158881B2 (en) * | 2005-07-14 | 2012-04-17 | Konarka Technologies, Inc. | Tandem photovoltaic cells |
| US20080006324A1 (en) * | 2005-07-14 | 2008-01-10 | Konarka Technologies, Inc. | Tandem Photovoltaic Cells |
| JP2007027625A (ja) * | 2005-07-21 | 2007-02-01 | Matsushita Electric Works Ltd | 有機太陽電池及びその製造方法 |
| US20070028961A1 (en) * | 2005-08-04 | 2007-02-08 | General Electric Company | Organic dye compositions and use thereof in photovoltaic cells |
| JP5298308B2 (ja) * | 2005-09-06 | 2013-09-25 | 国立大学法人京都大学 | 有機薄膜光電変換素子及びその製造方法 |
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| US7799990B2 (en) * | 2007-03-12 | 2010-09-21 | Northwestern University | Electron-blocking layer / hole-transport layer for organic photovoltaics and applications of same |
| WO2008134492A1 (en) * | 2007-04-27 | 2008-11-06 | Konarka Technologies, Inc. | Organic photovoltaic cells |
| US20100193034A1 (en) * | 2007-09-18 | 2010-08-05 | Gwangju Institute Of Science And Technology | Organic-inorganic hybrid junction device using redox reaction and organic photovoltaic cell of using the same |
| US20090188558A1 (en) * | 2008-01-25 | 2009-07-30 | University Of Washington | Photovoltaic devices having metal oxide electron-transport layers |
| GB0802934D0 (en) * | 2008-02-18 | 2008-03-26 | Univ Denmark Tech Dtu | Air stable photovoltaic device |
| US20110049504A1 (en) * | 2008-05-13 | 2011-03-03 | Sumitomo Chemical Company, Limited | Photoelectric conversion element |
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| KR20080097462A (ko) * | 2006-02-16 | 2008-11-05 | 솔렉슨트 코포레이션 | 나노입자 감응형 나노구조형 태양 전지 |
| KR20090123739A (ko) * | 2008-05-28 | 2009-12-02 | 광주과학기술원 | 유무기 태양전지 및 이의 제조 방법 |
| KR20090131461A (ko) * | 2008-06-18 | 2009-12-29 | 한국과학기술원 | 유기기반 태양전지 및 그의 제조방법 |
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| WO2012002694A3 (ko) | 2012-05-03 |
| WO2012002694A4 (ko) | 2012-06-21 |
| JP2013529847A (ja) | 2013-07-22 |
| JP5466790B2 (ja) | 2014-04-09 |
| EP2590229A4 (en) | 2017-04-05 |
| CN102971864A (zh) | 2013-03-13 |
| WO2012002694A2 (ko) | 2012-01-05 |
| KR20120001046A (ko) | 2012-01-04 |
| EP2590229A2 (en) | 2013-05-08 |
| US20120111403A1 (en) | 2012-05-10 |
| US9166183B2 (en) | 2015-10-20 |
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