KR101351103B1 - 신규한 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 중합체의 제조방법, 및 올레핀 호모중합체 및 공중합체 - Google Patents
신규한 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 중합체의 제조방법, 및 올레핀 호모중합체 및 공중합체 Download PDFInfo
- Publication number
- KR101351103B1 KR101351103B1 KR1020117016447A KR20117016447A KR101351103B1 KR 101351103 B1 KR101351103 B1 KR 101351103B1 KR 1020117016447 A KR1020117016447 A KR 1020117016447A KR 20117016447 A KR20117016447 A KR 20117016447A KR 101351103 B1 KR101351103 B1 KR 101351103B1
- Authority
- KR
- South Korea
- Prior art keywords
- group
- carbon atoms
- methyl
- indenyl
- zirconium dichloride
- Prior art date
Links
- 0 C*OB(c(c(F)c(c(F)c1F)F)c1F)C(C(F)=C(C(C)(C1F)F)F)=C1F Chemical compound C*OB(c(c(F)c(c(F)c1F)F)c1F)C(C(F)=C(C(C)(C1F)F)F)=C1F 0.000 description 1
- FVZBVPIYUKXGQI-UHFFFAOYSA-N CC(C(BOC)C(F)=C1F)(C(F)=C1F)F Chemical compound CC(C(BOC)C(F)=C1F)(C(F)=C1F)F FVZBVPIYUKXGQI-UHFFFAOYSA-N 0.000 description 1
- UMSNYJLPJZWHGV-UHFFFAOYSA-N CC(C(C(F)=C1B(c(c(F)c(c(F)c2F)F)c2F)O)F)(C(F)=C1F)F Chemical compound CC(C(C(F)=C1B(c(c(F)c(c(F)c2F)F)c2F)O)F)(C(F)=C1F)F UMSNYJLPJZWHGV-UHFFFAOYSA-N 0.000 description 1
- LETYIFNDQBJGPJ-UHFFFAOYSA-N CCC1(C)CCCC1 Chemical compound CCC1(C)CCCC1 LETYIFNDQBJGPJ-UHFFFAOYSA-N 0.000 description 1
- IWKPBYPUIPVYNZ-UHFFFAOYSA-N Cc(c(F)c(c(C)c1F)F)c1F Chemical compound Cc(c(F)c(c(C)c1F)F)c1F IWKPBYPUIPVYNZ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2008/014144 WO2010077230A1 (fr) | 2008-12-31 | 2008-12-31 | Nouveaux composés de métallocène, catalyseurs comprenant ceux-ci, procédé pour produire un polymère d'oléfine par utilisation des catalyseurs, et homo- et copolymères d'oléfine |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20110094349A KR20110094349A (ko) | 2011-08-23 |
KR101351103B1 true KR101351103B1 (ko) | 2014-01-14 |
Family
ID=40936621
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020117016447A KR101351103B1 (ko) | 2008-12-31 | 2008-12-31 | 신규한 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 중합체의 제조방법, 및 올레핀 호모중합체 및 공중합체 |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2384343A1 (fr) |
JP (1) | JP2012513463A (fr) |
KR (1) | KR101351103B1 (fr) |
CN (1) | CN102257020B (fr) |
BR (1) | BRPI0823407A2 (fr) |
EA (1) | EA201170909A1 (fr) |
MX (1) | MX2011006667A (fr) |
SG (1) | SG172454A1 (fr) |
WO (1) | WO2010077230A1 (fr) |
ZA (1) | ZA201105497B (fr) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2402353B1 (fr) | 2010-07-01 | 2018-04-25 | Borealis AG | Métallocènes des métaux de groupe 4 comme catalyseurs pour la polymérisation d'oléfines |
ES2565438T3 (es) | 2010-07-01 | 2016-04-04 | Borealis Ag | Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores |
EP2573091A1 (fr) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Procédé de recyclage de ligand libre provenant de leurs complexes de métallocènes correspondants |
EP2722345B1 (fr) | 2012-10-18 | 2018-12-05 | Borealis AG | Catalyseur pour la polymérisation d'oléfines |
ES2622627T3 (es) | 2012-10-18 | 2017-07-06 | Borealis Ag | Procedimiento de polimerización |
EP2722346A1 (fr) | 2012-10-18 | 2014-04-23 | Borealis AG | Procédé de polymérisation et catalyseur |
JP6176015B2 (ja) | 2012-11-01 | 2017-08-09 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
JP5710035B2 (ja) | 2013-02-27 | 2015-04-30 | 日本ポリエチレン株式会社 | メタロセン化合物およびオレフィン重合体の製造方法 |
JP5695687B2 (ja) | 2013-03-05 | 2015-04-08 | 日本ポリエチレン株式会社 | エチレン/α−オレフィン共重合体の製造方法 |
US9458260B2 (en) | 2013-07-17 | 2016-10-04 | Exxonmobil Chemical Patents Inc. | Process using substituted metallocene catalysts and products therefrom |
CN105358589B (zh) | 2013-07-17 | 2018-07-03 | 埃克森美孚化学专利公司 | 金属茂和由其衍生的催化剂组合物 |
US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
US9464145B2 (en) | 2013-07-17 | 2016-10-11 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
CN105358586A (zh) | 2013-07-17 | 2016-02-24 | 埃克森美孚化学专利公司 | 环丙基取代的茂金属催化剂 |
ES2612627T3 (es) | 2013-07-24 | 2017-05-17 | Borealis Ag | Proceso |
KR102405286B1 (ko) * | 2017-12-06 | 2022-06-02 | 주식회사 엘지화학 | 메탈로센 담지 촉매의 제조방법, 상기 제조방법으로 제조된 메탈로센 담지 촉매, 및 이를 제조하여 제조한 폴리프로필렌 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20080033906A (ko) * | 2005-05-17 | 2008-04-17 | 노볼렌 테크놀로지 홀딩스 씨.브이. | 올레핀 중합을 위한 촉매 조성물 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69941894D1 (de) * | 1998-02-10 | 2010-02-25 | Artemis Medical Inc | Okklusions-, verankerungs-, span- oder stromsteuergerät |
KR100789201B1 (ko) * | 1999-12-23 | 2007-12-31 | 바젤 폴리올레핀 게엠베하 | 전이 금속 화합물, 리간드계, 촉매계와 올레핀의 중합 및공중합에 사용되는 이의 용도 |
JP2004502699A (ja) * | 2000-06-30 | 2004-01-29 | エクソンモービル・ケミカル・パテンツ・インク | 架橋ビス(インデニル)メタロセン化合物 |
CN101910216A (zh) * | 2007-10-25 | 2010-12-08 | 鲁姆斯诺沃伦技术公司 | 柄型金属茂化合物的外消旋选择性合成、柄型金属茂化合物、含有该化合物的催化剂、通过使用该催化剂制备烯烃聚合物的方法和烯烃均聚物及共聚物 |
CN101889030B (zh) * | 2007-10-25 | 2013-07-17 | 鲁姆斯诺沃伦技术公司 | 金属茂化合物,含有金属茂化合物的催化剂,使用该催化剂制备烯烃聚合物的方法 |
-
2008
- 2008-12-31 SG SG2011048345A patent/SG172454A1/en unknown
- 2008-12-31 EA EA201170909A patent/EA201170909A1/ru unknown
- 2008-12-31 BR BRPI0823407-8A patent/BRPI0823407A2/pt not_active IP Right Cessation
- 2008-12-31 MX MX2011006667A patent/MX2011006667A/es not_active Application Discontinuation
- 2008-12-31 CN CN200880132439.2A patent/CN102257020B/zh not_active Expired - Fee Related
- 2008-12-31 EP EP08876396A patent/EP2384343A1/fr not_active Withdrawn
- 2008-12-31 JP JP2011543489A patent/JP2012513463A/ja not_active Ceased
- 2008-12-31 KR KR1020117016447A patent/KR101351103B1/ko not_active IP Right Cessation
- 2008-12-31 WO PCT/US2008/014144 patent/WO2010077230A1/fr active Application Filing
-
2011
- 2011-07-26 ZA ZA2011/05497A patent/ZA201105497B/en unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20080033906A (ko) * | 2005-05-17 | 2008-04-17 | 노볼렌 테크놀로지 홀딩스 씨.브이. | 올레핀 중합을 위한 촉매 조성물 |
Also Published As
Publication number | Publication date |
---|---|
CN102257020A (zh) | 2011-11-23 |
WO2010077230A1 (fr) | 2010-07-08 |
KR20110094349A (ko) | 2011-08-23 |
CN102257020B (zh) | 2014-04-02 |
MX2011006667A (es) | 2011-07-20 |
JP2012513463A (ja) | 2012-06-14 |
SG172454A1 (en) | 2011-08-29 |
EA201170909A1 (ru) | 2012-01-30 |
ZA201105497B (en) | 2012-04-25 |
EP2384343A1 (fr) | 2011-11-09 |
BRPI0823407A2 (pt) | 2015-06-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101351103B1 (ko) | 신규한 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 중합체의 제조방법, 및 올레핀 호모중합체 및 공중합체 | |
US8415492B2 (en) | Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers | |
JP5763727B2 (ja) | メタロセンリガンド、メタロセン化合物およびメタロセン触媒、その合成、およびオレフィン重合のためのその使用 | |
JP5578473B2 (ja) | アンサ−メタロセン化合物のラセモ選択的合成、アンサ−メタロセン化合物、それを含む触媒、触媒の使用によってオレフィンポリマーを製造するプロセス、ならびにホモポリマーおよびコポリマー | |
CZ434598A3 (cs) | Metalocenové sloučeniny | |
EP2235071A2 (fr) | Composés métallocènes, catalyseurs les comportant, procédé de fabrication d'un polymère d'oléfine à l'aide des catalyseurs et homopolymères et copolymères d'oléfines | |
JP2014196319A (ja) | 新たなメタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー | |
US6365763B1 (en) | Method for producing metallocenes | |
JP6196581B2 (ja) | メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー | |
JP2014196496A (ja) | アンサ−メタロセン化合物のラセモ選択的合成、アンサ−メタロセン化合物、それを含む触媒、触媒の使用によってオレフィンポリマーを製造するプロセス、ならびにホモポリマーおよびコポリマー |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
LAPS | Lapse due to unpaid annual fee |